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    A comparative study of γ-Fe2O3 and ε-Fe2O3 nanoparticles arising in borate glasses doped with Fe and Gd / O. S. Ivanova [et al.] // J. Sib. Fed. Univ. Math. Phys. - 2016. - Vol. 9, Is. 4. - P. 459–462 ; Журн. СФУ. Сер. "Математика и физика", DOI 10.17516/1997-1397-2016-9-4-459-462. - Cited References: 6. - The work was supported partly by the RFBR, 14-02-01211-a, and by the President of Russia Grant NSh-7559.2016.2. . - ISSN 1997-1397
   Перевод заглавия: Сравнительное изучение γ-Fe2O3 и ϵ-Fe2O3 наночастиц, формирующихся в стекле, допированном железом и гадолинием
Кл.слова (ненормированные):
magnetic nanoparticles -- magnetic circular dichroism -- magnetic measurements -- магнитные наночастицы -- магнитный круговой дихроизм -- магнитные измерения
Аннотация: Formation and properties of the iron oxides γ -Fe2O3 and ϵ-Fe2O3 nanoparticles arising in glasses of basic compositions Ge2O-K2O-Al2O3-B2O3 and K2O-Al2O3-B2O3 doped with different concentrations of Fe2O3 and Gd2O3 and subjected to the additional thermal treatment are studied. The X-ray diffraction, TEM microscopy, magnetooptical effects, and electron spin resonance study allow elucidating the matrix and Gd role in determining the nanoparticle properties.
Изучены свойства наночастиц γ-Fe2O3 и ϵ-Fe2O3, формирующихся в стеклах основного состава Ge2O-K2O-Al2O3-B2O3 и K2O-Al2O3-B2O3, допированных Fe2O3 и Gd2O3 и подвергнутых дополни- тельной термической обработке. Результаты исследования рентгеновской дифракции, электрон- ной микроскопии, магнитооптических эффектов и электронного спинового резонанса позволили объяснить роль матрицы и гадолиния в определении свойств наночастиц.

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Доп.точки доступа:
Ivanova, O. S.; Иванова, Оксана Станиславовна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Edelman, I. S.; Эдельман, Ирина Самсоновна; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна

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A comparative study of γ-Fe2O3 and ε-Fe2O3 nanoparticles arising in borate glasses doped with Fe and Gd / O. S. Ivanova [et al.] // VI Euro-Asian Symposium "Trends in MAGnetism" (EASTMAG-2016) : abstracts / ed.: O. A. Maksimova, R. D. Ivantsov. - Krasnoyarsk : KIP RAS SB, 2016. - Ст. P9.11. - P. 397. - References: 1. - The work was supported partly by the RFBR grant No. 14-02-01211 . - ISBN 978-5-904603-06-9
Кл.слова (ненормированные):
magnetic nanoparticles -- magnetic circular dichroism -- magnetic measurements

Доп.точки доступа:
Ivanova, O. S.; Иванова, Оксана Станиславовна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Edelman, I. S.; Эдельман, Ирина Самсоновна; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна; Euro-Asian Symposium "Trends in MAGnetism"(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); "Trends in MAGnetism", Euro-Asian Symposium(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); Институт физики им. Л.В. Киренского Сибирского отделения РАН

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Actual composition and structure of manganese ferrite nanoparticles dispersed in the borate glass matrix / I. G. Vasilyeva [et al.] // Doklady Chemistry. - 2005. - Vol. 401, Is. 1-3. - P. 47-50, DOI 10.1007/s10631-005-0029-y . - ISSN 0012-5008
Кл.слова (ненормированные):
boric acid -- ferrite -- glass -- manganese derivative -- analytic method -- article -- chemical composition -- chemical structure -- nanoparticle -- stoichiometry -- structure analysis -- transmission electron microscopy -- X ray analysis

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Публикация на русском языке Реальный состав и структура наночастиц феррита марганца, диспергированных в матрице боратных стекол [Текст] / И. Г. Васильева [и др.] // Доклады Академии наук. - 2005. - Т. 401 № 3. - С. 349-352

Держатели документа:
Nikolaev Inst. of Inorg. Chemistry, Siberian Division, Russian Academy of Sciences, pr. akademika Lavrent'eva 3, Novosibirsk, 630090, Russian Federation
Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. akademika Lavrent'eva 5, Novosibirsk, 630090, Russian Federation
Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
All-Russia Research Center, Vavilov State Optical Institute, ul. Babushkina 36/1, St. Petersburg, 192371, Russian Federation

Доп.точки доступа:
Vasilyeva, I. G.; Dovlitova, L. S.; Zaikovskii, V. I.; Malakhov, V. V.; Edel'man, I. S.; Эдельман, Ирина Самсоновна; Stepanov, A. S.; Aleksandrov, K. S.; Александров, Кирилл Сергеевич
}
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Analysis of the electrical and optical properties of VBO3 single crystals and Fe1-xVxBO3 solid solutions on the basis of a many-electron model of energy band structure / N. B. Ivanova [et al.] // Phys. Solid State. - 2004. - Vol. 46, Is. 8. - P. 1462-1468, DOI 10.1134/1.1788779. - Cited References: 32. - One of the authors (M.M.A.) would like to thank the Deutsche Forschungsgemeinschaft (SFB608) for financial support. This study was supported by the Russian Foundation for Basic Research (project no. 03-02-16286), the program "Integration" (project no. B0017), and the program of the Division of Physical Sciences of the Russian Academy of Sciences "Strongly Correlated Electrons" . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
MAGNETIC-PROPERTIES
   CALCITE STRUCTURE
   PHASE-TRANSITION
   FERRIC BORATE
   HIGH-PRESSURE
   FEBO3
   FE1-XCRXBO3
   FERROMAGNET
   MOSSBAUER
   SPECTRA
Аннотация: A many-electron model of the energy band structure of VBO3 and of Fe1 - xVxBO3 solid solutions is proposed with strong electron correlations taken into account. Experimental optical absorption spectra and data on the resistivity are discussed in the framework of the suggested model. Variation in the magnetic and electronic properties of VBO3 and Fe1 - xVxBO3 under high pressure is predicted. For VBO3, a Mott-Hubbard (insulator-metal) transition is expected in the high-pressure phase. In Fe1 - xVxBO3 solid solutions, a nontrivial variation in the properties is predicted, leading to the appearance of a different magnetic state. (C) 2004 MAIK "Nauka / Interperiodica".

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Публикация на русском языке Анализ электрических и оптических свойств монокристаллов VBO[3] и твердых растворов Fe[1-x]V[x]BO[3] на основе многоэлектронной модели из зонной структуры [Текст] / Н. Б. Иванова [и др.] // Физ. тверд. тела. - 2004. - Т. 46 Вып. 8. - С. 1422-1427

Держатели документа:
Krasnoyarsk State Tech Univ, Krasnoyarsk 660074, Russia
Russian Acad Sci, Siberian Div, Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Univ Cologne, Inst Phys 2, D-50937 Cologne, Germany
ИФ СО РАН
Krasnoyarsk State Tech. University, Krasnoyarsk, 660074, Russian Federation
II. Physikalisches Institut, Universitat zu Koln, Koln, 50937, Germany

Доп.точки доступа:
Ivanova, N. B.; Иванова, Наталья Борисовна; Kazak, N. V.; Казак, Наталья Валерьевна; Markov, V. V.; Марков, Владимир Витальевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Rudenko, V. V.; Руденко, Валерий Васильевич; Abd-Elmeguid, M. M.
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    Anisotropy of the electromechanical characteristics of SH-waves and Lamb waves in yttrium aluminum borate single crystals / P. P. Turchin, S. I. Burkov, V. I. Turchin [et al.] // J. Sib. Fed. Univ. Math. Phys. - 2022. - Vol. 15, Is. 1. - P. 80-87 ; Журн. СФУ. Матем. и физика, DOI 10.17516/1997-1397-2022-15-1-80-87. - Cited References: 24. - The study was carried out within the framework of the state assignment of the Ministry of Science and Higher Education of the Russian Federation (research project code FSRZ-2020-0011) . - ISSN 1997-1397. - ISSN 2313-6022
   Перевод заглавия: Анизотропия и электромеханические характеристики SH-волн и волн Лэмба в монокристаллах иттриевого алюмобората

РУБ Mathematics

Кл.слова (ненормированные):
surface acoustic, SH and Lamb waves -- piezoelectrics -- multiferroics -- yttrium aluminum borates -- поверхностные акустические, SH- и Лэмба волны -- пьезоэлектрики -- мультиферроики -- алюмоборат иттрия
Аннотация: The anisotropy of the electromechanical properties of SH-waves and Lamb waves in yttrium aluminum borates, which are nonmagnetic representatives of the RMe3(BO3)4 single crystals family (where R=Y, La-Lu; M=Fe, Al, Cr, Ga, Sc) with unique properties of magnetoelectrics and multiferroics, has been studied. In the process of the numerical simulation of the acoustic waves characteristics, the values of linear electromechanical constants of YAl3(BO3)4 single crystals, previously measured by ultrasonic pulse echo and quasi-static methods, have been used.
Исследована анизотропия электромеханичеких характеристик SH-волн и волн Лэмба в иттриевых алюмоборатах, которые являются немагнитным представителем семейства монокри- сталлов RMe3(BO3)4 (где R=Y, La-Lu; M=Fe, Al, Cr, Ga, Sc) с уникальными свойствами магнитоэлектриков и мультиферроиков. При численном моделировании характеристик акустических волн использованы значения линейных электромеханических постоянных монокристаллов YAl3(BO3)4, измеренных ранее ультразвуковым эхо-импульсным и квазистатическим методами.

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Держатели документа:
Siberian Fed Univ, Krasnoyarsk, Russia.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk, Russia.

Доп.точки доступа:
Turchin, Pavel P.; Турчин, Павел Петрович; Burkov, S. I.; Turchin, Vladimir, I; Pletnev, Oleg N.; Chulkova, Marina Yu; Nechepuryshina, Anastasia G.; Ministry of Science and Higher Education of the Russian Federation [FSRZ-2020-0011]

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Antiferromagnetic resonance and magnetic anisotropy in single crystals of the YFe3(BO3)(4)-GdFe3(BO3)(4) system / A. I. Pankrats [et al.] // Phys. Solid State. - 2008. - Vol. 50, Is. 1. - P. 79-83, DOI 10.1134/S1063783408010150. - Cited References: 16 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
IRON BORATE GDFE3(BO3)(4)
ND3+
Аннотация: The antiferromagnetic resonance in single crystals of the YFe3(BO3)(4)-GdFe3(BO3)(4) system is studied in the frequency range 25-140 GHz and the temperature range 4.2-50.0 K. It is established that the YFe3(BO3)(4) crystal containing only the magnetic subsystem of Fe3+ ions is an antiferromagnet with an easy anisotropy plane. The temperature dependences of the gaps in the antiferromagnetic resonance spectra of GdFe3(BO3)(4) and YxGd1-xFe3(BO3)(4) are used to calculate the contributions of the Fe3+ and Gd3+ subsystems to the magnetic anisotropy of these crystals. The contributions are found to be close in magnitude and have opposite signs. This leads to a relatively weak uniaxial anisotropy field in the crystals under investigation. Since the exchange interaction between the Gd3+ and Fe3+ ions magnetizes the magnetic subsystem of gadolinium, both subsystems start to contribute simultaneously at the Neel temperature of the iron subsystem.

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Держатели документа:
[Pankrats, A. I.
Petrakovskii, G. A.
Bezmaternykh, L. N.
Temerov, V. L.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН

Доп.точки доступа:
Pankrats, A. I.; Панкрац, Анатолий Иванович; Petrakovskii, G. A.; Петраковский, Герман Антонович; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Temerov, V. L.; Темеров, Владислав Леонидович
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Coupled R and Fe magnetic excitations in RFe 3(BO 3) 4 multiferroics / A. M. Kuzmenko [et al.] // Diffusion and Defect Data Pt.B: Solid State Phenomena. - 2012. - Vol. 190. - P. 269-272, DOI 10.4028/www.scientific.net/SSP.190.269 . - ISBN 9783037854365
Кл.слова (ненормированные):
Magnetic resonance -- Rare-earth iron borates -- Terahertz spectroscopy -- Antiferromagnetics -- Coupled mode -- Exchange coupled -- Frequency ranges -- G factors -- Iron borate -- Magnetic excitations -- Multiferroics -- Resonance mode -- Strong interaction -- Transmission spectrums -- Antiferromagnetism -- Electron transitions -- Gadolinium -- Ions -- Magnetic materials -- Magnetic permeability -- Magnetic resonance -- Terahertz spectroscopy -- Neodymium
Аннотация: Various resonance modes were observed in the transmission spectra of rare-earth iron borates RFe 3(BO 3) 4 (R = Nd 3+, Sm 3+, Gd 3+) at the frequency range 100-600 GHz, which were attributed to collective magnetic excitations in the exchange coupled Fe- and R-subsystems, i.e. antiferromagnetic (Fe) resonance and electron transitions in the R-ions. Strong interaction of the Fe and R oscillations was revealed and theoretically analyzed taking into account feature of the R-ion ground state. Intensities of the coupled modes (contributions to magnetic permeability) strongly depend on a difference of Fe and R ions g-factors that allows defining the sign of the latter. In particular, an appreciable intensity of exchange (Nd) modes in NdFe 3(BO 3) 4 is caused by g Nd?,|| < 0 whereas in GdFe 3(BO 3) 4 with gGd ? gFe ? 2 the exchange (Gd) modes were hided due to compensation of Fe and Gd contributions. In SmFe 3(BO 3) 4, despite a negligible Sm g-factor, the Sm modes were clear observed due to their excitation via coupling with the Fe-subsystem. В© (2012) Trans Tech Publications.

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Доп.точки доступа:
Kuzmenko, A. M.; Кузьменко А.М.; Mukhin, A. A.; Ivanov, V.Yu.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Moscow International Symposium on Magnetism(5 ; 2011 ; Aug. ; 21-25 ; Moscow)
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Crystal and magnetic properties of the new copper-sodium borate CuNaB3O6 · 0.842H2O / A. M. Vorotynov [et al.] // J. Exp. Theor. Phys. - 2014. - Vol. 119, Is. 3. - P. 532-541, DOI 10.1134/S1063776114080202. - Cited References: 20 . - ISSN 1063-7761. - ISSN 1090-6509

РУБ Physics, Multidisciplinary
Рубрики:
ALPHA'-NaV2O5
CuGeO3
Аннотация: A new compound CuNaB3O6 · 0.842H2O was grown for the first time. Its crystal structure, magnetic susceptibility, and magnetic resonance properties are presented. It was proposed that CuNaB3O6 · 0.842H2O is a spin-Peierls magnet with the transition temperature T SP - 128 K and a ladder spin structure. The possibility of a structural phase transition at T ˂ T SP is predicted.

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Публикация "на русском языке" Crystal and magnetic properties of the new copper-sodium borate CuNaB3O6 · 0.842H2O [Текст] / A. M. Vorotynov [et al.] // Журн. эксперим. и теор. физ. : Наука, 2014. - Т. 146 Вып. 3.- С.607-617

Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia

Доп.точки доступа:
Vorotynov, A. M.; Воротынов, Александр Михайлович; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Rudenko, V. V.; Руденко, Валерий Васильевич; Bayukov, O. A.; Баюков, Олег Артемьевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Vorotynova, O. V.; Воротынова, Ольга Владленовна
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Crystal and magnetic properties of the new copper-sodium borate CuNaB3O6 · 0.842H2O / A. M. Vorotynov [et al.] // Журн. эксперим. и теор. физ. - 2014. - Т. 146, Вып. 3. - С. 607-617, DOI 10.7868/S004445101409020X. - Библиогр.: 20 назв. . - ISSN 0044-4510
Аннотация: A new compound CuNaB3O6 · 0.842H2O was grown for the first time. Its crystal structure, magnetic susceptibility, and magnetic resonance properties are presented. It was proposed that CuNaB3O6 · 0.842H2O is a spin-Peierls magnet with the transition temperature T SP ∼ 128 K and a ladder spin structure. The possibility of a structural phase transition at T ˂ T SP is predicted.

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"Переводная" версия Crystal and magnetic properties of the new copper-sodium borate CuNaB3O6 · 0.842H2O [Текст] / A. M. Vorotynov [et al.] // J. Exp. Theor. Phys. : Pleiades Publishing, 2014. - Vol. 119 Is. 3.- P.532-541

Держатели документа:
[Vorotynov, A.
Vasiliev, A.
Rudenko, V.
Bayukov, O.
Velikanov, D.
Ovchinnikov, S.] Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
[Vorotynova, O.] Siberian Fed Univ, Krasnoyarsk 660041, Russia

Доп.точки доступа:
Vorotynov, A. M.; Воротынов, Александр Михайлович; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Rudenko, V. V.; Руденко, Валерий Васильевич; Bayukov, O. A.; Баюков, Олег Артемьевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Vorotynova, O. V.; Воротынова, Ольга Владленовна
}
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10.

Crystal structure and structural phase transition in bismuth-containing HoFe3(BO3)4 in the temperature range 11–500 K / E. S. Smirnova, O. A. Alekseeva, A. P. Dudka [et al.] // Acta Crystallogr. B. - 2019. - Vol. 75. - P. 954-968, DOI 10.1107/S2052520619010473. - Cited References: 37. - The authors are grateful to D. Yu. Chernyshov (SNBL, ESRF, Grenoble) for his assistance in obtaining the experimental data. This work was performed using the equipment of the Shared Research Center FSRC ‘Crystallography and Photonics’ RAS and was supported by the Russian Ministry of Education and Science (project RFMEFI62119X0035). - This work was supported by the Ministry of Science and Higher Education within the State assignment FSRC ‘Crystallography and Photonics’ RAS and partially by the Russian Foundation for Basic Research (grant No. 17-02-00766) . - ISSN 2052-5192
Кл.слова (ненормированные):
holmium iron borate -- crystal structure -- structural phase transition -- Mossbauer spectroscopy -- characteristic temperatures
Аннотация: An accurate single-crystal X-ray diffraction study of bismuth-containing HoFe3(BO3)4 between 11 and 500 K has revealed structural phase transition at Tstr = 365 K. The Bi atoms enter the composition from Bi2Mo3O12-based flux during crystal growth and significantly affect Tstr. The content of Bi was estimated by two independent methods, establishing the composition as (Ho0.96Bi0.04)Fe3(BO3)4. In the low-temperature (LT) phase below Tstr the (Ho0.96Bi0.04)Fe3(BO3)4 crystal symmetry is trigonal, of space group P3121, whereas at high temperature (HT) above 365 K the symmetry increases to space group R32. There is a sharp jump of oxygen O1 (LT) and O2 (LT) atomic displacement parameters (ADP) at Tstr. O1 and O2 ADP ellipsoids are the most elongated over 90–500 K. In space group R32 specific distances decrease steadily or do not change with decreasing temperature. In space group P3121 the distortion of the polyhedra Ho(Bi)O6, Fe1O6 and Fe2O6, B2O3 and B3O3 increases with decreasing temperature, whereas the triangles B1O3 remain almost equilateral. All BO3 triangles deviate from the ab plane with decreasing temperature. Fe–Fe distances in Fe1 chains decrease, while distances in Fe2 chains increase with decreasing temperature. The Mössbauer study confirms that the FeO6 octahedra undergo complex dynamic distortions. However, all observed distortions are rather small, and the general change in symmetry during the structural phase transition has very little influence on the local environment of iron in oxygen octahedra. The Mössbauer spectra do not distinguish two structurally different Fe1 and Fe2 positions in the LT phase. The characteristic temperatures of cation thermal vibrations were calculated using X-ray diffraction and Mössbauer data.

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Держатели документа:
Shubnikov Inst. of Cristal. of Federal Scientific Research Centre Crystallography and Photonics, Russian Academy of Sciences, Moscow, 119333, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Smirnova, E. S.; Alekseeva, O. A.; Dudka, A. P.; Khmelenin, D. N.; Frolov, K. V.; Lyubutina, M. V.; Gudim, I. A.; Гудим, Ирина Анатольевна; Lyubutin, I. S.
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11.

Crystal structure of bismuth-containing NdFe3(BO3)4 in the temperature range 20–500 K / E. S. Smirnova, O. A. Alekseeva, A. P. Dudka [et al.] // Acta Crystallogr. B. - 2022. - Vol. 78, Pt. 1. - P. 1-13, DOI 10.1107/S205252062101180X. - Cited References: 44. - This work was performed using the equipment of the Shared Research Center FSRC `Crystallography and Photonics' RAS supported by the Russian Ministry of Science and Higher Education. This work was supported by the Ministry of Science and Higher Education within the State assignment FSRC `Crystallography and Photonics' RAS . - ISSN 2052-5206

РУБ Chemistry, Multidisciplinary + Crystallography
Рубрики:
MAGNETIC PHASE-TRANSITIONS
UNIT-CELL PARAMETERS
DIFFRACTION
Кл.слова (ненормированные):
neodymium iron borate -- multiferroic -- crystal structure -- multi-temperature -- single-crystal X-ray diffraction -- Mossbauer spectroscopy -- characteristic temperature
Аннотация: Neodymium iron borate NdFe3(BO3)4 is an intensively studied multiferroic with high electric polarization values controlled by a magnetic field. It is characterized by a large quadratic magnetoelectric effect, rigidity in the base plane and a rather strong piezoelectric effect. In this work, the atomic structure of (Nd0.91Bi0.09)Fe3(BO3)4 was studied by single-crystal X-ray diffraction in the temperature range 20–500 K (space group R32, Z = 3). The Bi atoms found in the composition partially substitute the Nd atoms in the 3a position; they entered the structure due to the growth conditions in the presence of Bi2Mo3O12. It was shown that in the temperature range 20–500 K there is no structural phase transition R32→P3121, which occurs in rare-earth iron borates (RE = Eu–Er, Y) with an effective rare-earth cation radius smaller than that of Nd. The temperature dependence of the unit-cell c parameter reveals a slight increase on cooling below 90 K, which is similar to the results obtained previously for iron borates of Gd, Y and Ho. The atomic distances (Nd,Bi)—O, (Nd,Bi)—B, (Nd,Bi)—Fe, Fe—O, Fe—B and Fe—Fe in the iron chains and between chains decrease steadily with decreasing temperature from 500 to 90 K, whereas the B1(3b)—O distance does not change and the average B2(9e)—O distance increases slightly. There is a uniform decrease in the atomic displacement parameters with decreasing temperature, with a more pronounced decrease for the Nd(3a) and O2(9e) atoms. The O2(9e) atoms are characterized by the maximum atomic displacement parameters and the most elongated atomic displacement ellipsoids. The characteristic Debye and Einstein temperatures, and the static component in the atomic displacements were determined for cations using multi-temperature diffraction data. It was shown that the Nd cations have the weakest bonds with the surrounding atoms and the B cations have the strongest.

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Держатели документа:
Russian Acad Sci, Fed Sci Res Ctr Crystallog & Photon, Shubnikov Inst Crystallog, Moscow 119333, Russia.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Smirnova, E. S.; Alekseeva, O. A.; Dudka, A. P.; Verin, I. A.; Artemov, V. V.; Lyubutina, M. V.; Gudim, I. A.; Гудим, Ирина Анатольевна; Frolov, K. V.; Lyubutin, I. S.; Russian Ministry of Science and Higher Education; Ministry of Science and Higher Education within the State assignment FSRC 'Crystallography and Photonics' RAS
}
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12.

Crystal structure, absolute configuration and characteristic temperatures of SmFe3(BO3)4 in the temperature range 11-400 K / E. S. Smirnova, O. A. Alekseeva, A. P. Dudka [et al.] // Acta Crystallogr. B. - 2022. - Vol. 78, Is. 3-2, Pt. 1. - P. 546-556, DOI 10.1107/S2052520622003948. - Cited References: 43. - The authors are grateful to D. Yu. Chernyshov (SNBL, ESRF, Grenoble) for assistance in obtaining the experimental data. This work was performed using the equipment of the Shared Research Center FSRC ‘Crystallography and Photonics’ RAS supported by the Russian Ministry of Science and Higher Education. This work was supported by the Ministry of Science and Higher Education within the State assignment FSRC ‘Crystallography and Photonics’ RAS . - ISSN 2052-5206
Кл.слова (ненормированные):
samarium bismuth iron borate -- absolute configuration -- crystal structure -- multi-temperature single-crystal X-ray diffraction -- Mossbauer spectroscopy -- characteristic temperatures -- solution-melt growth
Аннотация: The crystal structure of samarium iron borate was analyzed with regard to growth conditions and temperature. The inclusion of about 7% Bi atoms in the crystals grown using the Bi2Mo3O12-based flux was discovered and there were no impurities in the crystals grown using the Li2WO4-based flux. No pronounced structural features associated with Bi inclusion were observed. The different absolute configurations of the samples grown using both fluxes were demonstrated. Below 80 K, a negative thermal expansion of the c unit-cell parameter was found. The structure of (Sm0.93Bi0.07)Fe3(BO3)4 belongs to the trigonal space group R32 in the temperature range 90–400 K. A decrease in the (Sm,Bi)—O, Sm—B, Sm—Fe, Fe—O, Fe—B and Fe—Fe distances is observed with a lowering of the temperature, B1—O does not change, B2—O increases slightly and the B2O3 triangles deviate from the ab plane. The strongest decrease in the equivalent isotropic atomic displacement parameters (Ueq) with decreasing temperature is observed for atoms Sm and O2, and the weakest is observed for B1. The O2 atoms have the highest Ueq values, the most elongated atomic displacement ellipsoids of all the atoms and the smallest number of allowed vibrational modes of all the O atoms. The largest number of allowed vibrational modes and the strongest interactions with neighbouring atoms is seen for the B atoms, and the opposite is seen for the Sm atoms. The quadrupole splitting Δ(T) of the paramagnetic Mössbauer spectra increases linearly with cooling. The Néel temperature [TN = 31.93 (5) K] was determined from the temperature dependence of the hyperfine magnetic field Bhf(T), which has a non-Brillouin character. The easy-plane long-range magnetic ordering below TN was confirmed.

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Держатели документа:
Shubnikov Institute of Crystallography of Federal Scientific Research Centre 'Crystallography and Photonics', Russian Academy of SciencesMoscow 119333, Russian Federation
Moscow State University, Faculty of GeologyMoscow 119991, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Smirnova, E. S.; Alekseeva, O. A.; Dudka, A. P.; Sorokin, T. A.; Khmelenin, D. N.; Yapaskurt, V. O.; Lyubutina, M. V.; Frolov, K. V.; Lyubutin, I. S.; Gudim, I. A.; Гудим, Ирина Анатольевна
}
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13.

Crystal structure, phase transition and structural deformations in iron borate (Y0.95Bi0.05)Fe3(BO3)4 in the temperature range 90–500 K / E. S. Smirnova [et al.] // Acta Crystallogr. B. - 2018. - Vol. 74. - P. 226-238, DOI 10.1107/S2052520618002962. - Cited References:27. - The following funding is acknowledged: Russian Foundation for Basic Research (award No. 17-02-00766) and Federal Agency of Scientific Organizations (Agreement No 007-GZ/Ch3363/26). . - ISSN 2052-5206

РУБ Chemistry, Multidisciplinary + Crystallography
Рубрики:
HIGH-PRESSURES
   GDFE3(BO3)4
   SPECTROSCOPY
   IFEFFIT
Кл.слова (ненормированные):
rare-earth iron borates -- crystal structure -- structural phase transition -- structural deformations
Аннотация: An accurate X-ray diffraction study of (Y0.95Bi0.05)Fe3(BO3)4 single crystals in the temperature range 90–500 K was performed on a laboratory diffractometer and used synchrotron radiation. It was established that the crystal undergoes a diffuse structural phase transition in the temperature range 350–380 K. The complexity of localization of such a transition over temperature was overcome by means of special analysis of systematic extinction reflections by symmetry. The transition temperature can be considered to be Tstr ≃ 370 K. The crystal has a trigonal structure in the space group P3121 at temperatures of 90–370 K, and it has a trigonal structure in the space group R32 at 375–500 K. There is one type of chain formed by the FeO6 octahedra along the c axis in the R32 phase. When going into the P3121 phase, two types of nonequivalent chains arise, in which Fe atoms are separated from the Y atoms by a different distance. Upon lowering the temperature from 500 to 90 K, a distortion of the Y(Bi)O6, FeO6, B(2,3)O3 coordination polyhedra is observed. The distances between atoms in helical Fe chains and Fe—O—Fe angles change non-uniformly. A sharp jump in the equivalent isotropic displacement parameters of O1 and O2 atoms within the Fe—Fe chains and fluctuations of the equivalent isotropic displacement parameters of B2 and B3 atoms were observed in the region of structural transition as well as noticeable elongation of O1, O2, B2, B3, Fe1, Fe2 atomic displacement ellipsoids. It was established that the helices of electron density formed by Fe, O1 and O2 atoms may be structural elements determining chirality, optical activity and multiferroicity of rare-earth iron borates. Compression and stretching of these helices account for the symmetry change and for the manifestation of a number of properties, whose geometry is controlled by an indirect exchange interaction between iron cations that compete with the thermal motion of atoms in the structure. Structural analysis detected these changes as variations of a number of structural characteristics in the c unit-cell direction, that is, the direction of the helices. Structural results for the local surrounding of the atoms in (Y0.95Bi0.05)Fe3(BO3)4 were confirmed by EXAFS and Mössbauer spectroscopies.

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Держатели документа:
Russian Acad Sci, Fed Sci Res Ctr Crystallog & Photon, Shubnikov Inst Crystallog, Moscow 119333, Russia.
Natl Res Ctr, Kurchatov Inst, Moscow 123182, Russia.
Russian Acad Sci, Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Smirnova, Ekaterina S.; Alekseeva, Olga A.; Dudka, Alexander P.; Artemov, V. V.; Zubavichus, Yan V.; Gudim, I. A.; Гудим, Ирина Анатольевна; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Frolov, Kirill V.; Lyubutin, Igor S.; Russian Foundation for Basic Research [17-02-00766]; Federal Agency of Scientific Organizations [007-GZ/Ch3363/26]
}
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14.

Edelman, I.
Oxide glasses with magnetic nanoparticles: transparent magnets (Faraday rotation and electron magnetic resonance studies) / I. . Edelman, J. . Kliava // Phys. Status Solidi B. - 2009. - Vol. 246, Is. 10. - P. 2216-2231, DOI 10.1002/pssb.200945169. - Cited References: 87. - This work is supported in part by RFBR-CNRS joint project, grant No 07-02-92174. We are grateful to E. Petrakovskaja and O. Ivanova for measuring and discussing, respectively, the EMR spectra in thermally treated samples and the FR spectral and magnetic field dependences. . - ISSN 0370-1972

РУБ Physics, Condensed Matter
Рубрики:
SPIN-HAMILTONIAN PARAMETERS
   SINGLE-DOMAIN PARTICLES
   SUPERPARAMAGNETIC RESONANCE
   CRYSTALLIZATION BEHAVIOR
   FERRIMAGNETIC RESONANCE
   PARAMAGNETIC-RESONANCE
   TEMPERATURE-DEPENDENCE
   COMPUTER-SIMULATIONS
   FINE PARTICLES
   BORATE GLASSES
Аннотация: In the first part of this paper we outline the state of the art in the field of magnetic nanoparticles in oxide glasses. We describe the theoretical background of two complementary techniques used for the studies of the state of paramagnetic ions, clusters and magnetic particles in a diamagnetic matrix, viz., magnetooptical Faraday rotation (FR) and electron magnetic resonance (EMIR) and we overview previous results obtained with these techniques for several glass systems. In the second part, we highlight the case of potassium-alumina-borate glasses - a glassy system where doping with paramagnetic oxides results in formation of magnetic particles at very low contents of paramagnetic additions: Fe(2)O(3) and MnO. In the special case when the ratio of the iron and manganese oxides in the charge is 3/2, magnetic nanoparticles with characteristics close to those of manganese ferrite are formed already at the first stage of the glass preparation. After thermal treatment all glasses show FR and EMR spectra attesting to the presence of superparamagnetic nanoparticles, characterized by relatively broad size and shape distributions. The formation of magnetic nanoparticles confers to these glasses magnetic and magnetooptical properties typical of magnetically ordered substances. At the same time, the glasses remain transparent in a part of the visible and near infrared spectral range and display a high FR value. Such properties make them particularly interesting for use as new media for various magneto-optical devices. (C) 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

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Держатели документа:
[Edelman, Irina] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Kliava, Janis] Univ Bordeaux 1, Ctr Phys Mol Opt & Hertzienne, CNRS, UMR 5798, F-33405 Talence, France
ИФ СО РАН
L.V. Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 38, 660036 Krasnoyarsk, Russian Federation
Centre de Physique Moleculaire Optique et Hertzienne, Universite Bordeaux1-CNRS, UMR 5798, 351 cours de la Liberation, 33405 Talence cedex, France

Доп.точки доступа:
Kliava, J.; RFBR-CNRS [07-02-92174]
}
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15.

Effect of gadolinium on magnetic circular dichroism and electron magnetic resonance of ε-Fe2O3 nanoparticles formed in borate glasses / I. Edelman [et al.] // J. Non-Cryst. Solids. - 2019. - Vol. 506. - P. 68-79, DOI 10.1016/j.jnoncrysol.2018.12.006. - Cited References: 81. - The work is supported by Russian Academy of Sciences in the frame of the Project № 0356-2017-0030. . - ISSN 0022-3093
Кл.слова (ненормированные):
Iron oxides -- ε-Fe2O3 -- Borate glasses -- Nanoparticles -- Magnetic circular dichroism -- Electron magnetic resonance
Аннотация: A remarkable characteristic of borate glasses is the ability of forming magnetic nanoparticles at low doping with transition element oxides. We have studied structure and magnetic properties of iron oxide nanoparticles formed in borate glasses, in particular, concentration and temperature dependences of magnetic circular dichroism (MCD) and electron magnetic resonance (EMR) spectra. A series of glasses of molar composition 22.5K2O-22.5Al2O3–55B2O3 doped with 1.5 mass % of Fe2O3 and different contents of Gd2O3 from 0.1 to 1.0 mass % was prepared using a conventional melt quenching technique and subjected to an additional thermal treatment. The whole set of results allows to identify the predominant magnetic phase in these glasses as ε-Fe2O3 nanoparticles, with a considerable part of iron ions substituted by gadolinium. Analysis and computer simulations of the EMR spectra allow separating the contribution of electron paramagnetic resonance of diluted iron ions and together with the temperature dependences of magnetization demonstrate a superparamagnetic character of the nanoparticle magnetism.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
LOMA, UMR 5798 Universite de Bordeaux-CNRS, Talence cedex, 33405, France
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Boreskov Institute of Catalysis, Siberian Branch of RAS, Novosibirsk, 630090, Russian Federation
NRC “Kurchatov Institute”, Moscow, 123182, Russian Federation
Vavilov State Optical Institute, St.-Petersburg, 199053, Russian Federation

Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Kliava, J.; Ivanova, O. S.; Иванова, Оксана Станиславовна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Zaikovskii, V.; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна; Zubavichus, Y.; Stepanov, S.
}
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16.

Effect of synthesis conditions on the magnetic properties of chromium borate single crystals / N. V. Mikhashenok, A. I. Pankrats, I. A. Gudim [et al.] // V International Baltic Conference on Magnetism. IBCM : Book of abstracts. - 2023. - P. 127. - Cited References: 5. - РФН № 22-12-20019 ; Красноярский регион. фонд науки

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS
Federal Research Center KSC SB RAS

Доп.точки доступа:
Mikhashenok, N. V.; Михашенок, Наталья Владимировна; Pankrats, A. I.; Панкрац, Анатолий Иванович; Gudim, I. A.; Гудим, Ирина Анатольевна; Skorobogatov, S. A.; Molokeev, M. S.; Молокеев, Максим Сергеевич; International Baltic Conference on Magnetism(5 ; 2023 ; Aug. 20-24 ; Svetlogorsk, Russia); Балтийский федеральный университет им. И. Канта
}
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17.

Electron magnetic resonance and magnetooptical studies of nanoparticle-containing borate glasses / J. Kliava [et al.] // Journal of Magnetism and Magnetic Materials. - 2011. - Vol. 323, Is. 5. - P. 451-460, DOI 10.1016/j.jmmm.2010.09.045. - Cited Reference Count: 40. - RFBRRussian Foundation for Basic Research (RFBR) [07-02-92174]; CNRSCentre National de la Recherche Scientifique (CNRS)European Commission [07-02-92174]; Russian Federal Program [FCP NK-209P/GK P1227], This work was supported in part by RFBR-CNRS joint project, Grant no. 07-02-92174 and by the Russian Federal Program, project FCP NK-209P/GK P1227. It is a pleasure to thank I. Bruckental and Y. Yeshurun for the magnetization measurements. . - ISSN 0304-8853

ГРНТИ

29.19

Кл.слова (ненормированные):
borate glasses -- Electron magnetic resonance -- magnetic nanoparticles -- magnetooptics
Аннотация: We report electron magnetic resonance (EMR) and magnetooptical studies of borate glasses of molar composition 22.5K2O22.5Al2O 355B2O3 co-doped with low concentrations of Fe2O3

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Держатели документа:
CEMHTI,UPR3079 CNRS et Universit d'Orlans
CPMOH,UMR 5798,Universit Bordeaux 1-CNRS
CRMD,UMR 6619,Universit d'Orlans-CNRS
L.V. Kirensky Institute of Physics,Siberian Branch of the RAS
Synchrotron SOLEIL,L'Orme des Merisiers

Доп.точки доступа:
Kliava, J.; Edelman, I.; Ivanova, O.; Ivantsov, R.; Petrakovskaja, E. A.; Hennet, L.; Thiaudire, D.; Saboungi, M. L.
}
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18.

Electron paramagnetic resonance of Cr3+ ions in single crystals of yttrium aluminum borate YAl3(BO3)4 / A. Vorotynov [et al.] // Phys. Solid State. - 2018. - Vol. 60, Is. 9. - P. 1839-1843, DOI 10.1134/S1063783418090354. - Cited References: 13 . - ISSN 1063-7834
Аннотация: Single crystal of yttrium aluminum borate YAl3(BO3)4 doped with chromium ions (1 at %) was studied using electron paramagnetic resonance spectroscopy. It is shown that chromium ions introduced into the sample occupy yttrium ion sites in the crystal structure. The parameters of the spin Hamiltonian of Cr3+ ions in the YАl3(ВО3)4 matrix are determined at different temperatures. The sign of the fine structure parameter D allows the conclusion that the chromium ions in YА13(ВО3)4 single crystals have an easy-plane anisotropy.

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Публикация "на русском языке" Electron paramagnetic resonance of Cr3+ ions in single crystals of yttrium aluminum borate YAl3(BO3)4 [Текст] / A. Vorotynov [et al.] // Физ. тверд. тела. - 2018. - Т. 60 Вып. 9.- С.1793

Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Vorotynov, A. M.; Воротынов, Александр Михайлович; Shiyan, Ya. G.; Шиян, Ярослав Германович; Gudim, I. A.; Гудим, Ирина Анатольевна; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Vorotynova, O.
}
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19.

Electron paramagnetic resonance of Cr3+ ions in single crystals of yttrium aluminum borate YAl3(BO3)4 / A. Vorotynov [et al.] // Физ. тверд. тела. - 2018. - Т. 60, Вып. 9. - С. 1793, DOI 10.21883/FTT.2018.09.46399.075. - Библиогр.: 13. - Полный текст статьи опубликован в журнале "Physics of the Solid States" (Т. 60. Вып. 9). . - ISSN 0367-3294
Аннотация: Single crystal of yttrium aluminum borate YAl3(BO3)4 doped with chromium ions (1 at %) was studied using electron paramagnetic resonance spectroscopy. It is shown that chromium ions introduced into the sample occupy yttrium ion sites in the crystal structure. The parameters of the spin Hamiltonian of Cr3+ ions in the YАl3(ВО3)4 matrix are determined at different temperatures. The sign of the fine structure parameter D allows the conclusion that the chromium ions in YА13(ВО3)4 single crystals have an easy-plane anisotropy.

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Полная версия статьи Electron paramagnetic resonance of Cr3+ ions in single crystals of yttrium aluminum borate YAl3(BO3)4 [Текст] / A. Vorotynov [et al.] // Phys. Solid State. - 2018. - Vol. 60 Is. 9.- P.1839-1843

20.

Electron paramagnetic resonance of Mn2+ ions in single crystals of yttrium aluminum borate YAl3(BO3)4 / A. M. Vorotynov [et al.] // Phys. Solid State. - 2007. - Vol. 49, Is. 3. - P. 463-466, DOI 10.1134/S1063783407030122. - Cited References: 11 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
HUNTITE STRUCTURE
GROWTH
LASER
Аннотация: Single crystals of yttrium aluminum borate YAl3 (BO3)(4) doped with manganese ions are studied using electron paramagnetic resonance spectroscopy. It is shown that manganese ions introduced at low concentrations into the sample predominantly occupy yttrium ion sites in the crystal structure. The shape of the electron paramagnetic resonance spectrum unambiguously indicates that the valence of manganese ions in this case is equal to 2+. The parameters of the spin Hamiltonian of Mn2+, ions in the YAl3(BO3)(4) matrix are determined at room temperature. The magnitude and sign of the fine structure parameter D allow the conclusion that the YAl3(BO3)(4) single crystals doped with manganese ions have a strong crystal field at the yttrium ion sites and L easy-axis anisotropy.

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Держатели документа:
Russian Acad Sci, Siberian Div, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Institute of Physics, Polish Academy of Sciences, al. Lotnikow 32/46, Warsaw, 02-668, Poland

Доп.точки доступа:
Vorotynov, A. M.; Воротынов, Александр Михайлович; Petrakovskii, G. A.; Петраковский, Герман Антонович; Shiyan, Ya. G.; Шиян, Ярослав Германович; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Temerov, V. E.; Bovina, A. F.; Бовина, Ася Федоровна; Aleshkevych, P.
}
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