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Aver'yanov, E. M.
Mean polarizability of molecules and anisotropy of the Lorentz tensor upon a nematic-smectic a phase transition: Their behavior in a homologous series / E.M. Aver'yanov // Russ. J. Phys. Chem. A. - 2012. - Vol. 86, Is. 5. - P. 720-728, DOI 10.1134/S0036024412050044. - Cited References: 37 . - ISSN 0036-0244

РУБ Chemistry, Physical + Anisotropy + Molecules + Phase transitions + Tensors
Рубрики:
CHOLESTERIC LIQUID-CRYSTALS
   REFRACTIVE-INDEX DATA
   A PHASE
   MESOMORPHIC PROPERTIES
   ORIENTATIONAL ORDER
   OPTICAL ANISOTROPY
   LOCAL-FIELD
   POLYMORPHISM
   TEMPERATURE
   A-monotone
   Alkyl chain
   Experimental values
   Homologous series
   Homologues
   Limiting values
   Lorentz
   Mesophases
   Molecular core
   Molecular polarizabilities
   Nematic
   Orientational order parameters
   Polarizabilities
   Polarizability density
   Quadratic dependence
   A-monotone
   Smectic
   Smectic phase
   Smectic phasis
   Smectic-A phasis
Кл.слова (ненормированные):
molecular polarizability -- anisotropy -- phase transition -- nematic -- smectic -- homologues
Аннотация: Experimental values of the mean polarizability of molecules, (gamma) over bar, and components of the Lorentz tensor, L-j, in the nematic and smectic A phases are obtained for a homologous series of n-alkyl-p-(4-ethoxybenzylideneamino)-alpha-methylcinnamates. Dependences of the (gamma) over bar and L-j values on the mesophase temperature, the orientational order parameter S of molecules, and the number n in the homologous series are revealed. The quadratic dependence of (gamma) over bar (S) in the nematic and smectic phases is established that is invariant with respect to the nematic-smectic A transition. Polarizability densities of the molecular core and the alkyl chain are found from the monotone decreasing dependence (gamma) over bar (n)/v (where v is volume per one molecule) in the smectic phase. The presence (or absence) of the odd-even alternation of L-j(n) in the nematic (smectic) phase is shown. A monotone decrease in the Lorentz tensor anisotropy L with an increase in n is revealed in the smectic phase, and limiting values L-j(n -> infinity) are determined.

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Публикация на русском языке Аверьянов, Евгений Михайлович. Изменение средней поляризуемости молекул и анизотропии тензора Лорентца при фазовом переходе нематик – смектик А и в гомологическом ряду [Текст] / Е.М. Аверьянов // Журн. физ. химии : Наука, 2012. - Т. 86 № 5. - С. 810-818

Доп.точки доступа:
Аверьянов, Евгений Михайлович
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Spherical magnetic nanoparticles fabricated by laser target evaporation / A. P. Safronov [et al.] // AIP Adv. - 2013. - Vol. 3, Is. 5. - Ст. 052135. - P. , DOI 10.1063/1.4808368. - Cited References: 47. - This work was supported by the RFBR 10-02-96015 and 12-02-31385 projects, UrFU 215, Spanish MEC MAT2011-27573-C04 grants, Universidad del Pais Vasco UPV/EHU under UFI11/53 action and Physics Department of the University of Maryland visiting grant. Selected measurements were performed at SGIker service of UPV-EHU. We thank O.M. Samatov, Dr. A.M. Murzakayev, Dr. I. Orue, and A.A. Svalova for special support. . - ISSN 2158-3226

РУБ Nanoscience & Nanotechnology + Materials Science, Multidisciplinary + Physics, Applied
Рубрики:
IRON-OXIDE NANOPOWDERS
   CO2-LASER EVAPORATION
   FE3O4 NANOPARTICLES
   FINITE-SIZE
   TEMPERATURE
   FERROMAGNETS
   FERROFLUIDS
   DEPENDENCE
   EXPLOSION
   PARTICLES
Аннотация: Magnetic nanoparticles of iron oxide (MNPs) were prepared by the laser target evaporation technique (LTE). The main focus was on the fabrication of de-aggregated spherical maghemite MNPs with a narrow size distribution and enhanced effective magnetization. X-ray diffraction, transmission electron microscopy, magnetization and microwave absorption measurements were comparatively analyzed. The shape of the MNPs (mean diameter of 9 nm) was very close to being spherical. The lattice constant of the crystalline phase was substantially smaller than that of stoichiometric magnetite but larger than the lattice constant of maghemite. High value of M-s up to 300 K was established. The 300 K ferromagnetic resonance signal is a single line located at a field expected from spherical magnetic particles with negligible magnetic anisotropy. The maximum obtained concentration of water based ferrofluid was as high as 10g/l of magnetic material. In order to understand the temperature and field dependence of MNPs magnetization, we invoke the core-shell model. The nanoparticles is said to have a ferrimagnetic core (roughly 70 percent of the caliper size) while the shell consists of surface layers in which the spins are frozen having no long range magnetic order. The core-shell interactions were estimated in frame of random anisotropy model. The obtained assembly of de-aggregated nanoparticles is an example of magnetic nanofluid stable under ambient conditions even without an electrostatic stabilizer. (C) 2013 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution 3.0 Unported License.

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Держатели документа:
RAS, Inst Electrophys, Ekaterinburg 620016, Russia
Urals Fed Univ, Ekaterinburg 620000, Russia
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Univ Basque Country UPV EHU, Dept Elect & Elect, Bilbao 48080, Spain
Univ Basque Country UPV EHU, SGIker, Bilbao 48080, Spain
Univ Maryland, Dept Phys, FMR Grp, College Pk, MD 20742 USA

Доп.точки доступа:
Safronov, A. P.; Beketov, I. V.; Komogortsev, S. V.; Комогорцев, Сергей Викторович; Kurlyandskaya, G. V.; Medvedev, A. I.; Leiman, D. V.; Larranaga, A.; Bhagat, S. M.
}
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Synthesis and structural properties of cubic G0-Rb2KMoO3F3 oxyfluoride / V. V. Atuchin [et al.] // Ceram. Int. - 2012. - Vol. 38, Is. 3. - P. 2455-2459, DOI 10.1016/j.ceramint.2011.11.013. - Cited References: 23. - This study was partly supported by RFBR (Grant 09-02-00062) and SB RAS (Grant 34). . - ISSN 0272-8842

РУБ Materials Science, Ceramics
Рубрики:
PHASE-TRANSITIONS
   FERROELECTRIC K3WO3F3
   (NH4)(3)MOO3F3
   TEMPERATURE
   PEROVSKITE
   ELPASOLITE
   CRYSTALS
   BEHAVIOR
   High temperature
   Melt solidification
   Micromorphologies
   Melt solidification
   Microstructure-final
   Oxyfluorides
   Space Groups
   Oxyfluorides
   X ray methods
Кл.слова (ненормированные):
Powders: solid state reaction -- Microstructure-final -- X-ray methods -- Alkali oxides -- Halides
Аннотация: High-temperature G0 polymorph of Rb2KMoO3F3 has been prepared by melt solidification. Micromorphology and chemical properties of the final product were evaluated by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The elpasolite-related crystal structure of G0-Rb2KMoO3F3 has been refined by Rietveld method at T = 298 K (space group Fm-3m, a = 8.92446(8) Å, V = 710.76(1) Å3; RB = 3.55%). Ferroelectric G1-Rb2KMoO3F3 polymorph, earlier reported at T˂328 K, is not found at T = 298 K.

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Держатели документа:
[Atuchin, V. V.] SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090 90, Russia
[Gavrilova, T. A.] SB RAS, Inst Semicond Phys, Lab Nanolithog & Nanodiagnost, Novosibirsk 630090 90, Russia
[Isaenko, L. I.
Zhurkov, S. A.] SB RAS, Inst Geol & Mineral, Lab Crystal Growth, Novosibirsk 530090 90, Russia
[Kesler, V. G.] SB RAS, Inst Semicond Phys, Lab Phys Principles Integrated Microelect, Novosibirsk 630090 90, Russia
[Molokeev, M. S.] SB RAS, Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036 36, Russia

Доп.точки доступа:
Atuchin, V. V.; Gavrilova, T. A.; Isaenko, L. I.; Kesler, V. G.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zhurkov, S. A.
}
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Heat capacity and thermodynamic properties of GaFeO3 in the range 330-900 K / V. M. Denisov [et al.] // Inorg. Mater. - 2013. - Vol. 49, Is. 12. - P. 1227-1228, DOI 10.1134/S0020168513120042. - Cited References: 10 . - ISSN 0020-1685

РУБ Materials Science, Multidisciplinary
Рубрики:
MULTIFERROIC GAFEO3
   SINGLE-CRYSTALS
   TEMPERATURE
   BIFEO3
Аннотация: The heat capacity of multiferroic GaFeO3 has been measured in a wide temperature range and the results have been used to evaluate its thermodynamic functions (enthalpy increment and entropy change).

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Публикация на русском языке Теплоемкость и термодинамические свойства GaFeO3 в области 330–900 К. - [S. l. : s. n.]

Держатели документа:
Siberian Fed Univ, Inst Nonferrous Met & Mat Sci, Krasnoyarsk 660041, Russia
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660074, Russia

Доп.точки доступа:
Denisov, V. M.; Irtyugo, L. A.; Denisova, L. T.; Patrin, G. S.; Патрин, Геннадий Семёнович; Volkov, N. V.; Волков, Никита Валентинович
}
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Kagan, M. Y.
Anomalous resistivity and the electron-polaron effect in the two-band hubbard model with one narrow band / M. Y. Kagan, V. V. Val'kov // J. Supercond. Nov. Magn. - 2012. - Vol. 25, Is. 5. - P. 1379-1382, DOI 10.1007/s10948-012-1523-3. - Cited References: 28. - We are grateful to P. Fulde, Yu. Kagan, K. I. Kugel, N.V. Prokof'ev, P. Nozieres, and C. M. Varma for the numerous stimulating discussions. We acknowledge financial support of the RFBR Grant No. 11-02-00741. . - ISSN 1557-1939

РУБ Physics, Applied + Physics, Condensed Matter
Рубрики:
FERMI GAS
   SUPERCONDUCTIVITY
   SUPERFLUIDITY
   TEMPERATURE
   REPULSION
   SYSTEMS
Кл.слова (ненормированные):
Electron-polaron effect -- Two-band Hubbard model -- Marginality -- Anomalous resistivity
Аннотация: We search for anomalous normal and superconductive behavior in the two-band Hubbard model with one narrow band. We analyze the influence of the electron–polaron effect and the Altshuler–Aronov effect on effective mass enhancement and scattering times of heavy and light components in the clean case. We find anomalous behavior of resistivity at high temperatures T>W∗hT > W_{h}^{*} both in 3D and 2D situations. The SC instability in the model is governed by an enhanced Kohn–Luttinger effect for p-wave pairing of heavy electrons via polarization of light electrons.

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Держатели документа:
[Kagan, M. Y.] PL Kapitza Inst Phys Problems, Moscow 119334, Russia
[Val'kov, V. V.] Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
P.L. Kapitza Institute for Physical Problems, Kosygina st. 2, 119334 Moscow, Russian Federation
Kirenskii Institute of Physics, Akademgorodok 50, Building 38, 660036 Krasnoyarsk, Russian Federation

Доп.точки доступа:
Val'kov, V. V.; Вальков, Валерий Владимирович; Каган, Максим Юрьевич
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Caloric effects and phase transitions in ferromagnetic-ferroelectric composites xLa(0.7)Pb(0.3)MnO(3)-(1-x)PbTiO3 / E. A. Mikhaleva [et al.] // J. Mater. Res. - 2013. - Vol. 28, Is. 24. - P. 3322-3331, DOI 10.1557/jmr.2013.360. - Cited References: 24. - This study was supported in parts by The Russian Foundation for Basic Research (Grant No. 12-02-31253-mol-a), Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" (N 8379), and Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools (Grant NO. NSh-4828.2012.2). Dr. Maxim S. Molokeev is acknowledged for the x-ray characterization of the samples. . - ISSN 0884-2914. - ISSN 2044-5326

РУБ Materials Science
Рубрики:
PRESSURE
TEMPERATURE
Аннотация: Ceramic volumetric composites xLa(0.7)Pb(0.3)MnO(3)-(1-x)PbTiO3 (x = 0.18 and 0.85) were prepared. X-ray investigations have shown that rather low sintering temperature (800 degrees C) has allowed us to avoid the reaction and interdiffusion between two initial phases. Heat capacity, thermal expansion, and intensive magnetocaloric effect were measured in a wide temperature range. The sample composition has a low influence on temperatures of the ferromagnetic and ferroelectric phase transitions in composites. Electro- and barocaloric effects were determined by analysis in the framework of thermodynamic theory, electric equation of state, Maxwell relationships, and entropy-temperature-pressure phase diagram. Multicaloric efficiency of composites is discussed and compared with that of initial La0.7Pb0.3MnO3 and PbTiO3 compounds. Variation of a relationship between components can significantly increase both barocaloric and magnetocaloric efficiency of compositional material due to the mechanical stress appearing between grains of different ferroic phases under magnetic field.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660079, Russia

Доп.точки доступа:
Mikhaleva, E. A.; Михалева, Екатерина Андреевна; Flerov, I. N.; Флёров, Игорь Николаевич; Kartashev, A. V.; Карташев, Андрей Васильевич; Gorev, M. V.; Горев, Михаил Васильевич; Cherepakhin, A. V.; Черепахин, Александр Владимирович; Sablina, K. A.; Саблина, Клара Александровна; Mikhashenok, N. V.; Михашенок, Наталья Владимировна; Volkov, N. V.; Волков, Никита Валентинович; Shabanov, A. V.; Шабанов, Александр Васильевич; Russian Foundation for Basic Research [12-02-31253-mol-a]; Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" [N 8379]; Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools [NSh-4828.2012.2]
}
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Krasnov, P. O.
Interaction of Scandium and Titanium Atoms with a Carbon Surface Containing Five- and Seven-Membered Rings / P. O. Krasnov, N. S. Eliseeva, A. A. Kuzubov // J. Exp. Theor. Phys. - 2012. - Vol. 114, Is. 1. - P. 80-84, DOI 10.1134/S1063776111160059. - Cited References: 25. - We are grateful to the Joint Supercomputer Center, Russian Academy of Sciences, for the possibility of using the computer cluster for our quantum-chemical calculations. This work was supported by the Ministry of Education and Science of the Russian Federation (federal program "Human Capital for Science and Education in Innovative Russia" for 2009-2013). . - ISSN 1063-7761. - ISSN 1090-6509

РУБ Physics, Multidisciplinary
Рубрики:
MOLECULAR-HYDROGEN COMPLEXES
   STORAGE
   NANOTUBES
   TRANSITION
   ENERGY
   TEMPERATURE
   EXCHANGE
   DYNAMICS
   METALS
   C60
Аннотация: The use of carbon nanotubes coated by atoms of transition metals to store molecular hydrogen is associated with the problem of the aggregation of these atoms, which leads to the formation of metal clusters. The quantum-chemical simulation of cluster models of the carbon surface of a graphene type with scandium and titanium atoms has been performed. It has been shown that the presence of five- and seven-membered rings, in addition to six-membered rings, in these structures makes it possible to strongly suppress the processes of the migration of metal atoms over the surface, preventing their clustering.

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Публикация на русском языке Краснов, Павел Олегович. Взаимодействие атомов скандия и титана с углеродной поверхностью, содержащей пятичленные и семичленные кольца [Текст] / П. О. Краснов, Н. С. Елисеева, А. А. Кузубов // Журн. эксперим. и теор. физ. : Наука, 2012. - Т. 141 Вып. 1. - С. 90-95

Держатели документа:
[Krasnov, P. O.
Kuzubov, A. A.] Siberian State Technol Univ, Krasnoyarsk 660049, Russia
[Krasnov, P. O.
Kuzubov, A. A.] Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
[Eliseeva, N. S.
Kuzubov, A. A.] Siberian Fed Univ, Krasnoyarsk 660041, Russia

Доп.точки доступа:
Eliseeva, N. S.; Kuzubov, A. A.; Кузубов, Александр Александрович; Краснов, Павел Олегович; Ministry of Education and Science of the Russian Federation
}
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Measurement of Raman-scattering spectra of Rb2KMoO3F3 crystal: Evidence for controllable disorder in the lattice structure / A. S. Krylov [et al.] // Cryst. Growth Des. - 2014. - Vol. 14, Is. 3. - P. 923-927, DOI 10.1021/cg4008894. - Cited References: 31. - The authors are grateful to Prof. I. N. Flerov for valuable support and useful discussions. The authors acknowledge stimulating discussions with Dr. S. N. Sofronova and Dr. A. S. Aleksandrovsky. The assistance of Dr. S. Skokov is sincerely appreciated. This work was partly supported by Russian Foundation for Basic Research project nos. 11-02-98002-r and 12-02-00056 and integration project SB RAS no. 28, SS-4828.2012.2 grant, and Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" (no. 8379). . - ISSN 1528-7483. - ISSN 1528-7505

РУБ Chemistry, Multidisciplinary + Crystallography + Materials Science, Multidisciplinary
Рубрики:
PHASE-TRANSITIONS
   OXYFLUORIDE
   ELPASOLITE
   (NH4)3MOO3F3
   (NH4)3WO3F3
   TEMPERATURE
   DYNAMICS
   N-2
   Cs
Аннотация: The λ-shaped line width broadening anomalies of octahedron group vibrations in Rb2KMoO3F3 disordered crystal have been revealed in the wide temperature range by Raman technique. The line width of Mo-O and Mo-F vibrations in this crystal is connected with the lattice disorder. The dependence of ordering degree passing the phase transition point history has been discovered. Wide temperature-line width area is found below structural phase transition where different lattice disorder can be obtained at a given temperature by varying the rate of sample cooling. The current study demonstrates the ability of a dynamic temperature regime to control ordering processes in crystals. © 2014 American Chemical Society.

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Держатели документа:
SB RAS, LV Kirensky Inst Phys, Krasnoyarsk 660036, Russia
SB RAS, VS Sobolev Inst Geol & Mineral, Novosibirsk 630090, Russia

Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Kolesnikova, E. M.; Колесникова, Евгения Михайловна; Isaenko, L. I.; Krylova, S. N.; Крылова, Светлана Николаевна; Vtyurin, A. N.; Втюрин, Александр Николаевич; Russian Foundation for Basic Research [11-02-98002-r, 12-02-00056]; integration project SB RAS [28, SS-4828.2012.2]; Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" [8379]
}
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Vortex pinning and magnetic peak effect in Eu(Eu,Ba)2.125Cu3Ox / E. Altin [et al.] // J. Mater. Sci.-Mater. Electron. - 2014. - Vol. 25, Is. 3. - P. 1466-1473, DOI 10.1007/s10854-014-1753-1. - Cited References: 30 . - ISSN 0957-4522. - ISSN 1573-482X

РУБ Engineering, Electrical & Electronic + Materials Science, Multidisciplinary + Physics, Applied + Physics, Condensed Matter
Рубрики:
SUPERCONDUCTORS
   FIELD
   NANOCRYSTALLINE
   TEMPERATURE
   LOOP
Аннотация: Eu–Ba–Cu–O composition was synthesized by solid state reaction technique. To determine optimum growth temperature, heat treatment was examined on the material at 880–1,100 °C. Microstructural evolution, phase formation and elemental distribution depending on heat treatments were examined by using X-ray diffraction, scanning electron microscope, energy dispersive X-ray spectroscope analysis. Optimum fabrication conditions were determined as 1,020 °C for 24 h under oxygen atmosphere and detailed characterization of corresponding compound was performed. The magnetization hysteresis loops are expounded to be the product of superconducting Eu-123 grains and magnetic Eu2+ ions. The peak effect on the magnetization curves was described by the extended critical state model. Scaling of the pinning force was found such that the peak position is proportional to the irreversibility field H irr and the maximum pinning force is proportional to H irr 2 .

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Держатели документа:
Inonu Univ, Bilimsel & Teknolojik Arastirma Merkezi, TR-44280 Malatya, Turkey
LV Kirensky Inst Phys SB RAS, Krasnoyarsk 660036, Russia
Inonu Univ, Fen Edebiyat Fak, Fizik Bolumu, Superiletkenlik Arastirma Grubu, TR-44280 Malatya, Turkey

Доп.точки доступа:
Altin, E.; Gokhfeld, D. M.; Гохфельд, Денис Михайлович; Demirel, S.; Oz, E.; Kurt, F.; Altin, S.; Yakinci, M.E.
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10.

Synthesis and luminescence properties of Li2O–Y2O3–TeO2:Eu3+ tellurite glass / V. V. Atuchin [et al.] // Mater. Chem. Phys. - 2014. - Vol. 147, Is. 3. - P. 1191-1194, DOI 10.1016/j.matchemphys.2014.07.003. - Cited References: 26. - This study is partly supported by the Ministry of Education and Science of the Russian Federation. . - ISSN 0254-0584. - ISSN 1879-3312

РУБ Materials Science, Multidisciplinary
Рубрики:
LIGHT-EMITTING-DIODES
   SPECTROSCOPIC PROPERTIES
   OPTICAL-PROPERTIES
   ENERGY-TRANSFER
   CERAMICS
   Eu3+
   PHOTOLUMINESCENCE
   TEMPERATURE
   EMISSION
   PHOSPHOR
Кл.слова (ненормированные):
Glasses -- Heat treatment -- Photoluminescence spectroscopy -- Optical properties
Аннотация: The Eu3+-doped red-orange emitting phosphor of tellurite glass 0.25Li2O–0.20Y2O3–0.5TeO2–0.05Eu2O3 has been synthesized by the melt quenching method. The amorphous nature of the glass has been verified by XRD measurements. The photoluminescence excitation and emission spectra, the luminescence decay curves have been investigated for the composition. The phosphor can be efficiently excited by the near UV light to realize the intense narrow red emission line (611 nm) corresponding to forced electric dipole transition 5D0 → 7F2 of Eu3+ ions. The Li2O–Y2O3–TeO2:Eu3+glass phosphor is a potential red-orange emitting candidate for the application in WLEDs.

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Держатели документа:
SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia
SB RAS, Inst Geol & Mineral, Lab High Pressure Minerals & Diamond Deposits, Novosibirsk 630090, Russia
Novosibirsk State Univ, Dept Appl Phys, Novosibirsk 630090, Russia
SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Atuchin, V. V.; Yelisseyev, A. P.; Galashov, E. N.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Ministry of Education and Science of the Russian Federation
}
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