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Raman investigation of hydrostatic and nonhydrostatic compressions of OH- and F-apophyllites up to 8 GPa / S. V. Goryainov [et al.] // J. Raman Spectrosc. - 2012. - Vol. 43, Is. 3. - P. 439-447, DOI 10.1002/jrs.3049. - Cited References: 18. - This work was supported by the Siberian Division of RAS (Integration Project 109), the Russian Ministry of Science and Education and the CRDF (BRHE - REC-008 grant) and the Russian Foundation for Basic Research (RFBR-11-05-01121). . - ISSN 0377-0486

РУБ Spectroscopy
Рубрики:
RADIATION-INDUCED DEFECTS
   ALPHA-QUARTZ
   ROOM-TEMPERATURE
   MEMORY GLASS
   PRESSURE
   FLUORAPOPHYLLITE
   PHASE
   MODEL
Кл.слова (ненормированные):
Raman spectroscopy -- high pressure -- apophyllite -- layer silicate -- amorphization
Аннотация: Layer silicates F- and OH-apophyllites, KCa4Si8O20(F, OH)·8H2O, have been investigated by Raman spectroscopy at hydrostatic and nonhydrostatic pressures up to 8 GPa in diamond anvil cells using a 4 : 1 methanol–ethanol mix as pressure-transmitting medium. Our experiments show that at hydrostatic compression, apophyllites retain their crystalline states (i.e. no amorphization) up to 5 GPa. The wavenumbers of most bands exhibit linear dependences on pressure, except for a few ones, e.g. at 162 and 3565 cm–1 in OH-form (160.5 and 3558 cm–1 in F-form) that show nonlinear dependences. Nonhydrostatic compression with additional uniaxial loading induces amorphization of apophyllites. The majority of the bands in OH-apophyllite decreases markedly in intensity and shows considerable broadening under nonhydrostatic compression up to 3–6 GPa. In addition, the wavenumbers of several bands at nonhydrostatic compression exhibit considerable nonlinear dependences on pressure with strong hysteresis. These bands are mainly associated with vibrations of the interlayer ions and molecules and also of stretching and bending silicate sheets, hence being highly sensitive to the interlayer distance. Finally, we have calculated the lattice dynamics of F-apophyllite and interpreted the majority of bands, and these data are used to explain the complex baric behavior of the bands. Copyright © 2011 John Wiley & Sons, Ltd.

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Держатели документа:
[Goryainov, Sergei V.
Madyukov, Iliya A.] SB RAS, Inst Geol & Mineral, Novosibirsk 630090, Russia
[Goryainov, Sergei V.
Pan, Yuanming] Univ Saskatchewan, Dept Geol Sci, Saskatoon, SK S7N 5E2, Canada
[Goryainov, Sergei V.] Novosibirsk State Univ, Novosibirsk 630090, Russia
[Krylov, Alexander S.
Vtyurin, Alexander N.] SB RAS, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Smirnov, Mikhail B.] St Petersburg State Univ, Fac Phys, St Petersburg 198504, Russia

Доп.точки доступа:
Goryainov, S. V.; Krylov, A. S.; Крылов, Александр Сергеевич; Pan, Y. M.; Madyukov, I. A.; Smirnov, M. B.; Vtyurin, A. N.; Втюрин, Александр Николаевич
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