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полный	информационный	краткий

Поисковый запрос: (<.>S=RAY-EMISSION-SPECTROSCOPY<.>)

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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Atuchin V. V., Khyzhun O. Y., Chimitova O. D., Molokeev M. S., Gavrilova T. A., Bazarov B. G., Bazarova J. G.
Заглавие : Electronic structure of β-RbNd(MoO4)2 by XPS and XES
Коллективы : Ministry of Education and Science of the Russian Federation; RFBR [12-02-90806-mol_rf_nr]
Место публикации : J. Phys. Chem. Solids. - 2015. - Vol. 77. - P.101-108. - ISSN 0022-3697, DOI 10.1016/j.jpcs.2014.09.012
Примечания : Cited References: 52. - This study was partially supported by the Ministry of Education and Science of the Russian Federation and RFBR Grant 12-02-90806-mol_rf_nr.
Предметные рубрики: RAY-EMISSION-SPECTROSCOPY
CRYSTAL-STRUCTURE
PHOTOELECTRON-SPECTROSCOPY
LUMINESCENCE PROPERTIES
VIBRATIONAL PROPERTIES
PHOTOEMISSION SPECTRA
OPTICAL-PROPERTIES
TERNARY MOLYBDATE
AB-INITIO
SYSTEM
Ключевые слова (''Своб.индексиров.''): inorganic compounds--chemical synthesis--photoelectron spectroscopy--x-ray diffraction--electronic structure
Аннотация: β-RbNd(MoO4)2 microplates have been prepared by the multistage solid state synthesis method. The phase composition and micromorphology of the final product have been evaluated by XRD and SEM methods. The electronic structure of β-RbNd(MoO4)2 molybdate has been studied employing the X-ray photoelectron spectroscopy (XPS) and X-ray emission spectroscopy (XES). For the molybdate, the XPS core-level and valence-band spectra, as well as XES bands representing energy distribution of the Mo 4d- and O 2p-like states, have been measured. It has been established that the O 2p-like states contribute mainly to the upper portion of the valence band with also significant contributions throughout the whole valence-band region. The Mo 4d-like states contribute mainly to a lower valence band portion
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