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Каталог книг и брошюр библиотеки ИФ СО РАН

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    Layered hydroxyl sulfate: Controlled crystallization, structure analysis, and green derivation of multi-color luminescent (La,RE)2O2SO4 and (La,RE)2O2S phosphors (RE = Pr, Sm, Eu, Tb, and Dy) / X. Wang [et al.] // Chem. Eng. J. - 2016. - Vol. 302. - P. 577-586, DOI 10.1016/j.cej.2016.05.089. - Cited References: 50. - This work is supported in part by the National Natural Science Foundation of China (Grants Nos. 51172038, 51302032, and U1302272), the Fundamental Research Fund for the Central Universities (Grant No. N140204002), Grants-in-Aid for Scientific Research (KAKENHI No. 26420686), and the Russian Foundation for Basic Research (15-52-53080). X.J. Wang acknowledges financial support from the China Scholarship Council for her overseas Ph.D. study (Contract No. 201406080035) and the assistance of Q. Q. Zhu (University of Science and Technology of China) for his help with calcination. . - ISSN 1385-8947
   Перевод заглавия: Слоистые гидроксил сульфаты: контролируемая кристаллизация, структурный анализ, и зеленый синтез мультицветных люминофоров (La,RE)2O2SO4 и (La,RE)2O2S (RE=Pr, Sm, Eu, Tb, and Dy)

РУБ Engineering, Environmental + Engineering, Chemical
Рубрики:
PHOTOLUMINESCENCE PROPERTIES
   OXYSULFATE/OXYSULFIDE SYSTEMS
   CRYSTAL-STRUCTURE
   OXYGEN-STORAGE
   Ln
   NANOCOMPOSITES
   EMISSION
   CAPACITY
   FAMILY
   FABRICATION
Кл.слова (ненормированные):
Sulfate type layered rare earth hydroxide -- Luminescence -- Oxysulfate -- Oxysulfide
Аннотация: The two important groups of Ln2O2SO4 and Ln2O2S compounds are traditionally synthesized with the involvements of environmentally harmful sulfur-containing reagents. We developed in this work a unique green approach for their synthesis, using Ln2(OH)4SO4·2H2O layered hydroxyl sulfate as the precursor (Ln-241 phase). Phase selective crystallization of La-241 under both atmospheric pressure and hydrothermal conditions was firstly optimized, followed by transformation into La2O2S and La2O2SO4 by controlled calcination. Rietveld structure refinement was performed for La-241, La(OH)SO4, La2O2SO4, and La2O2S, and the crystal structure and cell parameters of La-241 were originally reported. The photoluminescence performances of several important activators (Pr3+, Sm3+, Eu3+, Tb3+, and Dy3+) in the two hosts, in terms of excitation, emission, quantum yield, and color coordinates of emission, were thoroughly investigated, and multi-color luminescence including bright red, green, orange red, and yellow was obtained under ultraviolet excitation. Detailed investigations of Tb3+ photoluminescence revealed that the lack of 5D3 emission in La2O2S and the gradual quenching of 5D3 blue emission at a higher Tb3+ content (hence decreasing I488/I545 ratio and changing color coordinates) in La2O2SO4 were suggested to be due to thermal activation of the 5D3 electrons into the conduction band and cross relaxation between adjacent Tb3+, respectively. The synthesis approach developed in this work for La2O2SO4 and La2O2S, with water vapor as the only exhaust gas, is environmentally benign and holds great potential in the facile synthesis of analogous compounds of other lanthanides. © 2016 Elsevier B.V.

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Держатели документа:
Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials Science and Engineering, Northeastern University, Shenyang, Liaoning, China
Advanced Materials Processing Unit, National Institute for Materials Science, Tsukuba, Ibaraki, Japan
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation

Доп.точки доступа:
Wang, X.; Li, J. -G.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zhu, Q.; Li, X.; Sun, X.
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Correlation between the magnetic and electrical properties of the (VS)(x)(Fe2O3)(2-x) oxysulfide system / G. V. Loseva [et al.] // Phys. Solid State. - 2000. - Vol. 42, Is. 4. - P. 730-733, DOI 10.1134/1.1131281. - Cited References: 7 . - ISSN 1063-7834

РУБ Physics, Condensed Matter

Аннотация: The correlation between the magnetic and electrical properties of the (VS)(x)(Fe2O3)(2-x) (0.9 x 1.25) oxysulfide solid solutions has been studied. The crossover of conductivity from the semimetallic to semiconducting type is accompanied by changes in the magnetic susceptibility, which are characteristic of the transition from delocalized to localized electrons. For x

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Держатели документа:
Kirenskii Inst. of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
ИФ СО РАН

Доп.точки доступа:
Loseva, G. V.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Chernov, V. K.; Ivanova, N. B.; Иванова, Наталья Борисовна; Kiselev, N. I.; Bovina, A. V.
}
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    Hydrothermal crystallization of a Ln2(OH)4SO4·nH2O layered compound for a wide range of Ln (Ln = La-Dy), thermolysis, and facile transformation into oxysulfate and oxysulfide phosphors / X. Wang [et al.] // RSC Adv. - 2017. - Vol. 7, Is. 22. - P. 13331-13339, DOI 10.1039/c7ra00645d. - Cited References: 54. - This work was partly supported by the National Natural Science Foundation of China (Grants No. 51672039, 51172038, and 51302032), the Fundamental Research Fund for the Central Universities (Grant No. N140204002), the Grants-in-Aid for Scientific Research (KAKENHI No. 26420686), and the Russian Foundation for Basic Research (15-52-53080). Xuejiao Wang acknowledges the financial support received from the China Scholarship Council for her overseas Ph. D. study at the National Institute of Materials Science (Contract No. 201406080035). . - ISSN 2046-2069
   Перевод заглавия: Гидротермальная кристаллизация слоистых соединений Ln2(OH)4SO4·nH2O с широким диапазоном Ln (Ln = La-Dy), термолиз и плавный переход в оксисульфатные и оксисульфидные люминофоры
Кл.слова (ненормированные):
Dysprosium -- Hydrothermal synthesis -- Light emission -- Phase structure -- Phosphors -- Rare earth elements -- Acceleration voltages -- Chemical compositions -- Electron beam irradiation -- Hydrothermal conditions -- Hydrothermal crystallization -- Lanthanide contraction -- Photoluminescence properties -- Structure refinements -- Dysprosium compounds
Аннотация: The synthesis of a layered Ln2(OH)4SO4·nH2O material (Ln-241) with a smaller lanthanide ion (Dy3+) was successfully achieved through the optimization of the hydrothermal conditions, and the effect of lanthanide contraction on the chemical composition, phase structure, and crystallite/particle morphology of the products was investigated and discussed. Structure refinement showed that the lattice parameters (a, b, and c), cell volume, and axis angle across the series (Ln = La-Dy) monotonously decrease as the size of Ln3+ decreases. Comparative TG/DTA analysis in air indicated that the dehydroxylation temperature of Ln-241 tends to increase, whereas the dehydration and desulfurization temperatures decrease as the size of Ln3+ decreases, thus narrowing the stable temperature range for Ln2O2SO4. Taking advantage of the fact that Ln-241 has exactly the same Ln/S molar ratio as Ln2O2SO4 and Ln2O2S, the latter two groups of important compounds (excluding Ce) were facilely transformed from the former via the removal of water by calcination. The photoluminescence properties of Eu3+ and Tb3+, in terms of excitation, emission, fluorescence decay, quantum yield, and emission color, were investigated and compared for the two hosts Gd2O2S and Gd2O2SO4, and the (Gd0.99Tb0.01)2O2S phosphor was shown to be stable under electron beam irradiation in the studied range and exhibited an increasingly higher emission brightness as the acceleration voltage (up to 7 kV) or beam current (up to 50 μA) increased.

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Держатели документа:
Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), Northeastern University, Shenyang, Liaoning, China
Institute of Ceramics and Powder Metallurgy, School of Materials Science and Engineering, Northeastern University, Shenyang, Liaoning, China
Research Centre for Functional Materials, National Institute for Materials Science, Tsukuba, Ibaraki, Japan
College of New Energy, Bohai University, Jinzhou, Liaoning, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou, Jiangsu, China
World Premier International Centre for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, Tsukuba, Ibaraki, Japan

Доп.точки доступа:
Wang, X.; Li, J. -G.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Liu, W.; Zhu, Q.; Tanaka, H.; Suzuta, K.; Kim, B. -N.; Sakka, Y.
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Properties of oxysulfide phases and phase diagram of the Nd2S3–Nd2O3 system / S. А. Osseni, P. O. Andreev, A. A. Polkovnikov [et al.] // J. Solid State Chem. - 2022. - Vol. 314. - Ст. 123438, DOI 10.1016/j.jssc.2022.123438. - Cited References: 51. - This research was funded by the Tyumen Oblast Government , as part of the West-Siberian Interregional Science and Education Center's project No. 89-DON (3) . - ISSN 0022-4596
Кл.слова (ненормированные):
Neodymium sulfide -- Neodymium oxysulfide -- Structure -- Melting enthalpy -- Phase diagram -- Optical bandgap
Аннотация: We have determined the thermal characteristics and optical properties of the sulfide and oxysulfide phases in the Nd2S3 - Nd2O3 system. A congruent melting peak at temperature 1801 ± 4.9 °C with ΔH = 65.2 ± 6.7 kJ/mol was detected for the Nd2S3 compound by the DSC method. The characteristics of the α-Nd2S3 → γ-Nd2S3 polymorphic transition are t = 1183 ± 1.8°С, and ΔH = 7.5 ± 0.3 kJ/mol. The γ-Nd2S3 phase obtained upon cooling during annealing at 800 °C is retained for up to 30 h, and then the γ-Nd2S3 → α-Nd2S3 transition occurs within 20 h. The microhardness of the phases is: α-Nd2S3 H = 451 ± 4 HV; γ-Nd2S3 H = 531 ± 4 HV. It was found by the TG method that the Nd10S14O phase thermally dissociates at temperatures above 1400 °C. The mass loss is 0.5 mass % at 1580 °C and 1.0 mass % at 1620 °C, but the samples remain single-phase ones after cooling. However, two impurity phases γ-Nd2S3-X and Nd2O2S appear in the Nd10S14O samples treated at temperatures above 1620 ± 20 °C. For samples of the Nd10S14O phase annealed in an argon atmosphere at temperatures of 1050, 1400, 1580 °C, a regular decrease in the unit cell parameters and optical band gap was recorded: 1050 °C a = 15.06291(28), c = 19.97864(35), Eg = 2, 63 eV, 1400 °C a = 15.04779(36), c = 19.97160(44), Eg = 2.64 eV; 1580 °C a = 15.03532(48), c = 19.94984(60), Eg = 2.51 eV. The microhardness of Nd10S14O is H = 549 ± 10 HV. The Nd2O2S phase has H = 593 ± 4 HV, Eg = 4.28 eV. The phase diagram of the Nd2S3 - Nd2O3 system from 1000 °C to the melt was constructed. The Nd2O2S phase melts congruently at 2050 ± 30 °C. Eutectics with coordinates 23 mol. % Nd2O3 (0.3484 Nd10S14O + 0.6516 Nd2O2S), t = 1553 ± 1.8°С; ΔH = 187 ± 19 J/g; 82 mol. % Nd2O3; (0.54 Nd2O2S + 0.46 Nd2O3), t = 1970 ± 30°С were obtained. The liquidus of the Nd2S3 - Nd2O3 system was built according to DSC data and calculated using the Redlich-Kister equation. The melting enthalpy of Nd2O2S ΔH = 67 kJ/mol was calculated using the Schroeder equation.

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Держатели документа:
Kaba Chemistry and Applications Research Laboratory, Faculty of Sciences and Technologies of Natitingou/ National University of Science, Technology, Engineering and Mathematics (UNSTIM), Abomey, BP: 2282, Benin
Institute of Chemistry, Tyumen State University, Tyumen, Volodarsky str. 6625003, Russian Federation
Boreskov Institute of Catalysis SB RAS, Novosibirsk, Lavrentiev Ave. 5630090, Russian Federation
Novosibirsk State University, Novosibirsk, Pirogova str. 2630090, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Akademgorodok str. 50, building 38660036, Russian Federation
Siberian Federal University, Krasnoyarsk, Svobodnyj av. 79660079, Russian Federation
Institute of Natural Sciences and Mathematics, Kurgan state University, Kurgan, Sovetskaya str. 2, b. 4640020, Russian Federation
Tyumen Industrial University, Tyumen, Volodarsky str 38625000, Russian Federation
Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Pervomaiskaya str. 91620990, Russian Federation

Доп.точки доступа:
Osseni, S. А.; Andreev, P. O.; Polkovnikov, A. A.; Zakharov, B. A.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Abulkhaev, M. U.; Volkova, S. S.; Kamaev, D. N.; Kovenskiy, I. M.; Nesterova, N. V.; Kudomanov, M. V.; Andreev, O. V.
}
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