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Processing of detonation diamonds with metal-containing high-frequency arc plasma and their properties / G. N. Churilov [et al.] // Fuller. Nanotub. Carbon Nanostruct. - 2012. - Vol. 20, Is. 4/7 SI. - P. 611-615, DOI 10.1080/1536383X.2012.657014. - Cited References: 5. - The work was partially supported by RFBR foundation (project 09-03-00383). . - ISSN 1536-383X

РУБ Chemistry, Physical + Nanoscience & Nanotechnology + Materials Science, Multidisciplinary + Physics, Atomic, Molecular & Chemical

Кл.слова (ненормированные):
Nanodiamond -- nanoparticle -- metal-containing plasma
Аннотация: This paper describes coating of diamond powder with metal by plasma. Arc plasma was generated in double jet high-frequency argon-operated plasmatron with atomized metal inserts. The diamond powder was added to the plasma in a flow of helium. Copper and nickel coated particles of detonation and industrial diamonds were studied by XRD, XPS, SEM methods and electron magnetic resonance. Results of these studies are presented.

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Держатели документа:
[Churilov, G. N.
Osipova, I. V.
Vnukova, N. G.
Glushenko, G. A.
Petrakovskaya, E. A.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Kolonenko, A. L.
Chiganov, A. S.] Krasnoyarsk State Pedag Univ, Krasnoyarsk, Russia
[Tomashevich, Ye. V.
Zhizhaev, A. M.] Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Churilov, G. N.; Чурилов, Григорий Николаевич; Osipova, I. V.; Осипова, Ирина Владимировна; Vnukova, N. G.; Внукова, Наталья Григорьевна; Glushchenko, G. A.; Глущенко, Гарий Анатольевич; Petrakovskaya, E. A.; Петраковская, Элеонора Анатольевна; Kolonenko, A. L.; Колоненко, Андрей Леонидович; Chiganov, A. S.; Tomashevich, Y. V.; Томашевич, Евгений Владимирович; Zhyzhaev, A. M.; Жижаев, Анатолий Михайлович
}
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Thermal decay of platinum metal acetylacetonates on the detonation nanodiamond surface / V. P. Isakov [et al.] // Экстремальные состояния вещества. Детонация. Ударные волны, междунар. конф. : Сб. тез. докл. - Саров, 2013. - P. 401-402

Доп.точки доступа:
Isakov, V. P.; Isakova, V. G.; Исакова, Виктория Гавриловна; Lyamkin, A. I.; Yunoshev, A. S.; Российский федеральный ядерный центр - Всероссийский научно-исследовательский институт экспериментальной физики; "Экстремальные состояния вещества. Детонация. Ударные волны", международная конференция (2013 ; 18-22 марта ; Саров); International conference "Extreme states of substance. Detonation. Shock waves" (2013 ; march ; 18- 22 ; Sarov, Russia); Харитоновские тематические научные чтения (15 ; 2013 ; март ; 18-22 ; Саров)
}
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Experimental study of the structure of milled diamond-containing particles obtained by the detonation method / A. Korets [et al.] // EPJ Appl. Phys. - 2012. - Vol. 57, Is. 3. - Ст. 30701, DOI 10.1051/epjap/2012110208. - Cited References: 15 . - ISSN 1286-0042

РУБ Physics, Applied
Рубрики:
PURIFICATION
NANODIAMOND
Кл.слова (ненормированные):
Chemical change -- Diamond grains -- Experimental spectra -- Experimental studies -- IR spectrum -- Mechanical force -- Detonation -- Diamonds -- X ray diffraction -- Agglomeration
Аннотация: A diamond-containing material (DCM) produced by detonation was mechanically milled using KM-1 and AGO-2S mills. Experimental spectra for infrared (IR) absorption, Raman scattering and X-ray diffraction patterns (XRD) were obtained for the treated DCM samples. We compared the Raman and IR spectra for the KM-1 milled samples and concluded that the surface of the DCM particles was not uniform. The mechanical force that resulted from milling with the AGO-2S destroyed the non-diamond part of the particles and initiated irreversible physical and chemical changes in them. The destruction of the diamond grains was the consequence of these irreversible changes. It follows from the experiments that the dipole momentum of the DCM particle was caused by the presence of polar fragments of molecules. The constant dipole momentum of the particles facilitated the aggregation. Based on this, we proposed a model of a structurally inhomogeneous DCM particle. В© 2012 EDP Sciences.

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Держатели документа:
Siberian Federal University, 26, Kirensky Str., Krasnoyarsk 660074, Russian Federation
Institute of Physics, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Institute of Chemistry and Chemical Technology, KSC SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Korets, A.; Krylov, A. S.; Крылов, Александр Сергеевич; Mironov, E.; Rabchevskii, E.
}
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Electrical and magnetic properties of nanodiamond and pyrocarbon composites / N. I. Kiselev [et al.] // Russ. J. Gen. Chem. - 2013. - Vol. 83, Is. 11. - P. 2173-2181, DOI 10.1134/S1070363213110376 . - ISSN 1070-3632
Аннотация: The electrical and magnetic properties of the nanodiamond composites comprising nanodiamond, pyrolytic carbon, and nanosized pores were studied. The composites are p-type semiconductors and their resistance decreases by 12 orders of magnitude as the pyrocarbon-to-diamond ratio γ increases from 0 to 80 wt %. Evidence for paramagnetic properties of the nanodiamond composites was obtained. The observed properties are explained by increased concentration of surface Tamm states. The paramagnetic properties are explained in terms of the electron spins localized on the nanodiamond surface in the composite.

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Держатели документа:
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Cent Res Inst Mat Fed Unitary Enterprise, St Petersburg, Russia
Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia
Inst Biophys, Siberian Branch,Russian Acad Sci, Krasnoyarsk, Russia;
Siberian Fed Univ, Youth Open Lab Perspect Res & Technol, Russia

Доп.точки доступа:
Kiselev, N. I.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Korchagina, S. B.; Petrakovskaya, E. A.; Петраковская, Элеонора Анатольевна; Vasil'ev, A. D.; Васильев, Александр Дмитриевич; Solov'ev, L. A.; Соловьев, Леонид Александрович; Balaev, D. A.; Балаев, Дмитрий Александрович; Bayukov, O. A.; Баюков, Олег Артемьевич; Denisov, I. A.; Денисов, И. А.; Tsegel'Nik, S. S.; Eremin, E. V.; Еремин, Евгений Владимирович; Znak, D. A.; Shaikhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Shubin, A. A.; Shestakov, N. P.; Шестаков, Николай Петрович; Volkov, N. V.; Волков, Никита Валентинович; Gordeev, S. K.; Belobrov, P. I.; Белобров, Петр Иванович
}
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    Temperature behavior of magnetization in multiphase Co-P powders in unsaturated regime / O. A. Li [et al.] // Solid State Phenom. : Selected, peer reviewed papers. - 2015. - Vol. 233-234: Achievements in Magnetism. - P. 522-525, DOI 10.4028/www.scientific.net/SSP.233-234.522 . - ISSN 1662-9779. - ISSN 978-3-038
   Перевод заглавия: Температурный ход намагниченности в многофазных порошках Со-Р в режиме неполного насыщения
Рубрики:
Achievements in magnetism
Кл.слова (ненормированные):
ferromagnetic powder -- local magnetic anisotropy -- nanocorundum -- nanodiamond
Аннотация: In this paper we have proposed a modified expression for the fitting M(T) data in Co-P powders with nanocorundum and nanodiamond precipitates. The expression for M(T) takes into account the effects from both thermal magnetic excitations – Bloch’s T 3/2 law and temperature dependence of the magnetic anisotropy. The fitting parameters are spontaneous magnetization at absolute zero temperature, Bloch constant and order of magnetic anisotropy constant. The obtained Bloch constant is in good agreement with literature data. The order of magnetic anisotropy constant is found to be about 3 that is surprising result and supposedly comes from multiphase nature of the investigated Co-P powder.

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Доп.точки доступа:
Perov, N. \ed.\; Semisalova, A. \ed.\; Li, O. A.; Ли О. А.; Komogortsev, S. V.; Комогорцев, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Chekanova, L. A.; Чеканова, Лидия Александровна; Eremin, E. V.; Еремин, Евгений Владимирович; Moscow International Symposium on Magnetism(6 ; 2014 ; June-July ; Moscow)
}
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Surface modification of detonation nanodiamonds with platinum and palladium nanoparticles / V. G. Isakova [et al.] // Int. J. Chem. - 2015. - Vol. 7, No. 1. - P. 1-9, DOI 10.5539/ijc.v7n1p1. - Cited References: 38 . - ISSN 1916-9698
Кл.слова (ненормированные):
detonation-synthesized nanodiamond supports -- platinum and palladium nanoparticles -- combustion -- chemical modific -- DND additional purification
Аннотация: Acetylacetonates of platinum group metals (M(acac)n, acac= CH3COCHCOCH3,n - oxidation state of metal) are the most suitable precursors for use in highly effective MOCVD (metal-organic chemical vapor deposition) processes because of their thermal properties, low price of initial ligand and accessible synthesis methods. In this study we have developed a simple, scalable inexpensive, MOCVD-like approach to the deposition of Pt and Pd nanoparticle dispersions on powder detonation nanodiamonds (DND) using combustion in air of powder mixtures of DND with Pt and Pd acetylacetonates. This one-step process requires no specialized apparatus, and is conducted at mild temperatures (180°C – 250°C). The substrate surface of DND initiates chemical thermal destruction of precursor and deposition of nanoparticle networks composed of constituent particles. DND-supported Pd and Pt nanoparticles with their loading being from 10 and 5wt. % were obtained the average of particle size 20-25 nm and 7-10nm decreases with decreasing the metal loading. For additional purification and disaggregation of the commercial detonation-synthesized nanodiamond (DNDcomm) the method of annealing of the powder mixtures DNDcomm with Na(acac) have been used. The purified diamond nanoparticulates (DND), as well as DNDcomm, Pt/DND and Pd/DND, were subjected to physicochemical characterizations, such as X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive X-ray (EDX) analysis.

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Доп.точки доступа:
Isakova, V. G.; Исакова, Виктория Гавриловна; Isakov, V. P.; Lyamkin, A. I.; Zharikova, N. V.; Yunoshev, A. S.; Nemtsev, I. V.; Немцев, Иван Васильевич
}
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The effect of silver ions electrolytically introduced into colloidal nanodiamond solution on its viscosity and thermal conductivity / A. P. Puzir’ [et al.] // Colloid J. - 2017. - Vol. 79, Is. 2. - P. 258-263, DOI 10.1134/S1061933X17020119. - Cited References: 22 . - ISSN 1061-933X
Кл.слова (ненормированные):
Dispersions -- Ions -- Metal ions -- Nanodiamonds -- Nanoparticles -- Silver -- Viscosity -- A-stable -- Detonation nanodiamond -- Diamond nano-particles -- Effect of silvers -- Silver concentration -- Silver ions -- Thermal conductivity
Аннотация: Experimental data have been presented on the influence of silver on the viscosity and thermal conductivity of a dispersion of diamond nanoparticles. A stable dispersion (5 wt %) of detonation nanodiamond particles has been used in the experiments. Silver ions have been introduced electrolytically into the dispersion of diamond nanoparticles. Silver concentration was not higher than 0.05 wt %. It has been shown that the introduction of silver ions significantly affects the thermal conductivity and viscosity of the dispersion.

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Публикация на русском языке Влияние электролитически введенных ионов серебра на вязкость и теплопроводность коллоидного раствора наноалмаза [Текст] / А. П. Пузырь [и др.] // Коллоид. журн. : Наука, 2017. - Т. 79 Вып. 2. - С. 206-211

Держатели документа:
Institute of Biophysics, Siberian Branch, Russian Academy of Sciences, ul. Akademgorodok 50/50, Krasnoyarsk, Russian Federation
Siberian Federal University, Svobodnyi pr. 79., Krasnoyarsk, Russian Federation
Special Design and Technology Bureau Nauka, Institute of Computational Technologies, Siberian Branch, Russian Academy of Sciences, pr. Mira 53, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, ul. Akademgorodok 50/38, Krasnoyarsk, Russian Federation
Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, ul. Akademgorodok 50/24, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Puzir’, A. P.; Minakov, A. V.; Burov, A. E.; Zharkov, S. M.; Жарков, Сергей Михайлович; Maksimov, N. G.; Pryazhnikov, M. I.
}
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The effect of copper and iron adsorption on the catalytic performance of alumina nanofiber / nanodiamond composite in sensing applications / N. O. Ronzhin, E. D. Posokhina, E. V. Mikhlina [et al.] // J. Phys. Chem. Solids. - 2022. - Vol. 167. - Ст. 110785, DOI 10.1016/j.jpcs.2022.110785. - Cited References: 68. - This work is supported by the Russian Foundation for Basic Research, Project 18–29–19078. The authors would like to express their special thanks to Krasnoyarsk Regional Center of Research Equipment of Federal Research Center «Krasnoyarsk Science Center SB RAS» for providing the equipment to ensure the accomplishment of this project . - ISSN 0022-3697
Кл.слова (ненормированные):
Nanodiamonds -- Alumina nanofibers -- Indicator system -- Copper ions -- Iron ions -- Phenol detection
Аннотация: Phenolic compounds are common environmental pollutants, which are used in many industries and contaminate water environment due to industrial wastewater discharge. Presently, there is an increasing demand for the development and improvement of inexpensive, easy-to-use analytical tools for in-situ detection of phenolic compounds. In this work, we investigate the effect of adsorption of Cu2+ and Fe2+ ions on the catalytic activity of a composite material based on alumina nanofibers (ANF) and detonation nanodiamonds (DND) in the co-oxidation of phenols with 4-aminoantipyrine in the presence of hydrogen peroxide. We have found more than two-fold increase of the catalytic activity for ANF + DND + Cu composite, while the activity of ANF + DND + Fe composite is found to decrease by several times in comparison with the original ANF + DND material. The results of FTIR analysis indicate that the adsorption of iron ions occurs with the formation of hydroxide surface groups and hydrogen bonds, which apparently block their catalytic activity in the Fenton redox cycle. The higher catalytic performance of AND + DND composite functionalized with copper ions makes it possible to detect two times lower concentrations of analytes (phenol and 4-chlorophenol) in comparison with the original composite. It is shown that the AND + DND + Cu composite provides a linear yield of the co-oxidation reaction product in a wide range of analyte concentrations (0.25–100 μM for phenol and 0.5–25 μM for 4-chlorophenol). Model experiments demonstrate the applicability of copper-functionalized composite as a reusable sensor for the determination of phenol in aqueous samples.

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Держатели документа:
Institute of Biophysics SB RAS, Akademgorodok 50/50, Krasnoyarsk, 660036, Russian Federation
Institute of Computational Modelling SB RAS, Akademgorodok 50/44, Krasnoyarsk, 660036, Russian Federation
Kirensky Institute of Physics SB RAS, Akademgorodok 50/38, Krasnoyarsk, 660036, Russian Federation
Federal Research Center KSC SB RAS, Akademgorodok 50/38, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Svobodny 79, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Ronzhin, N. O.; Posokhina, E. D.; Mikhlina, E. V.; Shestakov, N. P.; Шестаков, Николай Петрович; Nemtsev, I. V.; Немцев, Иван Васильевич; Bondar, V. S.; Ryzhkov, I. I.
}
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