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The cis-trans isomer transformation, spectroscopic and thermal properties of Li, Na, K 1,3-diethyl-2-thiobarbiturate complexes / N. N. Golovnev [et al.]> // Polyhedron. - 2015. - Vol. 85. - P. 493-498, DOI 10.1016/j.poly.2014.09.011. - Cited References:42. - The study has been carried out within the public task of the Ministry ofEducation and Science of the Russian Federation for research engineeringat the Siberian Federal University in 2014. V.V.A. is partly supportedby the Ministry of Education and Science of the Russian Federation.
. - ISSN 0277-5387 Перевод заглавия: Трансформация цис-транс изомеров, спектроскопические и термические свойства Li, Na, K 1,3-диэтил-2-тиобарбитуратных комплексовРУБ Chemistry, Inorganic & Nuclear + Crystallography Рубрики: CRYSTAL-STRUCTURE 2-THIOBARBITURIC ACID STRUCTURAL-CHARACTERIZATION HYDROGEN-BOND DIFFRACTION THIOBARBITURATE CHEMISTRY NETWORKS SPECTRA SERIES Кл.слова (ненормированные): 1,3-Diethyl-2-thiobarbituric acid -- Alkali ions -- X-ray diffraction -- Infrared spectroscopy -- Thermal analysis Аннотация: Three new complexes of 1,3-diethyl-2-thiobarbituric acid (C8H11N2O2S, HDETBA) with Li+, Na+, K+ alkali ions were synthesized. The complexes have been prepared by neutralization of 1,3-diethyl-2-thiobarbituric acid with the corresponding metal hydroxide in aqueous solution. The colorless crystals have been investigated using X-ray single crystal and powder techniques and characterized by differential scanning calorimetry, thermogravimetry and infrared spectroscopy. The compounds of MDETBA with M = Li and M = Na crystallize in the monoclinic lattice with a = 10.678(1) Å, b = 7.2687(9) Å, c = 13.202(2) Å, β = 108.841(2)°, Z = 4, V = 969.8(2) Å3, S.G. P21/n and a = 10.534(2) Å, b = 7.604(1) Å, c = 14.186(1) Å, β = 108.964(4)°, Z = 4, V = 1074.6(3) Å3, S.G. P21/n, respectively. Сompound KDETBA crystallizes in the orthorhombic lattice with a = 4.2541(6) Å, b = 14.739(2) Å, c = 16.635(3) Å, Z = 4, V = 1043.1(3) Å3, S.G. P212121. In Li(I) and Na(I) complexes, the DETBA− ion is in cis-configuration and, in the K(I) complex, this ion is in trans-configuration. The reason for the transformation from cis- to trans-configuration has been rationalized.
Смотреть статью, Scopus, WOS, Читать в сети ИФ Держатели документа: Siberian Fed Univ, Dept Chem, Krasnoyarsk 660041, Russia SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia SB RAS, Inst Chem & Chem Technol, Lab Catalyt Convers Small Mol, Krasnoyarsk 660036, Russia SB RAS, Irkutsk Favorsky Inst Chem, Phys Chem Lab, Irkutsk 664033, Russia Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia Доп.точки доступа: Golovnev, N. N.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Vereshchagin, Sergey N.; Sterkhova, I. V.; Atuchin, V. V.; Ministry of Education and Science of the Russian Federation } Найти похожие
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