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    Photoluminescence tuning via cation substitution in oxonitridosilicate phosphors: DFT calculations, different site occupations, and luminescence mechanisms / G. Li [et al.] // Chem. Mater. - 2014. - Vol. 26, Is. 9. - P. 2991-3001, DOI 10.1021/cm500844v. - Cited References: 62. - The authors would like to thank the Ministry of Science and Technology of Taiwan (Contract No. MOST 101-2113-M-002-014-MY3), the National Synchrotron Radiation Research Center, Taiwan, the National Natural Science Foundation of China (Grant No. NSFC 21301162), and the Fundamental Research Funds for the Central Universities (Grant No. CUG 130402) for financially supporting this research. Victor V. Atuchin gratefully acknowledges the Ministry of Education and Science of the Russian Federation for the financial support. . - ISSN 0897-4756. - ISSN 1520-5002
   Перевод заглавия: Управление фотолюминесценцией посредством замещения катионов в оксонитридосиликатных люминофорах: ТФП вычисления, заселения различных позиций и механизмы люминесценции

РУБ Chemistry, Physical + Materials Science, Multidisciplinary
Рубрики:
LIGHT-EMITTING-DIODES
   HIGH-TEMPERATURE SYNTHESIS
   LED CONVERSION PHOSPHORS
   CRYSTAL X-RAY
   WHITE-LIGHT
   ORDERED DISTRIBUTION
   GREEN PHOSPHOR
   LAYERED OXONITRIDOSILICATE
   REAL STRUCTURE
   AB-INITIO
Аннотация: Tuning and optimizing luminescent properties of oxonitridosilicates phosphors are important for white light-emitting diode (WLED) applications. To improve the color rendering index, correlated color temperature and thermal stability of layer-structured MSi2O2N2:Eu (M = Sr, Ba) phosphors, cation substitutions have been used to adjust their luminescent properties. However, the underlying mechanisms are still unclear. In this research, a series of (Sr1-xBax)Si2O2N2:Eu (0 ≤ x ≤ 1) compounds were prepared by solid-state reaction, after which systematic emission variations were investigated. The crystal structures of (Sr1-xBax)Si2O2N2:Eu (0 ≤ x ≤ 1) are nominally divided into three sections, namely, Phase 1 (0 ≤ x ≤ 0.65), Phase 2 (0.65 x 0.80), and Phase 3 (0.80 ≤ x ≤ 1) based on the X-ray diffraction measurements. These experimental results are further confirmed by optimizing the crystal structure data with first-principle calculations. Continuous luminescence adjustments from green to yellow are observed in Phase 1 with gradual replacement of Sr2+ with Ba2+, and the abnormal redshift is clarified through extended X-ray absorption fine structure analysis. Sr(Eu)-O/N bond length shrinkage in local structure causes the redshift emission, and the corresponding luminescence mechanism is proposed. Controllable luminescence in Phase 2 (from blue to white) and Phase 3 (from cyan to yellowish green) are observed. Based on the high-resolution transmission electron microscopy and selected area electron diffraction analysis, the two kinds of luminescence tuning are attributed to phase segregation. This study serves as a guide in developing oxonitride luminescent materials with controllable optical properties based on variations in local coordination environments through cation substitutions.

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Держатели документа:
Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan
China Univ Geosci, Fac Mat Sci & Chem, Wuhan 430074, Hubei, Peoples R China
SB RAS, Lab Crystal Phys, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
SB RAS, Lab Opt Mat & Struct, Inst Semicond Phys, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Univ St Andrews, Sch Chem, EaSTCHEM, St Andrews KY16 9ST, Fife, Scotland
Natl Cent Univ, Ctr Neutron Beam Applicat, Zhongli 320, Taiwan
Natl Synchrotron Radiat Res Ctr, Hsinchu 300, Taiwan
Chongqing Univ Posts & Telecommun, Coll Math & Phys, Chongqing 400065, Peoples R China
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia

Доп.точки доступа:
Li, G.; Lin, C. C.; Chen, W.-T.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Atuchin, V. V.; Chiang, C.-Y.; Zhou, W.; Wang, C.-W.; Li, W.-H.; Sheu, H.-S.; Chan, T.-S.; Ma, C.; Liu, R.-S.
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    Enhanced green emission and thermal stability of Ba3Si6O12N2:Eu2+ by Ce3+/P5+-doping: Unity energy transfer, charge compensation and lattice strain release / J. Hao, M. Tao, Z. Gao [et al.] // J. Lumines. - 2020. - Vol. 220. - Ст. 116995, DOI 10.1016/j.jlumin.2019.116995. - Cited References: 66. - This work is financially supported by the National Natural Science Foundation of China (NSFC No. 51672259 , 51601131 ) and the Fundamental Research Fund for National Universities , China University of Geosciences (Wuhan) . - ISSN 0022-2313
   Перевод заглавия: Улучшенное зеленое излучение и термическая стабильность Ba3Si6O12N2:Eu2 + путем легирования Ce3+/P5+: передача энергии, компенсация заряда и снятие деформации решетки
Кл.слова (ненормированные):
Oxonitridosilicate -- Green phosphor -- Unity energy transfer -- Charge compensation -- Thermal stability improvement
Аннотация: To optimize luminescence properties of oxonitridosilicate phosphors are extremely necessary for improving lighting quality of white light-emitting diodes (WLEDs). Herein, we designed Ce3+, Eu2+ codoping and P5+-Si4+ substitution in the presentative Ba3Si6O12N2:Eu2+ green phosphor to realize an enhancement of luminescence efficiency and thermal stability. Rietveld refinement results of Ce3+, Eu2+, P5+-doped Ba3Si6O12N2 (BSON) confirmed the formation of pure trigonal phase (P-3) of Ba3Si6O12N2 and the successful doping of Ce3+, Eu2+, P5+ ions. Ce3+ and Eu2+ ions randomly occupy two Ba crystallographic sites. Interestingly, a near unity energy transfer (ET, ~100%) from Ce3+ ions to Eu2+ ions is observed. Meanwhile, the doping of P5+ ions into BSON also helps improving the luminescence efficiency and thermal stability, which should be attributed to the charge compensation and the relax of lattice strain. In addition, the white light emitting diodes (WLEDs) fabricated by employing P5+-doped BSON: Eu2+ present a better electroluminescence performance than BSON: Eu2+. This study could serve as a guide in developing optimized oxonitridosilicates phosphors with improved luminescence performances based on complete energy transfer and lattice variations in local coordination environments through cation substitutions, and the as-prepared Ce3+/P5+-codoped Ba3Si6O12N2:Eu2+ could be an excellent green-emitting phosphor for UV-to-Visible LED chips pumped WLEDs.

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Держатели документа:
Engineering Research Center of Nano-Geomaterials of Ministry of Education, Faculty of Materials Science and Chemistry, China University of Geosciences, 388 Lumo Road, Wuhan, 430074, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, 660036, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Hao, J.; Tao, M.; Gao, Z.; Chen, S.; Liu, Y.; Wang, H.; Wei, Y.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Li, G.
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