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1.


   
    Antiferromagnetic dichroism in a complex multisublattice magnetoelectric CuB2O4 / K. N. Boldyrev [et al.] // Phys. Rev. Lett. - 2015. - Vol. 114, Is. 24. - Ст. 247210, DOI 10.1103/PhysRevLett.114.247210. - Cited References:40. - This study was supported by the Russian Academy of Sciences under the Programs for Basic Research, by the President of the Russian Federation (Grant No. MK-3521.2015.2, K. N. B.), by the Russian Foundation for Basic Research (Grants No. 15-32-20613, K. N. B., and No. 15-02-04222, R. V. P.), and by the Ministry of Education and Science of the Russian Federation (Grant No. 14.B25.0031.25, R. V. P.). . - ISSN 0031. - ISSN 1079-7114
   Перевод заглавия: Антиферромагнитный дихроизм в сложном многоподрешеточном магнетоэлектрике CuB2O4
РУБ Physics, Multidisciplinary
Рубрики:
MAGNETIC SOLITON LATTICE
   COPPER METABORATE

   GYROTROPIC BIREFRINGENCE

   SPECTROSCOPY

   EXCITATIONS

   TRANSITIONS

   CRYSTALS

   Cr2O3

   FIELD

Аннотация: Magnetic control of the crystal chirality was announced by Saito et al. [Phys. Rev. Lett. 101, (2008)] on the ground of experiments in CuB2O4. This claim has raised a sharp dispute in the literature because it seemed to contradict the fundamental symmetry principles. We settle this dispute on the basis of a high-resolution optical spectroscopy study of excitonic transitions in CuB2O4. We find that a large sublattice-sensitive antiferromagnetic linear dichroism (LD) emerges at the Néel temperature TN=21 K and show how it could simulate a “magnetic-field control of the crystal chirality.” We prove that the discovered LD is related microscopically to the magnetic Davydov splitting. This LD is highly sensitive to subtle changes in the spin subsystems, which allowed us to observe a splitting of the phase transition into an incommensurate magnetic phase into two transitions (T∗1=8.5 and T∗2=7.9 K) and to suggest elliptical spiral structures below T∗1, instead of a simple circular helix proposed earlier.
О магнитном контроле кристаллической хиральности сообщил Сайто и др. [Phys. Rev. Lett. 101, 117402 (2008)] на основании экспериментов в CuB2O4. Это требование вызвало резкий спор в литературе, потому что это казалось, противоречат основным принципам симметрии. Мы урегулировать этот спор на основе исследования с помощью оптической спектроскопии высокого разрешения экситонных переходов в CuB2O4. Мы считаем, что большой подрешетко-чувствительный антиферромагнитный линейный дихроизм (LD) возникает при температуре Нееля TN= 21 Kи показываем, как это может имитировать "контроль магнитным полем кристаллической хиральности." Мы докажем, что обнаруженный LD связанс микроскопическим магнитным Давыдовским расщеплением. Этот Л.Д. весьма чувствителен к тонким изменениям в спиновых подсистем, которые позволили нам наблюдать расщепление фазового перехода в несоизмеримы магнитная фаза в двух переходов (T*1= 8,5 и Т*2 = 7,9 К) и предположить эллиптическую спиральную структуру ниже T*1, вместо простой круговой спирали предложенный ранее.

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Держатели документа:
RAS, Inst Spect, Moscow 142190, Russia.
RAS, Ioffe Phys Tech Inst, St Petersburg 194021, Russia.
RAS, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Boldyrev, K. N.; Pisarev, R. V.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Popova, M. N.; Russian Academy of Sciences under the Programs for Basic Research; Russian Federation [MK-3521.2015.2]; Russian Foundation for Basic Research [15-32-20613, 15-02-04222]; Ministry of Education and Science of the Russian Federation [14.B25.0031.25]
}
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2.


   
    Bifurcations observed in the spectra of coupled electron-phonon modes in multiferroic PrFe3(BO3)4 subjected to a magnetic field / K. N. Boldyrev [et al.]. - Electronic text data // ArXiv. - 2016. - Ст. 1609.02125. - Cited References: 19. - This research was supported by the Russian Scientific Foundation under Grant No 14-12-01033, the President of Russian Federation (MK-3521-2015.2, K.N.B.), and the U.S. Department of Energy under Grant No DE-FG02-07ER46382 (experiments at U4-IR beamline NSLS-BNL, T.N.S. and A.A.S.). The National Synchrotron Light Source is operated as a User Facility for he U.S. Department of Energy under Contract No. DE-AC02-98CH10886. Part of this work was supported by EMFL (contract No. 26211). M.N.P. thanks B.Z. Malkin helpful discussions.
Аннотация: We report on bifurcations effect mediated by the electron-phonon coupling in a concentrated rare-earth-containing antiferromagnet, observed in the spectra of coupled 4f-electron-phonon modes under the influence of an external magnetic field. The effect was observed in the low-temperature far-infrared (terahertz) reflection spectra of a multiferroic easy-axis antiferromagnet PrFe3(BO3)4 in magnetic fields Bext||c. Both paramagnetic and magnetically ordered phases (including a spin-flop one) were studied in magnetic fields up to 30 T. We show that the field behavior of the coupled modes can be successfully explained and modeled on the base of the equation derived in the frame of the theory of coupled electron-phonon modes, with the same field-independent electron-phonon interaction constant |W|=14.8cm−1.

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Держатели документа:
Institute of Spectroscopy, Russian Academy of Sciences, 108840 Troitsk, Moscow, Russia
Department of Physics, New Jersey Institute of Technology, 07102 Newark, New Jersey, USA
High Field Magnet Laboratory (HFML-EMFL), Radboud University, 6525 ED Nijmegen, Netherlands
Kirenskiy Institute of Physics, Siberian Branch of RAS, 660036 Krasnoyarsk, Russia

Доп.точки доступа:
Boldyrev, K. N.; Stanislavchuk, T. N.; Sirenko, A. A.; Kamenskyi, D.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Popova, M. N.
}
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3.


   
    Bifurcations of coupled electron-phonon modes in an antiferromagnet subjected to a magnetic field / K. N. Boldyrev [et al.] // Phys. Rev. Lett. - 2017. - Vol. 118, Is. 16. - Ст. 167203, DOI 10.1103/PhysRevLett.118.167203. - Cited References: 26. - This research was supported by the Russian Scientific Foundation under Grant No. 14-12-01033, the President of Russian Federation (MK-3577.2017.2, K. N. B.), and the U.S. Department of Energy under Grant No. DE-FG02-07ER46382 (experiments at U4-IR beam line NSLS-BNL, T. N. S. and A. A. S.). The National Synchrotron Light Source is operated as a user facility for the U.S. Department of Energy under Contract No. DE-AC02-98CH10886. Part of this work was supported by EMFL (Contract No. 26211). M. N. P. thanks B. Z. Malkin and A. V. Popov for helpful discussions. . - ISSN 0031-9007
Кл.слова (ненормированные):
Antiferromagnetic materials -- Bifurcation (mathematics) -- Electron-phonon interactions -- Electrons -- Magnetic fields -- Magnetism -- Temperature -- Antiferromagnetic crystals -- Bifurcation points -- Electron phonon couplings -- Electronic excitation -- External magnetic field -- Field independents -- Low temperatures -- Reflection spectra -- Phonons
Аннотация: We report on a new effect caused by the electron-phonon coupling in a stoichiometric rare-earth antiferromagnetic crystal subjected to an external magnetic field, namely, the appearance of a nonzero gap in the spectrum of electronic excitations in an arbitrarily small field. The effect was registered in the low-temperature far-infrared (terahertz) reflection spectra of an easy-axis antiferromagnet PrFe3(BO3)4 in magnetic fields Bext-c. Both paramagnetic and magnetically ordered phases (including a spin-flop one) were studied in magnetic fields up to 30 T, and two bifurcation points were observed. We show that the field behavior of the coupled modes can be successfully explained and modeled on the basis of the equation derived in the framework of the theory of coupled electron-phonon modes, with the same field-independent electron-phonon interaction constant |W|=14.8 cm-1. © 2017 American Physical Society.

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Держатели документа:
Institute of Spectroscopy, Russian Academy of Sciences, Troitsk, Moscow, Russian Federation
Department of Physics, New Jersey Institute of Technology, Newark, NJ, United States
High Field Magnet Laboratory (HFML-EMFL), Radboud University, Nijmegen, Netherlands
Kirenskiy Institute of Physics, Siberian Branch of RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Boldyrev, K. N.; Stanislavchuk, T. N.; Sirenko, A. A.; Kamenskyi, D.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Popova, M. N.
}
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4.


   
    Coupling between phonon and crystal-field excitations in multiferroic PrFe3(BO3)4 / K. N. Boldyrev [et al.] // Phys. Rev. B. - 2014. - Vol. 90, Is. 12. - Ст. 121101, DOI 10.1103/PhysRevB.90.121101. - Cited References: 35. - This research was supported by the Russian Scientific Foundation under Grant No. 14-12-01033, the President of Russian Federation (MK-1700.2013.2; K.N.B.), and the U.S. Department of Energy under Grant No. DE-FG02-07ER46382 (experiments at U4-IR beamline NSLS-BNL; T.N.S. and A.A.S.). The National Synchrotron Light Source is operated as a User Facility for the U.S. Department of Energy under Contract No. DE-AC02-98CH10886. M.N.P. thanks B. Z. Malkin for drawing her attention to the work [33] and for helpful discussions. . - ISSN 1098-0121. - ISSN 1550-235X
   Перевод заглавия: Взаимодействие между фононами и возбуждениями кристаллического поля в мультиферроике PrFe3(BO3)4
РУБ Physics, Condensed Matter
Рубрики:
MAGNETOELECTRIC PROPERTIES
   GROUND-STATE

   SM

Аннотация: Far-infrared reflection and ellipsometry measurements on multiferroic PrFe3(BO3)4 and SmFe3(BO3)4 single crystals were used to investigate the interaction between lattice phonons and electronic excitations associated with 4f crystal-field transitions. A temperature-dependent interference between two types of excitations was observed in PrFe3(BO3)4 in which the frequency of 4f crystal-field electronic excitation of Pr3+ falls into the TO-LO frequency interval of the optical phonon mode near 50 cm−1 (1.5 THz). Experimental data were explained on the basis of a theoretical model of coupled electron-phonon modes. The fitting procedure revealed the value 14.8 cm−1 for the electron-phonon coupling constant. This rather large value points to an essential role played by the electron-phonon interaction in the physics of multiferroics.

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Держатели документа:
RAS, Inst Spect, Troitsk 142190, Russia
New Jersey Inst Technol, Dept Phys, Newark, NJ 07102 USA
RAS, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Boldyrev, K. N.; Stanislavchuk, T. N.; Sirenko, A. A.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Popova, M. N.; Russian Scientific Foundation [14-12-01033]; President of Russian Federation [MK-1700.2013.2]; U.S. Department of Energy [DE-FG02-07ER46382, DE-AC02-98CH10886]
}
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5.


   
    Evidence for a collinear easy-plane magnetic structure of multiferroic EuFe3(BO3)4: Spectroscopic and theoretical studies / M. N. Popova [et al.] // Phys. Rev. B. - 2016. - Vol. 94, Is. 18. - Ст. 184418, DOI 10.1103/PhysRevB.94.184418. - Cited References: 49. - This work was supported by the Russian Science Foundation under Grant No. 14-12-01033. I.A.G. and V.L.T. are grateful to L. N. Bezmaternykh for useful comments concerning the crystal growth, to M. S. Molokeev for the XRD characterization of the samples, and to the Russian Foundation for Basic Research for a financial support (Grants No. 13-02-12442 and No. 14-02-00307a). . - ISSN 1098-0121
   Перевод заглавия: Фактические данные по коллинеарности легкоплоскостной магнитной структуры мультиферроика EuFe3 (BO3) 4: спектроскопические и теоретические исследования
Аннотация: We performed high-resolution polarized optical transmission spectroscopy and theoretical studies of multiferroic EuFe3(BO3)4 single crystals in the three phases: paramagnetic R32(T˃Ts=84K) and P3121(Ts˃T˃TN=34K), and antiferromagnetic (T˂TN) ones. The analysis of the spectra reveals interesting details of the magnetic structure, namely, a collinear arrangement of the iron magnetic moments along the C2 symmetry axis in the ab crystallographic plane of EuFe3(BO3)4 below TN. Spectral signatures of the phase transitions and the spin-phonon interaction are observed and discussed. Reliable crystal-field and exchange-interaction parameters are obtained and used to model the magnetic susceptibility of the compound. The results of detailed calculations of the electric polarization of EuFe3(BO3)4 in the R32 phase are presented, and mechanisms of the magnetoelectric response are discussed. We detect a strong effect of impurities (that enter the crystal from a flux in the course of the crystal growth) on the structural phase-transition temperature and demonstrate a coexistence of both R32 and P3121 phases down to the lowest temperatures in a EuFe3(BO3)4 crystal grown with the Bi2Mo3O12 based flux, due to inhomogeneous distribution of impurity Bi3+ ions. Our study can be considered as a demonstration of the abilities of optical spectroscopy in delivering new information on a magnetic compound, even in the case when other methods fail. © 2016 American Physical Society.

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Держатели документа:
Institute for Spectroscopy, Russian Academy of Sciences, Troitsk, Moscow, Russian Federation
Kazan Federal University, Kazan, Russian Federation
Department of Physics, New Jersey Institute of Technology, Newark, NJ, United States
Moscow Institute of Physics and Technology, State University, Dolgoprydny, Moscow region, Russian Federation
L. V. Kirensky Institute of Physics, Siberian Branch of RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Popova, M. N.; Malkin, B. Z.; Boldyrev, K. N.; Stanislavchuk, T. N.; Erofeev, D. A.; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна
}
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6.


   
    Exotic spin structures and phase transitions in a complex magnetoelectric CuB2O4 as evidenced by optical linear dichroism studies / K. N. Boldyrev [et al.] // 20th Int. Сonf. on Magnetism (ICM-2015) : book of abstracts. - 2015. - Ст. TH.C-P107

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Доп.точки доступа:
Boldyrev, K. N.; Болдырев, Кирилл Николаевич; Popova, M. N.; Попова, Марина Николаевна; Pisarev, R. V.; Писарев, Роман Васильевич; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; International Conference on Magnetism(20 ; 2015 ; Jul ; 5-10 ; Barselona, Spain)
}
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7.


   
    High-resolution spectroscopy of YbAl(3)(BO(3))(4) stoichiometric nonlinear laser crystals / M. N. Popova [et al.] // J. Phys.: Condens. Matter. - 2008. - Vol. 20, Is. 45. - Ст. 455210, DOI 10.1088/0953-8984/20/45/455210. - Cited References: 20. - The authors thank E Antic-Fidancev for helpful discussions on the 'barycenter curves', P Aschehoug for technical assistance, and B Mavrin for assistance in Raman spectra measurements. This work was supported by the CNRS-RAS exchange program (project No. 21241), by the Russian Foundation for Basic Research (Grants Nos 07-02-01185 and 06-02-16088), and by the Russian Academy of Sciences under the Programs for Basic Research. . - ISSN 0953-8984
РУБ Physics, Condensed Matter
Рубрики:
YB-YAB LASER
   GROWTH

   FREQUENCY

   BORATE

Кл.слова (ненормированные):
Crystal symmetry -- Crystals -- Light emission -- Light sources -- Luminescence -- Spectroscopic analysis -- Ytterbium -- Electronic levels -- High resolutions -- Luminescence spectroscopies -- Main lines -- Nonlinear laser crystals -- Raman spectrums -- Vibronic structures -- Weak lines -- Single crystals
Аннотация: We present temperature-dependent high-resolution polarized transmittance spectroscopy as well as luminescence spectroscopy of YbAl(3)(BO(3))(4) single crystals. Positions and symmetries of all the Yb(3+) crystal-field electronic levels have been found from the analysis of the spectra. Near the main line of the optical transition (2)F(7/2)(0) -> (2)F(5/2)(0) we observe a lot of narrow weak lines. These lines point to the presence of several different distorted sites of Yb(3+). We analyze the possible origin of the distorted sites. Vibronic structure in transmittance and luminescence spectra was observed and compared with room-temperature Raman spectra.

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Держатели документа:
[Popova, M. N.
Boldyrev, K. N.] Russian Acad Sci, Inst Spect, Troitsk 142190, Moscow Region, Russia
[Petit, P. O.
Viana, B.] Ecole Natl Super Chim Paris 11, Lab Chim Mat Condensee Paris, CNRS UMR 7574, F-75005 Paris, France
[Bezmaternykh, L. N.] RAS, Kirenskii Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Institute of Spectroscopy, Russian Academy of Sciences, 5 Fizicheskaya street, Troitsk, Moscow region 142190, Russian Federation
Laboratoire de Chimie de la Matiere Condensee de Paris, CNRS-UMR 7574, Ecole Nationale Superieure de Chimie de Paris 11, rue Pierre et Marie Curie, F-75005 Paris, France
Kirenskii Institute of Physics, Siberian Branch, RAS, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Popova, M. N.; Boldyrev, K. N.; Petit, P. O.; Viana, B.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
}
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8.


   
    High-resolution spectroscopy, crystal-field calculations, and quadrupole helix chirality of DyFe3(BO3)(4) / M. N. Popova [et al.] ; ed. E. A. Vinogradov [et al.] // XXV Congress on Spectroscopy. - 2017. - Vol. 132. - Ст. 03041. - (EPJ Web of Conferences), DOI 10.1051/epjconf/201713203041. - Cited References:2 . - ISSN 2100-014X
РУБ Spectroscopy

Аннотация: High-resolution polarized transmission spectra of DyFe3(BO3)(4) single crystals were investigated in broad spectral (10-23000 cm(-1)) and temperature (3.5-300 K) ranges. Energies of the dysprosium levels in the paramagnetic and antiferromagnetic phases were determined. On the basis of these data and preliminary calculations in the frameworks of the exchange-charge model, we determined the crystal-field and Dy-Fe exchange interaction parameters of the Dy3+ ions at sites with the point C-2 symmetry corresponding to the enantiomorphic P3(1)21 and P3(2)21 space groups. The values of electronic quadrupole moments of the Dy3+ ions were calculated, which enabled us to interpret results of the work [Usui et al., Nature Mater. 13, 611 (2014)] on the observation of domains of different quadrupole chirality in DyFe3(BO3)(4).

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Доп.точки доступа:
Popova, M. N.; Попова, Марина Николаевна; Malkin, B. Z.; Stanislavchuk, T. N.; Chukalina, E. P.; Boldyrev, K. N.; Болдырев, Кирилл Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Vinogradov, E.A. \ed.\; Naumov, A.V. \ed.\; Gladush, M.G. \ed.\; Karimullin, K.R. \ed.\; Congress on Spectroscopy(25 ; 2016 ; Oct ; 03-07 ; Troitsk)
}
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9.


   
    Higt-resolution spectroscopy of Yb3+ centers in RAl3(BO3)4:Yb single crystals / K. N. Boldyrev, M. N. Popova [et al.] // Excit. St. of Trans. Elem. and Worksh. on Luminesc.: ESTE2010 : book of abstracts. - Wrocław : Wydział Chemii Uniwersytetu Wrocławskiego, 2010. - Ст. Tu-7

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Доп.точки доступа:
Boldyrev, K.N.; Popova, M. N.; Попова, Марина Николаевна; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Bettinelli, M.; Loiseau, P.; Leonyuk, N. I.; Excited States of Transition Elements and Workshop on Luminescence(2010 ; Sept. ; 04-09 ; Wrocław & Piechowice, Poland)
}
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10.


   
    Investigation of manganese-doped copper metaborate Cu1-xMnxB2O4 by linear antiferromagnetic dichroism / A. D. Molchanova [et al.] // Магнитные материалы. Новые технологии : тез. докл. VII Байкал. Междунар. конф. / Иркутский гос. ун-т. - Иркутск, 2016. - P. 166. - Библиогр.: 4 назв. - This work was supported by the Russian Foundation for Basic Research (Grant No 15-02-07451a) and the President of the Russian Federation (Grant No MK-3521-2015.2) . - ISBN 978-591-345-152-1. - ISBN 978-591-345-152-1

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Доп.точки доступа:
Исхаков, Рауф Садыкович \чл. прогр. ком.\; Iskhakov, R. S.; Аплеснин, Сергей Степанович \чл. прогр. ком.\; Aplesnin, S. S.; Овчинников, Сергей Геннадьевич \чл. прогр. ком.\; Ovchinnikov, S. G.; Molchanova, A. D.; Boldyrev, K. N.; Болдырев, Кирилл Николаевич; Moshkina, E. M.; Мошкина, Евгения Михайловна; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; "Магнитные материалы. Новые технологии", Байкальская международная конференция(7 ; 2016 ; авг. ; 22-26 ; Листвянка, пос. (Иркутская обл.)); "Magnetic materials. New tecnologies", Baikal International Conference(7 ; 2016 ; Aug. ; 22-26 ; Listvyanka, Irkutsk region); Байкальская международная конференция "Магнитные материалы. Новые технологии"(7 ; 2016 ; авг. ; 22-26 ; п. Листвянка, Иркутская обл.); Иркутский государственный университет
}
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11.


   
    Lattice dynamics of piezoelectric copper metaborate CuB2O4 / R. V. Pisarev [et al.] // Phys. Rev. B. - 2013. - Vol. 88, Is. 2. - Ст. 024301. - P. DOI 10.1103/PhysRevB.88.024301
   Перевод заглавия: Динамика решетки пьезоэлектрического медного метабората CuB2O4
Аннотация: Tetragonal piezoelectric copper metaborate CuB2O4 (space group I4̅ 2d, Z=12) became a subject of active research during the last decade because it demonstrates unique magnetic, optical, and magnetooptical properties. We report results of the optical studies of polarized infrared reflection and transmission spectra and Raman back-scattering spectra in the range from 20 to 2500 cm−1. In accordance with the symmetry analysis, infrared studies allowed us to identify all polar B2(z), and E(x,y) normal vibrational modes. Frequencies of all longitudinal (LO) and transverse (TO) optical phonons were determined by fitting the observed infrared reflection spectra. Raman measurements revealed the frequencies of the majority of nonpolar A1(xx,yy,zz) and B1(xx,yy) modes and polar B2(z) and E(x,y) LO modes. We show that several groups of closely spaced spectral lines observed in the vibrational spectra of CuB2O4 can be considered as a result of the Davydov splitting, which takes place in the case of several equivalent molecular units in a primitive crystal cell. Multiphonon absorption in the range of 1200–2500 cm−1 was analyzed and a tentative assignment of some features was given. Ab initio calculations of all zone-center polar and nonpolar modes were performed using density functional theory (DFT). The computed frequency distribution is in a good agreement with observed line positions in the infrared and Raman spectra. All these results allowed us to suggest reliable identification of all zone-center phonon modes thus providing a firm basis for further experimental and theoretical studies of this material with complex crystal, magnetic, and electronic structures and fascinating physical properties.
Тетрагональный пьезоэлектрический медный метаборат CuB2O4 (пространственная группа I-42d, Z = 12) стал предметом активных исследование в течение прошлого десятилетия, потому что демонстрирует уникальные магнитные, оптические, и магнитооптические свойства. Мы сообщаем о результатах оптических исследований спектров поляризованного инфракрасного отражения и пропускания и Рамановских спектров обратного рассеяния в диапазоне от 20 до 2500 cm−1. В соответствии с анализом симметрии, инфракрасные исследования позволили нам идентифицировать все полярные B2 (z), и E (x, y) нормальные вибрационные моды. Частоты всех продольных (LO) и поперечных (К) оптических фононов были определены подгонкой наблюдаемых инфракрасных спектров отражения. Рамановские измерения показали частоты большинства неполярного A1 (xx, yy, zz) andB1 (xx, yy) мод и полярных B2(z)andE (x, y) LO мод. Мы показали, что несколько групп близко расположенных спектральных линий, наблюдаемых в вибрационные спектры CuB2O4, могут быть результатом расщепления Давыдова, которое имеет место в случай нескольких эквивалентных молекулярных единиц в примитивной кристаллической ячейке. Поглощения мультифонона в диапазоне 1200–2500 cm−1 были проанализированы, и предварительное предположения для некоторых особенностей было дано. Изначальные вычисления всех центрозональных полярных и неполярных мод был выполнены, используя теорию плотности функций (DFT). Вычисленное распределение плотности находится в хорошем согласии с наблюдаемыми положениями линий в Рамановском и инфракрасном спектрах. Все эти результаты позволили нам предложить надежную идентификацию всех мод центрозонального фонона, таким образом обеспечивая надежное основание для дальнейших экспериментальных и теоретических исследований этого материала со сложными кристаллической, магнитной и электронной структурами и захватывающими физическими свойствами.

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Держатели документа:
Russian Acad Sci, AF Ioffe Phys Tech Inst, St Petersburg 194021, Russia
Russian Acad Sci, Inst Spect, Troitsk 142190, Russia
Russian Acad Sci, Siberian Branch, Inst Phys, Krasnoyarsk 660036, Russia
St Petersburg State Univ, Dept Phys, St Petersburg 199034, Russia
Joint Inst Nucl Res, Dubna 141980, Russia

Доп.точки доступа:
Pisarev, R. V.; Писарев, Роман Васильевич; Boldyrev, K. N.; Болдырев, Кирилл Николаевич; Popova, M. N.; Попова, Марина Николаевна; Smirnov, A. N.; Смирнов А. Н.; Davydov, V. Yu.; Давыдов В. Ю.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Smirnov, M. B.; Смирнов М. Б.; Kazimirov, V.Yu.; Казимиров В. Ю.
}
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12.


   
    Magnetic and magnetoelastic properties of TmAl3(BO3)4 [Текст] / A. I. Begunov [et al.] // Moscow int. Symp. on Magnet. (MISM-2014) : Book of abstracts. - 2014. - Ст. 30PO-M-18. - P. 275 . - ISBN 978-5-91978-025-0

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Доп.точки доступа:
Begunov, A. I.; Demidov, A. A.; Volkov, D. V.; Волков, Д. В.; Gudim, I. A.; Гудим, Ирина Анатольевна; Eremin, E. V.; Еремин, Евгений Владимирович; Boldyrev, K. N.; Moscow International Symposium on Magnetism(6 ; 2014 ; 29 June-3 July ; Moscow); Московский государственный университет им. М.В. Ломоносова
}
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13.


   
    Magnetic and structural features of multiferroic EuFe3(BO3)4: Spectroscopic studies / K. N. Boldyrev [et al.] // 20th Int. Сonf. on Magnetism (ICM-2015) : book of abstracts. - 2015. - Ст. TU.A-P87. - P. 1203

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Доп.точки доступа:
Boldyrev, K. N.; Болдырев, Кирилл Николаевич; Popova, M. N.; Попова, Марина Николаевна; Erofeev, D. A.; Ерофеев Д. А.; Stanislavchuk, T. N.; Malkin, B. Z.; Малкин Б. З.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; International Conference on Magnetism(20 ; 2015 ; Jul ; 5-10 ; Barselona, Spain)
}
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14.


   
    Magnetic phase transitions and linear magnetic dichroism in manganese-doped copper metaborate (Cu,Mn)B2O4 / A. D. Molchanova [et al.] // J. of Phys.: Conf. Ser. : IOP, 2017. - Vol. 917. - Ст. 072003DOI 10.1088/1742-6596/917/7/072003. - Cited References: 10. - This work was supported by the Russian Foundation for Basic Research (Grant No 15-02-07451a) and the President of the Russian Federation (Grant МК-3577.2017.2)
   Перевод заглавия: Магнитные фазовые переходы и линейный магнитный дихроизм в допированном марганцем метаборате меди (Cu,Mn)B2O4
Аннотация: The work presents a study of manganese-doped copper metaborate (Cu,Mn)B2O4 using optical spectroscopy. The temperature of the antiferromagnetic phase transition TN = 19 K has been defined according to the absorption spectra. Polarization studies (Cu,Mn)B2O4 in isotropic ab-plane show the presence of linear antiferromagnetic dichroism in the magnetically ordered state previously observed in pure copper metaborate CuB2O4.This measurement allows to find the magnetic phase transition into an elliptical structure at the temperature T* = 7.0 K.

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Доп.точки доступа:
Molchanova, A. D.; Boldyrev, K. N.; Erofeev, A. S.; Moshkina, E. M.; Мошкина, Евгения Михайловна; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; International School and Conference on Optoelectronics, Photonics, Engineering and Nanostructures(4 ; 2017 ; 3-6 Apr. ; Saint Petersburg)
}
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15.


   
    Magnetic structure of ErFe3(BO3)4: Spectroscopic and thermodynamic studies / E. A. Popova, E. P. Chukalina, K. N. Boldyrev [et al.] // J. Magn. Magn. Mater. - 2020. - Vol. 500. - Ст. 166374, DOI 10.1016/j.jmmm.2019.166374. - Cited References: 14. - E.P.Ch., and K.N.B. acknowledge a financial support of the Russian Science Foundation under Grant # 19-12-00413. The calculational part of the article was prepared by . E.A.P. within the framework of the Academic Fund Program at the National Research University Higher School of Economics (HSE University) in 2019 (grant №19-04-030) and by the Russian Academic Excellence Project «5-100» . - ISSN 0304-8853
Кл.слова (ненормированные):
Erbium iron borate -- High-resolution optical spectroscopy -- Modeling of magnetic properties
Аннотация: We report on the high-resolution spectroscopic study of multiferroic ErFe3(BO3)4. The energies of all eight Kramers doublets of the ground 4I15/2 multiplet of the Er3+ ion were determined by the high-resolution 4I13/2 → 4I15/2 infrared luminescence spectra. The spectroscopically determined temperature dependence of the splitting of the ground Kramers doublet was used to calculate the contribution of the erbium subsystem into the specific heat and the magnetic susceptibility of erbium iron borate. The analysis of the thermodynamic properties based on these calculations allowed us to suggest the domain structure in the easy-plane antiferromagnetically ordered iron subsystem, with two magnetically nonequivalent erbium positions in each domain.

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Держатели документа:
National Research University Higher School of Economics, Moscow, 101000, Russian Federation
Institute of Spectroscopy, Russian Academy of Sciences, Troitsk, Moscow, 108840, Russian Federation
Moscow Institute of Physics and Technology (National Research University), Dolgoprudnyi, 141701, Russian Federation
Kirenskiy Institute of Physics, Siberian Branch of RAS, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Popova, E. A.; Chukalina, E. P.; Boldyrev, K. N.; Jablunovskis, A.; Gudim, I. A.; Гудим, Ирина Анатольевна
}
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16.


   
    Magnetic, magnetoelastic, and spectroscopic properties of TmAl3(BO3)4 / A. A. Demidov [et al.] // J. Exp. Theor. Phys. - 2014. - Vol. 119, Is. 4. - P. 737-744, DOI 10.1134/S106377611410015X. - Cited References: 28. - This study was supported financially by the Russian Foundation for Basic Research (project no. 13-02-12442ofi_m2) and (K.N.B.) by the grant no. MK-1700.2013.2 from the President of the Russian Federation. . - ISSN 1063-7761. - ISSN 1090-6509
РУБ Physics, Multidisciplinary
Рубрики:
THERMAL-EXPANSION
   CRYSTALS

   MAGNETOSTRICTION

   HoAl3(BO3)4

   GARNETS

Аннотация: The thermodynamic properties of alumoborate TmAl3(BO3)4 single crystal are studied experimentally and theoretically. A theoretical analysis based on the crystal field model makes it possible to interpret all measured parameters. The crystal field parameters are determined. The temperature (3–300 K) and field (up to 9 T) dependences of magnetization are described. The field and temperature dependences of multipole moments of the Tm3+ ion in TmAl3(BO3)4 make it possible to describe magnetostriction and low-temperature anomalies in thermal expansion.

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Публикация на русском языке Магнитные, магнитоупругие и спектроскопические свойства TmAl3(BO3)4 [Текст] / А. А. Демидов [и др.] // Журн. эксперим. и теор. физ. : Наука, 2014. - Т. 146 Вып. 4. - С. 835-843

Держатели документа:
Bryansk State Tech Univ, Bryansk 241035, Russia
Moscow MV Lomonosov State Univ, Moscow 119992, Russia
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
Russian Acad Sci, Inst Spect, Moscow 142190, Russia

Доп.точки доступа:
Demidov, A. A.; Volkov, D. V.; Gudim, I. A.; Гудим, Ирина Анатольевна; Eremin, E. V.; Еремин, Евгений Владимирович; Boldyrev, K. N.; Russian Foundation for Basic Research [13-02-12442ofi_m2]; Russian Federation [MK-1700.2013.2]
}
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17.


   
    Magnetization, magnetoelectric polarization, and specific heat of HoGa3(BO3)4 / N. V. Volkov [et al.] // JETP Letters. - 2014. - Vol. 99, Is. 2. - P. 67-75, DOI 10.1134/S0021364014020106. - Cited References: 28. - This work was supported by the Russian Foundation for Basic Research (project no. 13-02-12442-ofi_m2). K.N.B. also acknowledges the support from the Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools (project no. MK-1700.2013.2). . - ISSN 0021-3640. - ISSN 1090-6487
РУБ Physics, Multidisciplinary
Рубрики:
HoAl3(BO3)4
Аннотация: A comprehensive experimental and theoretical study of magnetic, magnetoelectric, thermal, and spectroscopic characteristics of HoGa3(BO3)4 gallium borate single crystals has been performed. A large magnetoelectric effect exceeding its values found in all iron and aluminum borates except HoAl3(BO3)4 has been observed. The magnetoelectric polarization of HoGa3(BO3)4 equals ΔP ba (B a ) ≈ −1020 μC/m2 at T = 5 K in a magnetic field of 9 T. The theoretical treatment based on the crystal field model for rare-earth ions provides a unified approach for the consistent interpretation of all measured characteristics. The crystal-field parameters are determined. The temperature (in the 3–300 K range) and magnetic field (up to 9 T) dependences of the magnetization, the Schottky anomaly in the temperature dependence of the specific heat, and its shift in the field B || c are described. To compare the thermal properties of HoGa3(BO3)4 with those of HoAl3(BO3)4 exhibiting record values of the polarization, the specific heat of HoAl3(BO3)4 at various B values and the temperature dependence of the polarization ΔP b (T) in the applied magnetic field of 9 T have been measured.

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Публикация на русском языке Намагниченность, магнитоэлектрическая поляризация и теплоемкость HoGa3(BO3)4 [Текст] / Н. В. Волков [и др.] // Письма в Журн. эксперим. и теор. физ. : Наука, 2014. - Т. 99 Вып. 1-2. - С. 72-80

Держатели документа:
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Bryansk State Tech Univ, Bryansk 241035, Russia
Russian Acad Sci, Inst Spect, Troitsk 142190, Moscow Region, Russia

Доп.точки доступа:
Volkov, N. V.; Волков, Никита Валентинович; Gudim, I. A.; Гудим, Ирина Анатольевна; Eremin, E. V.; Еремин, Евгений Владимирович; Begunov, A. I.; Demidov, A. A.; Boldyrev, K. N.; Russian Foundation for Basic Research [13-02-12442-ofi_m2]; Council of the Russian Federation for Support of Young Scientists and Leading Scientific Schools [MK-1700.2013.2]
}
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18.


   
    Multifunctional RFe3(BO3)4 materials: Quality control / K. N. Boldyrev [et al.] ; ed. V. V. Samartsev [et al.] // EPJ Web of Conf. - 2015. - Vol. 103. - Ст. 09001, DOI 10.1051/epjconf/201510309001. - Cited References: 3. - This work was supported by the Russian Science Foundation (Grant № 14-12-01033) . - ISSN 2100-014X
РУБ Optics of Crystals + Optical Materials


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Доп.точки доступа:
Samartsev, V. V. \ed.\; Vinogradov, E.A. \ed.\; Naumov, A.V. \ed.\; Karimullin, K.R. \ed.\; Boldyrev, K. N.; Popova, M. N.; Molchanova, A. D.; Stanislavchuk, T. N.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; International Workshop on Quantum Optics(12th ; Moscow)(Aug 11-16, 2015)
}
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19.


   
    Optical linear dichroism in the ab-plane of NdFe3(BO3)4 ferroborate / K. N. Boldyrev, M. Diab, I. A. Gudim, M. N. Popova // J. Exp. Theor. Phys. - 2023. - Vol. 137, Is. 4 : Special Issue dedicated to the 95th Anniversary of L. A. Prozorova. - P. 486-491, DOI 10.1134/S1063776123100011. - Cited References: 16. - This study was supported by the Ministry of Science and Higher Education (project no. FFUU-2022-0003) and partially (K.N. B., dichroism measurements) by the Russian Science Foundation (grant no. 19-72-10132P) . - ISSN 1063-7761. - ISSN 1090-6509
Аннотация: The high-resolution optical absorption spectra of NdFe3(BO3)4 single crystals have been recorded at temperatures from 4 to 40 K in the IR range of f–f transitions in a Nd3+ ion. Light linearly polarized at different angles to the C2 axes in the basal plane has been passed along the trigonal C3 axis. Below the temperature of magnetic moment ordering into a collinear antiferromagnetic structure (TN ≈ 30 K), dichroism, that is, the absorption versus polarization dependence, arises. The temperature and angular dependences of dichroism indicate that the magnetic moments of iron are directed along the C2 axes up to about 17 K, the number of domains with variously directed C2 axes being different. The mechanism of linear dichroism has been discussed. Below 17 K, a smooth transition to the helicoidal magnetic phase has been observed, with the collinear phase coexisting with the helicoidal one. Data presented in this article contradict the earlier concept of magnetic moments fluctuating in the low-temperature phase near the C2 axis within the ±10° interval.

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Публикация на русском языке Оптический линейный дихроизм в ab-плоскости ферробората NdFe3(BO3)4 [Текст] / К. Н. Болдырев, М. Диаб, И. А. Гудим, М. Н. Попова. - 6 с. // Журн. эксперим. и теор. физ. - 2023. - Т. 164 Вып. 4 : Специальный выпуск, посвященный 95-летию Л. А. Прозоровой. - С. 563-568

Держатели документа:
Institute of Spectroscopy, Russian Academy of Sciences, 108840, Troitsk, Moscow, Russia
Moscow Institute of Physics and Technology (State University), 141700, Dolgoprudnyi, Moscow oblast, Russia
Kirenskii Institute of Physics, Siberian Branch, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia

Доп.точки доступа:
Boldyrev, K. N.; Diab, M.; Gudim, I. A.; Гудим, Ирина Анатольевна; Popova, M. N.
}
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20.


   
    Pronounced coupling of 3D-excitons with magnetic phase transitions in CuB2O4 [Текст] / K. N. Boldyrev [et al.] // Moscow int. Symp. on Magnet. (MISM-2014) : Book of abstracts. - 2014. - Ст. 2OR-H-4. - P. 697 . - ISBN 978-5-91978-025-0

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Доп.точки доступа:
Boldyrev, K. N.; Popova, M. N.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Pisarev, R. V.; Moscow International Symposium on Magnetism(6 ; 2014 ; 29 June-3 July ; Moscow); Московский государственный университет им. М.В. Ломоносова
}
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