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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sukhinin Y. V.
Заглавие : Phase transitions in self-assembled monolayers of alkanethiols containing the polar group
Место публикации : J. Exp. Theor. Phys.: AMER INST PHYSICS, 1998. - Vol. 87, Is. 1. - P115-122. - ISSN 1063-7761, DOI 10.1134/1.558645
Примечания : Cited References: 38
Предметные рубрики: ORGANIZED MOLECULAR ASSEMBLIES
ALKYL THIOL MONOLAYERS
STRUCTURAL CHARACTERIZATION
DYNAMICS SIMULATION
LANGMUIR MONOLAYER
SURFACES
GOLD
FILMS
AU(111)
MODEL
Аннотация: Equilibrium states of the system of self-assembled monolayers (SAMs) of n-alkanethiol molecules HS(CH2)(n-1)(X) with polar group X chemiabsorbed on the Au(111) crystal surface are considered. The couplings between the atoms (C, H) of the n-alkanethiols are approximated by the Lennard-Jones potential. The couplings between the n-alkanethiols and the crystal surface are approximated by the 12-3 potential. The interactions of polar groups and the self-images with the metal substrate are taken into consideration. The phase-transition temperatures, the structural order and equilibrium tilt, and the twist and azimuthal angles of the macromolecules, which depend on the dipole moments, are found. (C) 1998 American Institute of Physics.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sukhinin Y. V.
Заглавие : Ising-like model of tilted phase transitions in Langmuir monolayers
Место публикации : Phys. Rev. B: AMERICAN PHYSICAL SOC, 2006. - Vol. 74, Is. 19. - Ст.195423. - ISSN 1098-0121, DOI 10.1103/PhysRevB.74.195423
Примечания : Cited References: 27
Предметные рубрики: MONTE-CARLO-SIMULATION
FATTY-ACID MONOLAYERS
AIR-WATER-INTERFACE
AMPHIPHILE MONOLAYERS
ROTATOR PHASES
ALKANES
DIAGRAM
POTENTIALS
ORDER
Аннотация: Two Ising models on a rectangular lattice (sigma(1) model and sigma(2) model) linked to three- and four-spin interactions are used to describe the sequence of tilted phase transitions in monolayers of amphiphilic long-chain molecules on an air-water surface. Starting from Morse atom-atom potentials self-consistent equations for basic thermal averages are derived in terms of a mean-field approximation. We employ the model for CH3(CH2)(18)COOH at two values of the molecule density and obtain all known tilted phases, including an intermediate one.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : SADREEV A. F., SUKHININ Y. V.
Заглавие : UNUSUAL GAUGE PROPERTIES OF THE LOW-TEMPERATURE PHASE OF PARAMAGNETIC SYSTEMS COUPLED WITH A RADIATION-FIELD
Место публикации : Phys. Lett. A: ELSEVIER SCIENCE BV, 1986. - Vol. 113, Is. 9. - P485-488. - ISSN 0375-9601, DOI 10.1016/0375-9601(86)90126-X
Примечания : Cited References: 12
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sadreev A. F., Sukhinin Y. V.
Заглавие : Phase transitions in a system of CH3(CH2)(n-1) self-assembled on the Au(111) crystal surface
Место публикации : Phys. Rev. B: AMERICAN PHYSICAL SOC, 1996. - Vol. 54, Is. 24. - P17966-17973. - ISSN 1098-0121, DOI 10.1103/PhysRevB.54.17966
Примечания : Cited References: 44
Предметные рубрики: ORGANIZED MOLECULAR ASSEMBLIES
ALKYL THIOL MONOLAYERS
STRUCTURAL CHARACTERIZATION
DYNAMICS SIMULATION
DEVILS STAIRCASE
GOLD SURFACES
FILMS
MODEL
CHAIN
DIFFRACTION
Аннотация: The n-alkanethiols CH3(CH2)(n-1) on the crystal surface of gold (111) are considered. Couplings between atoms (C, H) of the n-alkanethiols were modelled by the Morse potential, and couplings between the n-alkanethiols and the crystal surface were modelled by 12-3 potentials. Because of symmetry Z(2) of the n-alkanethiols in a tilted state, the system can be reduced to the Ising model on the triangular lattice, the phase diagram of which can be explicitly considered. Depending on the choice of the coupling parameters, the ordered state of the system may form an incommensurate or 2X1 superstructure. The temperatures of the phase transition, equilibrium tilting, twisting, and azimuthal angles are found to depend on the Morse coupling constants.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sadreev A. F., Sukhinin Y. V.
Заглавие : The microscopic theory of phase-transitions in nano2
Место публикации : Zhurnal Eksperimentalnoi Teor. Fiz. - 1991. - Vol. 100, Is. 6. - P.1999-2013. - ISSN 0044-4510
Примечания : Cited References: 29
Предметные рубрики: INCOMMENSURATE PHASE
Аннотация: The energy levels and eigen wavefunctions of nitrite groups (NG) in the crystal potential of NaNO2 are found and the four-dimensional representation of the Hubbard operators for NG is constructed. The Born-Mayer and dipole-dipole interactions between NG are projected into the Hubbard operator representation and the hamiltonian of the system is formulated with the involvement of NG coupling with the translational degrees of freedom. The quantitative temperature - pressure phase diagram of crystal is obtained. The dependence of the incommensurate phase wave vector on temperature, pressure, and NG dipole moment is found as well.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : SADREYEV A. F., SUKHININ Y. V.
Заглавие : MICROSCOPIC THEORY OF SUCCESSIVE PHASE-TRANSITIONS IN ALKALI-METAL CYANIDES
Место публикации : Zhurnal Eksperimentalnoi Teor. Fiz.: MEZHDUNARODNAYA KNIGA, 1990. - Vol. 97, Is. 1. - P283-301. - ISSN 0044-4510
Примечания : Cited References: 42
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : SADREEV A. F., SUKHININ Y. V.
Заглавие : DIPOLE-DIPOLE INTERACTION EFFECT ON RADIATION-FIELD CONDENSATION IN PARAMAGNETIC CRYSTAL-RESONATORS
Место публикации : Fiz. Tverd. Tela: MEZHDUNARODNAYA KNIGA, 1984. - Vol. 26, Is. 9. - P2808-2814. - ISSN 0367-3294
Примечания : Cited References: 13
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