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    Mironov, V. L.
    Retrieving temperature gradient in frozen active layer of arctic tundra soils from radiothermal observations in L-Band-Theoretical modeling / V. L. Mironov, K. V. Muzalevskiy, I. V. Savin ; funding agency Siberian Branch of the Russian Academy of Sciences (SB RAS) // IEEE J. Sel. Top. Appl. Earth Observ. Remote Sens. - 2013. - Vol. 6, Is. 3. - Ст. 6520003. - P. 1781-1785, DOI 10.1109/JSTARS.2013.2262108. - Cited References: 20 . - ISSN 1939-1404
   Перевод заглавия: Восстановление градиента температуры в активном слое мерзлой почвы арктической тундры по данным радиометрических наблюдений в L-диапазоне. Теоретическое моделирование
Рубрики:
WATER
   RADIOMETER
   BOREAL
Кл.слова (ненормированные):
Active layer -- Arctic tundra soil -- freezing -- microwave remote sensing -- radiometry -- soil moisture and ocean salinity (SMOS) -- soil temperature -- temperature profile -- thawing
Аннотация: Possibility of remote sensing of both the surface temperature and the temperature gradient in the permafrost active layer from L-band brightness temperature observations is theoretically investigated at a SMOS frequency of 1.4 GHz. Bare soil emission is simulated based on the semi-empirical L-MEB model. The brightness temperature is simulated using the soil density, surface roughness, temperature, and moisture profiles measured in situ at the Biosphere Station Franklin Bluffs, Alaska, USA (69°39'N, 148°43'W) from September 2, 1999, to August 23, 2001. The soil permittivity is calculated using the temperature-dependent generalized refractive mixing dielectric model for the organic rich soil sample collected in North Slope, Alaska (68°38'N, 149°35'W). This model predicts the complex dielectric constant of moist soil both thawed and frozen at temperatures from-30°C to +25°C and moistures from 0 to 0.94 g/g. The brightness temperatures simulated for field-of-view angles from 0 to 60\circ are inverted into the temperature profiles, and their deviations from the temperature profiles measured in situ are estimated. The error in reconstructing temperature profiles is found to be no greater than 1.8 °C to depths of 0.15 m. © 2013 IEEE.

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Доп.точки доступа:
Muzalevskiy, K. V.; Музалевский, Константин Викторович; Savin, I. V.; Савин, Игорь Викторович; Миронов, Валерий Леонидович; Siberian Branch of the Russian Academy of Sciences (SB RAS)
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    Nuclear magnetic resonance study of ice-based composite materials reinforced with nanodisperse aluminum oxide fibers / E. V. Morozov, A. S. Voronin, S. V. Kniga, V. M. Buznik // Inorg. Mater. Appl. Res. - 2022. - Vol. 13, Is. 1. - P. 217-224, DOI 10.1134/S2075113322010270. - Cited References: 21. - This work was performed within the scope of state contract no. 0287-2021-0012 of the Institute of Chemistry and Chemical Technology (Siberian Branch, Russian Academy of Sciences) in the part of developing the MRI methods for studying composite materials; also the work was supported by the Russian Science Foundation (project no. 18-1300392) in the part of the study of the processes of water crystallization and ice melting in ice-based composite materials . - ISSN 2075-1133. - ISSN 2075-115X
Рубрики:
SELF-DIFFUSION
   WATER
Кл.слова (ненормированные):
ice composite materials -- reinforcing -- freezing -- melting -- NMR spectroscopy -- magnetic resonance imaging
Аннотация: Pulsed-field gradient NMR spectroscopy and magnetic resonance imaging methods were used to investigate water suspensions of nanosized fibers of aluminum oxide and ice composite materials based on these fibers. Introduction of the nanofibers was shown to have no noticeable structural effect in the suspensions in the Al2O3 concentration range of 1-10 wt %. High content of the filler was found to change the morphology and texture of the ice matrix in the composites remarkably: it becomes more homogeneous and acquires a higher degree of continuity; the melting front does not visualize internal melting zones or integrity defects in the composite. At the same time, addition of the nanofibers to the ice composites weakly influences the quantitative dynamics of the heat transfer, which is manifested in close values of the propagation speeds of the freezing/melting front in the samples at similar temperatures.

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Публикация на русском языке Исследование ледовых композиционных материалов, армированных нанодисперсными волокнами оксида алюминия, методами ядерного магнитного резонанса [Текст] / Е. В. Морозов, А. С. Воронин, С. В. Книга, В. М. Бузник // Материаловедение. - 2021. - № 8. - С. 9-18

Держатели документа:
Russian Acad Sci, Krasnoyarsk Sci Ctr, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Krasnoyarsk Sci Ctr, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Krasnoyarsk Sci Ctr, Siberian Branch, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
All Russian Sci Res Inst Aviat Mat, Moscow 105005, Russia.
Tomsk State Univ, Tomsk 634050, Russia.

Доп.точки доступа:
Morozov, E. V.; Морозов, Евгений Владимирович; Voronin, A. S.; Kniga, S., V; Buznik, V. M.; Institute of Chemistry and Chemical Technology (Siberian Branch, Russian Academy of Sciences) [0287-2021-0012]; Russian Science FoundationRussian Science Foundation (RSF) [18-1300392]
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    Raman study of structural transformations in self-assembled diphenylalanine nanotubes at elevated temperatures / P. S. Zelenovskiy [et al.] // J. Raman Spectrosc. - 2017. - Vol. 48, Is. 11. - P. 1401-1405, DOI 10.1002/jrs.5084. - Cited References:50. - The equipment of the Ural Center for Shared Use 'Modern nanotechnology' UrFU was used. The research was supported by the President of Russian Federation grant for young scientists (Contract 14.Y30.15.6554-MK) and by the Government of the Russian Federation (Act 211, Agreement 02.A03.21.0006). A.K. acknowledges the Turkish-Portuguese project TUBITAK/0006/2014 and CICECO-Aveiro Institute of Materials (Ref. FCT UID/CTM/50011/2013) financed by national funds through the FCT/MEC and, when applicable, co-financed by FEDER under the PT2020 Partnership Agreement. . - ISSN 0377-0486. - ISSN 1097-4555
   Перевод заглавия: Исследование структурных превращений в самоорганизованных дифенилаланиновых нанотрубках при повышенных температурах методом комбинационного рассеяния света

РУБ Spectroscopy
Рубрики:
PEPTIDE NANOTUBES
   PIEZOELECTRIC PROPERTIES
   WATER
   MICROTUBES
Кл.слова (ненормированные):
peptide nanotubes -- diphenylalanine -- phase transition -- cyclization -- water
Аннотация: Self-assembled peptide diphenylalanine (NH2-Phe-Phe-COOH, FF) is one of the most important emergent functional materials, demonstrating wide range of fascinating physical and chemical properties including biocompatibility, chemical variability, exceptional rigidity, outstanding piezoelectric, pyroelectric and ferroelectric responses. Up to now, the phase transitions in FF nanotubes were investigated by scanning and transmission electron microscopy, atomic force microscopy, differential scanning calorimetry, thermogravimetry and mass spectroscopy. The Raman spectroscopy was implemented at room temperature only, and the microscopic details of these transitions remained unknown. In this work, the structural transformations in FF nanotubes at elevated temperatures (up to tubes destruction at 160 °C) were studied by Raman spectroscopy. Two structural transformations were observed in this region: hexagonal to orthorhombic transition at about 100 °C and the cyclization of FF molecules at about 150 °C. For the first time, these transformations were considered in the context of reconstruction of the water subsystem in the nanotubes, thus demonstrating the strong relation between the peptide tube and the state of the water inside. Using an effective frequency of nanotubes' lattice vibrations, we found that many effects observed earlier by other methods are induced by the variation of the water subsystem. The analysis of certain lines in the middle part of the Raman spectrum allowed us to describe the microscopic details of FF molecule cyclization. These results improve the understanding of the role of water in the origin of outstanding properties of FF nanotubes and thus promote developing new functional devices on their basis.

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Доп.точки доступа:
Zelenovskiy, P. S.; Davydov, A. O.; Krylov, A. S.; Крылов, Александр Сергеевич; Kholkin, A. L.; International GeoRAMAN Conference(12th ; June 9-15, 2016 ; Novosibirsk, Russia)
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    Ultrafine particles derived from mineral processing: A case study of the Pb-Zn sulfide ore with emphasis on lead-bearing colloids / Y. Mikhlin [et al.] // Chemosphere. - 2016. - Vol. 147. - P. 60-66, DOI 10.1016/j.chemosphere.2015.12.096. - Cited References: 47. - This research was supported by the Russian Science Foundation, Grant No. 14-17-00280. . - ISSN 0045-6535
   Перевод заглавия: Ультрадисперсные частицы, полученные при переработке минерального сырья: комплексный анализ колчеданной руды Pb-Zn и коллоидных частиц, содержащих свинец

РУБ Environmental Sciences
Рубрики:
GALENA DISSOLUTION
   METALLIC COPPER
   NANOPARTICLES
   SOIL
   ENVIRONMENT
   SEPARATION
   TRANSPORT
   FLOTATION
   WATER
   SIZE
Кл.слова (ненормированные):
Lead sulfide -- Lead-zinc ore -- Lead sulfide -- Ultrafine particles -- Aquatic nanoparticles
Аннотация: Although mining and mineral processing industry is a vast source of heavy metal pollutants, the formation and behavior of micrometer- and nanometer-sized particles and their aqueous colloids entered the environment from the technological media has received insufficient attention to date. Here, the yield and characteristics of ultrafine mineral entities produced by routine grinding of the Pb-Zn sulfide ore (Gorevskoe ore deposit, Russia) were studied using laser diffraction analysis (LDA), dynamic light scattering (DLS) and zeta potential measurement, microscopy, X-ray photoelectron spectroscopy, with most attention given to toxic lead species. It was revealed, in particular, that the fraction of particles less that 1 ?m in the ground ore typical reaches 0.4 vol. %. The aquatic particles in supernatants were micrometer size aggregates with increased content of zinc, sulfur, calcium as compared with the bulk ore concentrations. The hydrodynamic diameter of the colloidal species decreased with time, with their zeta potentials remaining about -12 mV. The colloids produced from galena were composed of 20-50 nm PbS nanoparticles associated with lead sulfate and thiosulfate, while the surface oxidation products at precipitated galena were largely lead oxyhydroxides. The size and zeta potential of the lead-bearing colloids decreased with time down to about 100 nm and from -15 mV to -30 mV, respectively. And, conversely, lead sulfide nanoparticles were mobilized before the aggregates during redispersion of the precipitates in fresh portions of water. The potential environmental impact of the metal-bearing colloids, which is due to the large-scale production and relative stability, is discussed. © 2015 Elsevier Ltd.

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Держатели документа:
Inst. of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, Akademgorodok, 50/24, Krasnoyarsk, Russian Federation
Siberian Federal University, Svobodny pr. 79, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50/38, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Mikhlin, Y.; Vorobyev, S.; Romanchenko, A.; Karasev, S.; Karacharov, A.; Zharkov, S. M.; Жарков, Сергей Михайлович
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