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Pulsed laser deposition of europium borate glass films and their optical and magneto-optical properties / A. S. Aleksandrovsky [et al.] // Laser-Assisted Micro- and Nanotechnologies. Proceedings of SPIE : [11-15 May 2005]. - 2006. - P. 61610A

РИНЦ
Держатели документа:
L. V. Kirensky Institute of Physics, Akademgorodok, Krasnoyarsk 660036

Доп.точки доступа:
Konov, V. I. \ed.\; Panchenko, V. Y. \ed.\; Sugioka, K. \ed.\; Veiko, V. P. \ed.\; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Krylov, A. S.; Крылов, Александр Сергеевич; Potseluyko, A. M.; Potseluyko; Seredkin, V. A.; Середкин, Виталий Александрович; Zaitsev, A. I.; Зайцев, Александр Иванович; Zamkov, A. V.; Замков, Анатолий Васильевич; International Conference on Lasers, Applications, and Technologies(2005 ; May ; St. Peterburg, Russia)
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    Structural field of K2Al2B2O7-family [borate] crystals / V. V. Atuchin [et al.]. ; Nonlinear Optics and Applications (VII ; April 15, 2013 ; Prague) // Proc. SPIE. - 2013. - Vol. 8772. - Ст. 877210. - P. DOI 10.1117/12.2017099
   Перевод заглавия: Структурная область боратных кристаллов семейства K2Al2B2O7
Аннотация: The known crystal structures of borate compounds with general composition AI2MIII 2B2O7 (AI: Na, K, Cs, Rb) have been considered. The structures in space groups P63/m, P-31c, P321 and P21/c have been found depending on cation combination. Criterion k = (r(MIII)+r(B)+2r(O))/r(AI) has been formulated and it controls the formation of trigonal K2Al2B2O7 (KABO) type structure. The existence of noncentrosymmetric KABO-type borates is possible over the range of k = 2.7 – 2.06. This range is promising for searching new borate crystals and solid solutions with pronounced nonlinear optical properties. © (2013) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.

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Доп.точки доступа:
Atuchin, V. V.; Bazarov, B. G.; Базаров Б.Г.; Grossman, V. G.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bazarova, Zh.G.; Базарова Ж.Г.; Nonlinear Optics and Applications (7 ; 2013 ; Apr. ; 15 ; Prague)
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    Structural limits of K2Al2B2O7-family borate crystals / V. V. Atuchin [et al.] // XVI Международная конференция "Опто-, наноэлектроника, нанотехнологии и микросистемы" : Труды. - Ульяновск, 2013. - P. 102-103
   Перевод заглавия: Структурные пределы кристаллов боратов семейства K2Al2B2O7

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Доп.точки доступа:
Atuchin, V. V.; Bazarov, B. G.; Grossman, V. G.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bazarova, Zh.G.; Институт нанотехнологий микроэлектроники РАН; Ульяновский государственный университет; Российский фонд фундаментальных исследований; Академия наук Татарстана; "Opto-, nanoelectronics, nanotechnology, and microsystems", International Conference (2013 ; Jul. ; 26-30 ; Ulyanovsk, Russia); "Опто-, наноэлектроника, нанотехнологии и микросистемы", международная конференция (2013 ; июль.; 26-30 ; Ульяновск)
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Terahertz spectroscopy of multiferroic EuFe3(BO3)4 / K. N. Boldyrev [et al.] // Phys. Lett. A. - 2012. - Vol. 376, Is. 37. - P. 2562-2564, DOI 10.1016/j.physleta.2012.06.028. - Cited References: 19. - This work was partially supported by the Russian Foundation for Basic Research under Grants No. 10-02-01071-a and No. 09-02-00171-a, by the Ministry of Education and Science under Grant HIII-4828.2012.2, and by the Russian Academy of Sciences under the programs for basic research. . - ISSN 0375-9601

РУБ Physics, Multidisciplinary
Рубрики:
SINGLE-CRYSTAL
GDFE3(BO3)4
Кл.слова (ненормированные):
Terahertz spectroscopy -- Multiferroics -- Europium iron borate
Аннотация: The terahertz spectra of a rare-earth iron borate with the huntite structure are obtained for the first time. We study the low-temperature (4.0–90 K) α-polarized transmittance spectra of the EuFe3(BO3)4 single crystal in the region 0.9–6.0 THz. Pronounced shifts of phonon frequencies and appearance of new phonon modes at the temperature T S = 58 K of the R 32 → P 3 1 21 structural phase transition are observed. Additional shifts of phonon frequencies occur at the temperature T N = 34 K of the magnetic ordering of the Fe subsystem, thus evidencing the spin–phonon coupling in this multiferroic material.

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Держатели документа:
[Boldyrev, K. N.
Klimin, S. A.
Popova, M. N.] RAS, Inst Spect, Troitsk 142190, Moscow Region, Russia
[Stanislavchuk, T. N.] New Jersey Inst Technol, Dept Phys, Newark, NJ 07102 USA
[Bezmaternykh, L. N.] RAS, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Boldyrev, K. N.; Stanislavchuk, T. N.; Klimin, S. A.; Popova, M. N.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
}
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Quality of the rare earth aluminum borate crystals for laser applications, probed by high-resolution spectroscopy of the Yb3+ ion / K. N. Boldyrev [et al.] // Opt. Mater. - 2012. - Vol. 34, Is. 11. - P. 1885-1889, DOI 10.1016/j.optmat.2012.05.021. - Cited References: 20. - This work was supported by the Russian Academy of Sciences under the Programs for Basic Research, the Russian Foundation for Basic research under Grants No 10-02-01071-a and No 09-02-00171-a, and by the Ministry of Education and Science under Grant HIII-4828.2012.2. . - ISSN 0925-3467

РУБ Materials Science, Multidisciplinary + Optics
Рубрики:
GROWTH
   Y1-XYBXAL3(BO3)4
   LUMINESCENCE
   FREQUENCY
   CENTERS
Кл.слова (ненормированные):
Ytterbium -- Aluminum borates -- Impurities -- High-resolution spectroscopy -- UV edge
Аннотация: A comparative study was performed of the low-temperature high-resolution absorption spectra of the Yb3+ probe in R1−xYbxAl3(BO3)4 (R = Y, Tm, Lu) crystals grown by flux technique independently in four different laboratories using different solvents. We show that the incorporation of solvent components into the crystal in the course of crystallization gives rise to spectral satellites of the Yb3+ 0(2F7/2) → 0′(2F5/2) absorption lines and assign particular satellites to the Yb3+ centers near the bismuth and molybdenum impurities (which decrease the transparency of YAB in the UV spectral range). We suggest this spectroscopic method for a rapid analysis of the quality of UV laser crystals and for improvement of growth technologies.

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Держатели документа:
[Boldyrev, K. N.
Popova, M. N.] RAS, Inst Spect, Troitsk 142190, Moscow Region, Russia
[Bettinelli, M.] Univ Verona, Dept Biotechnol, I-37134 Verona, Italy
[Bettinelli, M.] UdR Verona, INSTM, I-37134 Verona, Italy
[Temerov, V. L.
Gudim, I. A.
Bezmaternykh, L. N.] RAS, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Loiseau, P.
Aka, G.] ENSCP, CNRS, LCMCP, UMR 7574, F-75005 Paris, France
[Leonyuk, N. I.] Moscow MV Lomonosov State Univ, Fac Geol, Moscow 119899, Russia

Доп.точки доступа:
Boldyrev, K. N.; Popova, M. N.; Bettinelli, M.; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, Irina A.; Гудим, Ирина Анатольевна; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Loiseau, P.; Aka, G.; Leonyuk, N. I.
}
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Optical and nonlinear optical properties of orthorhombic BiB3O6 / A. V. Cherepakhin [et al.] // Opt. Mater. - 2012. - Vol. 34, Is. 5. - P. 790-792, DOI 10.1016/j.optmat.2011.11.004. - Cited References: 13. - The work was supported by Ministry of Education and Science of Russian Federation (Contract 16.740.11.0150), Grant of President of Russian Federation for support of leading scientific schools No. SS-4645.2010.2, Grant No. RNP.2.1.1.3455, Project 3.9.1 of PSB RAS, and Projects No. 27.1 and No. 5 of SB RAS. . - ISSN 0925-3467

РУБ Materials Science, Multidisciplinary + Optics
Рубрики:
BISMUTH BORATE BIB3O6
   CRYSTAL
   LASER
   GENERATION
   GROWTH
   BIBO
Кл.слова (ненормированные):
Orthorhombic bismuth triborate delta-BiBO -- Refractive indices -- Nonlinear optical coefficients -- Nonlinear optical materials -- Phase matching
Аннотация: Dispersion of refraction coefficients of orthorhombic BiB3O6 in the wavelength range between 435.8 and 1060 nm is studied, nonlinear optical coefficients are determined, and phase matching angles, angular and spectral bandwidths for second harmonic generation processes are calculated. delta-BiBO may be suitable for doubling of lasers with a wavelength in the 1.3 mu m region as well as the matrix for self-doubling lasing media. (C) 2011 Elsevier B.V. All rights reserved.

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Держатели документа:
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660079, Russia

Доп.точки доступа:
Cherepakhin, A. V.; Черепахин, Александр Владимирович; Zaitsev, A. I.; Зайцев, Александр Иванович; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Zamkov, A. V.; Замков, Анатолий Васильевич
}
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Ensembles OF[[d]]γ[[/d]]-Fe[[d]]2[[/d]]O[[d]]3[[/d]] nanoparticles formed during devitrification of borate glasses [Текст] / O. S. Ivanova [и др.] // V Euro-Asian simposium "Trend in MAGnetism": Nanomagnetism : abstracts. - Vladivostok : FEFU, 2013. - P138 . - ISBN 978-5-7444-3124-2

Доп.точки доступа:
Ivanova, O. S.; Иванова, Оксана Станиславовна; Edelman, I. S.; Эдельман, Ирина Самсоновна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Petrakovskaya, E. A.; Петраковская, Элеонора Анатольевна; Великанов, Дмитрий Анатольевич; Velikanov, D. A.; Trofimova, N. N.; Трофимова, Н. Н.; Zubavichus, Y. V.; Зубавичус, Я. В.; Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism(5 ; 2013 ; Sept. ; 15-21 ; Vladivostok)
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    Высокотемпературная теплоёмкость бората меди / Л. Т. Денисова [и др.] // Журн. СФУ. Сер. "Химия". - 2013. - Т. 6, №. 1. - С. 60-64 ; J. Sib. Fed. Univ. Chem.
   Перевод заглавия: High-Temperature Heat Capacity of Copper Borate
Кл.слова (ненормированные):
heat capacity -- thermodynamic properties -- copper-Borate
Аннотация: This paper reports experimental data obtained on the heat capacity of copper borate within the 380 – 1020 К temperature range. The thermodynamic functions have been calculated using this data.

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Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Денисова, Л. Т.; Денисов, Виктор Михайлович; Саблина, Клара Александровна; Sablina, K. A.; Чумилина, Любовь Геннадьевна; Патрин, Геннадий Семёнович; Patrin, G.S.; Иртюго, Лилия Александровна

}
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Magnetic properties and morphology of manganese ferrite nanoparticles in glasses / I. Edelman [et al.] // IOP Conf. Ser.: Mater. Sci. Eng. - 2011. - Vol. 25, Is. 1. - Ст. 012017, DOI 10.1088/1757-899X/25/1/012017
Кл.слова (ненормированные):
Average diameter -- Borate glass -- Co-doped -- Electron magnetic resonance -- Magnetic and magneto-optical properties -- Magnetic behaviour -- Magnetic circular dichroisms -- Magnetic nanoparticles -- Magnetically ordered material -- Manganese ferrite nanoparticles -- Manganese ferrites -- Morphological characteristic -- Paramagnetic ions -- Resonance field -- Size and shape -- Static magnetization -- Temperature dependence -- Temperature dependent -- Variable temperature -- Visible and near infrared -- Alumina -- Dichroism -- Ferrite -- Glass -- Iron oxides -- Magnetic properties -- Magnetic resonance -- Magnetocrystalline anisotropy -- Manganese -- Manganese oxide -- Nanoparticles -- Paramagnetism -- Silicates -- Spectroscopy -- Nanomagnetics
Аннотация: Static magnetization (SM), magnetic circular dichroism (MCD) and electron magnetic resonance (EMR) studies are reported of borate glasses 22.5 K 2O-22.5 Al 2O 3-55 B 2O 3 co-doped with iron and manganese oxides. In as-prepared glasses the paramagnetic ions usually are in diluted state; however, if the ratio of the iron and manganese oxides in the charge is 3/2, magnetic nanoparticles are found already in as-prepared glass. After additional thermal treatment all glasses show magnetic behaviour, MCD and EMR due to the presence of magnetic nanoparticles with characteristics close to those of manganese ferrite. By computer simulating the EMR spectra at variable temperatures, their morphological characteristics are deduced: relatively broad size and shape distribution with average diameter of ca. 3-4 nm. The characteristic temperature-dependent shift of the apparent resonance field is explained by a strong temperature dependence of the magnetocrystalline anisotropy in the nanoparticles. The potassium-alumina-borate glasses containing magnetic nanoparticles represent a novel class of materials: "transparent magnets". Indeed, they remain transparent in a part of visible and near infrared spectral range while showing magnetic and magneto-optical properties characteristic of magnetically ordered materials.

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Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Ivanova, O. S.; Иванова, Оксана Станиславовна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна; Artemenko, A.; Curely, J.; Kliava, J.; Zaikovskiy, V. I.; Stepanov, S.; Baltic Conference on Silicate Materials(5 ; 2011 ; May ; 23-25 ; Riga, Latvia)
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10.

Coupled R and Fe magnetic excitations in RFe 3(BO 3) 4 multiferroics / A. M. Kuzmenko [et al.] // Diffusion and Defect Data Pt.B: Solid State Phenomena. - 2012. - Vol. 190. - P. 269-272, DOI 10.4028/www.scientific.net/SSP.190.269 . - ISBN 9783037854365
Кл.слова (ненормированные):
Magnetic resonance -- Rare-earth iron borates -- Terahertz spectroscopy -- Antiferromagnetics -- Coupled mode -- Exchange coupled -- Frequency ranges -- G factors -- Iron borate -- Magnetic excitations -- Multiferroics -- Resonance mode -- Strong interaction -- Transmission spectrums -- Antiferromagnetism -- Electron transitions -- Gadolinium -- Ions -- Magnetic materials -- Magnetic permeability -- Magnetic resonance -- Terahertz spectroscopy -- Neodymium
Аннотация: Various resonance modes were observed in the transmission spectra of rare-earth iron borates RFe 3(BO 3) 4 (R = Nd 3+, Sm 3+, Gd 3+) at the frequency range 100-600 GHz, which were attributed to collective magnetic excitations in the exchange coupled Fe- and R-subsystems, i.e. antiferromagnetic (Fe) resonance and electron transitions in the R-ions. Strong interaction of the Fe and R oscillations was revealed and theoretically analyzed taking into account feature of the R-ion ground state. Intensities of the coupled modes (contributions to magnetic permeability) strongly depend on a difference of Fe and R ions g-factors that allows defining the sign of the latter. In particular, an appreciable intensity of exchange (Nd) modes in NdFe 3(BO 3) 4 is caused by g Nd?,|| < 0 whereas in GdFe 3(BO 3) 4 with gGd ? gFe ? 2 the exchange (Gd) modes were hided due to compensation of Fe and Gd contributions. In SmFe 3(BO 3) 4, despite a negligible Sm g-factor, the Sm modes were clear observed due to their excitation via coupling with the Fe-subsystem. В© (2012) Trans Tech Publications.

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Доп.точки доступа:
Kuzmenko, A. M.; Кузьменко А.М.; Mukhin, A. A.; Ivanov, V.Yu.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Moscow International Symposium on Magnetism(5 ; 2011 ; Aug. ; 21-25 ; Moscow)
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11.

Magnetic structure of iron borate DyFe3(BO3)4: A neutron diffraction study / C. Ritter [et al.] // J. Phys.: Conf. Ser. - 2012. - Vol. 340. - Ст. 012065, DOI 10.1088/1742-6596/340/1/012065. - Cited References: 22 . - ISSN 1742-6588

РУБ Physics, Condensed Matter + Physics, Particles & Fields

Кл.слова (ненормированные):
Antiferromagnetics -- Crystallographic structure -- Easy-axis anisotropy -- Iron borate -- Kramers doublet -- Low temperatures -- Magnetic propagation -- Neutron diffraction measurements -- Repopulation -- Room temperature -- Spin reorientation -- Sub-lattices -- Thermal dependences -- Unit cells
Аннотация: Neutron diffraction measurements were performed on the iron borate DyFe3(BO3)4 to investigate details of the crystallographic structure, the low temperature magnetic structure and its magnetic properties. DyFe3(BO3)4 adopts at room temperature the P3121 symmetry and becomes antiferromagnetic below TN = 39 K. Both, the rare earth and the iron sublattice, follow the same magnetic propagation vector τ = [0, 0, ½] which leads to a doubling of the crystallographic unit cell in the c-direction. The easy axis anisotropy of the rare earth determines the moment orientation to be mainly along c. No spin reorientation is found between TN and 1.5 K, however, a small anomaly in the thermal dependence of the unit cell a-parameter is found at about 27 K which could be connected to repopulation of low lying Kramers doublets of Dy3+. The magnetic moment value of the Fe-moment is at 1.5 K with μFe = 4.5 μB only slightly smaller than expected for an S = 5/2 ion while the Dy moment is strongly reduced and amounts only to μDy = 6.4 μB.

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Доп.точки доступа:
Ritter, C.; Pankrats, A. I.; Панкрац, Анатолий Иванович; Gudim, I. A.; Гудим, Ирина Анатольевна; Vorotynov, A. M.; Воротынов, Александр Михайлович; European Conference on Neutron Scattering(5 ; 2011 ; Jul. 17- 21 ; Prague, Czech Republic)
}
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12.

K2Al2B2O7-family borate crystals / V. V. Atuchin [et al.] // VI Сессия Научного совета РАН по механике : материалы всероссийской конференции. - Барнаул, 2012. - P. 91 . - ISBN 5756809376

Программа конференции,
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Доп.точки доступа:
Atuchin, V. V.; Атучин, Виктор Валерьевич; Bazarov, B. G.; Базаров Б.Г.; Grossman, V. G.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bazarova, Zh.G.; Базарова Ж.Г.; Российский национальный комитет по теоретической и прикладной механике; Объединенный Научный совет РАН по комплексной проблеме "Механика"; Научный совет по механике деформируемого твердого тела РАН; Институт проблем механики им. А.Ю. Ишлинского РАН; Институт проблем машиноведения РАН; Алтайский государственный технический университет им. И.И. Ползунова; Российский фонд фундаментальных исследований; "Сессия Научного совета РАН по механике", Всероссийская конференция (6 ; 26-31 июля 2012 ; Барнаул / Белокуриха, Россия)
}
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13.

Transperant nanomagnetic materials based on borate glasses co-doped with iron, manganese and rare-earth elements / I. Edelman [et al.] // XI International Conference on Nanostructured Materials. - 2012. - P.

Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Ivanova, O. S.; Иванова, Оксана Станиславовна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Zabluda, V. N.; Заблуда, Владимир Николаевич; Hennet, L.; Thiaudiere, D.; Saboungi, M.-L.; Zubavichus, Y. V.; Veligzhanin, A. A.; Zaikovskiy, V. I.; Stepanov, S.; Curély, J.; Kliava, J.; International Conference on Nanostructured Materials (11 ; 2012 ; August ; 26 – 31 ; Rhodes, Greece)
}
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14.

Structural field of K2Al2B2O7 family borate crystals / B. I. Kidyarov [et al.] ; , Иркутский гос. ун-т // Международная молодежная конференция по люминесценции и лазерной физике : тезисы лекций и докладов. - 2012. - P. 10-11

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Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Kidyarov, B. I.; Atuchin, V. V.; Атучин, Виктор Валерьевич; Grossman, V. G.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bazarov, B. G.; Базаров Б.Г.; Bazarova, Zh.G.; Базарова Ж.Г.; Научный совет по оптике и лазерной физике Российской академии наук; Научный совет по люминесценции Российской академии наук; Иркутский филиал Института лазерной физики Сибирского отделения РАН; Институт геохимии Сибирского отделения РАН; Иркутский государственный университет; Иркутский научный центр Сибирского отделения РАН; Международная молодежная конференция по люминесценции и лазерной физике(2012 ; июль ; 16-22 ; "Песчанка", турбаза, оз. Байкал, Иркутская обл.)
}
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15.

Magnetic structure of iron borate SmFe3(BO3)4: A neutron diffraction study / C. Ritter [и др.] // The 19th International Conference on Magnetism with Strongly Correlated Electron Systems : book of abstracts. - 2012. - Ст. IJ01. - P. 97

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Доп.точки доступа:
Ritter, C.; Pankrats, A. I.; Панкрац, Анатолий Иванович; Gudim, I. A.; Гудим, Ирина Анатольевна; Vorotynov, A. M.; Воротынов, Александр Михайлович; Korean Physical Society; Korean Magnetics Society; International Union of Pure and Applied Physics; International conference on magnetism (19 ; 2012 ; Jul ; 8-13 ; Busan, Korea / Bexco, Korea)
}
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16.

Heat treatment stimulation of the magnetic nanoparticles formation in borate glasses doped with transition elements / I. Edelman [et al.] // Heat Treat.: Theory, Tech. and Appl. : Chapter. - New York : Nova Science Publishers, 2011. - P. 225-239 . - ISBN 978-161728348-2
Аннотация: Evolution of the magnetic nanoparticles characteristics in glasses of the system 22.5 Al2O3 - 22.5 K2O - 55 B2O3 co-doped with Fe2O3 and MnO simultaneous is studied at different stages of the post-synthesis heat treatment with transmission electron microscopy (TEM) images, selected area electron diffraction (SAED), energy dispersive X-ray analysis (EDAX), and magneto-optical Faraday rotation (FR). Heat treatment of the glasses results in substantial changes of their structure and properties: ferrite nanoparticles of different size, composition, and structure arise in glass matrices. For several series of glasses with the same composition and molar concentration of the paramagnetic additions, the heat treatment regimes (temperature and duration) have been shown to be the main factors controlling the particle size and the order in the crystallite arrangements. Ensembles of particles in theirs turn determine magnetic and magneto-optical properties of glass as a whole. A correlation between the characteristics of nanoparticles and the heat treatment regimes is discussed qualitatively.

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Держатели документа:
Kirensky Institute of Physics, Siberian Branch of RAS, Krasnoyarsk, Russian Federation
S. I. Vavilov State Optical Institute, St.Petersburg, Russian Federation
Boreskov Institute of Catalysis, Siberian Branch of RAS, Novosibirsk, Russian Federation

Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Ivanova, O. S.; Иванова, Оксана Станиславовна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Stepanov, S.; Zaikovskiy, V. I.
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17.

Nature of optical properties of GdFe3(BO3)4 and GdFe2.1Ga0.9(BO3)4 crystals and other 3d5 antiferromagnets / A. V. Malakhovskii [et al.] // Eur. Phys. J. B. - 2012. - Vol. 85, Is. 2. - P. 80, DOI 10.1140/epjb/e2012-20953-1. - Cited References: 70. - The work was supported by the Russian Foundation for Basic Researches Grant 12-02-00026 and by Russian President Grant NSh-1044.2012.2. . - ISSN 1434-6028

РУБ Physics, Condensed Matter
Рубрики:
IRON BORATE GDFE3(BO3)4
   D-D TRANSITIONS
   EARTH FERROBORATES RFE3(BO3)4
   ABSORPTION-SPECTRA
   OCTAHEDRAL COMPLEXES
   ELECTRONIC-STRUCTURE
   NEEL TEMPERATURE
   FINE-STRUCTURE
   EXCHANGE
   IONS
Аннотация: Influence of the partial substitution of paramagnetic Fe3+ ions by diamagnetic Ga3+ ions in the trigonal crystal GdFe3 (BO3)4 on its optical and magnetic properties is studied and discussed in connection with problems common for all antiferromagnets containing 3d 5 ions. Polarized optical absorption spectra and linear birefringence of GdFe3 (BO3)4 and GdFe2.1Ga0.9 (BO3)4 single crystals have been measured in the temperature range 85–293 K. Specific heat temperature dependence (2–300 K) and structure of GdFe2.1Ga0.9 (BO3)4 crystal have been also studied. As a result of substitution of 30% Fe to Ga the Neel temperature diminishes from 38 till 16 K, the strong absorption band edge shifts on 860 cm-1 (0.11 eV) to higher energy and the d-d transitions intensity decreases substantially larger than the Fe concentration does. Strong absorption band edge is shown to be due to Mott-Hubbard transitions. Correlation between position of the strong absorption band edge and the Neel temperature of antiferromagnets has been revealed. Properties of the doubly forbidden d-d transitions in the studied crystals and in other antiferromagnets are explained within the framework of the model of the exchange-vibronic pair absorption, which is theoretically analyzed in detail. The model permitted us to determine the connection between parameters of d-d absorption bands (intensity, width and their temperature dependences), on the one hand, and the exchange, spin-orbit and electron-lattice interactions, on the other hand.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Vasil'ev, A. D.; Васильев, Александр Дмитриевич; Leont'ev, A. A.; Леонтьев, Андрей Александрович; Kartashev, A. V.; Карташев, Андрей Васильевич; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна
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18.

Melnikova, S. V.
Linear optical properties of γ-modification of bismuth borate BiB3O6 / S. V. Melnikova, L. I. Isaenko // Phys. Solid State. - 2012. - Vol. 54, Is. 10. - P. 1966-1969, DOI 10.1134/S1063783412100228. - Cited References: 9. - This study was supported by the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools of the Russian Federation (grant no. NSh-4828.2012.2) and the Siberian Branch of the Russian Academy of Science (integration project no. 28). . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
GROWTH
Аннотация: The refractive index dispersion of the γ-BiB3O6 crystal in the wavelength range 0.43–0.81 μm has been measured. It has been shown that the principal refractive indices n 1, n 2, and n 3 are on average higher than those of α-BiB3O6, but are slightly lower than those of δ-BiB3O6. The temperature dependences of the rotation angle φ(T) of the optical indicatrix and birefringence Δn 2(T) = (n 1 − n 3)(T) have been studied in the temperature range 100–963 K. It has been shown that the γ-BiB3O6 crystal is stable in this temperature region.

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Публикация на русском языке Мельникова, Светлана Владимировна. Линейные оптические свойства gamma-модификации висмутового бората BiB3O6 [Текст] / С. В. Мельникова, Л. И. Исаенко // Физ. тверд. тела : Физико-технический институт им. А.Ф.Иоффе РАН, 2012. - Т. 54 Вып. 10. - С. 1843-1846

Держатели документа:
[Melnikova, S. V.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Isaenko, L. I.] Russian Acad Sci, Siberian Branch, Sobolev Inst Geol & Mineral, Novosibirsk 630090, Russia

Доп.точки доступа:
Isaenko, L. I.; Мельникова, Светлана Владимировна
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19.

High-temperature magnetoelectricity of terbium aluminum borate: The role of excited states of the rare-earth ion / A. M. Kadomtseva [et al.] // Phys. Rev. B. - 2014. - Vol. 89, Is. 1. - Ст. 014418, DOI 10.1103/PhysRevB.89.014418. - Cited References: 25. - We thank Dr. Daniel Sando for useful comments and remarks. This work is supported by the Russian Foundation for Basic Research (Projects No. 13-02-01093, No. 13-02-12443, No. 13-02-01093, No. 12-02-01261, and No. 13-02-12442) and a grant from the Russian Federation President on support of sciences schools no. 4828.2012.2, The Ministry of Education and Science of Russian Federation, Project No. 8365. . - ISSN 1098-0121. - ISSN 1550-235X

РУБ Physics, Condensed Matter
Рубрики:
GROUND-STATE
PRFE3(BO3)4
MULTIFERROICS
Аннотация: Recently discovered magnetoelectricity in the rare-earth aluminum borates RAl3(BO3)4 has attracted attention due to the large values of magnetoinduced electric polarization. We have observed for the first time the magnetoelectric polarization in TbAl3(BO3)4 exhibiting anomalous temperature dependence: an electric polarization induced by in-plane magnetic field (P||a,H⊥c axis) which is small at low temperatures (4K), remarkably increases by almost an order of magnitude at high temperatures (150–300K). The observed nonmonotonic temperature behavior of the field-induced polarization, including a change of sign at ∼65–70K, is attributed to the competition of the ground and excited crystal-field states of Tb3+ ions. Quantum theory analysis, involving the combination of analytical and numerical methods, has enabled us to quantitatively describe the observed magnetic and magnetoelectric properties of TbAl3(BO3)4.
Недавно обнаруженное магнетоэлектричество в редкоземельных алюмоборатах RAl3 (BO3) 4 привлекло к себе внимание из-за больших значений магнитоиндуцированной электрической поляризации. Мы наблюдали в первый раз магнитоэлектрическую поляризацию в TbAl3 (BO3) 4, показывающую аномальную температурную зависимость: электрическая поляризация индуцируется в плоскости магнитного поля (Р | |, Н ⊥ оси с), и является небольшой при низких температурах (4K), Значительно увеличивается, почти на порядок величины, при высоких температурах (150-300 К). Наблюдаемая с изменением температуры немонотонность поляризации от поля, в том числе изменению знака на ~ 65-70 К, может быть отнесена к конкуренции между основном и возбужденном кристаллическим полем состояниями ионов ТЬ3 +. Теория квантового анализа, предполагающей сочетание аналитических и численных методов, позволила нам количественно описать наблюдаемые магнитные и магнитоэлектрические свойства TbAl3 (BO3) 4.

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Держатели документа:
Moscow MV Lomonosov State Univ, MSU, Dept Phys, Moscow 119992, Russia
Russian Acad Sci, Prokhorov Gen Phys Inst, Moscow, Russia
State Univ, Moscow Inst Phys & Technol, Moscow, Russia
Natl Res Univ Elect Technol MIET, Zelenograd, Russia
RAS, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Kadomtseva, A. M.; Popov, Y. F.; Vorob'ev, G. P.; Kostyuchenko, N. V.; Popov, A. I.; Mukhin, A. A.; Ivanov, V. Y.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Temerov, V. L.; Темеров, Владислав Леонидович; Pyatakov, A. P.; Zvezdin, A. K.; Russian Foundation for Basic Research [13-02-12443, 13-02-01093, 12-02-01261, 13-02-12442]; Russian Federation President on support of sciences schools [4828.2012.2]; Ministry of Education and Science of Russian Federation [8365]
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20.

Phase transitions and crystal-field and exchange interactions in TbFe3(BO3)4 as seen via optical spectroscopy / M. N. Popova [et al.] // J. Phys.: Condens. Matter. - 2012. - Vol. 24, Is. 19. - Ст. 196002, DOI 10.1088/0953-8984/24/19/196002. - Cited References: 45. - The assistance of E P Chukalina is acknowledged. This work was supported in part by the Russian Foundation for Basic Research (grants No 10-02-01071-a and No 09-02-00171-a), by the Ministry of Education and Science (grant HIII-4828.2012.2), and by the Russian Academy of Sciences under the Programs for Basic Research. . - ISSN 0953-8984

РУБ Physics, Condensed Matter
Рубрики:
IRON BORATE GDFE3(BO3)4
PROBE
ION
Аннотация: High-resolution polarized broadband (1800–23 000 cm−1) optical absorption spectra of Tb3+ in TbFe3(BO3)4 single crystals are studied between room temperature and 4.2 K. The spectral signatures of the structural (R32–P3121, TS = 192 K) and magnetic (TN = 41 K) phase transitions are found and analyzed. Energies and symmetries of the Tb3+ crystal-field (CF) levels were determined for both the high-temperature R32 and the low-temperature P3121 structures of TbFe3(BO3)4 and compared with the calculated ones. It follows unambiguously from the spectral data that the ground state is the Γ1 + Γ2 quasi-doublet of the local D3 point symmetry group for Tb3+ in the R32 high-temperature structure. The CF calculations revealed the CF parameters and wavefunctions for Tb3+ in TbFe3(BO3)4. The value of the Tb–Fe exchange integral and of the effective magnetic field created by the ordered Fe subsystem were estimated as Jfd = 0.26 K and Beff = 3.92 T, using the observed splitting Δ = 32 cm−1 of the Tb3+ ground quasi-doublet at the temperature 5 K. The reliability of the obtained parameters was proven by modeling the literature data on the magnetic susceptibility of TbFe3(BO3)4. Lattice distortions below TS were evidenced by the observed changes of probabilities of the forced electric dipole transitions of Tb3+.

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Держатели документа:
[Popova, M. N.] Russian Acad Sci, Inst Spect, Troitsk 142190, Moscow Region, Russia
[Stanislavchuk, T. N.] New Jersey Inst Technol, Dept Phys, Newark, NJ 07102 USA
[Malkin, B. Z.] Kazan Fed Univ, Kazan 420008, Russia
[Bezmaternykh, L. N.] RAS, Kirenskii Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Popova, M. N.; Stanislavchuk, T. N.; Malkin, B. Z.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
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