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    Studies of the heat capacity and thermal expansion of the Na0.95K0.05NbO3 solid solution / M. V. Gorev [et al.] // Phys. Solid State. - 2014. - Vol. 56, Is. 2. - P. 367-372, DOI 10.1134/S1063783414020115. - Cited References: 27. - This study was supported by the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools of the Russian Federation (grant no. NSh-4828.2012.2) and the Russian Foundation for Basic Research (project no. 12-02-31799 mol_a). . - ISSN 1063-7834. - ISSN 1090-6460
РУБ Physics, Condensed Matter
Рубрики:
SODIUM NIOBATE
   PHASE-TRANSITIONS

   TEMPERATURE-RANGE

   SINGLE-CRYSTALS

   KNBO3

   FERROELECTRICS

   DIFFRACTION

   OCTAHEDRA

Аннотация: The heat capacity and thermal expansion of ceramic samples of the Na0.95K0.05NbO3 solid solution have been investigated over a wide temperature range of 100-750 K. The observed anomalies in the heat capacity and thermal expansion at T (4) = 297 K, T (3) = 535 K, T (2) = 665 K, and T (1) a parts per thousand 710 K correspond to the sequences of phase transitions N - Q - G - S - T1. It has been shown that, as a result of the phase transitions, the unit cell volume at T (4) and T (2) decreases, and at T (3) and T (1), increases with increasing temperature. The directions of the shift of the phase transition temperatures induced by hydrostatic pressure have been determined. It has been established that all structural transformations are accompanied by relatively small variations in the entropy. Different mechanisms of the structural distortions have been discussed.

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Публикация на русском языке Исследования теплоемкости и теплового расширения твердого раствора Na0.95K0.05NbO3 [Текст] / М. В. Горев [и др.] // Физ. тверд. тела. - 2014. - Т. 56 Вып. 2. - С. 362-367

Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660074, Russia
Southern Fed Univ, Inst Phys Res, Rostov Na Donu 344090, Russia

Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Raevskaya, S. I.; Ivliev, M. P.; Raevskii, I. P.; Flerov, I. N.; Флёров, Игорь Николаевич; Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools of the Russian Federation [NSh-4828.2012.2]; Russian Foundation for Basic Research [12-02-31799 mol_a]
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