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    Thermal, mechanical and biodegradation studies of biofiller based poly-3-hydroxybutyrate biocomposites / S. Thomas [et al.] // Int. J. Biolog. Macromol. - 2020. - Vol. 155. - P. 1373-1384, DOI 10.1016/j.ijbiomac.2019.11.112. - This study was financially supported by Project “Agropreparations of the new generation: a strategy of construction and realization” (Agreement No 074-02-2018-328) in accordance with Resolution No 220 of the Government of the Russian Federation of April 9, 2010, “On measures designed to attract leading scientists to the Russian institutions of higher learning”. . - ISSN 1879-0003
   Перевод заглавия: Термические, механические и биодеградационные исследования биокомпозитов на основе бионаполнителей на основе поли-3-гидроксибутирата
Кл.слова (ненормированные):
Poly-3-hydroxybutyrate -- Biocomposite -- Physical properties -- Environmental degradation
Аннотация: Biodegradable poly-3-hydroxybutyrate [P(3HB)] and natural fillers - clay, peat, and birch wood flour – were used to prepare powdered composites to form pellets and granules. Pellets were produced by cold pressing of polymer and filler powder whereas granules were produced from the powders wetted with ethanol. Characterization techniques like IR spectroscopy, differential scanning calorimetry, X-ray analysis, mechanical analysis and electron microscopy were employed to study the properties of the initial P(3HB) and fillers and the composites. Analysis of the IR spectra of the composites showed the absence of chemical bonds between the components, i.e. the composites were physical mixtures. Young's moduli of the pellets prepared from initial materials varied considerably, and the highest value was obtained for P(3HB) pellets (350 MPa). Studies of biodegradation of composite pellets and granules in the soil for 35 days showed that the residual mass of the pellets had decreased to 68% for P(3HB); 56.4% for P(3HB)/peat; 67% for P(3HB)/wood flour, and 64% for P(3HB)/clay; granules exhibited a similar mass loss, residual mass of the granules of P(3HB) was 68.4%, P(3HB)/peat 46.4%; P(3HB)/wood flour 77%, and P(3HB)/clay 74%. This shows the significance of the material as an eco-friendly composite without sacrificing its mechanical properties.

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Держатели документа:
Siberian Federal University, 79 Svobodnyi Av., Krasnoyarsk 660041, Russia
International and Interuniversity Centre for Nano Science and Nano technology, Kottayam, Kerala, India
Institute of Biophysics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/50 Akademgorodok, Krasnoyarsk 660036, Russia
L.V. Kirensky Institute of Physics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 43/50 Akademgorodok, Krasnoyarsk 660036, Russia
Federal Research Center Krasnoyarsk Scientific Center of the Siberian Branch of Russian, Academy of Sciences, 50 Akademgorodok, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Thomas, Sabu; Shumilova, A. A.; Kiselev, E. G.; Baranovsky, S. V.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Nemtsev, I. V.; Kuzmin, A. P.; Sukovatyi, A. G.; Avinash, R. Pai; Volova, T. G.
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