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1.


    Golovnev, N. N.
    Crystal structure of potassium 2-thiobarbiturate / N. N. Golovnev, M. S. Molokeev, M. Y. Belash // J. Struct. Chem. - 2013. - Vol. 54, Is. 3. - P. 566-570, DOI 10.1134/S0022476613030141. - Cited References: 18. - The work was supported by the grant of the President of the Russian Federation for the support of leading scientific schools of the Russian Federation (NSh-4828.2012.2) and the Federal Targeted Program "Scientific and Scientific Pedagogical Personnel of Innovative Russia, 2009-2013" (State contracts Nos. 02.740.11.0269 and 02.740.11.0629). . - ISSN 0022-4766
РУБ Chemistry, Inorganic & Nuclear + Chemistry, Physical
Рубрики:
ACID
Кл.слова (ненормированные):
crystal structure -- potassium thiobarbiturate -- hydrogen bonds -- pi-pi interaction
Аннотация: The crystal and molecular structure of potassium thiobarbiturate C4H3KN2O2S (C4H4N2O2S-2-thiobarbituric acid, H(2)TBA) is determined. Crystallographic data for KHTBA are as follows: a = 11.2317(17) , b = 3.8687(6) , c = 14.557(2) , beta = 97.448(4)A degrees, V = 627.18(17) (3), space group P2/c, Z = 4. Each potassium ion is linked with four oxygen atoms and two S atoms forming a distorted octahedron. N-HaEuro broken vertical bar O and C-HaEuro broken vertical bar S hydrogen bonds form a branched three-dimensional network. The structure is also stabilized by the pi-pi interaction of heterocyclic HTBA(-) ions.

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Публикация на русском языке Головнёв, Николай Николаевич. Кристаллическая структура 2-тиобарбитурата калия / Н. Н. Головнёв // Журнал структурной химии : ФГУП "Издательство Сибирского отделения Российской акдемии наук", 2013. - Т. 54, № 3. - С. 512-516. - ISSN 0136-7463

Держатели документа:
Siberian Fed Univ, Krasnoyarsk, Russia
Russian Acad Sci, LV Kirensky Inst Phys, Siberian Div, Krasnoyarsk, Russia
Russian Acad Sci, Inst Chem & Chem Technol, Siberian Div, Krasnoyarsk, Russia;

Доп.точки доступа:
Molokeev, M. S.; Молокеев, Максим Сергеевич; Belash, M. Y.; Головнёв, Николай Николаевич
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2.


   
    Biodegradation of polyhydroxyalkanoates by soil microbial communities of different structures and detection of PHA degrading microorganisms / A. N. Boyandin [et al.] // Appl. Biochem. Microbiol. - 2012. - Vol. 48, Is. 1. - P. 28-36, DOI 10.1134/S0003683812010024. - Cited References: 39. - The work was supported by the project initiated by the Government of the Russian Federation for governmental support of scientific research conducted under the guidance of leading scientists at Russian institutions of higher learning (Agreement No. 11.G34.31.0013) and the Program of Integrated Research of the Presidium of the Siberian Branch of Russian Academy of Sciences (project no. 96). . - ISSN 0003-6838
РУБ Biotechnology & Applied Microbiology + Microbiology
Рубрики:
POLY-BETA-HYDROXYBUTYRATE
   CHAIN-LENGTH POLYHYDROXYALKANOATES

   DEGRADATION

   FILMS

   POLY(3-HYDROXYBUTYRATE-CO-3-HYDROXYVALERATE)

   BACTERIA

   ACID

Аннотация: Biodegradation of microbial linear polymers of hydroxyalkanoic acids (polyhydroxyalkanoates, PHAs) by soil microbial communities of different structures has been studied during two field seasons in different weather conditions. This process was shown to be influenced by the polymer chemical composition, temperature, humidity, and the microbial soil component. The PHA degradation was accompanied by a decrease in the polymer molecular weight and an increase in the degree of crystallinity, indicating the preferential destruction of the amorphous phase compared to the crystalline one. The quantity of the true PHA destructors developing at the surface of the polymer samples was lower than the quantity of accompanying bacteria. The dominant PHA degrading microorganisms under the test conditions were identified as bacteria of the genera Variovorax, Stenotrophomonas, Acinetobacter, Pseudomonas, Bacillus, and Xanthomonas and as micromycetes from Penicillium, Paecilomyces, Acremonium, Verticillium, and Zygosporium.

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Публикация на русском языке Биодеградация полигидроксиалканоатов почвенными микробиоценозами различной структуры и выявление микроорганизмов-деструкторов [Текст] / А. Н. Бояндин [и др.] // Прикл. биохимия и микробиол. : Наука, 2012. - Т. 48 № 1. - С. 35-44

Держатели документа:
[Boyandin, A. N.
Volova, T. G.] Russian Acad Sci, Inst Biophys, Siberian Branch, Krasnoyarsk 660036, Russia
[Prudnikova, S. V.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Filipenko, M. L.
Khrapov, E. A.] Russian Acad Sci, Siberian Branch, Inst Chem Biol & Fundamental Med, Novosibirsk 630090, Russia
[Vasil'ev, A. D.] Russian Acad Sci, Siberian Branch, Kirenskii Inst Phys, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Boyandin, A. N.; Бояндин, Анатолий Николаевич; Prudnikova, S. V.; Filipenko, M. L.; Khrapov, E. A.; Vasil'ev, A. D.; Васильев, Александр Дмитриевич; Volova, T. G.; Волова, Татьяна Григорьевна
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3.


    Golovnev, N. N.
    Enrofloxacinium citrate monohydrate: Preparation, crystal structure, thermal stability and IR-characterization / N. N. Golovnev, A. D. Vasiliev, S. D. Kirik // J. Mol. Struct. - 2012. - Vol. 1021. - P. 112-117, DOI 10.1016/j.molstruc.2012.04.059. - Cited References: 22. - The authors are grateful to the Ministry of Education and Science (Government Contracts # 02.740.11.0629) for the financial support of the investigation. . - ISSN 0022-2860
РУБ Chemistry, Physical
Рубрики:
COCRYSTAL
   ANTIBACTERIAL

   BEHAVIOR

   STATE

   ACID

Кл.слова (ненормированные):
Enrofloxacin -- Citric acid -- Crystal structure -- IR spectra -- Thermal analysis
Аннотация: Enrofloxacinium citrate monohydrate (I), C19H 23FN3O3+В·C6H7O7- В·H2O, [C19H22FN3O3 - enrofloxacin, EnrH] has been crystallized from the mutual solution of citric acid and enrofloxacin in ambient conditions. The colorless crystals have been investigated using X-ray single crystal and powder techniques, and characterized by differential scanning calorimetry, thermogravimetry and infrared spectroscopy. The obtained compound can be considered as a salt with enrofloxacinium in the role of a cation and citrate as an anion. The ions ratio equals to 1:1. The compound crystallizes in the triclinic lattice with a = 9.0489(8) A, b = 9.6531(8) A, c = 14.913(1) A, ? = 98.813(1)В°, ? = 92.029(1)В°, ? = 91.013(1)В°, Z = 2, V = 1286.1(2) A3, S.G. P1?. The crystal structure determination reveals the importance of inter- and intramolecular interactions in the crystal formation. The EnrH2+andH3Cit- molecular ions are packed in alternating layers with water molecules inserted into the citrate layers. A citrate ion in the layer is linked via H-bondings with two adjacent ones and three water molecules. Enrofloxacinium cations are packaged by means of a benched mode and every cation is linked by three intermolecular thymus type H-bondings with nitrogens of adjacent cations and by two links with the oxygen of the citrate ions. The infrared spectra gave the evidence of H-bonding formation in the obtained salt. The ?-stacking interactions are observed between the aromatic cycles of the adjacent cations which are located in an antiparallel style in a layer. В© 2012 Elsevier B.V. All rights reserved.

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Держатели документа:
Siberian Federal University, Svobodny Ave. 79, Krasnoyarsk 660041, Russian Federation
Kirensky Institute of Physics SB RAS, Krasnoyarsk 660036, Russian Federation
Institute of Chemistry and Chemical Technology SB RAS, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Vasiliev, A. D.; Васильев, Александр Дмитриевич; Kirik, S. D.; Головнёв, Николай Николаевич
}
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4.


    Golovnev, N. N.
    Crystal structures of cesium and rubidium 2-thiobarbiturates / N. N. Golovnev, M. S. Molokeev // Russ. J. Inorg. Chem. - 2014. - Vol. 59, Is. 9. - P. 943-946, DOI 10.1134/S003602361409006X. - Cited References: 13 . - ISSN 0036-0236. - ISSN 1531-8613
РУБ Chemistry, Inorganic & Nuclear
Рубрики:
ACID
   COLLECTION

Аннотация: The crystal structures of cesium 2-thiobarbiturate C4H3CsN2O2S (I) and rubidium 2-thiobarbiturate C4H3N2O2RbS (II) (C4H4N2O2S is 2-thiobarbituric acid, H2TBA) have been determined. Isostructural crystals are monoclinic; a = 7.9609(3) Å,b = 11.8474(3) Å, c = 7.7317(2) Å, β = 101.285(3)°, V = 715.13(4) Å3, space group C2/m, Z = 4 for I and a = 7.6369(2) Å, b = 11.7690(3) Å, c = 7.5568(2) Å, β = 100.212(1)°, V = 668.44(3) Å3, space group C2/m, Z = 4 for II. Each metal ion in complexes I and II is bonded to four oxygen atoms and two sulfur atoms at the vertices of a six-vertex polyhedron. N-H…O hydrogen bonds link HTBA-ions into chains. The structure is also stabilized by the “head-to-tail” π-π interaction of HTBA-ions.

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Публикация на русском языке

Держатели документа:
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Russian Acad Sci, Siberian Branch, Kirenskii Inst Phys, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Molokeev, M. S.; Молокеев, Максим Сергеевич; Головнёв, Николай Николаевич
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5.


    Golovnev, N. N.
    The crystal structure of lead(II) 1,3-diethyl-2-thiobarbiturate / N. N. Golovnev, M. S. Molokeev, I. I. Golovneva // Russ. J. Coord. Chem. - 2015. - Vol. 41, Is. 5. - P. 300-304, DOI 10.1134/S1070328415050012. - Cited References:25 . - ISSN 1070. - ISSN 1608-3318. -
РУБ Chemistry, Inorganic & Nuclear
Рубрики:
HYDROGEN-BOND
   COMPLEXES

   ACID

   2-THIOBARBITURATE

   DIFFRACTION

   SERIES

Аннотация: The complex [Pb2(DETBA)4] n (I), where HDETBA is 1,3-diethyl-2-thiobarbituric acid (C8H12N2O2S), was obtained and structurally characterized by X-ray diffraction (CIF file CCDC no. 1031501). The crystals of complex I are trigonal: a = 12.9503(3), c = 32.077(1) Å, V = 4658.9(3) Å3, space group R3¯ , Z = 9. One of the crystallographically independent lead ions, Pb(1)2+, is coordinated in an octahedral fashion by six DETBA− ions through the O atoms. The other ion, Pb(2)2+, is coordinated to six DETBA− ions through three O atoms and three S atoms making up a trigonal prism. The polyhedra Pb(1)O6 and Pb(2)O6 are united through bridging DETBA− ions into infinite layers. The ligands are linked by neither intermolecular hydrogen bonds nor π-π interactions.

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Публикация на русском языке Головнёв, Николай Николаевич. Кристаллическая структура 1,3-диэтил-2-тиобарбитурата свинца(II) [Текст] / Н. Н. Головнёв, М. С. Молокеев, И. И. Головнева // Координ. химия : Наука, 2015. - Т. 41 № 5. - С. 266–270

Держатели документа:
Siberian Fed Univ, Krasnoyarsk, Russia.
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk, Russia.
Far Eastern State Transport Univ, Khabarovsk, Russia.
State Agr Univ, Krasnoyarsk, Russia.

Доп.точки доступа:
Molokeev, M. S.; Молокеев, Максим Сергеевич; Golovneva, I. I.
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6.


   
    Structures based on graphitized nanotubulenes with a common electrode in a matrix of porous anodic alumina for the purpose of forming electrically switchable membranes / M. M. Simunin [et al.] // Tech. Phys. Lett. - 2015. - Vol. 41, Is. 11. - P. 1047-1050, DOI 10.1134/S1063785015110103. - Cited References:20. - This work was supported financially by the Russian Science Foundation, project no. 15-19-10017 . - ISSN 1063-7850. - ISSN 1090-6533
РУБ Physics, Applied
Рубрики:
POLYPEPTIDE BRUSH
   ION-TRANSPORT

   PERMEABILITY

   POLYMER

   PHOTOREGULATION

   PERMEATION

   ACID

Аннотация: A structure based on porous anodic alumina with through pores is synthesized. This structure may be of some interest in terms of fabricating electrically switchable membranes. Conducting tubulenes connected to a common input electrode are located in the pores of the structure. It is hypothesized that enhancement of the electric field nonuniformity associated with the indicated structure morphology should help raise the degree of ionic selectivity of the membrane and broaden the range of permissible concentrations of ions in the processed solution. An suggestion regarding the structure of synthesized tubulenes in the context of the problem of suppressing the physical sorption of ions on the pore surface and raising the hydrogen and oxygen reduction potentials relative to those of state-of-the-art field-switchable membranes is also made.

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Публикация на русском языке Структуры на основе графитизированных нанотубуленов с общим электродом в матрице пористого анодного оксида алюминия для задачи формирования переключаемых электрическим полем мембран [Текст] / М. М. Симунин [и др.] // Письма в ЖТФ. - Санкт-Петербург : Санкт-Петербургская издательско-книготорговая фирма "Наука", 2015. - Т. 41 Вып. 21. - С. 52-59

Держатели документа:
Natl Res Univ Elect Technol MIET, Moscow 124498, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Siberian Branch, Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia.
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Inst Computat Modeling, Siberian Branch, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Simunin, M. M.; Khartov, S. V.; Shiverskii, A. V.; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Fadeev, Yu. V.; Voronin, A. S.; Russian Science Foundation [15-19-10017]
}
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7.


    Golovnev, N. N.
    Crystal Structure and Properties of Levofloxacinium 2-Thiobarbiturate Trihydrate / N. N. Golovnev, M. S. Molokeev, M. K. Lesnikov // J. Struct. Chem. - 2018. - Vol. 59, Is. 3. - P. 646-651, DOI 10.1134/S0022476618030204. - Cited References: 20. - The work was performed within the State Task of the Ministry of Education and Science of the Russian Federation to the Siberian Federal University for 2017-2019 (4.7666.2017/BCh). . - ISSN 0022-4766. - ISSN 1573-8779
РУБ Chemistry, Inorganic & Nuclear + Chemistry, Physical
Рубрики:
CIPROFLOXACIN
   MONOHYDRATE

   QUINOLONE

   ACID

Кл.слова (ненормированные):
levofloxacin -- 2-thiobarbituric acid -- salt -- crystal structure -- absolute -- structure -- thermal stability -- IR spectrum
Аннотация: The structure of levofloxacinium 2-thiobarbiturate trihydrate LevoH 2 + Htba–·3H2O (I) (LevoH is levofloxacin, H2tba is 2-thiobarbituric acid) is determined (CIF file CCDC No. 1547466); its thermal decomposition and IR spectrum are studied. The crystals of I are triclinic: a = 8.670(1) Å, b = 9.605(1) Å, c = 15.786(2) Å, α = 89.144(5)°, β = 88.279(5)°, γ = 76.068(5)°, V = 1275.4(3) Å3, space group P1, Z = 2. The unit cell of I contains two LevoH 2 + ions, two Htba– ions, and six H2O molecules. The absolute structure of the crystal and the configuration of the chiral center in a levofloxacin molecule S are determined. Experiments for generating the second optical harmonics gave a positive result. Intermolecular hydrogen bonds (HBs) N–H···O and O–H···O in I form a bilayer system along the ab diagonal with hydrophilic moieties within a layer and hydrophobic moieties directed outward. The structure is stabilized by multiple HBs and the π–π interaction between the Htba–and LevoH 2 + ions and between the LevoH 2 + ions.

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Публикация на русском языке Головнёв Н. Н. Кристаллическая структура и свойства тригидрата 2-тиобарбитурата левофлоксациния [Текст] / Н. Н. Головнёв, М. С. Молокеев, М. К. Лесников // Журн. структ. химии. - 2018. - Т. 59 № 3. - С. 668-673

Держатели документа:
Siberian Fed Univ, Krasnoyarsk, Russia.
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk, Russia.
Far Eastern State Transport Univ, Khabarovsk, Russia.

Доп.точки доступа:
Molokeev, M. S.; Молокеев, Максим Сергеевич; Lesnikov, M. K.; Ministry of Education and Science of the Russian Federation [4.7666.2017/BCh]
}
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8.


   
    Crystal Structure of Norfloxacinium and 2,2 '-Bipyridyl-1 '-Ium 2-Thiobarbiturates / N. N. Golovnev, M. S. Molokeev, I. V. Sterkhova, M. K. Lesnikov // J. Struct. Chem. - 2020. - Vol. 61, Is. 10. - P. 1639-1647, DOI 10.1134/S0022476620100170. - Cited References: 33. - The reported study was funded by RFBR, project number 19-52-80003 . - ISSN 0022-4766. - ISSN 1573-8779
РУБ Chemistry, Inorganic & Nuclear + Chemistry, Physical
Рубрики:
THERMAL-STABILITY
   ACID

   FORMS

Кл.слова (ненормированные):
2,2 '-dipyridynium and norfloxacinium 2-thiobarbiturates -- synthesis -- structure -- thermal stability
Аннотация: Organic salts with the composition NfH2(Htba)·6H2O (I) and BipyH(Htba)·2H2O (II) (Н2tba is 2-thiobarbituric acid, NfH is norfloxacin and Bipy is 2,2′-dipyridyl) are prepared. Their structures are determined by XRD (CCDC cif-file No. 1967494-1967495). Crystals I are triclinic: a = 11.8821(4) Å, b = 11.9959(5) Å, c = 12.0038(4) Å, α = 119.835(1)°, β = 107.691(1)°, γ = 95.237(1)°, V = 1351.80(9) Å3, space group P-1, Z = 2. Crystals II are monoclinic: a = 7.9587(2) Å, b = 19.6272(4) Å, c = 10.1118(2) Å, β = 98.118(1)°, V = 1563.71(6) Å3, space group P21/n, Z = 4. The structures are stabilized by numerous hydrogen bonds and π–π interactions involving Нtba−, NfH+2, and BipyH+ ions. Thermal decomposition of these compounds in air includes dehydration and oxidative degradation stages.

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Публикация на русском языке Кристаллическая структура 2-тиобарбитуратов норфлоксациниума и 2,2'-дипиридил-1'-иума [Текст] / Н. Н. Головнев, М. С. Молокеев, И. В. Стерхова, М. К. Лесников // Журн. структ. химии. - 2020. - Т. 61 № 10. - С. 1724-1733

Держатели документа:
Siberian Fed Univ, Krasnoyarsk, Russia.
Russian Acad Sci, Fed Res Ctr KSC, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk, Russia.
Far Eastern State Transport Univ, Khabarovsk, Russia.
Russian Acad Sci, Favorsky Inst Chem, Siberian Branch, Irkutsk, Russia.

Доп.точки доступа:
Golovnev, N. N.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Sterkhova, I., V; Lesnikov, M. K.; RFBRRussian Foundation for Basic Research (RFBR) [19-52-80003]
}
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9.


   
    Production and properties of microbial polyhydroxyalkanoates synthesized from hydrolysates of Jerusalem artichoke tubers and vegetative biomass / T. G. Volova, E. G. Kiselev, A. V. Demidenko [et al.] // Polymers. - 2022. - Vol. 14, Is. 1. - Ст. 132, DOI 10.3390/polym14010132. - Cited References: 93. - This study was financially supported by Project "Agropreparations of the new generation: a strategy of construction and realization" (Agreement No. 075-15-2021-626) in accordance with Resolution No. 220 of the Government of the Russian Federation of 9 April 2010, "On measures designed to attract leading scientists to the Russian institutions of higher learning" (polymer synthesis, properties), and by the State Assignment of the Ministry of Science and Higher Education of the Russian Federation No. FSRZ-2020-0006 (films production, surface properties) . - ISSN 2073-4360
РУБ Polymer Science
Рубрики:
GLUCOSE-UTILIZING STRAIN
   RALSTONIA-EUTROPHA

   ASPERGILLUS-NIGER

   ACID

Кл.слова (ненормированные):
Jerusalem artichoke hydrolysates -- PHA synthesis -- productivity -- polyhydroxyalkanoates
Аннотация: One of the major challenges in PHA biotechnology is optimization of biotechnological processes of the entire synthesis, mainly by using new inexpensive carbon substrates. A promising substrate for PHA synthesis may be the sugars extracted from the Jerusalem artichoke. In the present study, hydrolysates of Jerusalem artichoke (JA) tubers and vegetative biomass were produced and used as carbon substrate for PHA synthesis. The hydrolysis procedure (the combination of aqueous extraction and acid hydrolysis, process temperature and duration) influenced the content of reducing substances (RS), monosaccharide contents, and the fructose/glucose ratio. All types of hydrolysates tested as substrates for cultivation of three strains—C. necator B-10646 and R. eutropha B 5786 and B 8562—were suitable for PHA synthesis, producing different biomass concentrations and polymer contents. The most productive process, conducted in 12-L fermenters, was achieved on hydrolysates of JA tubers (X = 66.9 g/L, 82% PHA) and vegetative biomass (55.1 g/L and 62% PHA) produced by aqueous extraction of sugars at 80 °C followed by acid hydrolysis at 60 °C, using the most productive strain, C. necator B-10646. The effects of JA hydrolysates on physicochemical properties of PHAs were studied for the first time. P(3HB) specimens synthesized from the JA hydrolysates, regardless of the source (tubers or vegetative biomass), hydrolysis conditions, and PHA producing strain employed, exhibited the 100–120 °C difference between the Tmelt and Tdegr, prevailing of the crystalline phase over the amorphous one (Cx between 69 and 75%), and variations in weight average molecular weight (409–480) kDa. Supplementation of the culture medium of C. necator B-10646 grown on JA hydrolysates with potassium valerate and ε-caprolactone resulted in the synthesis of P(3HB-co-3HV) and P(3HB-co-4HB) copolymers that had decreased degrees of crystallinity and molecular weights, which influenced the porosity and surface roughness of polymer films prepared from them. The study shows that JA hydrolysates used as carbon source enabled productive synthesis of PHAs, comparable to synthesis from pure sugars. The next step is to scale up PHA synthesis from JA hydrolysates and conduct the feasibility study. The present study contributes to the solution of the critical problem of PHA biotechnology—finding widely available and inexpensive substrates.

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Держатели документа:
Siberian Fed Univ, Sch Fundamental Biol & Biotechnol, Basic Dept Biotechnol, Krasnoyarsk 660041, Russia.
Krasnoyarsk Sci Ctr SB RAS, Fed Res Ctr, Inst Biophys, SB RAS, Krasnoyarsk 660036, Russia.
Krasnoyarsk Sci Ctr SB RAS, LV Kirensky Phys Inst, Fed Res Ctr, SB RAS, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Fed Res Ctr, Krasnoyarsk Sci Ctr, Siberian Branch, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Volova, Tatiana G.; Kiselev, Evgeniy G.; Demidenko, Alexey V.; Zhila, Natalia O.; Nemtsev, I. V.; Немцев, Иван Васильевич; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Project "Agropreparations of the new generation: a strategy of construction and realization" [075-15-2021-626]; State Assignment of the Ministry of Science and Higher Education of the Russian Federation [FSRZ-2020-0006]
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