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Altunin, R. R.
Structural phase transformations in Al/Pt bilayer thin films during the solid-state reaction / R. R. Altunin, E. T. Moiseenko, S. M. Zharkov // Phys. Solid State. - 2018. - Vol. 60, Is. 7. - P. 1413-1418, DOI 10.1134/S106378341807003X. - Cited References: 26. - This study was supported by the Russian Foundation for Basic Research, project no. 16-33-00475 mol_a. . - ISSN 1063-7834. - ISSN 1090-6460

РУБ Physics, Condensed Matter
Рубрики:
AL
   SYSTEM
   MULTILAYERS
   ALUMINUM
   HEAT
Аннотация: A sequence of phases forming during the solid-phase reaction in Al/Pt bilayer thin films has been investigated by in situ electron diffraction. It is shown that the amorphous PtAl2 phase forms first during the solid-phase reaction initiated by heating. Upon further heating, PtAl2, Pt2Al3, PtAl, and Pt3Al crystalline phases sequentially form, which is qualitatively consistent with an effective formation heat model. The content of phases forming during the reaction has been quantitatively analyzed and the structural phase transformations have been examined.

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Публикация на русском языке Алтунин, Роман Русланович. Структурные фазовые превращения при твердофазной реакции в тонких двухслойных пленках Al/Pt [Текст] / Р. Р. Алтунин, Е. Т. Моисеенко, С. М. Жарков // Физ. тверд. тела. - 2018. - Т. 60 Вып. 7. - С. 1397–1402

Держатели документа:
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Krasnoyarsk Sci Ctr, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Moiseenko, E. T.; Zharkov, S. M.; Жарков, Сергей Михайлович; Russian Foundation for Basic Research [16-33-00475 mol_a]
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Mechanochemical synthesis of intermetallic compounds in the gallium-iridium system / E. A. Pavlov [et al.] // Russ. Metall. - 2018. - Is. 8. - P. 728-732, DOI 10.1134/S0036029518080141. - Cited References: 18. - This work was performed in terms of project no. 1622/17 of the Krasnoyarsk Plant of Nonferrous Metals and the Institute of Solid State Chemistry and Mechanochemistry. . - ISSN 0036-0295. - ISSN 1555-6255

РУБ Metallurgy & Metallurgical Engineering
Рубрики:
ALUMINUM
Кл.слова (ненормированные):
mechanochemical synthesis -- intermetallic compounds -- gallium -- iridium -- complex compounds of iridium
Аннотация: The interaction between a solid inert metal (Ir) and an active liquid metal (Ga) during mechanical activation in a high-energy planetary mill is studied by X-ray diffraction and scanning electron microscopy with EDS-apparatus for high-resolution energy dispersive X-ray microanalysis. The influence of mechanical activation conditions on the formation of GaxIry intermetallic compounds and GaxIry/Ir composites and on their solubility in various acids is investigated. Being a surfactant for iridium, gallium propagates along the grain boundaries of polycrystalline iridium particles during mechanical activaiton and, hence, sharply decreases their strength. As a result of strong mechanical deformation during activation, the contact surface area between the solid and liquid metals, where the intermetallic compounds form intensely, increases sharply. As a result of treatment of the products of mechanical activaiton by a mixture of concentrated hydrochloric and nitric acids, iridium (>30%) from passes into an acid solution and forms HxIrCly complex compounds, which can interact with bases to form soluble complex salts.

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Публикация на русском языке Механохимический синтез интерметаллических соединений в системе галлий-иридий [Текст] / Е. А. Павлов [и др.] // Расплавы. - 2018. - № 3. - С. 291-298

Держатели документа:
OAO Krasnoyarsk Plant Nonferrous Met, Krasnoyarsk 660027, Russia.
Russian Acad Sci, Siberian Branch, Fed Res Ctr, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Inst Solid State Chem & Mechanochem, Novosibirsk 630128, Russia.
Russian Acad Sci, Ural Branch, Inst Met, Ekaterinburg 620016, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Pavlov, E. A.; Chuprov, I. V.; Nikulin, M. V.; Mal'tsev, E. V.; Pshenichnaya, A. A.; Пшеничная, Анастасия Александровна; Grigoreva, T. F.; Pastukhov, E. A.; Skuratov, A. P.; Lyakhov, N. Z.
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