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1.


   
    F-19-NMR study of the structure of SR0.75ND0.25F2.25 solid electrolyte / A. N. Matsulev [et al.] // Fiz. Tverd. Tela. - 1987. - Vol. 29, Is. 11. - P. 3247-3252. - Cited References: 14 . - ISSN 0367-3294
РУБ Physics, Condensed Matter


WOS
Доп.точки доступа:
Matsulev, A. N.; Buznik, V. M.; Livshits, A. I.; Fedorov, P. P.; Sobolev, B. P.
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2.


    Markevich, I. A.
    Impedance Spectroscopy Study of a Polymer Composite with Carbon Nanotubes in Contact with an Electrolyte / I. A. Markevich, N. A. Drokin, G. E. Selyutin // Tech. Phys. - 2019. - Vol. 64, Is. 9. - P. 1324-1329, DOI 10.1134/S1063784219090093. - Cited References: 14 . - ISSN 1063-7842. - ISSN 1090-6525
РУБ Physics, Applied
Рубрики:
BEHAVIOR
   CONDUCTIVITY

   RELAXATION

Кл.слова (ненормированные):
impedance spectroscopy -- nanotubes -- electrolyte
Аннотация: The measured frequency dependence of the electric impedance of a composite based on ultra-high molecular weight polyethylene reinforced with carbon nanotubes in contact with an electrolyte is presented. The behavior of the active and reactive impedance components, permittivity, and conductivity in the frequency range from 0.1 Hz to 120 MHz is analyzed. An equivalent electric circuit simulating the dispersion of the impedance of the polymer composite making contact with the electrolyte is proposed. The formation of a double electric layer at the interface between the polymer composite and electrolyte layer is demonstrated and the electrical characteristics of this layer are determined.

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Публикация на русском языке Маркевич И. А. Исследование методом импедансной спектроскопии полимерного композита с углеродными нанотрубками в контакте с электролитом [Текст] / И. А. Маркевич, Н. А. Дрокин, Г. Е. Селютин // Журн. техн. физ. - 2019. - Т. 89 Вып. 9. - С. 1400-1405

Держатели документа:
Russian Acad Sci, Krasnoyarsk Sci Ctr, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Krasnoyarsk Sci Ctr, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Drokin, N. A.; Дрокин, Николай Александрович; Selyutin, G. E.
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3.


   
    An update on inert anodes for aluminium electrolysis / A. S. Yasinskiy, S. K. Padamata, P. V. Polyakov, A. V. Shabanov // Non-Ferrous Met. - 2020. - Vol. 48, Is. 1. - P. 15-23, DOI 10.17580/nfm.2020.01.03. - Cited References: 62. - The work is performed as a part of the state assignment for the science of Siberian Federal University, project number FSRZ-2020-0013. Use of equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS” is acknowledged . - ISSN 2072-0807
Кл.слова (ненормированные):
Inert anodes -- aluminium electrolysis -- CO2 emission -- metallic anode -- cermet anode -- ceramic anode -- oxygenevolving electrode -- fluoride melt -- corrosion -- oxidation -- low-temperature electrolyte -- Hall-Heroult cell
Аннотация: This update includes the literature related to the inert anodes which were published in the past decade. The metallic anodes are widely regarded as promising candidates to replace the carbon anodes due to its attractive properties like good electrical conductivity, easy to manufacture and high resistance to high thermal shocks. The metals have been tested in pure state and alloy (binary, ternary) form. The oxide scale formed on the anode surface acts as a barrier between the electrolyte and the anode, which protects the anode from being dissolved. The layer of molten fluorides is formed between the scale and the metal anode after a certain time of polarization, and the oxide scale acts as a bipolar electrode. Metal like Cu is reduced at the internal side of the scale. This paper elaborates the effects of various parameters on the performance of the anode. Cu-based alloys (Cu – Ni – Fe and Cu – Al) have shown promising results and could perform well in low-temperature electrolytes. It has been well established that the Cu content in Cu – Ni – Fe and Cu – Al alloys plays a major role in the metal dissolution as the CuO/Cu2O scales formed on the outer layer act as a sacrificial one. The corrosion rate of an anode can be reduced by decreasing the operating temperature, which is possible by using the KF – AlF3 melts. The use of suspensions can increase the purity of the produced metal by stop-ping the anode products to come in contact with cathode metal. Many industries including RUSAL and ELYSIS are still conducting a considerable amount of research to develop an inert anode and are expecting to have a carbon-free cell in the nearest future.

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Держатели документа:
Laboratory of Physics and Chemistry of Metallurgical Processes and Materials, Siberian Federal University, Krasnoyarsk, Russian Federation
Laboratory of Molecular Spectroscopy, Krasnoyarsk Science Center SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Yasinskiy, A. S.; Padamata, S. K.; Polyakov, P. V.; Shabanov, A. V.; Шабанов, Александр Васильевич
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