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    Solid-state synthesis, characterization, UV-induced coloration and photocatalytic activity – The Sr6Bi2O11, Sr3Bi2O6 and Sr2Bi2O5 bismuthates / D. S. Shtarev [et al.] // Catal. Today. - 2020. - Vol. 340. - P. 70-85, DOI 10.1016/j.cattod.2018.09.035. - Cited References: 52. - The research was kindly funded by a grant from the Russian Science Foundation (project No. 17-73-00007). P.D. Murzin, A.V. Rudakova and V.K. Ryabchuk are grateful for financial support by the Mega-grant (No. 14.Z50.31.0016 ) from the Government of the Russian Federation within the Project “Establishment of the Laboratory of Photoactive Nanocomposite Materials” . The authors are very grateful to the staff of the Khabarovsk Innovation and Analytical Center of the Yu. A. Kosygin Institute of Tectonics and Geophysics FEB RAS, and the Resource Centers of the Research Park at the Saint-Petersburg State University: (i) Center for Diagnostics of Functional Materials for Medicine, Pharmacology and Nanoelectronics, (ii) Center for Physical Methods of Surface Investigation, (iii) Center for Optical and Laser Materials Research, and (iv) the Nanophotonics Center for their valuable assistance in carrying out the research and in providing the needed equipment. One of us (NS) is grateful to Prof. Angelo Albini for his continued hospitality in the PhotoGreen Laboratory at the University of Pavia, Italy. . - ISSN 0920-5861
   Перевод заглавия: Твердотельный синтез, характеризация, УФ-окрашивание и фотокаталитическая активность висмутатов Sr6Bi2O11, Sr3Bi2O6 и Sr2Bi2O5
Кл.слова (ненормированные):
Photocatalysts -- Strontium bismuthates -- Photocatalytic activity -- UV-induced coloration
Аннотация: This article reports on two novel strontium bismuthate photocatalysts (Sr6Bi2O11 and Sr3Bi2O6) prepared by a solid-state synthesis for which the number of strontium atoms exceeds the number of bismuth atoms in the cation sublattice; for comparison, the bismuthate Sr2Bi2O5 was also re-examined. All three bismuthates were characterized by a variety of spectroscopic techniques (XRD, XPS, EDX, DR, Raman, SEM, and EIS). Direct bandgap energies for the three bismuthates were assessed from diffuse reflectance spectra: 2.61 eV for Sr6Bi2O11; 3.40 eV for Sr3Bi2O6; 3.17 eV for Sr2Bi2O5, while the flatband potentials (versus NHE) of the corresponding valence bands were estimated from XPS spectra: +2.22 eV for Sr6Bi2O11; +1.71 eV for Sr3Bi2O6; +1.61 eV for Sr2Bi2O5. The two novel bismuthates displayed photocatalytic activity toward the photodegradation of acetaldehyde in the gas phase and phenol in aqueous media, with the Sr6Bi2O11 system exhibiting significantly greater photoactivity vis-à-vis the Sr3Bi2O6 bismuthate; by comparison, Sr2Bi2O5 was photocatalytically inactive in this case; their photoactivity was also assessed from the photodegradation of phenol in aqueous media (in all cases using UV-Vis irradiation from a Xe light source). Detailed photocatalytic mechanisms are proposed based on UV-induced coloration studies (carried out using a high-pressure Hg lamp; 365 nm) and on the photodegradation in the presence of radical scavengers to explain how composition and structure of the three bismuthates affect their photocatalytic activity. The role of point defects (oxygen vacancies) in their crystal lattice is described as they affect photocatalytic activity by acting as electron traps and potentially as electron/hole recombination centers.

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Держатели документа:
Yu. A. Kosygin Institute of Tectonics and Geophysics, Far Eastern branch of the Russian Academy of Sciences, 65 Kim Yu Chen Street, Khabarovsk, 680063, Russian Federation
Far Eastern State Transport University, 47 Seryshev Street, Khabarovsk, 680021, Russian Federation
St. Petersburg State University, Ulianovskaya 2, Petergof, Saint-Petersburg, 198904, Russian Federation
Kirensky Institute of Physics, Akademgorodok 50, bld. 38, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, 79 Svobodny pr., Krasnoyarsk, 660041, Russian Federation
PhotoGreen Laboratory, Dipartimento di Chimica, Universita di Pavia, via Taramelli 12, Pavia, 27100, Italy

Доп.точки доступа:
Shtarev, D. S.; Shtareva, A. V.; Ryabchuk, V. K.; Rudakova, A. V.; Murzin, P. D.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Koroleva, A. V.; Blokh, A. I.; Serpone, N.
}
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    About photocatalytic properties of some heterostructures based on strontium bismuthate / D. S. Shtarev [et al.] // Key Eng. Mater. - 2019. - Vol. 806 KEM. - P. 161-166, DOI 10.4028/www.scientific.net/KEM.806.161. - Cited References: 9. - The research was carried out at the expense of a grant from the Russian Science Foundation (project No. 17-73-00007). . - ISSN 1013-9826
   Перевод заглавия: О фотокаталитических свойствах некоторых гетероструктур на основе висмутата стронция
Кл.слова (ненормированные):
Alkaline earth metal bismuthate -- Diffuse reflectance spectroscopy -- Heterostructure -- Photocatalytic activity -- Strontium bismuthate -- Visible light active photocatalysts
Аннотация: In the work, some heterostructures consisting of two different strontium bismuthates from the following series are investigated: Sr2Bi2O5, Sr3Bi2O6 and Sr6Bi2O11. It is shown that the creation of such heterostructures affects both optical and photocatalytic properties. The results obtained are promising for the further development and research of new heterostructures based on two different strontium bismuthates and for studying the characteristics of their photocatalytic activity. © 2019 Trans Tech Publications Ltd, Switzerland

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Держатели документа:
Institute of Tectonics and Geophysics Named After Yu.A. Kosygin of Far Eastern Branch of the Russian Academy of Sciences, Khabarovsk, Russian Federation
Far Eastern State Transport University, 47 Seryshev St., Khabarovsk, 680021, Russian Federation
Kirensky Institute of Physics, Akademgorodok 50, bld. 38, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, 79 Svobodny pr., Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Shtarev, D. S.; Shtareva, A. V.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Syuy, A. V.; Nashchochin, E. O.; Asian School-Conference on Physics and Technology of Nanostructured Materials(4 ; 2018 ; Sept. ; 23-28 ; Vladivostok)
}
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    Phenomenological rule from correlations of conduction/valence band energies and bandgap energies in semiconductor photocatalysts: calcium bismuthates versus strontium bismuthates / D. S. Shtarev, V. K. Ryabchuk, A. V. Rudakova [et al.] // ChemCatChem. - 2020. - Vol. 12, Is. 6. - P. 1551-1555, DOI 10.1002/cctc.201902236. - Cited References: 13. - The research was supported from a grant from the Russian Science Foundation (project No. 19-73-10013). We are very grateful to the staff of the Khabarovsk Innovation and Analytical Center of the Yu. A. Kosygin Institute of Tectonics and Geophysics FEB RAS, and of the Research Center on Nanophotonics and the Center for Physical Methods of Surface Investigation (to Dr. Alexandra Koroleva) of the Research Park at Saint-Petersburg State University for their valuable assistance in carrying out the research and in providing the needed equipment. VKR and AVR acknowledge financial support from a grant by the Saint-Petersburg State University (Pure ID 39054581). One of us (NS) thanks Prof. A. Albini and the staff of the PhotoGreen Laboratory of the University of Pavia for their continued hospitality . - ISSN 1867-3880. - ISSN 1867-3899
   Перевод заглавия: Феноменологическое правило из соотношений энергий проводимости / валентной зоны и энергий запрещенной зоны в полупроводниковых фотокатализаторах: висмутаты кальция против висмутатов стронция

РУБ Chemistry, Physical
Рубрики:
STRUCTURAL-PROPERTIES
Кл.слова (ненормированные):
calcium bismuthates -- strontium bismuthates -- bandgap energies -- semiconductor photocatalysts -- linear correlation of ECB/EVB with Ebg
Аннотация: A number of calcium bismuthates were synthesized (25 to 50 mol% in Ca) and characterized by XRD, SEM, EDX, XPS and DRS techniques; the latter provided an estimate of the bandgap energies (Ebg=2.41 to 3.29 eV) via Tauc plots for indirect transitions, whereas XPS established the potentials (vs NHE) of their respective valence bands (and thus the conduction bands). Linear correlations existed between EVB/ECB and Ebg that when compared with those of strontium bismuthates (reported earlier) showed that differences in energies at Ebg=0 eV are related to the difference in the absolute electronegativities of Ca and Sr, from which the following empirical phenomenological rule is postulated: replacing one alkaline earth metal in bismuthates by another causes the points of intersection of the linear correlations ECB(Ebg) and EVB(Ebg) to be displaced by an amount equal to twice the difference in absolute electronegativities of these metals.

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Держатели документа:
Russian Acad Sci, Yu A Kosygin Inst Tecton & Geophys, Far Eastern Branch, 65 Kim Yu Chen St, Khabarovsk 680063, Russia.
Far Eastern State Transport Univ, 47 Seryshev St, Khabarovsk 680021, Russia.
St Petersburg State Univ, Dept Photon, Ulyanovskaya 1, St Petersburg 198904, Russia.
St Petersburg State Univ, Lab Photoact Nanocomposite Mat, Ulyanovskaya 1, St Petersburg 198904, Russia.
Kirensky Inst Phys, Akademgorodok 50,Bld 38, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, 79 Svobodny Pr, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Inst Mat Sci, Khabarovsk Sci Ctr, Far East Branch, 153 Tihookeanskaya St, Khabarovsk 680000, Russia.
Univ Pavia, Dipartimento Chim, PhotoGreen Lab, Via Taramelli 12, I-27100 Pavia, Italy.

Доп.точки доступа:
Shtarev, D. S.; Ryabchuk, V. K.; Rudakova, A. V.; Shtareva, A. V.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Kirichenko, E. A.; Serpone, N.; Russian Science FoundationRussian Science Foundation (RSF) [19-73-10013]; Saint-Petersburg State University [39054581]
}
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    New titania-based photocatalysts for hydrogen production from aqueous-alcoholic solutions of methylene blue / D. V. Markovskaya, A. V. Zhurenok, A. Y. Kurenkova [et al.] // RSC Adv. - 2020. - Vol. 10, Is. 56. - P. 34137-34148, DOI 10.1039/d0ra07630a. - Cited References: 57. - The XPS and XRD experiments were performed using facilities of the shared research center "National center for investigation of catalysts" at Boreskov Institute of Catalysis. The authors are grateful to Dr S. Cherepanova for the XRD study and Dr T. Larina and Dr D. Selishchev for the UV-vis measurements. The TEM investigations were conducted in the SFU Joint Scientific Center supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation . - ISSN 2046-2069
   Перевод заглавия: Новые катализаторы, основанные на диоксиде титана, для производства водорода из водно-спиртовых растворов метиленовой сини

РУБ Chemistry, Multidisciplinary
Рубрики:
Ray absorption-edge
   In-situ
   Ag nanoparticles
   Chemical-states
   XPS analysis
Аннотация: A series of CuOx–TiO2 photocatalysts were prepared using fresh and thermally activated Evonik Aeroxide P25 titanium dioxide. The photocatalysts were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, XANES, diffuse reflectance spectroscopy, and N2 adsorption technique. Photocatalytic activity of the samples was tested in hydrogen production from aqueous-alcoholic solutions of methylene blue under UV radiation (λ = 386 nm). It was found for the first time the synergistic effect of hydrogen production from two substrates—dye and ethanol. The maximum hydrogen production rate in the system water–ethanol–methylene blue was 1 μmol min−1, which is 25 times higher than a value measured in a 10% solution of ethanol in water. The thermal activation of titania also leads to a change in the rate of hydrogen production. The highest catalytic activity was observed for a CuOx–TiO2 photocatalyst based on titania thermally-activated at 600 °C in air. A mechanism of the photocatalytic reaction is discussed.

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Держатели документа:
Boreskov Inst Catalysis, Fed Res Ctr, Lavrentiev Ave 5, Novosibirsk 630090, Russia.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Akademgorodok 50-38, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, 79 Svobodny Pr, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Markovskaya, Dina, V; Zhurenok, Angelina, V; Kurenkova, Anna Yu; Kremneva, Anna M.; Saraev, Andrey A.; Zharkov, S. M.; Жарков, Сергей Михайлович; Kozlova, Ekaterina A.; Kaichev, Vasily V.
}
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Theoretical investigation of the prospect to tailor ZnO electronic properties with VP thin films / A. S. Kholtobina, E. A. Kovaleva, J. Melchakova [et al.] // Nanomaterials. - 2021. - Vol. 11, Is. 6. - Ст. 1412, DOI 10.3390/nano11061412. - Cited References: 75. - This research was funded by the Russian Science Foundation, grant number 20-73-00179. The authors would like to thank the Information Technology Centre, Novosibirsk State University for providing access to their supercomputers . - ISSN 2079-4991
Кл.слова (ненормированные):
ZnO -- vanadium phosphide -- thin films -- nanocomposite -- photocatalysts -- density functional theory
Аннотация: The atomic and electronic structure of vanadium phosphide one-to four-atomic-layer thin films and their composites with zinc oxide substrate are modelled by means of quantum chemistry. Favorable vanadium phosphide to ZnO orientation is defined and found to remain the same for all the structures under consideration. The electronic structure of the composites is analyzed in detail. The features of the charge and spin density distribution are discussed.

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Держатели документа:
Materials Science and Engineering, Industrial Engineering & Management School, KTH Royal Institute of Technology, Brinellvagen 23, Stockholm, 11428, Sweden
Kirensky Institute of Physics, Federal Research Center KSC Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, bld. 38, Krasnoyarsk, 660036, Russian Federation
Faculty of Physics, Tomsk State University, 36 Lenin Ave, Tomsk, 634050, Russian Federation

Доп.точки доступа:
Kholtobina, A. S.; Kovaleva, E. A.; Ковалева, Евгения Андреевна; Melchakova, J.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Kuzubov, A. A.; Кузубов, Александр Александрович
}
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