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Lopatin, V. N.
Modelling optical properties of organic-mineral complexes in water ecosystems / V. N. Lopatin, N. V. Shepelevich, I. V. Prostakova // J. Phys. D. - 2005. - Vol. 38, Is. 15. - P. 2556-2563, DOI 10.1088/0022-3727/38/15/005. - Cited References: 22 . - ISSN 0022-3727

РУБ Physics, Applied
Рубрики:
SCANNING FLOW-CYTOMETRY
   LIGHT-SCATTERING
   STRATIFIED SPHERE
   PARTICLES
   INDEX
Кл.слова (ненормированные):
Approximation theory -- Ecosystems -- Inverse problems -- Light scattering -- Mathematical models -- Refractive index -- Suspensions (fluids) -- Water -- Generalization -- Integral light scattering indicatrix -- Organic-mineral complexes -- Spherical particles -- Complexation
Аннотация: Characteristics of organic-mineral complexes have been theoretically and experimentally studied in the paper, based on the method of integral light scattering indicatrix. Modelling of optical properties was realized using models of the coated spherical particles with a shell which is constant and changeable in the refractive index profile. General regularities have been revealed and generalized parameters for the method of integral light scattering indicatrix have been suggested.

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Держатели документа:
Res Inst Ecol Fish Breeding & Terraneous Biosyst, Krasnoyarsk 660017, Russia
Russian Acad Sci, Siberian Div, Inst Computat Modeling, Krasnoyarsk 660036, Russia
ИВМ СО РАН
Research Institute of Ecology of Fish-Breeding and Terraneous Biosystems, Krasnoyarsk, 66017, Russian Federation
Institute of Computational Modeling, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Shepelevich, N. V.; Prostakova, I. V.
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Effect of complexation with closo-decaborate anion on photophysical properties of copolyfluorenes containing dicyanophenanthrene units in the main chain / A. A. Yakimanskiy, K. I. Kaskevich, T. G. Chulkova [et al.] // Micro. - 2023. - Vol. 3, Is. 4. - P. 930-940, DOI 10.3390/micro3040063. - Cited References: 23. - This work was supported by the Russian Science Foundation, grant no. 23-43-00060 . - ISSN 2673-8023
Кл.слова (ненормированные):
CAM-B3LYP -- charge transfer -- copolyfluorene -- energy transfer -- hole-electron distribution -- nitrilium derivatives of closo-decaborate anions -- lambda-diagnostic -- luminescence -- phenanthrene-9,10-dicarbonitrile -- TD-DFT
Аннотация: The functionalization of copolyfluorenes containing dicyanophenanthrene units by closo-decaborate anion is described. Target copolyfluorenes were analyzed using SEM, UV-vis, luminescence, NMR, and Fourier-transform infrared (FTIR) spectroscopy. The effect of complexation with the closo-decaborate anion on the photophysical properties was studied both experimentally and theoretically. The PL data indicate an efficient charge transfer from fluorene to the dicyanophenanthrene units coordinated to the closo-decaborate. The coordination of closo-decaborate clusters to the nitrile groups of copolyfluorenes provides an important route to new materials for sensors and light-emitting devices while, at the same time, serving as a platform for further study of the nature of boron clusters.

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Держатели документа:
Institute of Macromolecular Compounds, RAS, Bolshoi Prospect of Vasilyevsky Island 31, Saint Petersburg 199004, Russia
Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia
Kurnakov Institute of General and Inorganic Chemistry, RAS, Moscow 119991, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia
Laboratory for Digital Controlled Drugs and Theranostics, Federal Research Center KSC SB RAS, Krasnoyarsk 660041, Russia

Доп.точки доступа:
Yakimanskiy, Anton A.; Kaskevich, Ksenia I.; Chulkova, Tatiana G.; Krasnopeeva, Elena L.; Savilov, Serguei V.; Voinova, Vera V.; Neumolotov, Nikolay K.; Zhdanov, Andrey P.; Rogova, Anastasia V.; Рогова, Анастасия Владимировна; Tomilin, F. N.; Томилин, Феликс Николаевич; Zhizhin, Konstantin Yu.; Yakimansky, Alexander V.
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