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Magnetic properties of nanostructured Co-based alloys produced by dynamic compaction and plasma spray deposition / L. Kuzovnikova [et al.] // Diffusion and Defect Data Pt.B: Solid State Phenomena. - 2012. - Vol. 190. - P. 192-195, DOI 10.4028/www.scientific.net/SSP.190.192 . - ISBN 1012-0394. - ISBN 9783037854365
Кл.слова (ненормированные):
Bulk nanostructured materials -- Dynamic compaction -- Magnetic properties -- Plasma spray deposition -- Bulk nanostructured materials -- Co-based alloys -- Co-P alloy -- Dynamic compaction -- Ferromagnetic resonance linewidth -- Local magnetic anisotropy -- Magnetic characteristic -- Nano-structured -- Plasma spray deposition -- Compaction -- Magnetic materials -- Magnetic properties -- Plasma jets -- Plasma spraying -- Saturation magnetization -- Deposits
Аннотация: The bulk nanostructured Co-P alloys were prepared by dynamic compaction and a plasma spray deposition techniques. The magnetic characteristics, such as the saturation magnetization, M 0, the Bloch constant, B, the local magnetic anisotropy field, H a, the ferromagnetic resonance linewidth, ?H, the coercivity, H c, were investigated. A comparison between the magnetic properties of the Co-P alloys prepared by dynamic compaction and a plasma spray deposition techniques was carried out. В© (2012) Trans Tech Publications.

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Доп.точки доступа:
Kuzovnikova, L. A.; Кузовникова, Людмила Александровна; Denisova, E. A.; Денисова, Елена Александровна; Kuzovnikov, A. A.; Кузовников А.А.; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Lepeshev, A.
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Bobrov, P. P.
Dielectric permittivity spectra of oil-water-saturated sandy-clayey rocks of different mineralogical compositions and relaxation properties of water in these rocks / P. P. Bobrov, V. L. Mironov, A. V. Repin // Russ. Geol. Geophys. - 2015. - Vol. 56, Is. 7. - P. 1065-1073, DOI 10.1016/j.rgg.2015.06.007. - Cited References: 21. - This work was supported by RFBR (grant nos. 12-05-00502a and 14-05-00151a). . - ISSN 1068-7971

РУБ Geosciences, Multidisciplinary
Рубрики:
MOIST SOILS
   FREQUENCY
   MODEL
   TEMPERATURE
   SALINITY
   RANGE
   GHZ
Кл.слова (ненормированные):
Conductivity -- Dielectric permittivity -- Multifrequency dielectric relaxation -- Oil-bearing deposits -- Sandy-clayey rocks
Аннотация: Experimental measurements of the dielectric permittivity and equivalent conductivity of sandy-clayey samples (a mixture of river sand with bentonite or kaolin) saturated with salt-solution-diesel-fuel emulsions were performed in the frequency range from 10 kHz to 1 GHz at temperatures of 25-65 °C. It is shown that when the content of the salt solution in the saturating fluid does not exceed 10%, the dielectric permittivity in the frequency range from 1 MHz to 1 GHz depends little on the mineral composition of the sample and on the concentration of the saturating solution. When the portion of water is 33.3% or higher, increasing the concentration of the salt solution leads to an increase in the equivalent conductivity and the real part of the complex dielectric permittivity. Using the refractive model of the complex dielectric permittivity, we have estimated the dielectric properties of bound water, which depend on temperature and the type of clay (bentonite or kaolin) in the sand-clay mixture but are independent of the water saturation and the amount of clay in the sample.

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Публикация на русском языке Бобров, Павел Петрович. Спектры диэлектрической проницаемости нефтеводонасыщенных песчано-глинистых пород различного минералогического состава и релаксационные свойства воды в этих породах [Текст] / П. П. Бобров, В. Л. Миронов, А. В. Репин // Геол. и геофиз. - Новосибирск : Изд-во СО РАН, 2015. - Т. 56 № 7. - С. 1359-1368

Держатели документа:
Omsk State Pedagogical University, Naberezhnaya im. Tukhachevskogo 14, Omsk, Russian Federation
L.V. Kirenskii Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50, str. 38, Krasnoyarsk, Russian Federation
M.F. Reshetnev Siberian State Aerospace University, pr. im. Gazety Krasnoyarskii Rabochii 31, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Mironov, V. L.; Миронов, Валерий Леонидович; Repin, A. V.; RFBR [12-05-00502a, 14-05-00151a]
}
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    Типоморфизм арсенопирита золоторудных месторождений Благодатное и Олимпиада (Енисейский кряж) / А. М. Сазонов [и др.] // Минералогия. - 2016. - № 3. - С. 53-70. - Библиогр.: 24. - Работа выполнена при финансовой поддержке Министерства образования и науки РФ, программа «Организация проведения научных исследований», № 1025 и Фонда Михаила Прохорова (договор № АМ-94/15 и АМ-35/16).
   Перевод заглавия: Typomorphism of arsenopyrite from the Blagodatnoye and Olimpiada gold ore deposits (Yenisei ridge)
Кл.слова (ненормированные):
месторождения золота Олимпиада и Благодатное -- типоморфизм арсенопирита -- кристаллическая структура -- неоднородность состава -- концентрации золота -- температура -- активность серы -- Olimpiada and Blagodatnoye deposits -- typomorphism of arsenopyrite -- crystal structure -- heterogeneity of composition -- gold concentrations -- temperature -- sulphur activity
Аннотация: Присутствие арсенопирита является показателем золотоносности гидротермальной минерализации в месторождениях Олимпиада и Благодатное, где производится около 40 т золота ежегодно. Парагенетические ассоциации арсенопирита, морфология зёрен, кристаллическая структура и химический состав характеризуются значительной неоднородностью в пределах одного зерна, соседних зёрен, разновозрастных генераций, в различных участках рудных тел и в месторождениях. Кристаллизация минерала осуществлялась в интервале температур < 300–542.5 °С при изменчивой активности серы в растворах (log αS2 ⋍ -5.7... -14.6) как в различных пробах, так и зёрнах, принадлежащих одной выборке. Повышенные концентрации золота и других благородных металлов отмечены в арсенопиритах с избытком серы и с избытком мышьяка.
The presence of arsenopyrite is an indicator of gold in hydrothermal mineralization of the Olimpiada and Blagodatnoye deposits producing about 40t of gold annually. The paragenetic associations of arsenopyrite, the morphology of grains, the crystal structure and chemical composition are characterized by significant heterogeneity within a single grain, neighbouring grains, generations of different ages, in different parts of ore bodies and deposits. Mineral crystallization occurred in the temperature range of < 300–542.5 °С, with variable sulphur activity in solutions (log αS2⋍ –5.7…–14.6). The increased concentrations of gold and other precious metals are noted in arsenopyrite with excess of sulphur and excess of arsenic with reduced structural and chemical stoichiometry.

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Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Сазонов, А. М.; Кирик, С. Д.; Сильянов, С. А.; Баюков, Олег Артемьевич; Bayukov, O. A.; Тишин, П. А.
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Morozov, E. V.
New insight into the wax precipitation process: in situ NMR imaging study in a cold finger cell / E. V. Morozov, O. V. Falaleev, O. N. Martyanov // Energy Fuels. - 2016. - Vol. 30, Is. 11. - P. 9003-9013, DOI 10.1021/acs.energyfuels.6b01535. - Cited References: 69. - This research was performed with the financial support of the Russian Science Foundation (Project No. 15-19-00119). . - ISSN 0887-0624
Кл.слова (ненормированные):
Cells -- Crude oil -- Cytology -- Deposits -- Diffusion -- Gelation -- Magnetic resonance imaging -- Ostwald ripening -- Phase separation -- Polymer blends -- Deposit formation -- Deposit structures -- Diffusion controlled growth -- Dominant mechanism -- Lower temperatures -- Morphology and dynamics -- Phase-separation process -- Temperature regimes -- Image processing
Аннотация: A cold finger cell intended for the wax deposition measurements was fabricated and integrated into an NMR imaging probe for the noninvasive study of wax precipitation processes in situ. The cell was first tested with a model system; then, a series of experiments with different thermal gradients applied to the cell were performed for a waxy crude oil. NMR imaging of the operating cell revealed the formation of a deposit with the morphology and dynamics strongly correlating with the temperature regime. At higher temperatures of cold finger, the incipient wax gel ages uniformly, giving rise to the hard and thin inner layer of deposit accompanied by a branched loosely consolidated outer layer. Conversely, the lower temperatures facilitate formation of a thick deposit which no longer ages uniformly and slow down the diffusion-controlled growth of the branched deposit structure. The results obtained are consistent with the majority of the data previously reported. Thus, gelation of the wax at temperatures below the cloud point and subsequent thermal-driven diffusion processes are considered to be the dominant mechanisms of the deposit formation. The counter diffusion and Ostwald ripening aging concepts were found to be relevant in the case of the cold finger study and account for the phenomena observed in this work. The information obtained via NMR imaging is highly complementary to the results obtained by other techniques that can aid in understanding the essential processes behind the wax precipitation phenomena. The approach developed can be effectively extended to study any thermal-driven phase separation process. © 2016 American Chemical Society.

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Держатели документа:
Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50/38, Krasnoyarsk, Russian Federation
Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50/24, Krasnoyarsk, Russian Federation
Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Ak. Lavrentieva 5, Novosibirsk, Russian Federation
Krasnoyarsk Scientific Centre, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Falaleev, O. V.; Martyanov, O. N.; Морозов, Евгений Владимирович
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    Сильянов, С. А.
    Cтруктура арсенопирита золоторудных месторождений енисейского кряжа по данным мессбауэровской спектроскопии / С. А. Сильянов, Ю. В. Князев, Н. А. Некрасова // Взаимодействие учрежд. Роснедра, Минобрнауки России и РАН при регион. геол. изучении территории РФ и ее континент. шельфа : материалы конференции : ВСЕГЕИ, 2017. - С. 813-815. - Библиогр.: 6 . - ISBN 978-5-93761-255-7
   Перевод заглавия: Structure of arsenopyrite from gold ore deposits of the yenisei ridge as per the Mossbauer spectroscopy data
Аннотация: Проведено мессбауэровское исследование структуры арсенопиритов золоторудныхместорождений Енисейского кряжа. В структуре минерала обнаружены неэквивалентные позиции атомов железа, которые можно соотнести с таковыми в пирите, леллингите и арсенопирите. В изученных арсенопиритах одновременно возникают позиции железа с составом координационной сферы: {6S}, {5S1As}, {4S2As}, {3S3As}, {2S4As}, {1S5As}, {6As}. Для арсенопиритовой позиции {3As3S} установлены дополнительные конфигурации лигандного окружения, что указывает на разупорядочение арсенопиритовой фазы. Заселенность позиций железа с различными конфигурациями лигандов зависит от соотношения S и As в образце.
The Mossbauer study of the structure of arsenopyrite from the gold ore deposits of the Yenisei Ridge has been performed. The non-equivalent positions of iron atoms have been identiﬁ ed in the structure of the mineral. They correspond conventionally to pyrite, lollingite and arsenopyrite. In the studied arsenopyrites the iron positions occur simultaneously with the composition of the coordination sphere: {6S}, {5S1As}, {4S2As}, {3S3As}, {2S4As}, {1S5As}, and {6As}. Additional conﬁ gurations of the ligand surroundings have been identiﬁ ed for the arsenopyrite position {3As3S}. This indicates the disordering of the arsenopyrite phase. The occupancy of the iron positions with different ligand conﬁ gurations depends on the S to As ratio in the specimen.

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Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Князев, Юрий Владимирович; Knyazev, Yu. V.; Некрасова, Н. А.; Министерство природных ресурсов и экологии Российской Федерации; Федеральное агентство по недропользованию; Всероссийский научно-исследовательский геологический институт им. А. П. КарпинскогоМеждународная конференция молодых ученых и специалистов памяти академика А. П. Карпинского(5 ; 2017 ; 28 февр. - 3 марта ; Санкт-Петербург)
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    Composition and Ligand Microstructure of Arsenopyrite from Gold Ore Deposits of the Yenisei Ridge (Eastern Siberia, Russia) / A. M. Sazonov [et al.] // Minerals. - 2019. - Vol. 9, Is. 12. - Ст. 737, DOI 10.3390/min9120737. - Cited References: 62. - The work was supported by the Russian Foundation for Basic Research (project number 19-35-90017) and the Government of the Russian Federation (project 14.Y26.31.0012). . - ISSN 2075-163X
   Перевод заглавия: Состав и лигандная микроструктура арсенопирита золоторудных месторождений Енисейского хребта (Восточная Сибирь, Россия)
Кл.слова (ненормированные):
arsenopyrite -- crystal lattice -- ligand surroundings -- non-equal positions -- Mössbauer Effect -- gold -- “invisible” gold -- gold ore deposits
Аннотация: The Mössbauer spectroscopy method was used to study the ligand microstructure of natural arsenopyrite (31 specimens) from the ores of the major gold deposits of the Yenisei Ridge (Eastern Siberia, Russia). Arsenopyrite and native gold are paragenetic minerals in the ore; meanwhile, arsenopyrite is frequently a gold carrier. We detected iron positions with variable distribution of sulfur and arsenic anions at the vertexes of the coordination octahedron {6S}, {5S1As}, {4S2As}, {3S3As}, {2S4As}, {1S5As}, {6As} in the mineral structure. Iron atoms with reduced local symmetry in tetrahedral cavities, as well as iron in the high-spin condition with a high local symmetry of the first coordination sphere, were identified. The configuration {3S3As} typical for the stoichiometric arsenopyrite is the most occupied. The occupation degree of other configurations is not subordinated to the statistic distribution and varies within a wide range. The presence of configurations {6S}, {3S3As}, {6As} and their variable occupation degree indicate that natural arsenopyrites are solid pyrite {6S}, arsenopyrite {3S3As}, and loellingite {6As} solutions, with the thermodynamic preference to the formation of configurations in the arsenopyrite–pyrite–loellingite order. It is assumed that in the variations as part of the coordination octahedron, the iron output to the tetrahedral positions and the presence of high-spin Fe cations depend on the physical and chemical conditions of the mineral formation. It was identified that the increased gold concentrations are typical for arsenopyrites with an elevated content of sulfur or arsenic and correlate with the increase of the occupation degree of configurations {5S1As}, {4S2As}, {1S5As}, reduction of the share of {3S3As}, and the amount of iron in tetrahedral cavities.

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Держатели документа:
Institute of Mining, Geology and Geotechnology, Siberian Federal University, 79 pr. Svobodny, 660041 Krasnoyarsk, Russia
Kirensky Institute of Physics, Federal Research Center Krasnoyarsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences, 50 Bld. 38 Akademgorodok, 660036 Krasnoyarsk, Russia
Faculty of Geology and Geography, Tomsk National Research State University, 36 Lenina, 634050 Tomsk, Russia

Доп.точки доступа:
Sazonov, A. M.; Silyanov, S. A.; Bayukov, O. A.; Баюков, Олег Артемьевич; Knyazev, Yu. V.; Князев, Юрий Владимирович; Zvyagina, Y. A.; Tishin, P. A.
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Microstructure and magnetic properties of Co58Ni10Fe5B16Si11 and Co58Ni10Fe5B16Si11-Al2O3 bulk amorphous coatings prepared by plasma spraying / E. A. Denisova, I. V. Nemtsev, S. V. Telegin [et al.] // J. Phys.: Conf. Ser. - 2020. - Vol. 1582, Is. 1. - Ст. 012078DOI 10.1088/1742-6596/1582/1/012078. - Cited References: 18. - This work was funded by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory, the Krasnoyarsk Regional Fund for the Support of Scientific and Technical Activities (project no. 18-42-240006 Nanomaterials with magnetic properties determined by the topological features of the nanostructure). The authors thank the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS” for the provided equipment
Кл.слова (ненормированные):
Alumina -- Aluminum oxide -- Cobalt alloys -- Composite coatings -- Deposits -- Glass -- Heat treatment -- Industrial research -- Iron alloys -- Magnetic properties -- Magnetism -- Microstructure -- Nanocrystalline materials -- Nanocrystals -- Plasma jets -- Plasma spraying -- Silicon -- Silicon alloys
Аннотация: The bulk soft magnetic glassy Co58Ni10Fe5B16Si11 alloy specimens have been prepared by plasma spray deposition. In order to increase resistivity of the material, the bulk Co58Ni10Fe5B16Si11-Al2O3 composite materials were fabricated. The investigations of structure and magnetic properties of the bulk samples were carried out by X-ray diffraction, electron microscopy and magnetic measurements. The relation of the structural features and magnetic characteristics of the bulk coating to the main parameters of the deposition regimes was determined. Optimized plasma spray deposition parameters allowed obtaining bulk glassy samples with magnetic parameters that are not inferior to the characteristics of a thermally treated rapidly quenched ribbon with the same composition. It was found that the bulk amorphous coatings can be characterized as a heterophase system. The relaxation annealing of the Co58Ni10Fe5B16Si11 bulk coating leads to a phase transition in this alloy in the precrystallization temperature range. The magnetic properties of the both kinds of coatings are correlated with changes in the microstructure. The appearance of nanocrystalline phase with TC640 K during relaxation heat treatment leads to a decrease of the coercivity and to an increase of the permeability. A comparison between the magnetic properties of the CoNiFe-BSi coating and (CoNiFe-BSi)-Al2O3, composite coating is carried out.

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Держатели документа:
Kirensky Institute of Physics, Sb Russian Academy of Sciences, 50/38, Akademgorodok str., Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, 73 Svobodny ave., Krasnoyarsk, 660041, Russian Federation
Scientific Center, Federal Research Center Ksc Sb Ras, 50 Akademgorodok str., Krasnoyarsk, 660036, Russian Federation
Reshetnev Siberian State University of Science and Technology, 31 Krasnoyarsky Rabochy ave., Krasnoyarsk, 660037, Russian Federation
Krasnoyarsk Institute of Railways Transport, Novaja Zarja str., Krasnoyarsk, Russian Federation

Доп.точки доступа:
Denisova, E. A.; Денисова, Елена Александровна; Nemtsev, I. V.; Telegin, S. V.; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Kuzovnikova, L. A.; Shepeta, N. A.; International Conference on High-Tech and Innovations in Research and Manufacturing(2020 ; 28 Feb. ; Krasnoyarsk)
}
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Use of magnetic resonance imaging in petroleum research: Potentialities and prospects (a Review) / E. V. Morozov, D. A. Sandzhieva, A. G. Dedov, V. M. Buznik // Pet. Chem. - 2023. - Vol. 63, Is. 1. - P. 52-66, DOI 10.1134/S0965544123020196. - Cited References: 76. - The study was supported by the Russian Science Foundation (project no. 22-13-00410, http://rscf.ru/project/22-13-00410/) . - ISSN 0965-5441. - ISSN 1555-6239
Кл.слова (ненормированные):
magnetic resonance imaging -- crude oil -- transport -- stability -- deposits
Аннотация: Potentialities of magnetic resonance imaging (MRI) in petroleum research are analyzed. Major attention is paid to technical features of the method as applied to oil extraction and preparation. Available published data are systematized. Four key directions of MRI, which undergo active development now, are distinguished: oil in a porous matrix; oil interfaces; destabilization of petroleum systems; transport of crude oils and petroleum systems. Key studies in this field are considered, essential points reflecting the MRI efficiency are presented, and the range of problems that can be solved using MRI, including prospects for further expansion of the application fields, is outlined. The possibilities of studying the morphological, structural, and dynamic aspects of the interaction of crude oils with the environment and the phase behavior of oils under the conditions of intense external actions are discussed. The review favors expansion of the experimental potential of specialists in the field of oil extraction, preparation, and refining, and also in the adjacent fields of physical and colloidal chemistry, chemistry of surface phenomena, and macromolecular chemistry.

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Публикация на русском языке Возможности и перспективы применения магнитно-резонансной томографии в исследовании нефтей (обзор) [Текст] / Е. В. Морозов, Д. А. Санджиева, А. Г. Дедов, В. М. Бузник. - 17 с. // Петролеомика. - 2023. - Т. 3 № 1. - С. 57-73

Держатели документа:
Institute of Chemistry and Chemical Technology, Krasnoyarsk Scientific Center, Siberian Branch, Krasnoyarsk, 660036, Russian Federation
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Krasnoyarsk, 660036, Russian Federation
Gubkin Russian State University of Oil and Gas (National Research University), Moscow, 119991, Russian Federation
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russian Federation
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Moscow, 119991, Russian Federation

Доп.точки доступа:
Morozov, E. V.; Морозов, Евгений Владимирович; Sandzhieva, D. A.; Dedov, A. G.; Buznik, V. M.
}
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