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Thermodynamic investigations of ferroelastic phase transitions in K 2ZnCl4 and K2CoCl4 / I. N. Flerov [et al.] // Journal of the Physical Society of Japan. - 1992. - Vol. 61, Is. 5. - P. 1606-1608, DOI 10.1143/JPSJ.61.1606 . - ISSN 0031-9015
Кл.слова (ненормированные):
(NH4) 2SO4 family ferroelectrics -- Ferroelasticity -- Ferroelectricity -- Heat capacity -- Hydrostatic pressure -- K2CoCl4 -- K2ZnCl4 -- Rb2ZnCl 4group ferroelectrics
Аннотация: Using the adiabatic calorimeter the heat capacity of K2ZnCl 4 and K2CoCl4 crystals was measured in temperature range 100?300 K. The entropy change for ferroelastic phase transition was estimated to be ? S=0.34 (Zn) and 0.33 (Co) JВ·mol-1K-1. The effect of hydrostatic pressure on the phase transition was investigated for both crystals.

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Держатели документа:
L. V. Kirensky Institute of Physics, Krasnoyarsk, 660036, Russian Federation
Department of Electrical Engineering, College of Science and Engineering, Meisei University, 2-1-1 Hodokubo, Hino-shi, Tokyo 191, Japan
Department of Electronic Engineering, College of Science and Engineering, Iwaki Meisei University, 5-5-1 Iino, Chuohdai, Iwaki-shi, Fukushima-ken 970, Japan

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Yamaguchi, T.; Sawada, S.; Горев, Михаил Васильевич; Gorev, M. V.; Aleksandrov, K. S.; Александров, Кирилл Сергеевич
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Investigation of structural and physical properties of cesium-lithium double sulfate / K. S. Aleksandrov [и др.] // Sov. Phys. Solid State. - 1980. - Vol. 22, Is. 12. - P. 2150-2152 ; Phys. Solid State . - ISSN 0584-5807
Кл.слова (ненормированные):
LITHIUM COMPOUNDS -- FERROELASTICITY -- PHASE TRANSITIONS -- CESIUM COMPOUNDS
Аннотация: A study was made of the temperature dependences of the integrated intensities of the 006 and 021 x-ray reflections, deviation of the angle gamma from 90 degree , NMR of **7Li, specific heat c//p, thermal expansion, and permittivity. Moreover, the effects of hydrostatic pressure on the phase transition were studied. It was definitely established that a ferroelastic phase transition of the second kind occurs at 202. 07 degree K and this transition does not alter the number of atoms in a unit cell.

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Доп.точки доступа:
Aleksandrov, K. S.; Zherebtsova, L. I.; Iskornev, I. M.; Kruglik, A. I.; Rozanov, O. V.; Flerov, I. N.

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Optical and calorimetric studies of K2TaF7 / S. V. Mel'nikova [et al.] // J. Fluor. Chem. - 2019. - Vol. 222-223. - P. 75-80, DOI 10.1016/j.jfluchem.2019.04.016. - Cited References: 26. - The reported study was funded by RFBR according to the research project № 18-02-00269. . - ISSN 0022-1139
Кл.слова (ненормированные):
Phase transition -- Ferroelasticity -- Optical properties -- Photoelasticity -- Heat capacity -- Entropy
Аннотация: Optical and calorimetric experiments on K2TaF7 are performed in a wide temperature range. No features were found in the behavior of the birefringence Δnb(T), the angle of rotation of the indicatrix ϕ(T) and the heat capacity ΔCp(T) except for those associated with the Pnma↔P21/c phase transition. Structural transformation was characterized as strong first order “proper” ferroelastic accompanied by a huge angle ϕ ≈40° and strong pre-transition phenomena in Δnb(T). Two contributions to the anomalies of the optical properties were found associated with the photoelastic effect and the transition parameter related linearly to the spontaneous deformation. Thermal treatments cause correlated changes in temperature and enthalpy of the phase transition, which leads to the invariance of the large magnitude of the corresponding entropy ΔS = 22 J/mol·K which does not match the model with the absence of structural disorder in the Pnma phase.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Engineering Systems and Energy, Krasnoyarsk State Agrarian University, Krasnoyarsk, 660049, Russian Federation
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, 660074, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation
Institute of Chemistry, Far Eastern Department of RAS, Vladivostok, 690022, Russian Federation

Доп.точки доступа:
Mel'nikova, S. V.; Мельникова, Светлана Владимировна; Bogdanov, E. V.; Богданов, Евгений Витальевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Laptash, N. M.; Flerov, I. N.; Флёров, Игорь Николаевич
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