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Two-dimensional-layered perovskite ALaTa2O7:Bi3+ (A = K and Na) phosphors with versatile structures and tunable photoluminescence / G. J. Zhou [et al.]> // ACS Appl. Mater. Interfaces. - 2018. - Vol. 10, Is. 29. - P. 24648-24655, DOI 10.1021/acsami.8b08129. - Cited References: 48. - The authors acknowledge the support from the National Natural Science Foundation of China (Nos. 51722202, 91622125, and 51572023) and the Natural Science Foundations of Beijing (2172036) and RFBR (17-52-53031).
. - ISSN 1944-8244 Перевод заглавия: 2D-слоистые перовскитоподобные люминофоры ALaTa2O7:Bi3+ (A = K and Na) с разнообразными структурами и управляемой люминесценцией.РУБ Nanoscience & Nanotechnology + Materials Science, Multidisciplinary Рубрики: GENERALIZED GRADIENT APPROXIMATION YELLOW-EMITTING PHOSPHOR Кл.слова (ненормированные): 2D-layered perovskite -- Bi3+ emission -- ion exchange -- photoluminescence tuning -- white light LEDs Аннотация: Topological chemical reaction methods are indispensable for fabricating new materials or optimizing their functional properties, which is particularly important for two-dimensional (2D)-layered compounds with versatile structures. Herein, we demonstrate a low-temperature (∼350 °C) ion exchange approach to prefabricate metastable phosphors ALa1–xTa2O7:xBi3+ (A = K and Na) with RbLa1–xTa2O7:xBi3+ serving as precursors. The as-prepared ALa0.98Ta2O7:0.02 Bi3+ (A = Rb, K, and Na) share the same Dion–Jacobson type 2D-layered perovskite phase, and photoluminescence analyses show that ALa0.98Ta2O7:0.02 Bi3+ (A = Rb, K, and Na) phosphors exhibit broad emission bands peaking at 540, 550, and 510 nm, respectively, which are attributed to the nonradiative transition of Bi3+ from excited state 3P1 or 3P0 to ground state 1S0. The various Bi3+ local environments at the crystallographic sites enable the different distributions of emission and excitation spectra, and the photoluminescence tuning of ALa0.98Ta2O7:0.02 Bi3+ (A = Rb, K, and Na) phosphors are realized through alkali metal ion exchange. Notably, the combination of superior trivalent bismuth emission and low-temperature ion exchange synthesis leads to a novel yellow-emitting K(La0.98Bi0.02)Ta2O7 phosphor which is successfully applied in a white LED device based on a commercially available 365 nm LED chip. Our realizable cases of this low-temperature ion exchange strategy could promote exploration into metastable phosphors with intriguing properties.
Смотреть статью, WOS, Читать в сети ИФ Держатели документа: Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing Municipal Key Lab New Energy Mat & Techno, Beijing 100083, Peoples R China. Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China. Univ Chinese Acad Sci, Beijing 100049, Peoples R China. SB RAS, KSC, Fed Res Ctr, Kirensky Inst Phys,Lab Crystal Phys, Krasnoyarsk 660036, Russia. Siberian Fed Univ, Krasnoyarsk 660041, Russia. Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia. Доп.точки доступа: Zhou, Guojun; Jiang, Xingxing; Zhao, Jing; Molokeev, M. S.; Молокеев, Максим Сергеевич; Lin, Zheshuai; Liu, Quanlin; Xia, Zhiguo } Найти похожие
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