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    Ultrafine particles derived from mineral processing: A case study of the Pb-Zn sulfide ore with emphasis on lead-bearing colloids / Y. Mikhlin [et al.] // Chemosphere. - 2016. - Vol. 147. - P. 60-66, DOI 10.1016/j.chemosphere.2015.12.096. - Cited References: 47. - This research was supported by the Russian Science Foundation, Grant No. 14-17-00280. . - ISSN 0045-6535
   Перевод заглавия: Ультрадисперсные частицы, полученные при переработке минерального сырья: комплексный анализ колчеданной руды Pb-Zn и коллоидных частиц, содержащих свинец

РУБ Environmental Sciences
Рубрики:
GALENA DISSOLUTION
   METALLIC COPPER
   NANOPARTICLES
   SOIL
   ENVIRONMENT
   SEPARATION
   TRANSPORT
   FLOTATION
   WATER
   SIZE
Кл.слова (ненормированные):
Lead sulfide -- Lead-zinc ore -- Lead sulfide -- Ultrafine particles -- Aquatic nanoparticles
Аннотация: Although mining and mineral processing industry is a vast source of heavy metal pollutants, the formation and behavior of micrometer- and nanometer-sized particles and their aqueous colloids entered the environment from the technological media has received insufficient attention to date. Here, the yield and characteristics of ultrafine mineral entities produced by routine grinding of the Pb-Zn sulfide ore (Gorevskoe ore deposit, Russia) were studied using laser diffraction analysis (LDA), dynamic light scattering (DLS) and zeta potential measurement, microscopy, X-ray photoelectron spectroscopy, with most attention given to toxic lead species. It was revealed, in particular, that the fraction of particles less that 1 ?m in the ground ore typical reaches 0.4 vol. %. The aquatic particles in supernatants were micrometer size aggregates with increased content of zinc, sulfur, calcium as compared with the bulk ore concentrations. The hydrodynamic diameter of the colloidal species decreased with time, with their zeta potentials remaining about -12 mV. The colloids produced from galena were composed of 20-50 nm PbS nanoparticles associated with lead sulfate and thiosulfate, while the surface oxidation products at precipitated galena were largely lead oxyhydroxides. The size and zeta potential of the lead-bearing colloids decreased with time down to about 100 nm and from -15 mV to -30 mV, respectively. And, conversely, lead sulfide nanoparticles were mobilized before the aggregates during redispersion of the precipitates in fresh portions of water. The potential environmental impact of the metal-bearing colloids, which is due to the large-scale production and relative stability, is discussed. © 2015 Elsevier Ltd.

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Держатели документа:
Inst. of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, Akademgorodok, 50/24, Krasnoyarsk, Russian Federation
Siberian Federal University, Svobodny pr. 79, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50/38, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Mikhlin, Y.; Vorobyev, S.; Romanchenko, A.; Karasev, S.; Karacharov, A.; Zharkov, S. M.; Жарков, Сергей Михайлович
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