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Synthesis, structural, magnetic, and electronic properties of cubic CsMnMoO3F3 oxyfluoride / V. V. Atuchin [et al.]> // J. Phys. Chem. C. - 2012. - Vol. 116, Is. 18. - P. 10162-10170, DOI 10.1021/jp302020f. - Cited References: 64. - We thank Dr. A.M. Ziatdinov for the electron paramagnetic resonance measurements. This study was partly supported by SB RAS (Grant 28).
. - ISSN 1932-7447РУБ Chemistry, Physical + Nanoscience & Nanotechnology + Materials Science, Multidisciplinary Рубрики: RAY PHOTOELECTRON-SPECTROSCOPY PHASE-TRANSITIONS CORE LEVELS SURFACE CHARACTERIZATION CRYSTAL-STRUCTURE CLEAVED SURFACE MIXED-VALENCE OXIDES MN MOLYBDENUM Chemical bondings Cubic phase Energy differences Heat capacity measurements Oxyfluorides Powder samples Solid-state synthesis Space Groups Temperature range Valence electron Binding energy Chemical bonds Electronic structure Fluorine compounds Magnetic properties Metal ions Photoelectrons Rietveld method X ray photoelectron spectroscopy Electronic properties Аннотация: A powder sample of CsMnMoO3F3 oxyfluoride has been prepared by solid state synthesis. The pyrochlore-related crystal structure of CsMnMoO3F3 has been refined by the Rietveld method at T = 298 K (space group Fd-3m, a = 10.59141(4) angstrom, V = 1188.123(8) angstrom(3); R-B = 3.44%). The stability of the cubic phase has been obtained over the temperature range T = 110-293 K by heat capacity measurements. Magnetic properties have been measured over the range of T = 2-300 K. The electronic structure of CsMnMoO3F3 has been evaluated by X-ray photoelectron spectroscopy. Chemical bonding effects have been discussed for all metal ions using binding energy difference parameters and wide comparison with related oxides and fluorides. The competition between O-2(-) and F- ions for metal valence electrons has been found.
Смотреть статью, Scopus, WoS, Читать в сети ИФ Держатели документа: Atuchin, Victor V. Gavrilova, Tatyana A. Kesler, Valery G.] SB RAS, Inst Semicond Phys, Novosibirsk 630090, Russia Molokeev, Maxim S. Yurkin, Gleb Yu. Flerov, Igor N. Patrin, Gennadii S.] SB RAS, Inst Phys, Krasnoyarsk 660036, Russia Laptash, Natalia M.] FEB RAS, Inst Chem, Vladivostok 690022, Russia Flerov, Igor N. Patrin, Gennadii S.] Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660074, Russia Доп.точки доступа: Atuchin, V. V.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Yurkin, G. Yu.; Юркин, Глеб Юрьевич; Gavrilova, T. A.; Kesler, V. G.; Laptash, N. M.; Flerov, I. N.; Флёров, Игорь Николаевич; Patrin, G. S.; Патрин, Геннадий Семёнович } Найти похожие
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