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Near-zero thermal expansion and high ultraviolet transparency in a borate crystal of Zn4B6O13 / X. X. Jiang [et al.] // Adv. Mater. - 2016. - Vol. 28, Is. 36. - P. 7936-7940, DOI 10.1002/adma.201601816. - Cited References:38. - The authors acknowledge Zhuohong Yin for useful discussion and Dr. Siyang Luo for the help in crystal fabrication. This work was supported by the Special Foundation of the Director of Technical Institute of Physics and Chemistry (TIPC), the National Scientific Foundations of China (Grant 11474292 and 51401224), and China "863" project (No. 2015AA034203).
. - ISSN 0935-9648. - ISSN 1521-4095
Перевод заглавия: Нулевое тепловое расширение и высокая ультрафиолетовая прозрачность в борате Zn4B6O13РУБ Chemistry, Multidisciplinary + Chemistry, Physical + Nanoscience
Рубрики:
ZN4O(BO2)6
TETRAHEDRA
BEHAVIOR
RANGE
Аннотация: Intrinsic isotropic near-zero thermal expansion is discovered in borate crystal Zn4B6O13 with high transparency in the ultraviolet region. First-principles calculations demonstrate that the very low thermal expansion originates mainly from the invariability of the solid [B24O48] truncated octahedra that are fixed by the [Zn4O13] clusters in the ZBO structure.
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Держатели документа:
Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Funct Crystals & Laser Technol, Ctr Crystal R&D, Beijing 100190, Peoples R China.
Univ Chinese Acad Sci, Beijing 100049, Peoples R China.
RAS, Lab Crystal Phys, Kirensky Inst Phys, SB, Krasnoyarsk 660036, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.
Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Cryogen, Beijing 100190, Peoples R China.
Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China.
Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China.
Univ Sci & Technol Beijing, Dept Phys Chem, Beijing 100083, Peoples R China.
Доп.точки доступа:
Jiang, Xingxing; Molokeev, M. S.; Молокеев, Максим Сергеевич; Gong, Pifu; Yang, Y.i.; Wang, Wei; Wang, Shuaihua; Wu, Shaofan; Wang, Yingxia; Huang, Rongjin; Li, Laifeng; Wu, Yicheng; Xing, Xianran; Lin, Zheshuai; Special Foundation of the Director of Technical Institute of Physics and Chemistry (TIPC); National Scientific Foundations of China [11474292, 51401224]; China "863" project [2015AA034203]
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