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    Insights into Ba4Si6O16 structure and photoluminescence tuning of Ba4Si6O16:Ce3+,Eu2+ phosphors / Chen M. [et al.] // J. Mater. Chem. C. - 2015. - Vol. 3, Is. 48. - P. 12477-12483, DOI 10.1039/c5tc03271g. - Cited References: 39. - This work was supported by the National Natural Science Foundations of China (Grant No. 51572023 and 51272242), Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), the Funds of the State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University (KF201306), and Fundamental Research Funds for the Central Universities (FRF-TP-14-005A1). . - ISSN 2050-7534
   Перевод заглавия: Исследования структуры Ba4Si6O16 и люминесцентных свойств Ba4Si6O16:Ce3+,Eu2+
РУБ Materials Science, Multidisciplinary + Physics, Applied
Рубрики:
LIGHT-EMITTING-DIODES
   ENERGY-TRANSFER

   LUMINESCENCE PROPERTIES

   WHITE-LIGHT

   GLASS-CERAMICS

   BA PHOSPHORS

   EMISSION

   GREEN

   EU2+

   FLUORESCENCE

Аннотация: The versatile polymorphism and chemical compositions of barium silicates have been studied for a long time and their crystal structures have been established. Herein, we focused on the understanding of the crystal structure of the Ba4Si6O16 phase and the structural correlation of Ba4Si6O16 and Ba2Si3O8; moreover, the luminescence properties of Ce3+,Eu2+-co-activated Ba4Si6O16 phosphors have been discussed. Ba4Si6O16:Ce3+,Eu2+ phosphors show tunable blue-green emission upon excitation with 365 nm ultraviolet (UV) light. The blue emission originates from Ce3+, whereas the bluish-green emission is ascribed to Eu2+, and variation in the emission peak wavelength from 442 to 497 nm can be achieved by properly tuning the Ce3+/Eu2+ ratio. Energy transfer from Ce3+ to Eu2+ in the Ba4Si6O16 host has been validated by the variation of emission spectra as well as the variation of Ce3+ decay lifetimes with increasing Eu2+ concentration, and the energy transfer mechanism is demonstrated to be a resonant type via a dipole-dipole process. The results suggest that Ba4Si6O16:Ce3+,Eu2+ phosphors are potential candidates as a blue-green component for UV-excited white light-emitting diodes. © 2015 The Royal Society of Chemistry.

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Держатели документа:
Key Laboratory of New Energy Materials and Technologies, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation

Доп.точки доступа:
Chen M.; Xia Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Liu Q.
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