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Ferroelastic phase transition in Cs3Bi2I9: A neutron diffraction study / A. . Jorio [et al.] // Phys. Rev. B. - 2000. - Vol. 61, Is. 6. - P. 3857-3862, DOI 10.1103/PhysRevB.61.3857. - Cited References: 16
. - ISSN 1098-0121РУБ Physics, Condensed Matter
Рубрики:
CRYSTAL
SCATTERING
CS3SB2I9
Аннотация: Crystalline Cs3Bi2I9, With the P6(3)/mmc symmetry at room temperature was studied by Laue and four-circle neutron diffractometry from room temperature down to 50 K. At T-0 = 220 K the crystal undergoes a second-order proper ferroelastic phase transition to a polydomain structure with a nonprimitive monoclinic C12/m1 space group. Satellites were not found below T-0, indicating that the continuous distribution of sites observed in previous I-127 nuclear quadrupole resonance experiments is due either to an undetected incommensurate phase characterized by a very small displacement amplitude, or due to the fraction of the crystal volume occupied by domain walls. We argue that thick domain walls are expected in the present structure due to the absence of mechanical compatibility between domains.
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Держатели документа:
Univ Fed Minas Gerais, Dept Fis, BR-30123970 Belo Horizonte, MG, Brazil
Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France
LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Ecole Cent Paris, LSPMM, CNRS, UMR 8580, F-92295 Chatenay Malabry, France
CENS, Lab Leon Brillouin, F-91191 Gif Sur Yvette, France
Univ Toulon & Var, LMMI, F-83957 La Garde, France
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Доп.точки доступа:
Jorio, A.; Currat, R.; Myles, DAA; McIntyre, G. J.; Aleksandrova, I. P.; Александрова, Инга Петровна; Kiat, J. M.; Saint-Gregoire, P.
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