Библиотека института физики им. Л.В. Киренского СО РАН

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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanov Y. N., Sukhovskii A. A., Volkov N. V.
Заглавие : B-11 NMR study of Ho1−x Y x Al3(BO3)4 multiferroics
Место публикации : J. Struct. Chem. - 2013. - Vol. 54, Is. 1: Suppl. - P.130-136. - DOI 10.1134/S0022476613070135
Аннотация: The 11B NMR method is used to study the crystals of trigonal alumina borates Ho1−x Y x Al3(BO3)4 (x = 0, 0.5, 1). The temperature-field evolution of quadrupole and hyperfine interactions in these compounds is studied and described.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrova I. P., Ivanov Y. N., Bondarev V. S., Sukhovskii A. A., Voronov V. N.
Заглавие : Calorimetric and 23Na MAS NMR study of the phase diagram of NANB1_xTAxO3 solid solutions
Место публикации : Functional Materials. - 2010. - Vol. 17, Is. 1. - P.18-23. - ISSN 1027-5495
Аннотация: The heat capacity of NaNb1_xTaxO3 solid solutions was measured in the temperature range 100 to 770 K. The step-like change of phase transition temperature is observed in the T-x phase diagram at concentration x = 0.55. The obtained results are in a good agreement with the data of dielectric studies. The 23Na MAS NMR spectra were obtained at Larmor frequency 79.35 MHz using a Bruker AVANCE 300 spectrometer. The quadru-polar coupling constant, (CQ=e2qQ/h) and asymmetry parameter (n) were determined by computer fitting of the NMR line shape using the DMFit software. The found parameters show that solid solution structure is NaTa03-based at 0.7<X ?1 and NaNbO3-based at 0?x?0.5. The spectra in the intermediate region (0.5<x?0.7) can be described at a reasonable accuracy when assuming the coexistence of NaTaO3 and NaNbO3 structures. В© 2010 - STC "Institute for Single Crystals".
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanov Y. N., Totz J., Michel D., Klotzsche G., Sukhovsky A. A., Aleksandrova I. P.
Заглавие : Chemical exchange in NH4HSeO4 single crystals studied by two-dimensional H-2 nuclear magnetic resonance
Разночтения заглавия :авие SCOPUS: Chemical exchange in NH4HSeO4 single crystals studied by two-dimensional 2H nuclear magnetic resonance
Место публикации : J. Phys.: Condens. Matter: IOP PUBLISHING LTD, 1999. - Vol. 11, Is. 18. - P.3751-3760. - ISSN 0953-8984, DOI 10.1088/0953-8984/11/18/310
Примечания : Cited References: 16
Предметные рубрики: PHASE-TRANSITIONS
CONDUCTIVITY PROCESSES
AMMONIUM
Ключевые слова (''Своб.индексиров.''): hydrogen bonds--nuclear magnetic resonance--single crystals--thermal effects--ammonium hydrogen selenate--ammonium compounds
Аннотация: Processes of chemical exchange of deuterons in partially deuterated ammonium hydrogen selenate, NH4HSeO4 (AHSe), crystals are investigated by means of H-2 nuclear magnetic resonance (NMR) experiments over a wide temperature range. The temperature dependencies of the quadrupole line splittings in the one-dimensional spectra of AHSe above 350 K revealed lineshape changes which are characteristic for chemical exchange processes. A detailed study of these exchange processes in AHSe is achieved by means of two-dimensional H-2 NMR experiments. In the temperature range investigated, a chemical exchange occurs only between those deuteron (proton) sites which are involved in hydrogen bonds (alpha- and beta-positions). It was established that the rates of exchange between all types of hydrogen-bound deuteron are approximately the same. Exchange between these positions and the deuterons in the ND4 groups could not be detected. On the basis of our findings, we finally discuss a model for the microscopic mechanism of hydrogen transport in AHSe.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krylov A. S., Molokeev M. S., Misyul S. V., Krylova S. N., Oreshonkov A. S., Ivanenko A. A., Zykova V. A., Ivanov Y. N., Sukhovsky A. A., Voronov V. N., Safonov I. N., Vtyurin A. N.
Заглавие : Crystal structure and phase transitions of a layered perovskite-like CsScF4 crystal
Коллективы : Russian Foundation for Basic Research [16-02-00102]
Место публикации : CrystEngComm: Royal Society of Chemistry, 2016. - Vol. 18, Is. 43. - P.8472-8486. - ISSN 1466-8033, DOI 10.1039/c6ce01144f
Примечания : Cited References:47. - The authors are grateful to Prof. I. N. Flerov for valuable support and useful discussions. This work was partly supported by the Russian Foundation for Basic Research, Project 16-02-00102. The research is partially conducted within the framework of the state task of the Ministry of Education and Science of the Russian Federation for Siberian Federal University on R&D performance in 2014 (Task 3.2534.2014/K). X-ray data from powders, Raman NMR, and IR spectra were obtained with use the analytical equipment of Krasnoyarsk Center of collective use SB RAS.
Предметные рубрики: NEGATIVE THERMAL-EXPANSION
RAMAN-SCATTERING
LATTICE-DYNAMICS
Аннотация: This work is devoted to the complex research on temperature phase transitions in a CsScF4 crystal. The crystal structure was solved and refined at different temperatures by using the Rietveld method. Structural phase transitions were investigated by using the following spectroscopic methods, some of them for the first time: Brillouin spectroscopy, Raman spectroscopy, IR absorption spectroscopy and NMR. The symmetry analysis of the Brillouin zone center of all phases is presented. The vibrational spectra of the crystal in three phases have been calculated. The structural phase transition mechanism was determined. The transitions at T-1 = 475 K and T-2 = 317.5 K are of displacement type. The Raman soft modes have been associated with rotations of the ScF6 octahedral group.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrova I. P., Rosanov O. V., Sukhovsky A. A., Moskvich Y. N.
Заглавие : Detection of the incommensurate modulation of the hydrogen-bond double-minimum potential in the antiferroelectric phase of NH4HSEO4
Место публикации : Phys. Lett. A. - 1983. - Vol. 95, Is. 6. - P.339-342. - ISSN 0375-9601, DOI 10.1016/0375-9601(83)90035-X
Примечания : Cited References: 15
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrova I. P., Moskvich Yu. N., Rozanov O. V., Sadreev A. F., Sukhovskii A. A.
Заглавие : Dislocation instability of an incommensurate phase in connection with the floating phase in an NH4HSeO4 crystal
Место публикации : JETP Letters. - 1984. - Vol. 40, Is. 4. - P.879-881. - ISSN 0021-3640
Примечания : Cited References: 7
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrova I. P., Moskvich Yu. N., Rozanov O. V., Sukhovsky A. A.
Заглавие : Dislocations and time-dependent dynamics of the incommensurate phase of NH4HSEO4
Место публикации : Ferroelectr. Lett. Sect. - 1984. - Vol. 1, Is. 5-6. - P.131-134. - ISSN 0731-5171, DOI 10.1080/07315178408202410
Примечания : Cited References: 5
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrova I. P., Bartolome J., Falvello L. R., Torres J. M., Sukhovskii A. A.
Заглавие : Effect of impurities on the successive phase transitions in (Cs1-xRbx)(2)ZnI4 compounds
Разночтения заглавия :авие SCOPUS: Effect of impurities on the successive phase transitions in (Cs1-xRbx)2ZnI4 compounds
Место публикации : J. Phys.: Condens. Matter: IOP PUBLISHING LTD, 2002. - Vol. 14, Is. 49. - P.13623-13634. - ISSN 0953-8984, DOI 10.1088/0953-8984/14/49/316
Примечания : Cited References: 27
Предметные рубрики: X-RAY
CS2ZNI4
SYSTEM
HEAT
Ключевые слова (''Своб.индексиров.''): phase transitions--point defects--specific heat--temperature--x ray diffraction analysis--zinc compounds--lock-in transition--nuclear quadrupole resonance--single crystals
Аннотация: The heat capacity, nuclear quadrupole resonance (NQR) and x-ray diffraction of (Cs1-xRbx)(2)ZnI4 single crystals have been measured, for x = 0, 0.001, 0.005, 0.01, 0.025 and 0.05. The normal to incommensurate (N-Inc) phase transition at T-I, the incommensurate to commensurate (Inc-C) lock-in transition at T-L and the structural commensurate monoclinic to triclinic transition at T-LT, observed in the parent compound (x = 0), takes place for x = 0, 0.001, 0.005 and 0.01. For x = 0.025 only T-I and T-L are detected, while for x = 0.05 no transitions were observable. The values of T-I and T-L increase with x while T-LT decreases and disappears at the concentration x = 0.025. The effect of defects, besides modifying the transition temperatures, is that of broadening and lowering the heat capacity anomaly at the lock-in transition until its total quenching for x = 0.05. No observable hysteresis is detected in this transition. NQR and x-ray diffraction data show the Inc-C transition up to the highest concentration. We conclude that this phenomenology is caused by weak interaction of the incommensurate modulation with point defects even in the region close to the Inc-C transition.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krylov A. S., Sofronova S. N., Kolesnikova E. M., Ivanov Y. N., Sukhovsky A. A., Goryainov S. V., Ivanenko A. A., Shestakov N. P., Kocharova A. G., Vtyurin A. N.
Заглавие : Experimental and theoretical methods to study structural phase transition mechanisms in K3WO3F3 oxyfluoride
Коллективы : Russian Foundation for Basic Research [4828.2012.2, 12-02-31205]; Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" [8379]
Место публикации : J. Solid State Chem. - 2014. - Vol. 218. - P.32-37. - ISSN 0022-4596, DOI 10.1016/j.jssc.2014.05.028. - ISSN 1095-726X
Примечания : Cited References: 21. - The Authors are grateful to Prof. Zinenko V.I. for constructive discussion of the results. The work has been done with financial support of the Russian Foundation for Basic Research projects nos. 4828.2012.2, 12-02-31205; Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" project no. 8379.
Предметные рубрики: LATTICE-DYNAMICS
RAMAN-SCATTERING
ELPASOLITE
(NH4)3WO3F3
SPECTROSCOPY
CRYSTALS
Ключевые слова (''Своб.индексиров.''): raman spectroscopy--ir spectroscopy--nmr spectroscopy--high hydrostatic pressure--oxyfluorides--lattice dynamics calculations
Аннотация: The results of structural phase transitions mechanisms study in K3WO3F3oxyfluoride are represented by different experimental and theoretical methods. The structural phase transition anomalies at T1=452 K and T2=414 K of Raman and IR spectra have been analyzed. Using vibrational spectroscopy methods, the NMR-experiment has been done to clarify the nature of found phase transitions: displacive types or order-disorder types. The model of “disordered” crystal was proposed, and the results of lattice dynamics calculation in frameworks of the generalized Gordon–Kim method of ordered (R3) and “disordered” crystals were compared. The high pressure phases were studied by the Raman technique too.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanov Y. N., Aleksandrova I. P., Sukhovsky A. A., Baranov A. I.
Заглавие : H-2 NMR investigation of the transition to the proton glass state in the CS5H3(SO4)(4)center dot 0.5H(2)O crystal
Разночтения заглавия :авие SCOPUS: 2H NMR investigation of the transition to the proton glass state in the Cs5H3(SO4)4В·0.5H 2O crystal
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007. - Vol. 49, Is. 6. - P1142-1148. - ISSN 1063-7834, DOI 10.1134/S1063783407060200
Примечания : Cited References: 19
Предметные рубрики: DIELECTRIC-RELAXATION
MAGNETIC-RESONANCE
PHASES
Аннотация: A crystal of the CS5H3(SO4)(4) (.) xH(2)O (x approximate to 0.5) (PCHS) compound, which belongs to the family of proton conductors with a complex system of hydrogen bonds, is investigated by H-2 NMR spectroscopy. The temperature and orientation dependences of the H-2 NMR spectra are measured and analyzed. It is established that, upon transition to the glassy phase at the temperature T-g = 260 K, the parameters characterizing the proton exchange between positions in hydrogen bonds remain unchanged to within the limits of experimental error. The protons in the two-dimensional network of hydrogen bonds in the (001) plane are dynamically disordered over possible positions down to temperatures considerably lower than the glass transition point T-g. However, water molecules are fixed at particular structural positions in the phase transition range. In PCHS crystals with a nonstoichiometric water content, this circumstance can be responsible for the frustration that leads to the formation of the glassy state.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrov I. P., Bovina A. F., Ageev O. A., Sukhovskii A. A.
Заглавие : Incommensurate phase in the layered hexagonal crystal Cs3Bi2I9
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 1997. - Vol. 39, Is. 6. - P991-994. - ISSN 1063-7834, DOI 10.1134/1.1130118
Примечания : Cited References: 12
Аннотация: An incommensurate phase is observed in a Cs3Bi2I9 crystal, which belongs to the family of layered A(3)B(2)X(9) structures. Data from I-127 NQR and x-ray powder diffraction patterns show that the second-order normal phase-incommensurate phase transition at T-i = 220 K is accompanied by a P6(3)/mmc ↔ P2(1)/m symmetry change and takes place at the center of the Brillouin zone. The nature of the instability leading to the appearance of this little-studied form of incommensurability is discussed. (C) 1997 American Institute of Physics.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrova I. P., Sukhovsky A. A., Ivanov Yu. N., Yablonskaya Yu.E., Vakhrushev S.B.
Заглавие : Local and average structure of relaxor Na1/2Bi1/2TiO3 from the point of view of NMR
Место публикации : Ferroelectrics. - 2009. - Vol. 378. - P.16–22
Примечания : Библиогр.: 12
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13.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Yablonskaya Yu. E., Aleksandrova I. P., Sukhovsky A. A., Ivanov Yu. N., Vakhrushev S. B.
Заглавие : Local and Average Structure of Relaxor Na1/2Bi1/2TiO3 From the Point of View of NMR
Коллективы : Russia/CIS/Baltic/Japan Symposium on Ferroelectricity
Место публикации : 9th Russai/CIS/Baltic/Japan symposium on ferroelectricity: abstracts book : June 15-19, 2008, Vilnius, Lithuania. - p.156
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrova I. P., Sukhovsky A. A., Ivanov Y. N., Raevsky I. P.
Заглавие : Local structure of disordered PbSc1/2Nb1/2O3 in the region of the diffuse tetragonal phase-rhombohedral phase transition
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 54, Is. 2. - P.316-323. - ISSN 1063-7834, DOI 10.1134/S1063783412020047
Примечания : Cited References: 16. - This study was supported by the Council on Grants from the President of the Russian Federation for Support of the Leading Scientific Schools of the Russian Federation (grant no. NSh-4645.2010.2).
Предметные рубрики: Neutron-diffraction
Order
BaTiO3
PbNiO3
NMR
Аннотация: The local structure of the ferroelectric-relaxor PbSc1/2Nb1/2O3 in the temperature range from 550 to 220 K has been investigated using 45Sc nuclear magnetic resonance. It has been found that, in the paraelectric phase at temperatures below 550 K, the crystal consists of regions of an ordered elpasolite structure and inclusions of the disordered tetragonal perovskite phase with displacements along directions of the [001] type. The relative weight of the tetragonal structure in the region of the paraelectric phase is approximately equal to 0.28. Below the temperature of the phase transition from the disordered modification to the polar phase, the relative weight of the tetragonal phase decreases with decreasing temperature. The tetragonal structure is replaced by the trigonal polar structure. In a wide temperature range (∼50 K), there exists a heterophase structure that is characteristic of relaxors. Note that the correlation length of displacements in the tetragonal phase should be very small to explain the absence of indications of the existence of this phase in the diffraction data.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Falaleev O. V., Kriger A. I., Sukhovskii A. A., Moskvich Yu. N.
Заглавие : Measurement of the anisotropy of weak indirect interaction between magnetic nuclei in cesium tgse
Место публикации : Fiz. Tverd. Tela. - 1981. - Vol. 23, Is. 6. - P.1853-1857. - ISSN 0367-3294
Примечания : Cited References: 12
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mironov V. L., Sukhovskii A. A., Lukin Y. I., Aleksandrova I. P.
Заглавие : Measurement of the maximum content of bound water in bentonitic clay using dielectric and NMR methods
Место публикации : Russ. Phys. J.: SPRINGER, 2011. - Vol. 54, Is. 1. - P.71-76. - ISSN 1064-8887
Примечания : Cited References: 4
Ключевые слова (''Своб.индексиров.''): dielectric permittivity--nuclear magnetic resonance--bentonitic clay--bound water
Аннотация: An investigation of moisture dependences of refractive index and spectral width of the nuclear magnetic resonance (NMR) is performed for bentonitic clay specimens at different temperatures. These moisture dependences allowed identifying two types of moisture: bound and free water. The maximum content of water in the bentonitic clay is measured.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanov Y. N., Sukhovsky A. A., Aleksandrova I. P., Totz J., Michel D.
Заглавие : Mechanism of Protonic Conductivity in an NH(4)HSeO(4) Crystal
Коллективы : Russian Foundation for Basic Research [00-15-96790]
Разночтения заглавия :авие SCOPUS: Mechanism of protonic conductivity in an NH4HSeO4 crystal
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2002. - Vol. 44, Is. 6. - P1077-1084. - ISSN 1063-7834, DOI 10.1134/1.1485011
Примечания : Cited References: 20. - This work was supported by the Russian Foundation for Basic Research, project no. 00-15-96790.
Аннотация: The chemical exchange of deuterons in a partly deuterated ammonium hydrogen selenate crystal is investigated by deuteron magnetic resonance ((2)H NMR) spectroscopy over a wide range of temperatures. The changes observed in the line shape of the NMR spectra at temperatures above 350 K are characteristic of chemical exchange processes. The exchange processes are thoroughly examined by two-dimensional (2)H NMR spectroscopy. It is established that, over the entire temperature range, only deuterons of hydrogen bonds are involved in the exchange and the rates of exchange between deuterons of all types are nearly identical. No deuteron exchange between the ND(4) groups and hydrogen bonds is found. A new model of proton transport in ammonium hydrogen selenate is proposed on the basis of the experimental data. This model makes it possible, within a unified context, to explain all the available experimental data, including macroscopic measurements of the electrical conductivity. (C) 2002 MAIK "Nauka/Interperiodica".
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanov Y. N., Sukhovsky A. A., Aleksandrova I. P., Michel D.
Заглавие : Micromechanism of proton conduction in a KHSeO4 crystal
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2006. - Vol. 48, Is. 9. - P1698-1702. - ISSN 1063-7834, DOI 10.1134/S1063783406090125
Примечания : Cited References: 11
Предметные рубрики: EXCHANGE NMR
Аннотация: The proton exchange in a potassium hydrogen selenate crystal is investigated in detail. Partial deuteration of the crystal (approximately 80% of the protons are replaced by deuterons) makes it possible to use the method of nuclear magnetic resonance (NMR) on quadrupole nuclei to perform research into proton (deuteron) transport. In addition to conventional Fourier-transform NMR spectroscopy, elementary processes of deuteron chemical exchange are studied by two-dimensional NMR spectroscopy, which provides unique information regarding these processes. Slow exchange between protons of hydrogen bond chains and dimers consisting of two SeO4 groups is revealed. It is established that this process is responsible for the proton conduction in the potassium hydrogen selenate. The NMR data are compared with the results of dielectric measurements carried out at a frequency of 1 kHz.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrova I. P., Ivanov Y. N., Sukhovskii A. A., Vakhrushev S. B.
Заглавие : Na-23 NMR in the relaxor ferroelectric Na1/2Bi1/2TiO3
Разночтения заглавия :авие SCOPUS: 23Na NMR in the relaxor ferroelectric Na1/2Bi 1/2TiO3
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2006. - Vol. 48: 17th All-Russia Conference on the Physics of Ferroelectrics (VKS-XVII) (JUN 26-JUL 01, 2005, Penza, RUSSIA), Is. 6. - P1120-1123. - ISSN 1063-7834, DOI 10.1134/S106378340606031X
Примечания : Cited References: 8
Предметные рубрики: NEUTRON-SCATTERING
PHASE-TRANSITION
NA0.5BI0.5TIO3
Аннотация: The Na-23 NMR spectra of a Na1/2Bi1/2TiO3 crystal are studied at frequencies of 79.4 and 15.7 MHz in the temperature range 150-720 K. It is revealed that, at all temperatures, the crystal contains regions with a nearly cubic matrix and polar clusters. The temperature dependence of the local distortion of the Na environment in the clusters is determined. The dynamics of the reorientation of the local cluster polarization in the tetragonal and trigonal NBT phases is analyzed.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrova I. P., Sukhovskii A. A., Ivanov Y. N., Yablonskaya Y. E., Vakhrushev S. B.
Заглавие : Na-23 NMR study of the local order in the Na1/2Bi1/2TiO3 structure in a weak magnetic field
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2008. - Vol. 50, Is. 3. - P496-501. - ISSN 1063-7834, DOI 10.1134/S1063783408030177
Примечания : Cited References: 14
Предметные рубрики: PHASE-TRANSITIONS
PEROVSKITE
Аннотация: The orientation dependences of the second-order quadrupole shifts of the central component in the Na-23 NMR spectrum were studied in the temperature range 293-760 K. The profile of the spectral distribution is calculated using various models of the Na1/2Bi1/2TiO3 structure. The calculations agree with the experimental data for the monoclinic structure of a polar cluster with two Na displacement components: a displacement along the [111](P) direction and a small displacement statistically or dynamically disordered over six equally probable [100](P)-type directions. Tetragonal-phase nuclei and monoclinic clusters with a very small displacement component along the [111](P) direction are found to coexist and have close energies over the temperature range 580-610 K. The results obtained provide new information concerning the character of the diffuse phase transition at 610 K.
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