Библиотека института физики им. Л.В. Киренского СО РАН

Главная

Базы данных

Труды сотрудников ИФ СО РАН - результаты поиска

Вид поиска

Каталог книг и брошюр библиотеки ИФ СО РАН

Каталог журналов библиотеки ИФ СО РАН

Труды сотрудников ИФ СО РАН

Область поиска

в найденном

Найдено в других БД:

Каталог книг и брошюр библиотеки ИФ СО РАН (3)

Формат представления найденных документов:
полный	информационный	краткий

Отсортировать найденные документы по:
автору	заглавию	году издания	типу документа

Поисковый запрос: (<.>K=CALORIMETRY<.>)

Общее количество найденных документов : 27
Показаны документы с 1 по 20

1-20 21-27

Heat capacity and structure of Rb2KMeO3F3 (Me: Mo, W) elpasolites / A. V. Kartashev [et al.] // Solid State Sci. - 2012. - Vol. 14, Is. 1. - P. 166-170, DOI 10.1016/j.solidstatesciences.2011.11.019. - Cited References: 12. - This study was supported by the Siberian Branch of the Russian Academy of Sciences (Grant no. 34) and the Council on Grants from the President of the Russian Federation for the Support of Leading Scientific Schools of the Russian Federation (NSh-4645.2010.2). . - ISSN 1293-2558

РУБ Chemistry + Physics
Рубрики:
T PHASE-DIAGRAM
Rb2KMoO3F3
TRANSITION
Кл.слова (ненормированные):
Oxyfluorides -- Crystal structure -- Phase transition -- Calorimetry
Аннотация: X-ray and heat capacity measurements were performed on Rb2KMoO3F3 and Rb2KWO3F3 single crystals. A significant difference in the thermal parameters of atoms in 4a and 8c sites of Fm-3m structure was found, which depended on the central atom. Calorimetric measurements have revealed the heat capacity anomalies at 195 and 67 K, respectively, in Rb2KMoO3F3 and Rb2KWO3F3. The standard molar enthalpy and entropy were determined. Entropy changes associated with phase transitions in oxyfluorides under study and related Rb2KTiOF5 are discussed. 2011 Elsevier Masson SAS. All rights reserved.

Смотреть статью,
Scopus,
WoS,
Читать в сети ИФ
Держатели документа:
[Gorev, Michail V.] Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Kartashev, Andrey V.
Gorev, Michail V.
Flerov, Igor N.] Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660074, Russia
[Isaenko, Lyudmila I.
Zhurkov, Sergey A.] Russian Acad Sci, Inst Geol & Mineral, Novosibirsk 630090, Russia

Доп.точки доступа:
Kartashev, A. V.; Карташев, Андрей Васильевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Isaenko, L. I.; Zhurkov, S. A.; Fokina, V. D.; Фокина, Валентина Дмитриевна; Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич; Siberian Branch of the Russian Academy of Sciences [34]; Russian Federation for the Support of Leading Scientific Schools of the Russian Federation [NSh-4645.2010.2]
}
Найти похожие

Unusual sequence of phase transitions in (NH4)3TiF7 detected by optic and calorimetric studies / S. V. Mel'nikova [et al.] // J. Fluor. Chem. - 2014. - Vol. 165. - P. 14-19, DOI 10.1016/j.jfluchem.2014.05.016. - Cited References: 13. - This work was supported by Russian Foundation for Basic Research (Grant no. 12-02-00056), and the Council on Grants from the President of the Russian Federation for the Support of Leading Scientific Schools of the Russian Federation (Grant no. NSh-924.2014.2). . - ISSN 0022-1139. - ISSN 1873-3328

РУБ Chemistry, Inorganic & Nuclear + Chemistry, Organic
Рубрики:
CRYSTAL-STRUCTURE
DIFFRACTION
NH4F
Кл.слова (ненормированные):
Cubic fluorides -- Phase transitions -- Crystal-optic -- Calorimetry
Аннотация: For the first time structural transformations were observed for one of the compounds belonging to the family of double salt fluorides A3MeF7 = A2MeF6·AF. Single crystals of (NH4)3TiF7 = (NH4)2TiF6·NH4F were grown by evaporation of the aqueous solution. Polarizing optical observations, heat capacity and birefringence Δn = (no − ne) measurements were performed in a wide temperature range 100–400 K. Two reversible, first order structural phase transitions were found to be followed by an unusual sequence of symmetry changes: cubic (G3) (T2↓ = 287.5 K; T2↑ = 291–310 K) ↔ P4/mnc (G2) (T1↓ = 358.5 K; T1↑ = 360 K) ↔ 4/m (G1). The twin structures observed were described assuming the existence of cubic parent phase G0 with P m 3 ¯ m symmetry.

Смотреть статью,
Scopus,
WoS,
Читать в сети ИФ
Держатели документа:
RAS, LV Kirensky Phys Inst, Siberian Dept, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660074, Russia
Russian Acad Sci, Inst Chem, Far Eastern Dept, Vladivostok 690022, Russia

Доп.точки доступа:
Mel'nikova, S. V.; Мельникова, Светлана Владимировна; Pogoreltsev, E. I.; Погорельцев, Евгений Ильич; Flerov, I. N.; Флёров, Игорь Николаевич; Laptash, N. M.; Russian Foundation for Basic Research [12-02-00056]; Council on Grants from the President of the Russian Federation for the Support of Leading Scientific Schools of the Russian Federation [NSh-924.2014.2]
}
Найти похожие

Ferroelastic phase transition in Cs3Bi2I9 crystal / S. V. Melnikova [et al.] // Ferroelectrics, Letters Section. - 1996. - Vol. 20, Is. 5-6. - P. 163-167 . - ISSN 0731-5171
Кл.слова (ненормированные):
Birefringence -- Cesium compounds -- Crystal symmetry -- Crystals -- Differential scanning calorimetry -- Elasticity -- Ferroelectricity -- Permittivity -- Stiffness -- Twinning -- Cesium bismuth iodide -- Elastic constant -- Elastic stiffness -- Ferroelastic phase transition -- Phase transitions
Аннотация: Phase transition (PT) was found in Cs3Bi2I9 single crystal at T0=223 K. Optical birefringence, dielectric and elastic constants and differential scanning calorimetry have been studied. It was found that birefringence ?nc and twinning picture appeared on (001) - and (100) - plates below T0, as well as softening of elastic stiffness C44 above T0. It allows to classify the PT as proper ferroelastic one with symmetry change 6/mmm - 2/m. В© 1996 OPA (Overseas Publishers Association) Amsterdam B.V. Published in The Netherlands under license by Gordon and Breach Science Publishers SA.

Scopus

Доп.точки доступа:
Melnikova, S. V.; Мельникова, Светлана Владимировна; Shabanova, L. A.; Zaitsev, A. I.; Зайцев, Александр Иванович; Parshikov, S. A.; Ageev, O. A.; Aleksandrov, K. S.; Александров, Кирилл Сергеевич
}
Найти похожие

Phase transitions in Cs2CdI4 single crystals / K. S. Aleksandrov [et al.] // Phys. Status Solidi A. - 1988. - Vol. 105, Is. 2. - P. 441-446 . - ISSN 0031-8965
Кл.слова (ненормированные):
CALORIMETRY -- CRYSTALS - Structure -- DIELECTRIC PROPERTIES -- OPTICAL PROPERTIES -- X-RAY ANALYSIS -- BIREFRINGENCE -- CESIUM CADMIUM IODIDE -- DIELECTRIC PERMEABILITY -- SPECIFIC HEAT -- SYMMETRY -- CESIUM COMPOUNDS
Аннотация: Cs//2CdI//4 crystals were grown from the melt (A) and from water solution (B). Optic, dielectric, X-ray, and calorimetric investigations were carried out. Crystal A shows three phase transitions at 332. 3, 259. 6, and 183. 4 K with the following sequence of phases: commensurate orthorhombic of beta -K//2SO//4 type ( alpha //0 equals 1. 074, b//0 equals 0. 8458, c equals 1. 4852 nm) B ARR LR incommensurate B ARR LR monoclinic ferroelastic (P2//1/n) B ARR LR triclinic ferroelastic (P1 OVER BAR ). The B-crystal belongs to monoclinic symmetry (P2//1/m) and undergoes transformation into the orthorhombic phase of beta -K//2SO//4 type at 420 K.

Scopus,
WOS
Держатели документа:
USSR Acad of Sciences, Krasnoyarsk, USSR, USSR Acad of Sciences, Krasnoyarsk, USSR

Доп.точки доступа:
Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Melnikova, S. V.; Мельникова, Светлана Владимировна; Flerov, I. N.; Флёров, Игорь Николаевич; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Kruglik, A. I.; Круглик, Анатолий Иванович; Kokov, I. T.
}
Найти похожие

Investigation of ferroelectric phase transitions in CsLiMoO//4 type crystals / K. S. Aleksandrov [et al.] // Ferroelectrics. - 1983. - Vol. 54, Is. 1. - P. 573-576 . - ISSN 0015-0193
Кл.слова (ненормированные):
CALORIMETRY -- CESIUM COMPOUNDS - X-Ray Analysis -- PHASE TRANSITIONS -- FERROELECTRIC MATERIALS
Аннотация: X-ray and calorimetric investigations of successive phase transitions (PTs) in crystals of CsLiMoO//4 type were made. The theoretical model description of these PTs as of order-disorder type ones is suggested and thermodynamical properties of the model are discussed.

Scopus

Доп.точки доступа:
Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Blat, D. H.; Zinenko, V. I.; Зиненко, Виктор Иванович; Iskornev, I. M.; Kruglik, A. I.; Flerov, I. N.; Флёров, Игорь Николаевич; European Meeting on Ferroelectricity(5 ; 1983 ; Sept. ; 26-30 ; Malaga, Sp)
}
Найти похожие

Heat capacity, entropy, dielectric properties and T–p phase diagram of (NH4)3TiF7 / E. I. Pogoreltsev [et al.] // J. Fluor. Chem. - 2014. - Vol. 168. - P. 247-250, DOI 10.1016/j.jfluchem.2014.10.016. - Cited References: 16. - This work was supported by the Russian Foundation for Basic Research (Grant no. 15-02-02009), and the Council on Grants from the President of the Russian Federation for the Support of Leading Scientific Schools of the Russian Federation (Grant no. NSh-924.2014.2). . - ISSN 0022-1139. - ISSN 1873-3328

РУБ Chemistry, Inorganic & Nuclear + Chemistry, Organic
Рубрики:
CRYSTAL-STRUCTURE
   TRANSITIONS
   FLUORIDES
   NH4F
Кл.слова (ненормированные):
Cubic fluorides -- Phase transitions -- Dielectric -- Phase diagram -- Calorimetry
Аннотация: Successive phase transitions G1 --> G2 --> G3 in the double salt (NH4)(3)TiF7 have been studied by detailed calorimetric, DTA under hydrostatic pressure and dielectric measurements. Rather large entropy jumps at phase transition points were found to be followed by large additional contributions associated with the temperature dependence of the excess heat capacity. The permittivity behaviour and the tangent of the dielectric losses proved the nonferroelectric nature of both transformations. Two triple-points were found on the temperature-pressure phase diagram, suggesting the existence of a hypothetical parent G0 = Pm-3m cubic phase. A direct transformation between high (G0) and low (G3) temperature cubic phases takes place at p > 0.41 GPa with a baric coefficient dT(G0) --> (G3)/dp = -40 K/GPa. (C) 2014 Elsevier B.V. All rights reserved.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ
Держатели документа:
RAS, Siberian Dept, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660074, Russia
Krasnoyarsk State Agr Univ, Krasnoyarsk 660049, Russia
Russian Acad Sci, Far Eastern Dept, Inst Chem, Vladivostok 690022, Russia

Доп.точки доступа:
Pogoreltsev, E. I.; Погорельцев, Евгений Ильич; Flerov, I. N.; Флёров, Игорь Николаевич; Kartashev, A. V.; Карташев, Андрей Васильевич; Bogdanov, E. V.; Богданов, Евгений Витальевич; Laptash, N. M.; Russian Foundation for Basic Research [15-02-02009]; Council on Grants from the President of the Russian Federation for the Support of Leading Scientific Schools of the Russian Federation [NSh-924.2014.2]
}
Найти похожие

Optical and X-ray studies of mixed crystals CsxRb1-xLiSO4 / S. V. Melnikova [et al.] // Ferroelectrics : Proceedings of the 1994 5th Russian-Japanese Symposium on Ferroelectricity. Part 2 (of 2) (22 August 1994 through 27 August 1994, Moscow, Russia. - 1995. - Vol. 170, Is. 1. - P. 139-143 . - ISSN 0015-0193
Кл.слова (ненормированные):
Birefringence -- Cesium compounds -- Differential scanning calorimetry -- Phase diagrams -- Phase transitions -- Polarization -- Single crystals -- Solid solutions -- Thermal effects -- Twinning -- X ray analysis -- Mixed crystals -- Ferroelectric materials
Аннотация: (T-x) phase diagram has been investigated by polarizing optic and birefringence methods, differential scanning calorimetry and X-ray study. A small amount of rubidium in CsLiSO4 as well as cesium in RbLiSO4 reduces the temperature of transition into ferroelastic phase P1121/n which disappear for x?0.15 and x?0.9. The region of phase P21/c11 (c = 2c0) expands and becomes the most stable below ambient temperature for 0.9>x>0.2.

Scopus,
Смотреть статью

Доп.точки доступа:
Melnikova, S. V.; Мельникова, Светлана Владимировна; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Grankina, V. A.; Voronov, V. N.; Воронов, Владимир Николаевич; Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Russian-Japanese symposium on ferroelectricity(1994 ; Aug. ; 22-27 ; Moscow)
}
Найти похожие

    Structural transformation between two cubic phases of (NH4)3SnF7 / I. N. Flerov [et al.] // J. Fluor. Chem. - 2015. - Vol. 178. - P. 86-92, DOI 10.1016/j.jfluchem.2015.06.024. - Cited References: 19. - We thank T.A. Kaidalova for the idea of doubling the unit cell parameter of (NH4)3SnF7 at room temperature. The reported study was partially supported by RFBR, research project No. 15-02-02009 a. . - ISSN 0022-1139
   Перевод заглавия: Структурный переход между двумя кубическими фазами в (NH4)3SnF7

РУБ Chemistry, Inorganic & Nuclear + Chemistry, Organic
Рубрики:
CRYSTAL-STRUCTURE
TRANSITION
NH4F
Кл.слова (ненормированные):
Cubic fluorides -- Phase transitions -- X-ray -- Calorimetry -- Crystal optics
Аннотация: Reinvestigations of the room temperature structure of ammonium heptafluorostannate (NH4)3SnF7 = (NH4)2SnF6·NH4F = (NH4)3[SnF6]F by both powder and single crystal X-ray diffractions have revealed that its real symmetry is Pa−3 (Z = 8) instead of Pm−3m (Z = 1) suggested earlier. Polarizing optical observations, heat capacity, X-ray powder, and single crystal measurements were performed in a wide temperature range (100–420 K). A reversible structural phase transition of the first order between two cubic modifications Pa−3 ↔ Pm−3m was found at about T0 = 360 K. The structural models associated with partially disordered and totally ordered high and low temperature phases, respectively, comply with a large value of phase transition entropy.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ
Держатели документа:
L.V. Kirensky Institute of Physics, Siberian Branch of RAS, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Far Eastern State Transport University, Khabarovsk, Russian Federation
Institute of Chemistry, Far Eastern Branch of RAS, Vladivostok, Russian Federation

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Laptash, N. M.; Udovenko, A. A.; Pogoreltsev, E. I.; Погорельцев, Евгений Ильич; Mel'nikova, S. V.; Мельникова, Светлана Владимировна; Misyul, S. V.; Мисюль, Сергей Валентинович
}
Найти похожие

Удод, Любовь Викторовна.
Влияние катионного замещения на полиморфные переходы в пирасаннате висмута Bi2Sn2O7 / Л. В. Удод, М. Н. Ситников // Вестник СибГАУ. - 2015. - Т. 16, № 4. - С. 975-982. - Библиогр.: 53. - Работа выполнена при финансовой поддержке Российского фонда фундаментальных исследований, грант № 15-42-04099 р_сибирь_а, и государственного задания № 114090470016 . - ISSN 1816-9724
Кл.слова (ненормированные):
полиморфные переходы -- диэлектрическая проницаемость -- электросопротивление -- катионное замещение -- дифференциальная сканирующая калориметрия -- polymorphic transitions -- dielectric permeability -- cation substitution -- electrical resistivity -- differential scanning calorimetry
Аннотация: Рассмотрена разработка технологии новых сенсорных материалов, необходимых для газочувствительных приборов, применяемых в ракетостроении. Целью данной работы является изучение влияния допирования разновалентными катионами на кристаллографическую структуру, диэлектрические и электрические свойства пирохлорного соединения Bi 2Sn 2O 7, обладающего селективной избирательностью к газам. Методом твердофазного синтеза впервые синтезированы соединения Bi2(Sn1-xMex)2O7, где Me = Mn, Cr, x = 0, 0,05, находящиеся сразу в двух полиморфных модификациях - орторомбической и кубической. В твердых растворах Bi2(Sn0,95Cr0,05)2O 7 методом сканирующей калориметрии обнаружено два новых структурных перехода, по сравнению со станнатом висмута Bi2Sn2O7. Ионы Mn 4+ сместили фазовые границы полиморфных переходов в сторону меньших температур, а фазовый α→β-переход около 370 К, характерный для Bi2(Sn1-xCrx)2O7, где x = 0, 0,05, подавили почти полностью. Полиморфный переход при Т = 543 К для Bi 2(Sn0,95Mn0,05) 2O 7 протекает с выделением тепла, в отличие от Bi2(Sn1-xCrx)2O7, где x = 0, 0,05. Исследована взаимосвязь структурных, электрических и диэлектрических свойств. Установлены аномалии в температурной зависимости электросопротивления и диэлектрической проницаемости (мнимой и реальной частями) как в области низких температур, так и при высоких температурах. Эти особенности объясняются в рамках модели мартенситных фазовых переходов. Методом сканирующей калориметрии найдены температуры структурных фазовых переходов, которые коррелируют с аномалиями электросопротивления в интервале температур 300 < T < 1000 К для Bi2(Sn1-xCrx)2O7, x = 0, 0,05.
The goal of this work is to develop a new technology of sensor materials required for gas sensing devices used in missile. The aim of this work is to study the effect of doping cations with different valency on the crystallographic structure, dielectric and electrical properties of pyrochlore compound Bi2Sn2O7 with selectivity to gases. Polycrystalline compounds Bi2(Sn1-xMex)2O7, where Me = Mn, Cr, x = 0, 0.05 have been synthesized by conventional solid-state reaction. According to the X-ray powder diffraction research, our sample consists of two polymorphs phases: cubic and rhombic. Two new structural transition are found in Bi2(Sn0.95Cr0.05)2O7 solid solutions by scanning calorimetry, as compared to bismuth pyrostannate Bi2Sn2O7. Ions Mn 4+ leads to shift of phase boundary of polymorphic transitions towards lower temperatures, and the phase α→β-transition at about 370 K, which is characteristic for Bi2(Sn1-xCrx)2O7, where x = 0, 0.05 is suppressed. The polymorphic transition at T = 543 K for Bi2(Sn0.95Mn0.05)2O7 occurs with calorification, in contrast to Bi2(Sn1-xCrx)2 7, where x = 0, 0.05. The relationship between structural, electrical and dielectric properties is investigated. Anomalies in the temperature dependence of electrical resistivity and dielectric permeability (real and imaginary part) as in the low region temperatures as in the high region temperature are found. These features are explained within a model of martensitic phase transitions. The temperature of the structural phase transitions correlates with temperature of maximum of the electrical resistivity in the temperature range 300 < T < 1000 K for Bi2(Sn1-xCrx)2O7, x = 0, 0.05 was found by scanning calorimetry method.

РИНЦ,
Читать в сети ИФ
Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Ситников, Максим Николаевич; Sitnikov, M.N.; Udod, L. V.
}
Найти похожие

10.

Morozov, E. V.
Probing flocculant-induced asphaltene precipitation via NMR imaging: from model toluene-asphaltene systems to natural crude oils / E. V. Morozov, O. N. Martyanov // Appl. Magn. Reson. - 2016. - Vol. 47, Is. 2. - P. 223-235, DOI 10.1007/s00723-015-0741-9. - Cited References:46. - This research was performed with the financial support of Russian Science Foundation (project no. 15-19-00119). . - ISSN 0937-9347. - ISSN 1613-7507

РУБ Physics, Atomic, Molecular & Chemical + Spectroscopy
Рубрики:
PETROLEUM ASPHALTENES
   MOLECULAR-DYNAMICS
   AGGREGATION
   MICROSCOPY
   SCATTERING
   RESONANCE
   SEDIMENTATION
   ASSOCIATION
   CALORIMETRY
   RELAXATION
Аннотация: An nuclear magnetic resonance (NMR) imaging approach for studying flocculant-induced asphaltene precipitation processes is introduced in this report. Unlike commonly accepted techniques, which primarily measure aggregation processes on the submicron scale (the level of asphaltene molecules and their aggregates), NMR imaging demonstrates the capability to obtain new useful information about bulk system behavior on the macro scale. To reveal the capabilities of the method, the model toluene-asphaltene system and two samples of natural crude oils with different chemical composition and physical properties (such as asphaltene content and density) were employed for experiments. The process of colloidal suspension formation and two different patterns of its evolution were observed depending on both the asphaltene content and the flocculant concentration. In the first pattern, the flocculant-induced precipitation leads to the slow uniform compacting of the suspension and descent of the sedimentation front, whereas the second pattern is characterized by sediment accumulation and the upwards drift of the front. It was found that the behavior of the precipitated asphaltenes in the model system correlates well with those observed in natural crude oils. The results achieved in this work are in agreement with the data obtained previously via other techniques. Thus, NMR imaging proved to be an efficient method for probing flocculant-induced precipitation in crude oils.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ
Держатели документа:
Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Akademgorodok 50-24, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Akademgorodok 50-24, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Pr Ak Lavrentieva 5, Novosibirsk 630090, Russia.
Novosibirsk State Univ, Pirogova St 2, Novosibirsk 630090, Russia.

Доп.точки доступа:
Martyanov, O. N.; Морозов, Евгений Владимирович; Russian Science Foundation [15-19-00119]
}
Найти похожие

11.

Magnetic and specific heat properties of YFe3(BO3)(4) and ErFe3(BO3)(4) / E. A. Popova [et al.] // J. Phys.: Condens. Matter. - 2010. - Vol. 22, Is. 11. - Ст. 116006, DOI 10.1088/0953-8984/22/11/116006. - Cited References: 26. - This work was supported by DFG grants 436 RUS and HE 3439/6 (FOR 520). The authors are indebted to M N Popova and B Z Malkin for valuable discussions. . - ISSN 0953-8984

РУБ Physics, Condensed Matter
Рубрики:
LINEAR-CHAIN ANTIFERROMAGNETISM
   CRYSTAL-STRUCTURE
   GDFE3(BO3)(4)
   MULTIFERROICS
   BA2COS3
   ORDER
Кл.слова (ненормированные):
Antiferromagnetic orders -- Basal planes -- Experimental data -- Magnetically ordered state -- Antiferromagnetism -- Calorimetry -- Erbium -- Magnetic moments -- Single crystals -- Specific heat -- Magnetic domains
Аннотация: The present paper reports on the specific heat and magnetization of the YFe3(BO3)(4) and ErFe3(BO3)(4) single crystals. In both compounds, antiferromagnetic order of the iron spins evolves at T-N = 38 K. The experimental data suggest that the magnetic moments are in the basal plane of the trigonal crystal for both compounds. In the magnetically ordered state the crystal is subdivided into three types of domains, the magnetic moments of the Fe3+ ions being aligned along the a axis within each domain. For ErFe3(BO3)(4), two non-equivalent magnetic positions of the Er3+ ions in each domain are observed.

WOS,
Scopus,
Читать в сети ИФ
Держатели документа:
[Popova, E. A.] Tech Univ, Moscow State Inst Elect & Math, Moscow 109028, Russia
[Vasiliev, A. N.] Moscow MV Lomonosov State Univ, Low Temp Phys & Superconduct Dept, Moscow 119991, Russia
[Temerov, V. L.
Bezmaternykh, L. N.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Tristan, N.
Klingeler, R.
Buechner, B.] Leibniz Inst Solid State & Mat Res IFW Dresden, D-01171 Dresden, Germany
ИФ СО РАН
Moscow State Institute of Electronics and Mathematics (Technical University), 109028 Moscow, Russian Federation
Low Temperature Physics and Superconductivity Department, Moscow State University, 119991 Moscow, Russian Federation
L v Kirensky Institute of Physics, Siberian Branch of RAS, Krasnoyarsk 660036, Russian Federation
Leibniz-Institute for Solid State and Materials Research IFW Dresden, D-01171 Dresden, Germany

Доп.точки доступа:
Popova, E. A.; Vasiliev, A. N.; Temerov, V. L.; Темеров, Владислав Леонидович; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Tristan, N.; Klingeler, R.; Buchner, B.
}
Найти похожие

12.

Heat capacity and thermal expansion study of relaxor-ferroelectric Ba0.92Ca0.08Ti0.76Zr0.24O3 / M. . Gorev [et al.] // J. Phys.: Condens. Matter. - 2004. - Vol. 16, Is. 39. - P. 7143-7150, DOI 10.1088/0953-8984/16/39/045. - Cited References: 18 . - ISSN 0953-8984

РУБ Physics, Condensed Matter
Рубрики:
CERAMICS
BA(TI1-XZRX)O-3
PEROVSKITES
Кл.слова (ненормированные):
Calorimetry -- Dielectric properties -- Ferroelectric materials -- Perovskite -- Phase transitions -- Solid solutions -- Specific heat -- Thermal expansion -- Adiabatic calorimetry -- Frequency dispersion -- Polar domains -- Relaxor ferroelectrics -- Barium compounds
Аннотация: Heat capacity and thermal expansion of the Ba0.92Ca0.08Ti0.76Zr0.24O3 compound is measured using the methods of adiabatic calorimetry and optic-mechanical dilatometry in the temperature range 100-370 K. Three blurred anomalies on the C-p(T) and alpha(T) dependencies are observed in the temperature range 200-360 K. The results of the studies are discussed together with data on the structure and dielectric properties in the framework of spherical random bond-random field model.

WOS,
Scopus,
Читать в сети ИФ
Держатели документа:
CNRS, CEMES, F-31055 Toulouse, France
ИФ СО РАН
L V kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Sciau, P.; Savariault, J. M.
}
Найти похожие

13.

Heat capacity study of relaxor PbMg1/3Nb2/3O3 in a wide temperature range / M. V. Gorev [et al.] // J. Exp. Theor. Phys. - 2003. - Vol. 96, Is. 3. - P. 531-537, DOI 10.1134/1.1567427. - Cited References: 21 . - ISSN 1063-7761

РУБ Physics, Multidisciplinary
Рубрики:
DIFFUSE PHASE-TRANSITION
FERROELECTRICS
Кл.слова (ненормированные):
Differential scanning calorimetry -- Mathematical models -- Phonons -- Random processes -- Specific heat -- Spectrum analysis -- Thermal effects -- Bond-random field models -- Wide temperature intervals -- Lead compounds
Аннотация: Heat capacity of the PbMg1/3Nb2/3O3 compound is measured using the methods of adiabatic and differential scanning calorimetry in the temperature range 80-750 K. Two blurred anomalies on the C-p(T) dependence are observed in wide temperature intervals of 200- 400 K and 500-700 K. The results of studies are discussed together with data on the structure and phonon spectrum in the framework of spherical random bond-random field model. (C) 2003 MAIK "Nauka/Interperiodica".

WOS,
Scopus,
Читать в сети ИФ
Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
CNRS, CEMES, F-31055 Toulouse, France
ИФ СО РАН
L. V. Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
CEMES-CNRS, 31055 Toulouse, France

Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Sciau, P.
}
Найти похожие

14.

Heat capacity study of relaxors BaTi0.65Zr0.35O3 and BaTi0.60Zr0.40O3 / M. . Gorev [et al.] // J. Phys.: Condens. Matter. - 2006. - Vol. 18, Is. 17. - P. 4407-4416, DOI 10.1088/0953-8984/18/17/026. - Cited References: 21 . - ISSN 0953-8984

РУБ Physics, Condensed Matter
Рубрики:
CERAMICS
BA(TI1-XZRX)O-3
BATIO3
Кл.слова (ненормированные):
Calorimetry -- Composition -- Data reduction -- Lead compounds -- Mathematical models -- Permittivity -- Specific heat -- Adiabatic calorimetry -- Burns temperature -- Diffuse anomalies -- Barium compounds
Аннотация: The heat capacity of two relaxors BaTi(1-x)ZrxO(3) (x = 0.35, 0.40) was measured using adiabatic calorimetry in the temperature range 100-360 K. The Cp(T) dependence of both compositions is characterized by the presence of two diffuse anomalies near the Burns temperature T-d and the temperature of the maximum in permittivity T-m in the temperature ranges 250-350 K and 120 200 K. The anomalous heat capacity near T-d was analysed taking into account the distribution of Zr concentration in nanoregions leading to the distribution of their transition temperatures into the polar phase. Excess heat capacity near Tm was discussed in the framework of the spherical random bond-random field model. The results are compared with the data obtained by the same procedures for PbMg1/3Nb2/3O3 studied experimentally earlier.

WOS,
Scopus,
Читать в сети ИФ
Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
CNRS, CEMES, F-31055 Toulouse, France
ИФ СО РАН
L V Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
CEMES-CNRS, 31055 Toulouse, France

Доп.точки доступа:
Gorev, M.; Bondarev, V.; Sciau, P.; Savariault, J. M.
}
Найти похожие

15.

    Bogdanov, E. V.
    Calorimetric study of the fluoro-oxygen crystal (ND4)2MoO2F4 / E. V. Bogdanov, E. I. Pogoreltsev // Proc. of int. conf. on therm. analys. and calorim. in Russia (RTAC-2016). - 2016. - Vol. I. - P. 181 . - ISBN 978-5-7422-5447-8
   Перевод заглавия: Калориметрические исследования фтор-кислородного кристалла (ND4)2MoO2F4

Материалы конференции

Доп.точки доступа:
Pogoreltsev, E. I.; Погорельцев, Евгений Ильич; Богданов, Евгений Витальевич; International conference on thermal analysis and calorimetry in Russia(2016 ; Sept. ; 16-23 ; Saint-Petersburg); Международная конференция по термическому анализу и калориметрии в России(15 ; 16 - 23 сентября 2016 г. ; г. Санкт-Петербург); Институт общей и неорганической химии им. Н.С. Курнакова РАНСанкт-Петербургский политехнический университет им. Петра Великого
}
Найти похожие

16.

    Диэлектрический метод измерения скрытой теплоты плавления льда при оттаивании мерзлой почвы / В. Л. Миронов [и др.] // Журн. радиоэлектрон. : электронный журнал. - 2018. - № 12. - Ст. 14, DOI 10.30898/1684-1719.2018.12.14. - Библиогр.: 14 . - ISSN 1684-1719
   Перевод заглавия: The dielectric method of measurement the latent heat of ice fusion during thawing of frozen soil
Кл.слова (ненормированные):
диэлектрическая модель -- диэлектрическая проницаемость -- мерзлые почвы -- незамерзшая вода -- незамерзающая вода -- связанная вода -- фазовые переходы -- дифференциальная сканирующая калориметрия -- dielectric model -- dielectric constant -- frozen soil -- unfrozen water -- nonfreezable water -- bound water -- phase transitions -- differential scanning calorimetry
Аннотация: Проведены экспериментальные исследования изменения массы незамерзшей воды, содержащейся в мерзлой Nа-бентонитовой глине в диапазоне температур от -30 до 0 °C и диапазоне массовых влажностей от 0 до 1 г/г с помощью диэлектрического метода. Предложен калориметрический метод измерения удельной скрытой теплоты плавления льда в связанную и несвязанную воду при нагревании мерзлой почвы. Предложен метод измерения скрытой теплоты плавления льда в мерзлой почве в процессе нагревания методом диэлектрических измерений. С целью обоснования предложенной методики проведено сравнение скрытой теплоты плавления льда при нагревании бентонитовой глины, полученной методом дифференциальной сканирующей калориметрии (ДСК), с рассчитанной с помощью диэлектрического метода.
Experimental studies of the change in the mass of unfrozen water contained in frozen Na-bentonite clay in the temperature range from -30 to 0 °C and a gravimetric moistures range from 0 to 1 g/g have been carried out by the dielectric method. The calorimetric method is proposed for measuring the specific latent heat of fusion of ice into bound and unbound water when the frozen soil is heated. The method of dielectric measurements is proposed for measuring the latent heat of fusion of ice in frozen soils during heating. In order to substantiate the proposed technique, the latent heat of fusion of ice in frozen bentonite clay measured by the differential scanning calorimetry during heating was compared with this value obtained by the dielectric method.

Смотреть статью,
РИНЦ,
Читать в сети ИФ,
Читать в сети ИФ
Держатели документа:
Институт физики им. Л.В. Киренского СО РАН, 660036, г. Красноярск, ул. Академгородок, 50/38

Доп.точки доступа:
Миронов, Валерий Леонидович; Mironov, V. L.; Каравайский, Андрей Юрьевич; Karavaisky, A. Yu.; Лукин, Юрий Иванович; Lukin, Y. I.; Погорельцев, Евгений Ильич; Pogoreltsev, E. I.
}
Найти похожие

17.

Flerov, I. N.
Conversial and inversial barocaloric effects around triple points in ferroelastics (NH4)3NbOF6 and (NH4)3TiOF5 / I. N. Flerov, M. V. Gorev, E. V. Bogdanov // 2nd Journale of Thermal analysis and calorimetry conference : book of abstracts. - 2019. - P. 489-490. - Cited References:. - The reported study was funded by RFBR according to the research project No 18-02-00269 . - ISBN 978-963-454-416-6

Материалы конференции,
Читать в сети ИФ
Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk
Institute of Engineering Systems and Energy, Krasnoyarsk State Agrarian University, Krasnoyarsk

Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Bogdanov, E. V.; Богданов, Евгений Витальевич; Флёров, Игорь Николаевич; Journale of Thermal Analysis and Calorimetry Conference(2 ; 2019 ; June. ; 18-21 ; Budapest, Hungary); Joint Czech-Hungarian-Polish-Slovakian) Thermoanalytical Conference(7 ; 2019 ; June. ; 18-21 ; Budapest, Hungary)
}
Найти похожие

18.

Mixed-valence hydrated iron fluoridotitanate: synthesis, optics and calorimetry / S. V. Mel'nikova, N. M. Laptash, M. V. Gorev, E. I. Pogoreltsev // J. Phys. Chem. Solids. - 2020. - Vol. 142. - Ст. 109444, DOI 10.1016/j.jpcs.2020.109444. - Cited References: 35 . - ISSN 0022-3697
Кл.слова (ненормированные):
Crystal growth -- Fluoridotitanate -- Mixed valence -- Phase transition -- Optical properties -- Heat capacity
Аннотация: Mixed-valence hydrated fluoridotitanate with idealized formula FeTiF6·6H2O is the main product of fluoride processing of natural mineral ilmenite with hydrofluoric acid. Its single crystals were grown and optical and calorimetric experiments were carried out in the temperature range 200–350 K. Charge re-distribution, Fe2+Ti4+ to Fe3+Ti3+, in the compound studied was evident in XPS spectra. A first order ferroelastic phase transition occurs at temperatures T0↓ = 271.5 K, T0↑ = 274 ÷ 275.5 K with the symmetry change P3‾↔ P1‾. The structural transformation is accompanied by the appearance of a very weak optical anisotropy in the slice (001), a small anomaly of the heat capacity (ΔS = 1.5 J/mol K = 0.2R), and positive baric coefficients dT0/dp ≈ 30 ± 10 K/GPa.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ
Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Chemistry, Far Eastern Branch of RAS, Vladivostok, 690022, Russian Federation
Siberian Federal University, Krasnoyarsk, 660074, Russian Federation

Доп.точки доступа:
Mel'nikova, S. V.; Мельникова, Светлана Владимировна; Laptash, N. M.; Gorev, M. V.; Горев, Михаил Васильевич; Pogoreltsev, E. I.; Погорельцев, Евгений Ильич
}
Найти похожие

19.

Synthesis, structure, and thermophysical properties of EuGaGe2O7 / L. T. Denisova, M. S. Molokeev, L. A. Irtyugo [et al.] // Inorg. Mater. - 2020. - Vol. 56, Is. 8. - P. 854-858, DOI 10.1134/S002016852008004X. - Cited References: 18 . - ISSN 0020-1685. - ISSN 1608-3172

РУБ Materials Science, Multidisciplinary
Рубрики:
TEMPERATURE HEAT-CAPACITY
THERMODYNAMIC PROPERTIES
CRYSTAL-STRUCTURE
Кл.слова (ненормированные):
europium gallium germanate -- solid-state synthesis -- differential scanning calorimetry -- heat capacity -- structure -- thermodynamic properties
Аннотация: The europium gallium germanate EuGaGe2O7 has been prepared by solid-state reaction in air in the temperature range 1273–1473 K using a stoichiometric mixture of Eu2O3, Ga2O3, and GeO2. Its crystal structure has been determined by X-ray diffraction (sp. gr. P21/c, a = 7.1693(7) Å, b = 6.57008(6) Å, c = 12.7699(1) Å, β = 117.4522(5)°, V = 533.768(8) Å3). The heat capacity of polycrystalline samples has been determined by differential scanning calorimetry in the temperature range 350–1053 K and the experimental data have been used to calculate the thermodynamic properties (enthalpy increment, entropy change, and reduced Gibbs energy change) of EuGaGe2O7.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ

Публикация на русском языке Синтез, структура и теплофизические свойства EuGaGe2O7 [Текст] / Л. Т. Денисова, М. С. Молокеев, Л. А. Иртюго [и др.] // Неорган. матер. - 2020. - Т. 56 № 8. - С. 901-905

Держатели документа:
Siberian Fed Univ, Inst Nonferrous Met & Mat Sci, Svobodnyi Pr 79, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Siberian Branch, Fed Res Ctr, Kirensky Inst Phys,Krasnoyarsk Sci Ctr, Akademgorodok 50-38, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Ul Akad Kirenskogo 28-12 B, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Baikov Inst Met & Mat Sci, Leninskii Pr 49, Moscow 119991, Russia.

Доп.точки доступа:
Denisova, L. T.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Irtyugo, L. A.; Beletskii, V. V.; Kargin, Yu. F.; Denisov, V. M.
}
Найти похожие

20.

    Structure and properties of phases in the Cu2-ХSe-Sb2Se3 system. The Cu2-XSe-Sb2Se3 phase diagram / M. A. Shtykova, M. S. Molokeev, B. A. Zakharov [et al.] // J. Alloys Compd. - 2022. - Vol. 906. - Ст. 164384, DOI 10.1016/j.jallcom.2022.164384. - Cited References: 111. - The research was supported for R.S. Bubnova by the Ministry of Science and Higher Education of the Russian Federation within the scientific tasks of the Institute of Silicate chemistry (Russian Academy of Sciences) [project number 0097-2019-0013]. The equipment of Research and Education Center "Molecular design and ecologically safe technologies" (Novosibirsk State University) was used for single-crystal X-ray diffraction experiments. BAZ and EVB acknowledge support by the Ministry of Science and Higher Education, project AAAA-A21-121011390011-4 . - ISSN 0925-8388
   Перевод заглавия: Структура и свойства фаз в системе Cu2-xSe-Sb2Se3; фазовая диаграмма Cu2-xSe-Sb2Se3
Кл.слова (ненормированные):
Phase equilibria -- Phase diagram -- High-temperature X-ray diffraction -- Redlich-Kister polynomial model -- Scanning electron microscopy -- Differential scanning calorimetry
Аннотация: The phase diagram of the Cu2−XSe-Sb2Se3 system is revisited to clarify ambiguity/disagreement in previously reported data. Ternary Cu3SbSe3 and CuSbSe2 compounds were obtained. In order to confirm that the phases have been identified correctly, crystal structures were solved, and the energy band gaps measured. For the sample containing 75 mol% Sb2Se3 and 25 mol% Cu1.995Se the temperature range of the stability of the high-temperature CuSb3Se5 phase was determined for the first time. This phase is formed at 445 °С, decomposes following a peritectic reaction at 527 °С, and can be quenched. A high-temperature X-ray diffraction study of a sample containing 75 mol% Sb2Se3 and 25 mol% Cu2Se allowed us to measure the thermal expansion of the CuSbSe2 and Sb2Se3 phases present in the sample. The anisotropy of thermal expansion of CuSbSe2 is similar to that of As2S3 (orpiment); thermal expansion of Sb2Se3 is similar to that of AsS (realgar). The 6 balance equations of the invariant phase transformations involving all the ternary compounds existing in the Cu2−XSe-Sb2Se3 system were suggested for the first time. The temperature and the enthalpies of all these transformations were measured. A phase diagram of the Cu2−XSe-Sb2Se3 system was found for the first time in all the range of concentrations at temperatures from ambient to the complete melting. This diagram takes into consideration the phase equilibria that involve all the ternary compounds that are possible in this system. The liquidus of the Cu2−XSe-Sb2Se3 system was calculated according to Redlich-Kister equation; it agrees with the experimental data within 1–17 °С.

Смотреть статью,
Scopus,
Читать в сети ИФ
Держатели документа:
Department of Inorganic and Physical Chemistry, Institute of Chemistry, Tyumen State University, Volodarsky str. 6, Tyumen, 625003, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Akademgorodok Str. 50, Building 38, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Svobodnyj av. 79, Krasnoyarsk, 660079, Russian Federation
Boreskov Institute of Catalysis SB RAS, Lavrentiev Ave. 5, Novosibirsk, 630090, Russian Federation
Novosibirsk State University, Pirogova str. 2, Novosibirsk, 630090, Russian Federation
Department of Condensed Matter Physics and Nanoscale Systems, Institute of Natural Sciences and Mathematics, Ural Federal University, Mira str. 19, Yekaterinburg, 620002, Russian Federation
Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, Makarov Emb., 2, St. Petersburg, 199034, Russian Federation
Department of Physical and Applied Chemistry, Institute of Natural Sciences and Mathematics, Kurgan State University, Sovetskaya str. 2, b. 4, Kurgan, 640020, Russian Federation
Laboratory of Electron and Probe Microscopy, REC “Nanotechnology”, Tyumen State University, Volodarsky str. 6, Tyumen, 625003, Russian Federation
Engineering Center of Composite Materials Based on Tungsten Compounds and Rare Earth Elements, Tyumen State University, Volodarsky str. 6, Tyumen, 625003, Russian Federation
Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Pervomaiskaya str. 91, Yekaterinburg, 620990, Russian Federation

Доп.точки доступа:
Shtykova, M. A.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zakharov, B. A.; Selezneva, N. V.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Bubnova, R. S.; Kamaev, D. N.; Gubin, A. A.; Habibullayev, N. N.; Matigorov, A. V.; Boldyreva, E. V.; Andreev, O. V.
}
Найти похожие