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Heat capacity and thermal expansion study of Ba0.9Bi0.067(Ti1-xZrx)O-3 ceramics / M. . Gorev [et al.] // J. Phys.: Condens. Matter. - 2007. - Vol. 19, Is. 34. - Ст. 346237, DOI 10.1088/0953-8984/19/34/346237. - Cited References: 15 . - ISSN 0953-8984

РУБ Physics, Condensed Matter
Рубрики:
BA(TI1-XZRX)O-3
STATE
Кл.слова (ненормированные):
Adiabatic calorimeters -- Temperature range -- Temperature regions -- Thermal expansion anomaly -- Barium -- Ceramic materials -- Dielectric properties -- Expansion -- Specific heat -- Zirconium -- Thermal expansion
Аннотация: For Ba0.9Bi0.067(Ti1-xZrx)O-3 (x = 0.04, 0.15) ceramics, the heat capacity C-p(T) and the thermal expansion alpha(T) were measured using an adiabatic calorimeter and an optical-mechanical dilatometer in the temperature range 100-420 K. Both compounds reveal diffuse heat capacity and thermal expansion anomalies: three anomalies in the temperature regions 150-250 K, 250-300 K (alpha(T) only) and 300-400 K at x = 0.04 and two anomalies in the regions 200 250 K and 250-350 K at x = 0.15. The results obtained are discussed together with the data on the dielectric properties.

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Держатели документа:
[Gorev, Michail
Bondarev, Vitaly
Flerov, Igor] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
[Maglione, Mario
Simon, Annie] Univ Bordeaux 1, CNRS, ICMCB, F-33608 Pessac, France
ИФ СО РАН
LVKirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
ICMCB-CNRS, Universite de Bordeaux i, 87 avenue ASchweitzer, 33608 Pessac, France

Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Flerov, I. N.; Флёров, Игорь Николаевич; Maglione, M.; Simon, A.
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Heat capacity study of double perovskite-like compounds BaTi1-xZrxO3 / M. V. Gorev [et al.] // Phys. Solid State. - 2005. - Vol. 47, Is. 12. - P. 2304-2308, DOI 10.1134/1.2142895. - Cited References: 19 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
BATIO3
   BA(TI1-XZRX)O-3
   FERROELECTRICS
   CERAMICS
   STATE
   FILMS
   FIELD
Аннотация: The temperature dependence of the heat capacity of two compositions in the solid solution system BaTi1 - xZrxO3 (x = 0.25, 0.35) was measured using adiabatic calorimetry. In the T-x phase diagram, these compounds occupy positions near the crossover from conventional ferroelectric behavior to the relaxor state. Both compounds reveal diffuse heat capacity anomalies: two anomalies in the temperature ranges 250-350 and 150-200 K at x = 0.35 and one anomaly within the range similar to 150-320 K at x = 0.25. The results obtained are discussed together with structural and dielectric measurements. (c) 2005 Pleiades Publishing, Inc.

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Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
CNRS, CEMES, F-31055 Toulouse, France
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, Akademgorodok, 660036, Russian Federation
CEMES-CNRS, 29 rue Jeanne Marvig, Toulouse, 31055, France

Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Flerov, I. N.; Флёров, Игорь Николаевич; Sciau, P.; Savariault, J. M.
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Heat capacity and thermal expansion study of relaxor-ferroelectric Ba0.92Ca0.08Ti0.76Zr0.24O3 / M. . Gorev [et al.] // J. Phys.: Condens. Matter. - 2004. - Vol. 16, Is. 39. - P. 7143-7150, DOI 10.1088/0953-8984/16/39/045. - Cited References: 18 . - ISSN 0953-8984

РУБ Physics, Condensed Matter
Рубрики:
CERAMICS
BA(TI1-XZRX)O-3
PEROVSKITES
Кл.слова (ненормированные):
Calorimetry -- Dielectric properties -- Ferroelectric materials -- Perovskite -- Phase transitions -- Solid solutions -- Specific heat -- Thermal expansion -- Adiabatic calorimetry -- Frequency dispersion -- Polar domains -- Relaxor ferroelectrics -- Barium compounds
Аннотация: Heat capacity and thermal expansion of the Ba0.92Ca0.08Ti0.76Zr0.24O3 compound is measured using the methods of adiabatic calorimetry and optic-mechanical dilatometry in the temperature range 100-370 K. Three blurred anomalies on the C-p(T) and alpha(T) dependencies are observed in the temperature range 200-360 K. The results of the studies are discussed together with data on the structure and dielectric properties in the framework of spherical random bond-random field model.

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Держатели документа:
CNRS, CEMES, F-31055 Toulouse, France
ИФ СО РАН
L V kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Sciau, P.; Savariault, J. M.
}
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Heat capacity study of relaxors BaTi0.65Zr0.35O3 and BaTi0.60Zr0.40O3 / M. . Gorev [et al.] // J. Phys.: Condens. Matter. - 2006. - Vol. 18, Is. 17. - P. 4407-4416, DOI 10.1088/0953-8984/18/17/026. - Cited References: 21 . - ISSN 0953-8984

РУБ Physics, Condensed Matter
Рубрики:
CERAMICS
BA(TI1-XZRX)O-3
BATIO3
Кл.слова (ненормированные):
Calorimetry -- Composition -- Data reduction -- Lead compounds -- Mathematical models -- Permittivity -- Specific heat -- Adiabatic calorimetry -- Burns temperature -- Diffuse anomalies -- Barium compounds
Аннотация: The heat capacity of two relaxors BaTi(1-x)ZrxO(3) (x = 0.35, 0.40) was measured using adiabatic calorimetry in the temperature range 100-360 K. The Cp(T) dependence of both compositions is characterized by the presence of two diffuse anomalies near the Burns temperature T-d and the temperature of the maximum in permittivity T-m in the temperature ranges 250-350 K and 120 200 K. The anomalous heat capacity near T-d was analysed taking into account the distribution of Zr concentration in nanoregions leading to the distribution of their transition temperatures into the polar phase. Excess heat capacity near Tm was discussed in the framework of the spherical random bond-random field model. The results are compared with the data obtained by the same procedures for PbMg1/3Nb2/3O3 studied experimentally earlier.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
CNRS, CEMES, F-31055 Toulouse, France
ИФ СО РАН
L V Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
CEMES-CNRS, 31055 Toulouse, France

Доп.точки доступа:
Gorev, M.; Bondarev, V.; Sciau, P.; Savariault, J. M.
}
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Thermal expansion of (Ba1-x La (x) )Ti1-x/4O3 solid solutions / M. V. Gorev [et al.] // Phys. Solid State. - 2009. - Vol. 51, Is. 4. - P. 790-796, DOI 10.1134/S106378340904026X. - Cited References: 22. - This work was supported by the Russian Foundation for Basic Research (project no. 07-02-00069) and the Council on Grants from the President of the Russian Federation for the Support of Leading Scientific Schools of the Russian Federation (grant NSh-1011.2008.2). . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
CERAMICS
   BATIO3
   BA(TI1-XZRX)O-3
   FERROELECTRICS
   CONDUCTIVITY
   BEHAVIOR
   SYSTEM
   PHASE
   HEAT
Аннотация: Deformation and the thermal expansion coefficient of ceramic samples of (Ba1 - x La (x) )Ti1 - x/4O3 solid solutions (x = 0, 0.026, 0.036, 0.054) were studied in the temperature range 120-700 K. Based on an analysis of the data obtained, the temperature-composition phase diagram is refined, and the temperature dependence of the polarization is calculated. The results are discussed in combination with the dielectric measurement data.

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Держатели документа:
[Gorev, M. V.
Flerov, I. N.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Gorev, M. V.
Flerov, I. N.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Sciau, Ph.] Univ Toulouse, CNRS, CEMES, Toulouse, France
[Guillemet-Fritsch, S.] Univ Toulouse, CNRS, INPT, CIRIMAT,UPS, Toulouse, France
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Siberian Federal University, Svobodny pr. 79, Krasnoyarsk 660041, Russian Federation
CEMES-CNRS, Universite de Toulouse, Toulouse, France
CIRIMAT CNRS/UPS/INPT, Universite de Toulouse, Toulouse, France

Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич; Sciau, P.; Guillemet-Fritsch, S.; Russian Foundation for Basic Research [07-02-00069]; Russian Federation [NSh-1011.2008.2]
}
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Thermal expansion, polarization and phase diagrams of Ba1-yBi2y/3Ti1-xZrxO3 and Ba1-yLayTi1-y/4O3 compounds / M. . Gorev [et al.] // J. Phys.: Condens. Matter. - 2009. - Vol. 21, Is. 7. - Ст. 75902. - P., DOI 10.1088/0953-8984/21/7/075902. - Cited References: 28. - This work was supported by the Russian Foundation for Basic Research ( project no. 07-02-00069) and the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools ( project no. NSh-1011.2008.2). . - ISSN 0953-8984

РУБ Physics, Condensed Matter
Рубрики:
HEAT-CAPACITY
   CERAMICS
   BA(TI1-XZRX)O-3
   FERROELECTRICS
   BEHAVIOR
   BATIO3
   BATI0.65ZR0.35O3
   CONDUCTIVITY
   PEROVSKITES
   CHEMISTRY
Кл.слова (ненормированные):
Barium -- Dielectric properties -- Lanthanum -- Phase diagrams -- Polarization -- Thermal stress -- Zirconium -- Ceramic compositions -- Root mean squares -- Temperature ranges -- Temperature-dependent measurements -- Thermal expansion co-efficient -- Thermal-expansion properties -- Thermal expansion
Аннотация: The thermal expansion properties of the ceramic compositions Ba1-yLayTi1-y/4O3 (y = 0.0, 0.026, 0.036, 0.054) and Ba1-yBi2y/3Ti1-xZrxO3 (y = 0.10; x = 0.0, 0.04, 0.05, 0.10, 0.15) were determined in the temperature range 120-700 K. We report the temperature- dependent measurements of the strain, thermal expansion coefficient and the magnitude of root mean square polarization. The results obtained are discussed together with the data on the structure and dielectric properties.

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Держатели документа:
[Gorev, Michail
Bondarev, Vitaly
Flerov, Igor] Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Gorev, Michail
Bondarev, Vitaly
Flerov, Igor] Siberian Fed Univ, Inst Engn Phys, Krasnoyarsk 660041, Russia
[Maglione, Mario
Simon, Annie] Univ Bordeaux 1, ICMCB CNRS, F-33608 Pessac, France
[Sciau, Philippe] Univ Toulouse, CEMES CNRS, F-31055 Toulouse, France
[Boulos, Madona
Guillemet-Fritsch, Sophie] Univ Toulouse, CIRIMAT CNRS UPS INPT, F-31062 Toulouse, France
ИФ СО РАН
L v Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Institute of Engineering Physics, Siberian Federal University, av. Svobodny 79, Krasnoyarsk, 660041, Russian Federation
ICMCB-CNRS, Universite de Bordeaux i, 87 avenue A Schweitzer, 33608 Pessac, France
CEMES-CNRS, Universite de Toulouse, 29 rue Jeanne Marvig, 31055 Toulouse, France
CIRIMAT CNRS/UPS/INPT, Universite de Toulouse, Batiment 2R1, 118 route de Narbonne, 31062 Toulouse, France

Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Flerov, I. N.; Флёров, Игорь Николаевич; Maglione, M.; Simon, A.; Sciau, P.; Boulos, M.; Guillemet-Fritsch, S.; Russian Foundation for Basic Research [07-02-00069]; Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools [NSh-1011.2008.2]
}
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