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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mikhlin Y., Vorobyev S., Romanchenko A., Karasev S., Karacharov A., Zharkov S. M.
Заглавие : Ultrafine particles derived from mineral processing: A case study of the Pb-Zn sulfide ore with emphasis on lead-bearing colloids
Место публикации : Chemosphere: Elsevier, 2016. - Vol. 147. - P.60-66. - ISSN 00456535 (ISSN), DOI 10.1016/j.chemosphere.2015.12.096
Примечания : Cited References: 47. - This research was supported by the Russian Science Foundation, Grant No. 14-17-00280.
Предметные рубрики: GALENA DISSOLUTION
METALLIC COPPER
NANOPARTICLES
SOIL
ENVIRONMENT
SEPARATION
TRANSPORT
FLOTATION
WATER
SIZE
Ключевые слова (''Своб.индексиров.''): lead sulfide--lead-zinc ore--lead sulfide--ultrafine particles--aquatic nanoparticles
Аннотация: Although mining and mineral processing industry is a vast source of heavy metal pollutants, the formation and behavior of micrometer- and nanometer-sized particles and their aqueous colloids entered the environment from the technological media has received insufficient attention to date. Here, the yield and characteristics of ultrafine mineral entities produced by routine grinding of the Pb-Zn sulfide ore (Gorevskoe ore deposit, Russia) were studied using laser diffraction analysis (LDA), dynamic light scattering (DLS) and zeta potential measurement, microscopy, X-ray photoelectron spectroscopy, with most attention given to toxic lead species. It was revealed, in particular, that the fraction of particles less that 1 ?m in the ground ore typical reaches 0.4 vol. %. The aquatic particles in supernatants were micrometer size aggregates with increased content of zinc, sulfur, calcium as compared with the bulk ore concentrations. The hydrodynamic diameter of the colloidal species decreased with time, with their zeta potentials remaining about -12 mV. The colloids produced from galena were composed of 20-50 nm PbS nanoparticles associated with lead sulfate and thiosulfate, while the surface oxidation products at precipitated galena were largely lead oxyhydroxides. The size and zeta potential of the lead-bearing colloids decreased with time down to about 100 nm and from -15 mV to -30 mV, respectively. And, conversely, lead sulfide nanoparticles were mobilized before the aggregates during redispersion of the precipitates in fresh portions of water. The potential environmental impact of the metal-bearing colloids, which is due to the large-scale production and relative stability, is discussed. © 2015 Elsevier Ltd.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mironov V. L., Lukin Y. I.
Заглавие : A PHYSICAL MODEL OF DIELECTRIC SPECTRA OF THAWED AND FROZEN BENTONITIC CLAY WITHIN THE FREQUENCY RANGE FROM 1 TO 15 GHZ
Место публикации : Russ. Phys. J.: SPRINGER, 2011. - Vol. 53, Is. 9. - P956-963. - ISSN 1064-8887, DOI 10.1007/s11182-011-9516-4
Примечания : Cited References: 7. - This study has been supported by the Complex integration project of the SB RAS Presidium, Grant No. 6 and a joint RFBR - France grant No. 09-05-91061-NTSNI.
Предметные рубрики: SOIL
Ключевые слова (''Своб.индексиров.''): dielectric spectra--moist specimens--bentonitic clay--microwaves--phase transitions--bentonitic clay--dielectric spectra--microwaves--moist specimens--phase transitions
Аннотация: The dielectric spectra of moist specimens of bentonitic clay are measured within the frequency range from 1 to 15 GHz at positive and negative temperatures. The phase transitions in different types of water present in the clay specimen are investigated in the process of its freezing. The parameters of dielectric relaxation and conductivity of different water types in the specimen are determined. A thermal dielectric model for thawed and frozen bentonitic clay is developed.
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