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Magnetic circular dichroism analysis of crude oil / I. S. Edelman [et al.] // J. Struct. Chem. - 2016. - Vol. 57, Is. 2. - P. 382-389, DOI 10.1134/S0022476616020207. - Cited References:33. - The work was carried out with the partial support of the grant of the President of the Russian Federation (NSh-2886.2014.2), and in the frameworks of the base budget financing of Kirensky Institute of Physics and Boreskov Institute of Catalysis (Siberian Branch, Russian Academy of Sciences) (V.44.1.15.). . - ISSN 0022-4766. - ISSN 1573-8779

РУБ Chemistry, Inorganic & Nuclear + Chemistry, Physical
Рубрики:
Near-UV/visible spectroscopy
   Electron-spin-resonance
   Asphaltene dispersions
   Single-crystals
   Absorption
   VO2+
   EPR
   FLuorescence
   Aggregation
   Absorbency
Кл.слова (ненормированные):
magnetic circular dichroism (MCD) -- MCD spectroscopy -- absorption spectroscopy of oil
Аннотация: Optical and magneto-optical properties of solutions of crude oil of different origin (i.e., taken from different fields) are studied in the visible and near-UV region of optical emission. Magnetic circular dichroism (MCD) spectra of oil are obtained in the vicinity of wavelengths of ~410 nm, 533 nm, and 576 nm. It is demonstrated that the intensity of the MCD signal depends on the origin of crude oil, and it is proportional to the oil concentration in the solution. The comparison of the magneto-optical spectroscopy data with the chemical composition of samples allows us to conclude that the observed magneto-optical activity is determined by the presence of VO2+ complexes in the oil samples studied. The revealed magneto-optical activity of conventional oil can form a basis of a new method for the analysis of the composition and properties of oil of different origin.

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Публикация на русском языке Исследование природной нефти с помощью спектроскопии магнитного кругового дихроизма [Текст] / И. С. Эдельман [и др.] // Журн. структ. химии. - 2016. - Т. 57 № 2. - С. 394-401

Держатели документа:
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk, Russia.
Siberian Fed Univ, Krasnoyarsk, Russia.
Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk, Russia.

Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Sokolov, A. E.; Соколов, Алексей Эдуардович; Zabluda, V. N.; Заблуда, Владимир Николаевич; Shubin, A. A.; Martyanov, O. N.; Russian Federation [NSh-2886.2014.2]; Kirensky Institute of Physics (Siberian Branch, Russian Academy of Sciences) [V.44.1.15]; Boreskov Institute of Catalysis (Siberian Branch, Russian Academy of Sciences) [V.44.1.15]
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EPR-determined anisotropy of the g-factor and magnetostriction of a Cu2MnBO5 single crystal with a ludwigite structure / A. A. Dubrovskiy [et al.] // JETP Letters. - 2017. - Vol. 106, Is. 11. - P. 716-719, DOI 10.1134/S0021364017230072. - Cited References:18. - This study was supported jointly by the Russian Foundation for Basic Research and the Government of the Krasnoyarsk Territory (project no. 16-42-243028). . - ISSN 0021-3640. - ISSN 1090-6487
Рубрики:
ELECTRON-SPIN-RESONANCE
Аннотация: Electron paramagnetic resonance (EPR) and magnetostriction of the Cu2MnBO5 single crystal have been studied. The EPR spectrum consists of a single Lorentzian line due to the exchange-coupled system of spins of Cu2+ and Mn3+ ions. It has been established experimentally that the g-factor in the paramagnetic region is strongly anisotropic and anomalously small, which is not typical of the exchange-coupled system of spins of Cu2+ and Mn3+ ions. At a temperature of 150 K, the g-factors along the crystallographic a, b, and c axes are 2.04, 1.96, and 1.87, respectively. Such small effective g-factor values can be due to the effect of the anisotropic Dzyaloshinskii-Moriya exchange interaction between the spins of Cu2+ and Mn3+ ions directed along the a axis. The presence of two Cu2+ and Mn3+ Jahn-Teller ions occupying four nonequivalent positions in the crystal is responsible for the absence of the inversion center. It is found that the behavior of the magnetostriction of Cu2MnBO5 is not typical of transition-metal crystals but is closer to the behavior of crystals containing rare-earth ions.

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Публикация на русском языке Анизотропия g-фактора, определенная методом ЭПР, и магнитострикция монокристалла Cu2MnBO5 со структурой людвигита [Текст] / А. А. Дубровский [и др.] // Письма в Журн. эксперим. и теор. физ. - 2017. - Т. 106 Вып. 11. - С. 685-688

Держатели документа:
Russian Acad Sci, Siberian Branch, Fed Res Ctr KRC, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Zavoisky Phys Tech Inst, Kazan 420029, Russia.

Доп.точки доступа:
Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Rautskii, M. V.; Рауцкий, Михаил Владимирович; Moshkina, E. M.; Мошкина, Евгения Михайловна; Yatsyk, I. V.; Eremina, R. M.; Russian Foundation for Basic Research; Government of the Krasnoyarsk Territory [16-42-243028]
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Morozov, E. V.
Temperature-Triggered Rearrangement of Asphaltene Aggregates as Revealed by Pulsed-Field Gradient NMR / E. V. Morozov, P. V. Yushmanov, O. N. Martyanov // Energy Fuels. - 2019. - Vol. 33, Is. 8. - P. 6934-6945, DOI 10.1021/acs.energyfuels.9b00600. - Cited References: 119. - This research was performed using the equipment of Krasnoyarsk Regional Research Equipment Centre of Siberian Branch of Russian Academy of Sciences with the financial support of Russian Science Foundation (Project No. 15-19-00119). . - ISSN 0887-0624. - ISSN 1520-5029

РУБ Energy & Fuels + Engineering, Chemical
Рубрики:
CRITICAL NANOAGGREGATE CONCENTRATION
ELECTRON-SPIN-RESONANCE
Аннотация: The tendency of asphaltenes for aggregation followed by precipitation and deposition plays a crucial role in the petroleum industry since these processes present severe problems during the production, recovery, and processing of crude oils and fossil hydrocarbon feedstocks. The dynamics of oil asphaltene aggregates dissolved in chloroform at different concentrations varied in a wide range that was investigated at temperatures from 0 to 55 °C using the Pulsed-Field Gradient NMR technique. The components attributed to nanoaggregates and macroaggregates were successfully resolved, which allowed us to measure their diffusion coefficients. The diffusion coefficients for all types of aggregates grow as the asphaltene concentration decreases, whereas the partial weight of the aggregates increases with the increase of asphaltene concentration. The difference in diffusion behavior of the aggregates of different types was registered when passing the critical concentration range 10–20 g/L. The nano- and macroaggregates behave independently when the asphaltene concentration is higher than 20 g/L (concentrated regime), while below 20 g/L (semidiluted regime) the components related to the different types of aggregates cannot be properly resolved. It was found that regardless of the asphaltene concentration, the diffusion coefficients for nano- and macroaggregates demonstrate similar temperature behavior giving the straight lines in the Arrhenius coordinates which change their slopes when passing the temperature range 20–30 °C. The phenomenon evidences the thermally induced cleavage of noncovalent bonds with subsequent rearrangement of asphaltene aggregates that is observed for all concentration regimes covering the existence of asphaltene aggregates of all types. The data obtained are well consistent with the modern concept of asphaltene aggregate structure and fairly agree with the data obtained earlier. We believe these results will contribute essentially to a better understanding of the fundamental behavior of asphaltenes and their aggregates, providing a deep insight into aggregate transformation triggered by the temperature.

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Держатели документа:
SB RAS, Inst Chem & Chem Technol, Fed Res Ctr, Krasnoyarsk Sci Ctr, Akademgorodok 50-24, Krasnoyarsk 660036, Russia.
SB RAS, Kirensky Inst Phys, Fed Res Ctr, Krasnoyarsk Sci Ctr, Akademgorodok 50-38, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Ak Lavrentieva 5, Novosibirsk 630090, Russia.
P&L Sci Instrument Serv, Box 1241, S-18124 Lidingo, Sweden.
Novosibirsk State Univ, Pirogova Str 2, Novosibirsk 630090, Russia.

Доп.точки доступа:
Yushmanov, Pavel, V; Martyanov, Oleg N.; Морозов, Евгений Владимирович; Russian Science FoundationRussian Science Foundation (RSF) [15-19-00119]
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