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Surface bonding states of nano-crystalline diamond balls / J. L. Peng [et al.] // Int. J. Mod. Phys. B. - 2001. - Vol. 15, Is. 31. - P. 4071-4085, DOI 10.1142/S0217979201007865. - Cited References: 20 . - ISSN 0217-9792

РУБ Physics, Applied + Physics, Condensed Matter + Physics, Mathematical
Рубрики:
PLASMON RESPONSE
   POWDER
   SPECTROSCOPY
   MICROSCOPY
   SILICON
   SI(111)
Кл.слова (ненормированные):
diamond -- article -- crystal structure -- electron -- energy transfer -- nanoparticle -- particulate matter -- structure analysis -- surface property -- transmission electron microscopy
Аннотация: The rough surface of nano-crystalline diamond spheres induces surface electronic states which appear as a broadened pre-peak over approx. 15 eV at the C K-edge energy threshold for carbon in the parallel electron energy loss spectrum (PEELS). This appears to be at least partially due to 1s-pi* transitions, although typically the latter occupy a range of only 4 eV for the sp(2) edge of highly-oriented pyrollytic graphite (HOPG). No pi* electrons appear in the conduction band inside the diamond particles, where all electrons are sp(3) hybridized. PEELS data were also obtained from a chemical vapour deposited diamond film (CVDF) and gem-quality diamond for comparison with the spectra of nano-diamonds. The density of sp(2) and sp(3) states on the surface of diamond nano-crystals is calculated for simple structural models of the diamond balls, including some conjecture about surface structures. The results are used to interpret the sp(2)/sp(3) ratios measured from the PEELS spectra recorded as scans across the particles. Surface roughness at the atomic scale was also examined using high-resolution transmission electron microscopy (HRTEM) and electron nano-diffraction patterns were used to confirm the crystal structures.

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Держатели документа:
RMIT Univ, Dept Appl Phys, Melbourne, Vic 3051, Australia
Univ Sydney, Electron Microscope Unit, Sydney, NSW 2006, Australia
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Mol Architecture Grp, Krasnoyarsk 660036, Russia
Russian Acad Sci, Siberian Branch, Inst Biophys, Krasnoyarsk 660036, Russia
Univ Melbourne, Sch Phys, Parkville, Vic 3052, Australia
ИФ СО РАН
ИБФ СО РАН
Department of Applied Physics, RMIT University, Swanston Street, Melbourne, Vic. 3051, Australia
Electron Microscope Unit, University of Sydney, NSW 2006, Australia
Molecular Architecture Group, Kirensky Institute of Physics, Institute of Biophysics, 660036 Krasnoyarsk, Russian Federation
School of Physics, University of Melbourne, Parkville, Vic. 3010, Australia

Доп.точки доступа:
Peng, J. L.; Bulcock, S.; Belobrov, P. I.; Белобров, Петр Иванович; Bursill, L. A.
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Dzebisashvili, D. M.
London Penetration Depth as a Test of Order Parameter Symmetry in Sodium Cobaltate Superconductors / D. M. Dzebisashvili, A. B. Klyuchantsev // Symmetry-Basel. - 2019. - Vol. 11, Is. 5. - Ст. 633, DOI 10.3390/sym11050633. - Cited References: 43. - The work was financially supported by the Russian Foundation for Basic Research (RFBR) (project no. 18-02-00837) and by the program of the Presidium of the Russian Academy of Sciences No. 12 "Fundamental problems of high-temperature superconductivity". . - ISSN 2073-8994

РУБ Multidisciplinary Sciences
Рубрики:
SPIN
   DEPENDENCE
   POWDER
   CHARGE
   PHASE
   GAP
Кл.слова (ненормированные):
chiral order parameter -- London penetration depth -- sodium cobaltate superconductor
Аннотация: Temperature dependence of the magnetic field penetration depth λ was calculated for water intercalated sodium cobaltate superconductor NaxCoO2⋅yH2O. Assuming that the system is in the chiral d+id–wave superconducting state, it was shown that the shifting of the excitation spectrum nodal points off the normal phase Fermi surface due to variation of the sodium content x changes the functional form of the temperature dependence of λ−2 from exponential to linear in the low temperatures region. It is argued that this change in the functional form of T–dependence of the λ−2 can serve as a proof for the chiral symmetry of the superconducting order parameter in the sodium cobaltate.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Reshetnev Siberian State Univ Sci & Technol, Krasnoyarsk 660037, Russia.

Доп.точки доступа:
Klyuchantsev, Andrey B.; Дзебисашвили, Дмитрий Михайлович; Russian Foundation for Basic Research (RFBR) [18-02-00837]; Presidium of the Russian Academy of Sciences [12]
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