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1.


   
    Reconstructive phase transition in (NH4)3TiF7 accompanied by the ordering of TiF6 octahedra / M. S. Molokeev [et al.] // Acta Crystallogr. B. - 2014. - Vol. 70. - P. 924-931, DOI 10.1107/S2052520614021192. - This study was supported by Russian Fund of Basic Research, project No. 12-02-00056 a . - ISSN 0108-7681. - ISSN 1600-5740
   Перевод заглавия: Реконструктивный фазовый переход в (NH4)3TiF7, сопровождающийся упорядочением октаэдров TiF6
РУБ Crystallography
Рубрики:
CRYSTAL-STRUCTURE
   NEUTRON-DIFFRACTION

   POWDER DIFFRACTION

   FLUORIDES

   DISORDER

   MECHANISM

   PATHWAYS

   COMPLEX

   LI3THF7

   ALPHA

Кл.слова (ненормированные):
reconstructive phase transition -- ammonium heptafluorotitanate -- order-disorder transition
Аннотация: An unusual phase transition P4/mnc →Pa3 has been detected after cooling the (NH4)3TiF7 compound. Some TiF6 octahedra, which are disordered in the room-temperature tetragonal structure, become ordered in the low-temperature cubic phase due to the disappearance of the fourfold axis. Other TiF6 octahedra undergo large rotations resulting in huge displacements of the F atoms by 1.5-1.8 Å that implies a reconstructive phase transition. It was supposed that phases P4/mbm and Pm3m could be a high-temperature phase and a parent phase, respectively, in (NH4)3TiF7. Therefore, the sequence of phase transitions can be written as Pm3m → P4/bm → P4/mnc → Pa3. The interrelation between (NH4)3TiF7, (NH4)3GeF7 and (NH4)3PbF7 is found, which allows us to suppose phase transitions in relative compounds.

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Держатели документа:
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Siberian State Univ, Inst Engn Phys & Radioelect, Krasnoyarsk 660074, Russia
Inst Chem, Vladivostok 660022, Russia

Доп.точки доступа:
Molokeev, M. S.; Молокеев, Максим Сергеевич; Misjul, S. V.; Мисюль, Сергей Валентинович; Flerov, I. N.; Флёров, Игорь Николаевич; Laptash, N. M.
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2.


   
    Phase transformation in Ca3(PO4)2:Eu2+ via the controlled quenching and increased Eu2+ content: Identification of new cyan-emitting α-Ca3(PO4)2:Eu2+ phosphor / H. Ji [et al.] // J. Am. Ceram. Soc. - 2015. - Vol. 98, Is. 10. - P. 3280-3284, DOI 10.1111/jace.13787. - Cited References: 23. - This work was partly supported by the National Natural Science Foundations of China (grant nos. 51272242, 51472222, 51511130035), the Research Fund for the Doctoral Program of Higher Education of China (grant no. 20130022110006), and the Russian Foundation for Basic Research (grant no. 15-52-53080 GFEN_a). VVA was partly supported by the Ministry of Education and Science of the Russian Federation. . - ISSN 0002-7820
   Перевод заглавия: Фазовый переход в Ca3(PO4)2:Eu2+ посредством контролируемой закалки и увеличения концентрации Eu2+: Идентификация нового голубого люминофора α-Ca3(PO4)2:Eu2+
РУБ Materials Science, Ceramics
Рубрики:
NEUTRON POWDER DIFFRACTION
   SOLID-SOLUTION PHOSPHORS

   CRYSTAL-STRUCTURE

   DIODES

   PHOTOLUMINESCENCE

   LUMINESCENCE

   TRANSITION

   ALPHA

Аннотация: A case of phosphor is reported where the cooling rate parameter significantly influences the luminescence property. By quenching the sample after the higherature solid-state reaction at 1250°C, we successfully prepared the Eu2+-doped α form Ca3(PO4)2 (α-TCP:Eu2+) as a new kind of bright cyan-emitting phosphor. The unusual emission color variation (from cyan to blue) depends on the cooling rate after sintering and Eu2+ doping level as it was observed in the TCP-based phosphors. By the Rietveld analysis, it is revealed that the cyan- and blue-emitting phosphors are two different TCP forms crystallizing in the monoclinic (space group P21/a, α-TCP) and the rhombohedral structure (space group R3c, β-TCP), respectively. Upon 365 nm UV light excitation, α-TCP:Eu2+ exhibits an asymmetric broad-band cyan emission peaking at 480 nm, while β-TCP:Eu2+ displays a relatively narrow-band blue emission peaking at 416 nm. The Eu2+-doping in Ca3(PO4)2 shifts the upper temperature limit of the stable structural range of β form from 1125°C to ≥1250°C. Moreover, the crystal structures of α/β-TCP:Eu2+ were compared in the aspects of compactness and cation site sets. The emission thermal stability of α/β-TCP:Eu2+ was comparatively characterized and the difference was related to the specific host structural features. © 2015 The American Ceramic Society.

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Держатели документа:
School of Materials Science and Technology, Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, China University of Geosciences, Beijing, China
School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, Russian Federation
Functional Electronics Laboratory, Tomsk State University, Tomsk, Russian Federation
Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk, Russian Federation

Доп.точки доступа:
Ji, H.; Huang, Z.; Xia, Zhiguo; Molokeev, M. S.; Молокеев, Максим Сергеевич; Chen, M.; Atuchin, V. V.; Fang, M.; Liu, Y.; Wu, Xiaowen
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3.


    Flerov, I. N.
    Calorimetric and optical studies of orthorhombic and cubic CsLiCrO4 crystals / I. N. Flerov, A. V. Kartashev, S. V. Mel'nikova // Phys. Solid State. - 2006. - Vol. 48, Is. 11. - P. 2171-2176, DOI 10.1134/S1063783406110242. - Cited References: 23 . - ISSN 1063-7834
РУБ Physics, Condensed Matter
Рубрики:
PHASE-TRANSITIONS
   X-RAY

   NH4LISO4

   ALPHA

Аннотация: Careful calorimetric and polarization optical studies of a metastable cubic modification of a CsLiCrO4 crystal (space group (F43m)) are performed. Anomalies of the heat capacity indicative of structural distortions at 92.4 and 69.1 K were revealed, and the values of the thermodynamic parameters of the phase transitions were determined. The crystal twinning in the intermediate phase was studied. A comparative analysis of the phase transitions occurring in a series of ALiMO(4) crystals (A=NH4, Cs; M=S, Cr, Mo, W) was performed. First studies of the monotropic structural transformation F43m - Pmcn and the enantiotropic phase transition Pmcn reversible arrow P112(1)/n were carried out using scanning calorimetry, and the thermodynamic parameters of these transitions were determined.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Kartashev, A. V.; Карташев, Андрей Васильевич; Mel'nikova, S. V.; Мельникова, Светлана Владимировна; Флёров, Игорь Николаевич
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4.


    Shabanov, V. F.
    Manifestation of vacancies in spectra of low frequencies and the calculations of migration energy in paradichlorobenzene and paradichlorobenzene at different temperatures / V. F. Shabanov, M. A. Korshunov // Fiz. Tverd. Tela. - 1995. - Vol. 37, Is. 11. - P. 3463-3469. - Cited References: 13 . - ISSN 0367-3294
РУБ Physics, Condensed Matter
Рубрики:
CRYSTAL
   ALPHA


WOS

Доп.точки доступа:
Korshunov, M. A.; Коршунов, Михаил Анатольевич; Шабанов, Василий Филиппович
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5.


    Avramov, P. V.
    Effects of the intense electron correlations on the shape of x-ray CuK absorption spectra of La2-xSrxCuO4 / P. V. Avramov, S. G. Ovchinnikov // Zhurnal Eksperimentalnoi Teor. Fiz. - 1995. - Vol. 108, Is. 4. - P. 1479-1488. - Cited References: 28 . - ISSN 0044-4510
РУБ Physics, Multidisciplinary
Рубрики:
HIGH-TC SUPERCONDUCTIVITY
   EDGE STRUCTURE

   LA2CUO4

   SATELLITES

   ALPHA

   EXCITATIONS

   COPPER

   OXIDES

   STATE

   SHAKE


WOS

Доп.точки доступа:
Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Аврамов, Павел Вениаминович
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6.


    Avramov, P. V.
    Non-diagram transitions in polarized X-ray absorption CuL(3) spectra of HTSC-ceramics / P. V. Avramov, S. G. Ovchinnikov // Fiz. Tverd. Tela. - 1996. - Vol. 38, Is. 11. - P. 3226-3240. - Cited References: 28 . - ISSN 0367-3294
РУБ Physics, Condensed Matter
Рубрики:
HIGH-TC SUPERCONDUCTIVITY
   LA2CUO4

   ALPHA

   SATELLITES

   STATES

   OXIDES

   XANES


WOS

Доп.точки доступа:
Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Аврамов, Павел Вениаминович
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