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Ferromagnetic resonance and magnetic anisotropy of 3d-metal wires with composition gradients / E. A. Denisova, L. A. Chekanova, S. V. Komogortsev [et al.] // Bull. Russ. Acad. Sci.: Phys. - 2024. - Vol. 88, Is. 4. - P. 531-535, DOI 10.1134/S1062873823706244. - Cited References: 13 . - ISSN 1062-8738. - ISSN 1934-9432
Кл.слова (ненормированные):
wires with gradients of composition -- electroless deposition -- ferromagnetic resonance -- magnetic anisotropy
Аннотация: Results are presented from investigating the ferromagnetic resonance spectra of arrays of Co‒Ni and Co‒Fe‒Ni wires with different composition gradients, deposited into polycarbonate track-etched membranes. The effect interfaces and concentration gradients have on the effective fields of the investigated wires is examined. An anomalous angular dependence of the fields of ferromagnetic resonance is observed for the wire arrays at a pore density of ~18% in the membrane.

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Держатели документа:
Kirensky Institute of Physics, Federal Reserch Center “Krasnoyarsk Science Centre,” Siberian Branch, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia
Siberian Federal University, 660041, Krasnoyarsk, Russia
Rechetnev Siberian State University of Science and Technology, 660049, Krasnoyarsk, Russia
Federal Reserch Center “Krasnoyarsk Science Center,” Siberian Branch, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia

Доп.точки доступа:
Denisova, E. A.; Денисова, Елена Александровна; Chekanova, L. A.; Чеканова, Лидия Александровна; Komogortsev, S. V.; Комогорцев, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Vazhenina, I. G.; Важенина, Ирина Георгиевна; Nemtsev, I. V.; Немцев, Иван Васильевич; Li, O. A.
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    Solid state synthesis, structural, DFT and spectroscopic analysis of EuAl3(BO3)4 / A. S. Oreshonkov, A. S. Aleksandrovsky, O. D. Chimitova [et al.] // Mater. Chem. Phys. - 2024. - Vol. 320. - Ст. 129400, DOI 10.1016/j.matchemphys.2024.129400. - Cited References: 55. - The work was carried out within the state assignment No FWES-2024-0003 of Kirensky Institute of Physics. This work was partially supported by the state order of BINM SB RAS (0273-2021-0008). The samples for this research were synthesized using equipment of the CCU BINM SB RAS. The reflectance spectrum was obtained at the Center for Optical and Laser Materials Research of Research park of St. Petersburg State University. The SEM measurements were performed at Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS" . - ISSN 0254-0584. - ISSN 1879-3312
   Перевод заглавия: Твердофазный синтез, структурный, квантово-химический (DFT) и спектроскопический анализ EuAl3(BO3)4
Кл.слова (ненормированные):
EuAl(BO) -- Huntite -- X-ray diffraction -- SEM -- DFT -- Charge transfer -- Raman -- Infrared -- Luminescence
Аннотация: Huntite-like borates are versatile and promising materials with wide range of applications in frequency conversion, UV light generation, lighting, displays, quantum information storage, and more, demonstrated by their various properties and uses in scientific research. In this work, EuAl3(BO3)4 powder was prepared through multi-stage solid-state reaction method using high-purity starting reagents: Eu2O3, Al2O3 and H3BO3, considering a 20 wt% excess of H3BO3 to compensate for B2O3 volatilization. Obtained samples undergo several treatments at varying temperatures and their phase purity is subsequently verified through powder X-ray diffraction analysis. The scanning electron microscopy reveals that resulting EuAl3(BO3)4 powder consists of granules exhibiting irregular morphologies with dimensions of 0.5–8 μm. The electronic band structure of EuAl3(BO3)4, calculated using the GGA PBE method, reveals f-states of Eu near 4 eV. These states do not produce emphasized peaks on simulated absorbance spectra. Using of DFT + U for the f-states of Eu pushed up f-bands above 6 eV and the charge transfer from p-O to d-Eu was obtained (Egdirect = 5.63 eV, Egindirect = 5.37 eV using Ueff = 4 eV). The variation of Ueff has a weak influence on the position of the bottom of the conduction band. The experimental bandgaps of EuAl3(BO3)4 crystalline powder, both direct and indirect, are found to be 3.96 and 3.67 eV, correspondingly. These values are lower than theoretical values what is associated with limitations of DFT calculations involving f electrons. The Raman spectrum of EuAl3(BO3)4 powder is discussed, detailing the contributions of different ions to specific spectral bands. Investigation of high-resolution luminescence spectra shows the possibility to estimate the content of defects by the testing the violation of the prohibition of ultranarrow 5D0 → 7F0 line that is forbidden in the ideal crystalline structure of trigonal EuAl3(BO3)4.

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Держатели документа:
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
School of Engineering and Construction, Siberian Federal University, Krasnoyarsk, 660041, Russia
Laboratory of Coherent Optics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, 660041, Russia
Laboratory of Oxide Systems, Baikal Institute of Nature Management, SB RAS, Ulan-Ude, 670047, Russia
Center for Optical and Laser Materials Research, Saint-Petersburg State University, Saint-Petersburg, 199034, Russia
Emanuel Institute of Biochemical Physics of Russian Academy of Sciences, Moscow, 119334, Russia
Plekhanov Russian University of Economics, Moscow, 117997, Russia
Moscow Institute of Physics and Technology, Dolgoprudny, 141700, Russia
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
School of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, 660041, Russia
Institute of Automation and Electrometry, Russian Academy of Sciences, Novosibirsk, 630090, Russia
Department of Molecular Electronics, Federal Research Center Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, 660036, Russia
Institute of Fundamental Biology and Biotechnology, Siberian Federal University, Krasnoyarsk, 660041, Russia

Доп.точки доступа:
Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Chimitova, O.D.; Pankin, D.V.; Popov, Z.I.; Sukhanova, E.V.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Adichtchev, S.V.; Pugachev, A.M.; Nemtsev, I. V.; Немцев, Иван Васильевич
}
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Correction: Volova et al. Laser processing of polymer films fabricated from PHAs differing in their monomer composition. Polymers 2021, 13, 1553 / T. G. Volova, A. I. Golubev, I. V. Nemtsev [et al.] // Polymers. - 2024. - Vol. 16, Is. 8. - Ст. 1075, DOI 10.3390/polym16081075. - Cited References: 1 . - ISSN 2073-4360

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Держатели документа:
Basic Department of Biotechnology, School of Fundamental Biology and Biotechnology, Siberian Federal University, 79 Svobodnyi Av., 660041 Krasnoyarsk, Russia
Institute of Biophysics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/50 Akademgorodok, 660036 Krasnoyarsk, Russia
L.V. Kirensky Institute of Physics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/38 Akademgorodok, 660036 Krasnoyarsk, Russia
Special Design and Technological Bureau ‘Nauka’ Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/45 Akademgorodok, 660036 Krasnoyarsk, Russia
Federal Research Center “Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences” 50 Akademgorodok, 660036 Krasnoyarsk, Russia

Доп.точки доступа:
Volova, T. G.; Golubev, A. I.; Голубев, Алексей И.; Nemtsev, I. V.; Немцев, Иван Васильевич; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Dudaev, A. E.; Shishatskaya, E. I.
}
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Spontaneous imbibition experiments for enhanced oil recovery with silica nanosols / M. I. Pryazhnikov, V. A. Zhigarev, A. V. Minakov, I. V. Nemtsev // Capillarity. - 2024. - Vol. 10, Is. 3. - P. 73-86, DOI 10.46690/capi.2024.03.02. - Cited References: 53. - This work is partially financed by Ministry of Science and Higher Education of the Russian Federation (No. FSRZ2020-0012) . - ISSN 2709-2119. - ISSN 2652-3310
Кл.слова (ненормированные):
Spontaneous imbibition -- enhanced oil recovery -- silica nanosols -- wettability -- interfacial tension
Аннотация: Experimental oil displacement as a result of spontaneous imbibition of silica nanosols has been carried out using two types of sandstone as the reservoir rock. The permeability of the cores ranged from 0.34 to 333 mD, while the porosity was 11% and 22%, respectively. During the research, the influence of the concentration and nanoparticle size, as well as the permeability of the rock, on the process of spontaneous imbibition, was studied. Silica nanosols were considered as an object of study. The nanoparticle size ranged from 10 to 35 nm. The mass concentration of nanoparticles varied from 0.01% to 0.25%. It was found that the use of silica nanosols significantly increases the rate of the spontaneous imbibition process. It was established that a silica nanosol with a nanoparticle size of 10 nm and a concentration of 0.25% allows to displace more than six times oil compared to the reservoir water model in the same time. As a result, it was shown that the oil displacement efficiency and the efficiency of spontaneous imbibition increase along with an increase in the nanoparticle concentration and a decrease in the nanoparticle size.

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Держатели документа:
Laboratory of Physical and Chemical Technologies for the Development of Hard-to-Recover Hydrocarbon Reserve, Siberian Federal University, Krasnoyarsk 660041, Russia
Laboratory of Heat Exchange Control in Phase and Chemical Transformations, Kutateladze Institute of Thermophysics, SB RAS, Novosibirsk 630090, Russia
Department of Molecular Electronics, Federal Research Center “Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences”, Krasnoyarsk 660036, Russia
Laboratory of molecular spectroscopy, L.V. Kirensky Institute of Physics, SB RAS, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Pryazhnikov, M. I.; Zhigarev, V. A.; Minakov, A. V.; Nemtsev, I. V.; Немцев, Иван Васильевич
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Corrigendum to "Properties of degradable polyhydroxyalkanoates with different monomer compositions" International Journal of Biological Macromolecules; Volume 182, Pages 98–114 / T. Volova, E. Kiselev, I. Nemtsev [et al.] // Int. J. Biol. Macromol. - 2024. - Vol. 263, Pt. 1. - Ст. 130252, DOI 10.1016/j.ijbiomac.2024.130252. - Cited References: 1 . - ISSN 0141-8130. - ISSN 1879-0003

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Держатели документа:
Siberian Federal University, 79 Svobodnyi av., Krasnoyarsk 660041, Russia
Institute of Biophysics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/50 Akademgorodok, Krasnoyarsk 660036, Russia
Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50 Akademgorodok, Krasnoyarsk 660036, Russia
L.V. Kirensky Institute of Physics, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/12 Akademgorodok, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Volova, T.; Kiselev, E.; Nemtsev, I. V.; Немцев, Иван Васильевич; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Sukovatyi, A.; Kuzmin, A.; Ryltseva, G.; Shishatskaya, E.
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    Resistive switching properties of a nanostructured layer of mixed ZrO2 phases obtained in low-pressure arc discharge plasma / I. V. Karpov, L. Yu Fedorov, A. K. Abkaryan [et al.] // Vacuum. - 2024. - Vol. 227. - Ст. 113375, DOI 10.1016/j.vacuum.2024.113375. - Cited References: 34. - The work was performed with a support of the grant of the Russian Science Foundation (Project No. 24-29-00374, https://rscf.ru/project/24-29-00374/) . - ISSN 0042-207X. - ISSN 1879-2715
   Перевод заглавия: Резистивные коммутационные свойства наноструктурированного слоя смешанных фаз ZrO2, полученного в плазме дугового разряда низкого давления
Кл.слова (ненормированные):
Zirconium oxide -- Vacuum arc -- Physical vapor deposition -- Phase stability
Аннотация: The controlled vacuum-arc synthesis of zirconium dioxide (ZrO2) nanoparticles is considered, which makes it possible to regulate the percentage ratio of the monoclinic and tetragonal phases. The samples were characterized using XRD analysis, SEM, HRTEM analysis, FT-IR analysis, TG/DTA analysis and EPR spectroscopy. It has been established that the formation of the tetragonal phase is associated with the formation of a large number of oxygen vacancies formed due to high-speed quenching of nanoparticles. Reducing the operating gas pressure in a vacuum chamber from 180 Pa to 30 Pa makes it possible to obtain nanoparticles up to 2 nm in size. The synthesized ZrO2 nanoparticles do not contain foreign impurities and when heated, the weight loss is up to 7 %. The process of local resistive switching in the contact of an atomic force microscope (AFM) probe to a nanostructured ZrO(2-x) layer on a conducting substrate has been studied. Cyclic current-voltage characteristics demonstrate the existence of stable states of high and low resistance, switched by changing the polarity of the applied voltage. The coexistence of the m- and t-ZrO2 phases (and the resulting oxygen nonstoichiometry in the interboundary regions) provides conditions for the formation/destruction of a filament from oxygen vacancies, which determine the conductivity of the dielectric in the LRS state.

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Держатели документа:
Siberian Federal University, 660041, Krasnoyarsk, Russian Federation
Federal Research Center Krasnoyarsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences, 660036, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Karpov, I.V.; Fedorov, L. Yu; Abkaryan, A.K.; Zharkov, S. M.; Жарков, Сергей Михайлович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Ivanenko, A. A.; Иваненко, Александр Анатольевич; Nemtsev, I. V.; Немцев, Иван Васильевич; Irtyugo, L.A.
}
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Biodegradable polymer casting films for drug delivery and cell culture / A. V. Murueva, A. E. Dudaev, E. I. Shishatskaya [et al.] // Giant. - 2024. - Vol. 19. - Ст. 100314, DOI 10.1016/j.giant.2024.100314. - Cited References: 112. - The study was funded by State Assignment of the Ministry of Science and Higher Education of the Russian Federation (project No. FWES-2021–0025) . - ISSN 2666-5425
Кл.слова (ненормированные):
Degradable polyhydroxyalkanoates -- Copolymers P(3HB--3HV) and P(3HB--4HB) -- Solvent casting films -- Microstructure and properties -- Drugs -- Release kinetics -- Antibacterial activity -- Keratinocytes proliferation
Аннотация: In this work, for the first time, films were obtained based on biodegradable polyhydroxyalkanoates (PHAs) - a copolymer of 3-hydroxybutyrate-co-3-hydroxyvalerate P(3HB-co-3HV) and a copolymer of 3-hydroxybutyrate-co-4-hydroxybutyrate P(3HB-co-4HB), containing drugs of different chemical structure and action - antibiotics (ceftazidime, doripenem), antiseptic (chlorhexidine) and tissue regeneration stimulator (Actovegin) for drug delivery and cell culture. Using SEM, AFM and measuring the contact angles of water wetting, it is shown how PHAs composition and loading of films of P(3HB-co-3HV) and P(3HB-co-4HB) with drugs affect the porosity, roughness indicators and adhesive properties of the surface. The constructed films are a depot form of drug, the release of which in vitro is realized for a long time, without burst releases, corresponds to Korsmeyer-Peppas and Higuchi models with diffusion character. Films loaded with antibiotics have pronounced antibacterial activity and suppress the development of pathogens S. aureus and E. coli, without a pronounced negative effect on the adhesion and proliferation of epidermal cells. In the cultures of human keratinocytes HaCaT it was shown that the presence of actovegin, as well as ceftazidime in the films, exhibits a stimulating effect, increasing their number. The results demonstrate the suitability of the depot-films for cellular technologies and are promising for the reconstruction of tissues complicated by infection.

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Держатели документа:
Institute of Biophysics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/50 Akademgorodok, Krasnoyarsk 660036, Russia
Siberian Federal University, 79 Svobodnyi av., Krasnoyarsk 660041, Russia
Infochemistry Scientific Centre, ITMO University, Lomonosova St. 9, St. Petersburg 191002, Russia
Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50 Akademgorodok, Krasnoyarsk, 660036, Russia
L.V. Kirensky Institute of Physics, Federal Research Center “Krasnoyarsk Science Center SB RAS, 50/12 Akademgorodok, Krasnoyarsk, 660036, Russia

Доп.точки доступа:
Murueva, A. V.; Dudaev, A. E.; Shishatskaya, E. I.; Ghorabe, F. D. E.; Nemtsev, I. V.; Немцев, Иван Васильевич; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Volova, T. G.
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Высокоэнтропийные сплавы FeCoNiP-Me (Me = Zn, Zr, W):микроструктура и магнитные свойства / С. В. Столяр, Л. А. Чеканова, Е. А. Денисова [и др.] // Нанофизика и наноэлектроника : Труды XXVIII Международного симпозиума : в 2-х т. - Нижний Новгород, 2024. - Т. 1, Секция : Магнитные наноструктуры. - С. 219-220. - Библиогр.: 7. - Выполнено в рамках госзадания ИФ СО РАН . - ISBN 978-5-8048-0123-7

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Держатели документа:
Красноярский научный центр СО РАН
Сибирский государственный университет науки и технологий им. М. Ф. Решетнева
Институт физики им. Л. В. Киренского СО РАН

Доп.точки доступа:
Денисова, Елена Александровна; Denisova, E. A.; Чеканова, Лидия Александровна; Chekanova, L. A.; Комогорцев, Сергей Викторович; Komogortsev, S. V.; Важенина, Ирина Георгиевна; Vazhenina, I. G.; Исхаков, Рауф Садыкович; Iskhakov, R. S.; Бондаренко, Галина Николаевна; Bondarenko, G. N.; Кох, Д.; Великанов, Дмитрий Анатольевич; Velikanov, D. A.; Немцев, Иван Васильевич; Nemtsev, I. V.; "Нанофизика и наноэлектроника", международный симпозиум(28 ; 2024 ; март ; 11-15 ; Нижний Новгород); Министерство науки и высшего образования Российской Федерации; Научный совет РАН по физике конденсированных сред; Научный совет РАН по физике полупроводников; Институт физики микроструктур РАН; Нижегородский государственный университет им. Н.И. Лобачевского
}
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Biodegradation of microbial plastic poly(3-hydroxybutyrate) in soil ecosystems at different latitudes / S. V. Prudnikova, E. G. Kiselev, A. V. Demidenko [et al.] // Giant. - 2024. - Vol. 18. - Ст. 100288, DOI 10.1016/j.giant.2024.100288. - Cited References: 96. - The study was funded by State Assignment of the Ministry of Science and Higher Education of the Russian Federation (project No. FWES-2021-0025) . - ISSN 2666-5425
Кл.слова (ненормированные):
Poly(3-hydroxybutyrate) -- Degradability -- Red soil -- Chernozem -- Climatic conditions -- Soil microorganisms
Аннотация: The features of the degradation of the "green" plastic poly(3-hydroxybutyrate) [P(3HB)] in the soil of various geographical regions were studied: in red ferralitic soil under tropical conditions (Kerala, India) and in chernozem soil under conditions of a sharply continental climate (Eastern Siberia, Russia). Significant differences in the chemical composition, temperature, and humidity of the studied soils were revealed. The number of bacteria and mycelial fungi in the Siberian chernozem was higher than in the red soil of India, from 2-3 to 10 or more times. The degradation of P(3HB) films in the chernozem occurred faster than in the red soil, which was drier, with a low content of humus and minerals, and fewer microorganisms than the chernozem. The half-life of polymer samples in Siberia and India was 64.8 and 126.4 days, respectively. During degradation, a decrease in the molecular weight and an increase in the degree of crystallinity of polymer samples were revealed, which indicates a more active biodegradation of the amorphous phase of the polymer by soil microorganisms. The primary degraders of the polymer have been isolated and identified, and it has been shown that the complexes of degrading bacteria and fungi in different types of soils did not have common species. Despite the presence of species with pronounced depolymerase activity, the rate of film degradation in red ferralitic soils was slowed down by unfavorable environmental conditions. The obtained results confirm the importance of studying the process of PHA degradation in natural conditions.

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Держатели документа:
Siberian Federal University, 79 Svobodny pr, Krasnoyarsk 660041, Russia
Institute of Biophysics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/50 Akademgorodok, Krasnoyarsk 660036, Russia
Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50 Akademgorodok, Krasnoyarsk 660036, Russia
L.V. Kirensky Institute of Physics, 50/12 Akademgorodok, Krasnoyarsk 660036, Russia
International and Interuniversity Centre for Nano Science and Nano Technology, Mahatma Gandhi University, Kottayam 686560, India

Доп.точки доступа:
Prudnikova, S. V.; Kiselev, E. G.; Demidenko, A. V.; Nemtsev, I. V.; Немцев, Иван Васильевич; Shishatskaya, E. I.; Thomas, S.; Volova, T. G.
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10.

Структура и магнитные свойства кобальт-никелевых сплавов,полученных методом химического осаждения в форме покрытий и пленок с использованием арабиногалактана в качестве восстанавливающего агента / С. В. Столяр, Л. А. Чеканова, Е. А. Денисова [и др.] // Нанофизика и наноэлектроника : Труды XXVIII Международного симпозиума : в 2-х т. - Нижний Новгород, 2024. - Т. 1, Секция : Магнитные наноструктуры. - С. 188-189. - Библиогр.: 14. - Выполнено в рамках госзадания ФИЦ КНЦ СО РАН . - ISBN 978-5-8048-0123-7

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Держатели документа:
Федеральный исследовательский центр "Красноярский научный центр Сибирского отделения Российской академии наук"
Сибирский федеральный университет
Институт физики им. Л. В. Киренского СО РАН
Институт химической кинетики и горения СО РАН

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Столяр, Сергей Викторович; Stolyar, S. V.; Чеканова, Лидия Александровна; Chekanova, L. A.; Денисова, Елена Александровна; Denisova, E. A.; Ярославцев, Роман Николаевич; Yaroslavtsev, R. N.; Черемискина, Елена Владимировна; Немцев, Иван Васильевич; Nemtsev, I. V.; Исхаков, Рауф Садыкович; Iskhakov, R. S.; Важенина, Ирина Георгиевна; Vazhenina, I. G.; Сухов, Б. Г.; "Нанофизика и наноэлектроника", международный симпозиум(28 ; 2024 ; март ; 11-15 ; Нижний Новгород); Министерство науки и высшего образования Российской Федерации; Научный совет РАН по физике конденсированных сред; Научный совет РАН по физике полупроводников; Институт физики микроструктур РАН; Нижегородский государственный университет им. Н.И. Лобачевского
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