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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shishatskaya, Ekaterina, Nemtsev I. V., Lukyanenko A. V., Vasiliev A. D., Kiselev, Evgeniy, Sukovatyi, Aleksey, Volova, Tatiana
Заглавие : Polymer Films of Poly-3-hydroxybutyrate Synthesized byCupriavidus necatorfrom Different Carbon Sources
Коллективы : RFBRRussian Foundation for Basic Research (RFBR); KKRF [19-43-240012]; Ministry of Education and Science of the Russian FederationMinistry of Education and Science, Russian Federation [FSRZ-2020-0006]
Место публикации : J. Polym. Environ. - 2021. - Vol. 29. - P.837-850. - ISSN 1566-2543, DOI 10.1007/s10924-020-01924-3. - ISSN 1572-8919(eISSN)
Примечания : Cited References: 54. - The reported study was funded by RFBR and KKRF Grant No. 19-43-240012 "Biological and physical principles of production of new generation biomaterials". The work was carried out as part of the State Assignment of the Ministry of Education and Science of the Russian Federation No. FSRZ-2020-0006. The authors would like to express their special thanks to Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS" for providing equipment to ensure the accomplishment of this project
Предметные рубрики: CHEMOMECHANICAL PROPERTIES
RALSTONIA-EUTROPHA
SURFACE-ROUGHNESS
Аннотация: Films were prepared from 2% solutions of biodegradable poly-3-hydroxybutyrate [P(3HB)] and investigated. The polymer was synthesized by the Cupriavidus necator B-10646 bacterium cultivated using various carbon sources (glucose and glycerol of different degrees of purity, containing 0.3 to 17.93% impurities). Glycerol as the substrate influenced molecular-weight properties and crystallinity of the polymer without affecting its temperature characteristics. The P(3HB) specimens synthesized from glycerol had reduced Mw (300–400 kDa) and degree of crystallinity (50–55%) compared to the specimens synthesized from glucose (860 kDa and 76%, respectively). The low-crystallinity P(3HB) specimens, regardless of the degree of purity of glycerol, produced a beneficial effect on the properties of polymer films, which had a better developed folded surface and increased hydrophilicity. The values of the highest roughness (Ra) of the films synthesized from glycerol were 1.8 to 4.0 times lower and the water angles 1.4–1.6 times smaller compared to the films synthesized from glucose (71.75 nm and 87.4°, respectively). Those films performed better as cell scaffolds: the number of viable NIH fibroblasts was 1.7–1.9 times higher than on polystyrene (control) or films of P(3HB) synthesized from glucose.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Wigneron J. P., Chanzy A., Kerr Y. H., Lawrence H., Shi J. C., Escorihuela M. J., Mironov V. L., Mialon A., Demontoux F., de Rosnay P., Saleh-Contell K.
Заглавие : Evaluating an improved parameterization of the soil emission in L-MEB
Коллективы : Workshop on Remote Sensing and Modeling of Surface Properties (2nd; Jun 09-11, 2009; Toulouse, France)
Место публикации : IEEE Trans. Geosci. Remote Sensing: IEEE-Institute Electrical and Electronics Engineers, 2011. - Vol. 49, Is. 4. - P.1177-1189. - ISSN 0196-2892, DOI 10.1109/TGRS.2010.2075935
Примечания : Cited References: 26
Предметные рубрики: BAND MICROWAVE EMISSION
SURFACE-ROUGHNESS
1.4 GHZ
MODEL
MOISTURE
LAND
RADIOMETER
FREQUENCY
FIELDS
SPACE
Ключевые слова (''Своб.индексиров.''): microwave remote sensing--radiometry--roughness--soil moisture (sm)--soil moisture and ocean salinity (smos)--soil surface
Аннотация: In the forward model [L-band microwave emission of the biosphere (L-MEB)] used in the Soil Moisture and Ocean Salinity level-2 retrieval algorithm, modeling of the roughness effects is based on a simple semiempirical approach using three main "roughness" model parameters: H-R, Q(R), and N-R. In many studies, the two parameters Q(R) and N-R are set to zero. However, recent results in the literature showed that this is too approximate to accurately simulate the microwave emission of the rough soil surfaces at L-band. To investigate this, a reanalysis of the PORTOS-93 data set was carried out in this paper, considering a large range of roughness conditions. First, the results confirmed that Q(R) could be set to zero. Second, a refinement of the L-MEB soil model, considering values of N-R for both polarizations (namely, N-RV and N-RH), improved the model accuracy. Furthermore, simple calibrations relating the retrieved values of the roughness model parameters H-R and (N-RH - N-RV) to the standard deviation of the surface height were developed. This new calibration of L-MEB provided a good accuracy (better than 5 K) over a large range of soil roughness and moisture conditions of the PORTOS-93 data set. Conversely, the calibrations of the roughness effects based on the Choudhury approach, which is still widely used, provided unrealistic values of surface emissivities for medium or large roughness conditions.
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