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Peculiarities in the magnetic, magnetoelectric, and magnetoelastic properties of SmFe3(BO3)(4) multiferroic / Y. F. Popov [et al.] // J. Exp. Theor. Phys. - 2010. - Vol. 111, Is. 2. - P. 199-203, DOI 10.1134/S1063776110080066. - Cited References: 14. - This study was supported in part by the Russian Foundation for Basic Research (project no. 10-02-00846-a). . - ISSN 1063-7761

РУБ Physics, Multidisciplinary
Рубрики:
GDFE3(BO3)(4)
Кл.слова (ненормированные):
External magnetic field -- Field dependence -- Field directions -- G factors -- Induced polarization -- Iron borate -- Magnetoelastic properties -- Multiferroics -- Samarium-ion -- Samarium-iron -- Temperature dependence -- Magnetic fields -- Magnetic susceptibility -- Magnetostriction -- Polarization -- Samarium -- Single crystals -- Samarium compounds
Аннотация: Results of a complex investigation of the magnetic, magnetoelectric, and magnetoelastic properties of a SmFe3(BO3)(4) single crystal are presented. Samarium iron borate is similar to another easy-plane iron borate, NdFe3(BO3)(4), in that it possesses a large value of the magnetic-field-induced polarization (about 500 mu C/m(2)), the sign of which changes when the field direction is changed between axes a and b of the crystal. However, the temperature dependence of the magnetic susceptibility and the field dependence of polarization and magnetostriction of the two compounds are significantly different, which is explained by the weak effect of external magnetic field on the ground-state multiplet of samarium ion, which is characterized by an extremely small value of its g-factor.

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Держатели документа:
[Popov, Yu. F.
Pyatakov, A. P.
Kadomtseva, A. M.
Vorob'ev, G. P.] Moscow MV Lomonosov State Univ, Dept Phys, Moscow 119991, Russia
[Pyatakov, A. P.
Zvezdin, A. K.
Mukhin, A. A.
Ivanov, V. Yu.] Russian Acad Sci, Prokhorov Gen Phys Inst, Moscow 119991, Russia
[Gudim, I. A.] Russian Acad Sci, Siberian Branch, Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
ИФ СО РАН
Department of Physics, Moscow State University, Moscow 119991, Russian Federation
Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow 119991, Russian Federation
Kirenskii Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Popov, Y. F.; Pyatakov, A. P.; Kadomtseva, A. M.; Vorob'ev, G. P.; Zvezdin, A. K.; Mukhin, A. A.; Ivanov, V. Y.; Gudim, I. A.; Гудим, Ирина Анатольевна
}
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Kikoin, K. A.
A novel explanation of the phase-transition with the valence change in cation-substituted samarium monochalcogenides / K. A. Kikoin, E. G. Goryachev, V. A. Gavrichkov // Solid State Commun. - 1986. - Vol. 60, Is. 8. - P. 663-667, DOI 10.1016/0038-1098(86)90264-4. - Cited References: 21 . - ISSN 0038-1098

РУБ Physics, Condensed Matter

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Держатели документа:
LV KIRENSKII PHYS INST,KRASNOYARSK 660036,USSR
ИФ СО РАН
Доп.точки доступа:
Goryachev, E. G.; Горячев, Евгений Геннадьевич; Gavrichkov, V. A.; Гавричков, Владимир Александрович
}
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Crystal structure and properties of polymeric hexaaqua-hexakis-(2-thiobarbiturato)-disamarium(III) / N. N. Golovnev [et al.] // J. Struct. Chem. - 2017. - Vol. 58, Is. 3. - P. 539-543, DOI 10.1134/S0022476617030155. - Cited References: 17 . - ISSN 0022-4766
Кл.слова (ненормированные):
structure -- synthesis -- complex -- 2-thiobarbituric acid -- samarium(III) -- thermal decomposition -- IR spectrum
Аннотация: The structure (CIF file CCDC No. 1401886) of the hexaaqua-hexakis(2-thiobarbiturato)-disamarium [Sm2(H2O)6(HTBA)6]n polymeric complex (I), where H2ТВА is 2-thiobarbituric acid, is determined; its thermal decomposition and IR spectrum are studied. The crystals of I are monoclinic: a = 14.072(1) Å, b = 10.0842(6) Å, c = 15.323(1) Å, β = 110.408(2)°, V = 2037.9(2) Å3, space group P2/n, Z = 2. All three independent thiobarbiturate anions HTBA– coordinate to Sm3+ through oxygen atoms. To one of independent Sm3+ ions six (two terminal and four bridging) HTBA– ions and two water molecules are coordinated; the second is bonded with four bridging HTBA– and four water molecules, forming square antiprisms. The bridging HТВА–anions arrange antiprisms in layers. The structure is stabilized by hydrogen bonds and a π–π interaction between the HТВА– ions. The topology of the polymer network of I is analyzed.

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Публикация на русском языке Кристаллическая структура и свойства полимерного гексааква-гексакис(2-тиобарбитурато)-дисамария(III) [Текст] / Н. Н. Головнев [и др.] // Журн. структ. химии. - 2017. - Т. 58 № 3. - С. 567-571

Держатели документа:
Siberian Federal University, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Far Eastern State Transport University, Khabarovsk, Russian Federation
Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russian Federation
Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Krasnoyarsk State Agrarian University, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Golovnev, N. N.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Sterkhova, I. V.; Vereshchagin, S. N.; Golovneva, I. I.
}
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Structure and thermodynamic properties of the SmGaGe2O7 oxide / L. T. Denisova, M. S. Molokeev, L. A. Irtyugo [et al.] // Phys. Solid State. - 2020. - Vol. 62, Is. 2. - P. 384-387, DOI 10.1134/S1063783420020109. - Cited References: 10. - This study was carried out within the state assignment of the Ministry of Science and Higher Education of the Russian Federation to the Siberian Federal University in 2017–2019, project no. 4.8083.2017/8.9 “Formation of a Data Bank of Thermodynamic Characteristics of the Complex-Oxide Multifunctional Materials Containing Rare and Scattered Elements.” . - ISSN 1063-7834
Кл.слова (ненормированные):
samarium gallium germanate -- structure -- heat capacity
Аннотация: The SmGaGe2O7 oxide material has been obtained from initial Sm2O3, Ga2O3, and GeO2 oxides by solid-phase synthesis with annealing in air in the temperature range of 1273–1473 K. The structure of the investigated germanate (sp. gr. P21/c, a = 7.18610(9) Å, b = 6.57935(8) Å, and c = 12.7932(2) Å) has been established by X-ray diffraction and the high-temperature heat capacity has been determined by differential scanning calorimetry. Using the experimental data on Cp = f(T), the thermodynamic properties of the compound have been calculated.

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Публикация на русском языке Структура и термодинамические свойства SmGaGe2O7 [Текст] / Л. Т. Денисова, М. С. Молокеев, Л. А. Иртюго [и др.] // Физ. тверд. тела. - 2020. - Т. 62 Вып. 2. - С. 332-335

Держатели документа:
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Denisova, L. T.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Irtyugo, L. A.; Beletskii, V. V.; Belousova, N. V.; Denisov, V. M.
}
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    Synthesis of samarium oxysulfate Sm2O2SO4 in the high-temperature oxidation reaction and its structural, thermal and luminescent properties / Y. G. Denisenko, E. I. Sal'nikova, S. A. Basova [et al.] // Molecules. - 2020. - Vol. 25, Is. 6. - Ст. 1330, DOI 10.3390/molecules25061330. - Cited References: 56. - This research was funded by the Russian Foundation for Basic Research (Grants 18-02-00754, 18-32-20011) and Russian Science Foundation (project 19-42-02003). . - ISSN 1420-3049
   Перевод заглавия: Синтез оксисульфата самария Sm2O2SO4 в реакции высокотемпературного окисления и его структурные, термические и люминесцентные свойства

РУБ Biochemistry & Molecular Biology + Chemistry, Multidisciplinary
Рубрики:
RARE-EARTH SULFATES
   SPECTROSCOPIC PROPERTIES
   OXYGEN-STORAGE
   LN
   LA
Кл.слова (ненормированные):
samarium -- oxysulfate -- structure -- luminescence -- thermochemistry
Аннотация: The oxidation process of samariumoxysulfide was studied in the temperature range of 500–1000 °C. Our DTA investigation allowed for establishing the main thermodynamic (∆Hºexp = −654.6 kJ/mol) and kinetic characteristics of the process (Ea = 244 kJ/mol, A = 2 × 1010). The enthalpy value of samarium oxysulfate (ΔHºf (Sm2O2SO4(monocl)) = −2294.0 kJ/mol) formation was calculated. The calculated process enthalpy value coincides with the value determined in the experiment. It was established that samarium oxysulfate crystallizes in the monoclinic symmetry class and its crystal structure belongs to space group C2/c with unit cell parameters a = 13.7442 (2), b = 4.20178 (4) and c = 8.16711 (8)Å, β = 107.224 (1)°, V = 450.498 (9)Å3, Z = 4. The main elements of the crystalline structure are obtained and the cation coordination environment is analyzed in detail. Vibrational spectroscopy methods confirmed the structural model adequacy. The Sm2O2SO4 luminescence spectra exhibit three main bands easily assignable to the transitions from 4G5/2 state to 6H5/2, 6H7/2, and 6H9/2 multiplets.

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Держатели документа:
Ind Univ Tyumen, Dept Gen & Special Chem, Tyumen 625000, Russia.
Tyumen State Univ, Inst Chem, Tyumen 625003, Russia.
Northen Trans Ural Agr Univ, Dept Gen Chem, Tyumen 625003, Russia.
RAS, Fed Res Ctr, Kirensky Inst Phys, KSC,SB,Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Sch Engn Phys & Radioelect, Krasnoyarsk 660041, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.
RAS, Kirensky Inst Phys, Fed Res Ctr, KSC,SB,Lab Mol Spect, Krasnoyarsk 660036, Russia.
RAS, Kirensky Inst Phys, Fed Res Ctr, KSC,SB,Lab Coherent Opt, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Inst Nanotechnol Spect & Quantum Chem, Krasnoyarsk 660041, Russia.
Siberian Fed Univ, Sch Engn & Construct, Krasnoyarsk 660041, Russia.
RAS, Inst Semicond Phys, Lab Opt Mat & Struct, SB, Novosibirsk 630090, Russia.
Novosibirsk State Univ, Lab Semicond & Dielectr Mat, Novosibirsk 630090, Russia.
Kemerovo State Univ, Res & Dev Dept, Kemerovo 650000, Russia.
Tyumen State Univ, Res Resource Ctr, Nat Resource Management & Physicochem Res, Tyumen 625003, Russia.
RAS, Inst Solid State Chem, Lab Chem Rare Earth Cpds, UB, Ekaterinburg 620137, Russia.

Доп.точки доступа:
Denisenko, Yu. G.; Sal'nikova, E. I.; Basova, S. A.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Krylov, A. S.; Крылов, Александр Сергеевич; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Atuchin, V. V.; Volkova, S. S.; Khritokhin, N. A.; Andreev, O. V.; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [18-02-00754, 18-32-20011]; Russian Science FoundationRussian Science Foundation (RSF) [19-42-02003]
}
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Synthesis, crystal structure, and thermodynamic properties of CuSm2Ge2O8 / L. T. Denisova, M. S. Molokeev, Y. F. Kargin [et al.] // Russ. J. Inorg. Chem. - 2021. - Vol. 66, Is. 12. - P. 1817-1821, DOI 10.1134/S0036023621120020. - Cited References: 30. - This work was carried out with partial financial support within the framework of the State assignment for science of the Siberian Federal University, project number FSRZ2020-0013 . - ISSN 0036-0236. - ISSN 1531-8613

РУБ Chemistry, Inorganic & Nuclear
Рубрики:
TEMPERATURE HEAT-CAPACITY
   CU-O
   PREDICTION
   GERMANATES
   GROWTH
Кл.слова (ненормированные):
copper samarium germanate -- crystal structure -- high-temperature heat capacity -- thermodynamic functions
Аннотация: Copper samarium germanate CuSm2Ge2O8 have been synthesized by the ceramic method from CuO, Sm2O3, and GeO2 in air at the final calcination temperature 1273 K (200 h), and its crystal structure has been determined (space group Cm; a = 9.7592(2) Å, b = 15.2608(4) Å, c = 8.2502(2) Å, β = 148.2566(8)°, V = 646.46(3) Å3). The temperature dependence of the molar heat capacity Cp = f(T) measured in the temperature range 350–1000 K shows a maximum at Tmax = 498.5 K caused by the phase transition. Thermodynamic properties have been calculated from experimental data.

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Публикация на русском языке Синтез, кристаллическая структура и термодинамические свойства CuSm2Ge2O8 [Текст] / Л. Т. Денисова, М. С. Молокеев, Ю. Ф. Каргин [и др.] // Журн. неорг. химии. - 2021. - Т. 66 № 12. - С. 1700-1705

Держатели документа:
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Baikov Inst Met & Mat Sci, Moscow 119991, Russia.

Доп.точки доступа:
Denisova, L. T.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Kargin, Yu F.; Irtyugo, L. A.; Belousova, N., V; Denisov, V. M.; Siberian Federal University [FSRZ2020-0013]
}
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Crystal structure, absolute configuration and characteristic temperatures of SmFe3(BO3)4 in the temperature range 11-400 K / E. S. Smirnova, O. A. Alekseeva, A. P. Dudka [et al.] // Acta Crystallogr. B. - 2022. - Vol. 78, Is. 3-2, Pt. 1. - P. 546-556, DOI 10.1107/S2052520622003948. - Cited References: 43. - The authors are grateful to D. Yu. Chernyshov (SNBL, ESRF, Grenoble) for assistance in obtaining the experimental data. This work was performed using the equipment of the Shared Research Center FSRC ‘Crystallography and Photonics’ RAS supported by the Russian Ministry of Science and Higher Education. This work was supported by the Ministry of Science and Higher Education within the State assignment FSRC ‘Crystallography and Photonics’ RAS . - ISSN 2052-5206
Кл.слова (ненормированные):
samarium bismuth iron borate -- absolute configuration -- crystal structure -- multi-temperature single-crystal X-ray diffraction -- Mossbauer spectroscopy -- characteristic temperatures -- solution-melt growth
Аннотация: The crystal structure of samarium iron borate was analyzed with regard to growth conditions and temperature. The inclusion of about 7% Bi atoms in the crystals grown using the Bi2Mo3O12-based flux was discovered and there were no impurities in the crystals grown using the Li2WO4-based flux. No pronounced structural features associated with Bi inclusion were observed. The different absolute configurations of the samples grown using both fluxes were demonstrated. Below 80 K, a negative thermal expansion of the c unit-cell parameter was found. The structure of (Sm0.93Bi0.07)Fe3(BO3)4 belongs to the trigonal space group R32 in the temperature range 90–400 K. A decrease in the (Sm,Bi)—O, Sm—B, Sm—Fe, Fe—O, Fe—B and Fe—Fe distances is observed with a lowering of the temperature, B1—O does not change, B2—O increases slightly and the B2O3 triangles deviate from the ab plane. The strongest decrease in the equivalent isotropic atomic displacement parameters (Ueq) with decreasing temperature is observed for atoms Sm and O2, and the weakest is observed for B1. The O2 atoms have the highest Ueq values, the most elongated atomic displacement ellipsoids of all the atoms and the smallest number of allowed vibrational modes of all the O atoms. The largest number of allowed vibrational modes and the strongest interactions with neighbouring atoms is seen for the B atoms, and the opposite is seen for the Sm atoms. The quadrupole splitting Δ(T) of the paramagnetic Mössbauer spectra increases linearly with cooling. The Néel temperature [TN = 31.93 (5) K] was determined from the temperature dependence of the hyperfine magnetic field Bhf(T), which has a non-Brillouin character. The easy-plane long-range magnetic ordering below TN was confirmed.

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Держатели документа:
Shubnikov Institute of Crystallography of Federal Scientific Research Centre 'Crystallography and Photonics', Russian Academy of SciencesMoscow 119333, Russian Federation
Moscow State University, Faculty of GeologyMoscow 119991, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Smirnova, E. S.; Alekseeva, O. A.; Dudka, A. P.; Sorokin, T. A.; Khmelenin, D. N.; Yapaskurt, V. O.; Lyubutina, M. V.; Frolov, K. V.; Lyubutin, I. S.; Gudim, I. A.; Гудим, Ирина Анатольевна
}
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Chukalina, E. P.
Study of the magnetic properties of neodymium and samarium iron borates by the method of erbium spectroscopic probe / E. P. Chukalina, A. Jablunovskis, I. A. Gudim // Opt. Spectrosc. - 2022. - Vol. 130, Is. 1. - P. 98-104, DOI 10.21883/EOS.2022.01.52993.23-21. - Cited References: 30. - This paper was carried out under financial support of the Russian Science Foundation (grant № 19-12-00413) . - ISSN 0030-400X. - ISSN 1562-6911
Кл.слова (ненормированные):
multiferroics -- optical spectroscopy -- crystals with rare earths -- Kramers ions
Аннотация: Iron borates NdFe3(BO3)4 and SmFe3(BO3)4 activated with 1% erbium, with a huntite structure (space symmetry group R32) were investigated by the method of erbium spectroscopic probe. From an analysis of the temperature dependence of the transmission spectra in the region of the 4I15/2 → 4I13/2 transition in the Er3+ ion, it was found that both studied compounds order antiferromagnetically at TN ≈ 33 K into an easy-plane magnetic structure. No other phase transitions were found.

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Публикация на русском языке Чукалина Е. П. Исследование магнитных свойств ферроборатов неодима и самария методом спектроскопического эрбиевого зонда [Текст] / Е. П. Чукалина, А. Яблуновский, И. А. Гудим // Опт. и спектроскоп. - 2022. - Т. 130 Вып. 1. - С. 104-110

Держатели документа:
Institute of Spectroscopy, Russian Academy of Sciences, Troitsk, Moscow, Russia
Moscow Institute of Physics and Technology (National Research University), Dolgoprudny, Moscow Region, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia

Доп.точки доступа:
Jablunovskis, A.; Gudim, I. A.; Гудим, Ирина Анатольевна
}
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Crystal structure of bismuth-containing samarium iron–aluminium borates Sm1−xBixFe3−yAly(BO3)4 (x = 0.05–0.07, y = 0–0.28) in the temperature range of 25–500 K / E. S. Smirnova, O. A. Alekseeva, V. V. Artemov [et al.] // Crystals. - 2023. - Vol. 13, Is. 7. - Ст. 1128, DOI 10.3390/cryst13071128. - Cited References: 59. - This work was supported by the Russian Science Foundation (project No 23-22-00286) . - ISSN 2073-4352
Кл.слова (ненормированные):
rare-earth iron–aluminium borates -- solid solutions -- low-temperature X-ray diffraction -- single crystals -- temperature structural dynamics -- negative thermal expansion
Аннотация: Structural features of new mixed bismuth-containing samarium iron–aluminium borate single crystals Sm1−xBixFe3−yAly(BO3)4 (x = 0.05–0.07, y = 0–0.28) were studied using X-ray diffraction analysis based on aluminium content and temperature in the range 25–500 K. The crystals were grown using the solution-in-melt technique with Bi2Mo3O12 in a flux. The composition of the single crystals was analyzed using energy-dispersive X-ray fluorescence and energy-dispersive X-ray elemental analysis. Temperature dependencies of Sm1−xBixFe3−yAly(BO3)4 unit-cell parameters were studied. Negative thermal expansion was identified below 100 K and represented by characteristic surfaces of the thermal expansion tensor. (Sm,Bi)–O, (Sm,Bi)–(Fe,Al), (Fe,Al)–(Fe,Al), and (Fe,Al)–O interatomic distances decreased with the addition of aluminium atoms. An increase in the (Fe,Al)–(Fe,Al) intrachain bond length at low temperatures in the magnetically ordered state weakened this bond, whereas a decrease in the (Fe,Al)–(Fe,Al) interchain distance strengthened super-exchange paths between different chains. It was found that the addition of aluminium atoms influenced interatomic distances in Sm1−xBixFe3−yAly(BO3)4 much more than lowering the temperature from 293 K to 25 K. The effect of aluminium doping on magnetoelectric properties and structural symmetry of rare-earth iron borates is also discussed.

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Держатели документа:
Shubnikov Institute of Crystallography of Federal Scientific Research Centre ‘Crystallography and Photonics’, Russian Academy of Sciences, Moscow 119333, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Smirnova, E. S.; Alekseeva, O. A.; Artemov, V. V.; Sorokin, T. A.; Khmelenin, D. N.; Sidorova, E. V.; Frolov, K. V.; Gudim, I. A.; Гудим, Ирина Анатольевна
}
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10.

The Sm2S3-X-SmS-Sm2O2S refractory system: thermal analysis, phase diagram, and properties of the phases / I. O. Yurev, A. S. Aleksandrovsky, D. N. Kamaev [et al.] // J. Therm. Anal. Calorim. - 2024. - Vol. 149, Is. 5. - P. 2057-2073, DOI 10.1007/s10973-023-12792-z. - Cited References: 90. - The authors thank Prof. P.P. Fedorov, Chief Researcher of Prokhorov Institute of General Physics, Russian Academy of Sciences, for scientific advices. The authors thank N.I. Lozhkin, engineer of the Department of Inorganic and Physical Chemistry, Tyumen State University for the technical support of the visual thermal analysis setup. The authors thank N.A. Shulaev, research engineer of the Center for Nature-Inspired Engineering, Tyumen State University, for determining the elemental composition of samples by scanning electron microscopy. The authors thank I.V. Palamarchuk, research engineer of the Center for Collective Use "Rational Nature Management and Physical and Chemical Research" of the Tyumen State University, for measuring the diffuse reflectance spectra. The authors thank Doctor of Philology O.V. Trofimova, Professor at the Institute of Social Sciences and Humanities of the Tyumen State University, for her advices on academic writing. - This study was funded by the Russian Science Foundation, Project No. 23–23-00488 “Search for EMF generation conditions in gradient ceramics of samarium monosulfide (SmS)” . - ISSN 1388-6150. - ISSN 1588-2926
Кл.слова (ненормированные):
Samarium sulfides -- Refractory system -- Thermal analysis -- Ternary eutectic -- Phase diagram -- Band gap
Аннотация: Samarium monosulfide, a strain gauge and barometric material, exists in equilibrium with Sm3S4 and Sm2O2S in the S-Sm–O system. Therefore, studying phase equilibria in the refractory Sm2S3-X-SmS-Sm2O2S system is a scientifically interesting task. In this system, 49 samples were synthesized and studied by powder XRD, differential scanning calorimetry, visual thermal analysis, and microstructural analysis. Melting points of Sm3S4, SmS, and Sm2O2S compounds were determined. Eutectic diagrams of Sm3S4-Sm2O2S, SmS-Sm2O2S, SmS-Sm3S4 systems were constructed. Temperatures and compositions of the binary eutectic points were determined. Fusion enthalpies for Sm3S4, SmS, and Sm2O2S phases were estimated using the Schröder–Le Chatelier equation. The liquidus lines were calculated using second-degree polynomials and Redlich–Kister model. Coordinates of the ternary eutectic point in the Sm3S4-SmS-Sm2O2S system were calculated using the cutting-plane method and the Scheffé method. The calculated compositions of ternary eutectic points were averaged at one most probable point, in accordance with the data on the samples microstructure. The experimental temperature of the ternary eutectic point coincides with the calculated values within the margin of error. Positions of eutectic valleys and approximate positions of isotherms in the system were established. Thermodynamic parameters of the α-Sm2S3 → γ-Sm2S3 polymorphic transition and the dependence of the Sm2S3-X composition on heat treatment conditions were determined. According to the scanning electron microscopy data, the approximate composition of the crystallized from the melt Sm2S3 sample is Sm2S2.95. The Sm10S14O phase decomposes at 1470 ± 15 °C in the course of a solid-phase reaction. The phase diagram of the Sm2S3-X-Sm2O2S system was revisited. Optical band gaps of Sm10S14O and Sm2O2S phases were determined. The Sm10S14O compound was optically characterized for the first time; its direct and indirect optical bandgaps were found equal to 2.48 and 2.37 eV, respectively. The determined direct and indirect optical bandgaps of Sm2O2S (4.4 eV and 3.95 eV, respectively) agree with the earlier measurements, thus confirming the accuracy of the chosen synthesis procedures.

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Держатели документа:
Institute of Chemistry, Tyumen State University, Volodarsky Str. 6, Tyumen, 625003, Russia
Department of Physical and Applied Chemistry, Kurgan State University, Sovetskaya Str. 63/4, Kurgan, 640020, Russian Federation
Federal Research Center KSC SB RAS, Kirensky Institute of Physics, Akademgorodok Str. 50, Building 38, Krasnoyarsk, 660036, Russia
Siberian Federal University, Svobodnyj Av. 79, Krasnoyarsk, 660079, Russia
Institute of Physical Materials Science, SB RAS, Sakhyanova Str. 6, Ulan-Ude, 670047, Russian Federation
Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Pervomaiskaya Str. 91, Yekaterinburg, 620990, Russian Federation

Доп.точки доступа:
Yurev, I. O.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Kamaev, D. N.; Polkovnikov, A. A.; Grigorchenko, V. M.; Yarovenko, A. A.; Zelenaya, A. E.; Parfenova, M. D.; Andreev, O. V.
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