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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Павлов А. В., Квеглис, Людмила Иосифовна, Джес А. В., Сапрыкин Д. Н., Насибуллин Р. Т., Великанов, Дмитрий Анатольевич, Немцев, Иван Васильевич, Шалаев П. О.
Заглавие : Магнетизм бериллиевой керамики со структурой перовскита BeTiO3
Место публикации : Фундамент. пробл. совр. материаловед. - 2022. - Т. 19, № 1. - С. 115-124. - ISSN 1811-1416, DOI 10.25712/ASTU.1811-1416.2022.01.013; Basic Probl. Mater. Sci.
Примечания : Библиогр.: 24
Аннотация: Известно, что введение в ВеО-керамику добавки TiO2 после термообработки в восстановительной атмосфере сопровождается значительным увеличением электропроводности и способностью поглощать электромагнитное излучение в широком диапазоне частот. До сих пор механизм этого влияния до конца не установлен. С использованием методов Лоренцевой электронной микроскопии в сканирующем электронном микроскопе, а также вибрационного магнитометра, установлено проявление ферромагнетизма. Такая особенность бериллиевой керамики способствует поглощению электромагнитной энергии в объемных образцах, содержащих наночастицы TiO2. Установлено, что присутствие наночастиц способствует формированию структуры перовскита в зонах спекания BeO + TiO2. В структуре перовскита возможна поляризация молекул за счет формирования поляронов, что приводят к деформации решетки и смещению атомов. В результате такого смещения происходит изменение ближнего порядка в структуре перовскита и к образованию икосаэдрической фазы из исходной фазы со структурой кубоктаэдра. Малый размер атома бериллия позволяет организоваться тетраэдрической плотной упаковке в форме икосаэдра из атомов кислорода вокруг центрального атома бериллия. В результате повышается атомная плотность и плотность электронных состояний на уровне Ферми. Предлагаются модели для объяснения причины появления ферромагнетизма и электропроводности, которые обнаружены в бериллиевой керамике. С помощью метода спин-поляризованных электронов проведены расчеты электронной структуры нанокластеров с различным ближним порядком.It is known that the introduction of TiO2 additives into BeO ceramics after heat treatment in a reducing atmosphere is accompanied by a significant increase in electrical conductivity and the ability to absorb electromagnetic radiation in a wide frequency range. Until now, the mechanism of this influence has not been fully established. Using the methods of Lorentzian electron microscopy in a scanning electron microscope, as well as a vibration magnetometer, the manifestation of ferromagnetism was established. This feature of beryllium ceramics promotes the absorption of electromagnetic energy in bulk samples containing TiO2 nanoparticles. It was found that the presence of nanoparticles promotes the formation of the perovskite structure in the BeO + TiO2 sintering zones. In the structure of perovskite, polarization of molecules is possible due to the formation of polarons, which leads to deformation of the lattice and displacement of atoms. As a result of this displacement, a change in the short-range order in the perovskite structure occurs and to the formation of an icosahedral phase from the initial phase with a cuboctahedral structure. The small size of the beryllium atom makes it possible to organize a tetrahedral close packing in the form of an icosahedron of oxygen atoms around the central beryllium atom. As a result, the atomic density and the density of electronic states at the Fermi level increase. Models are proposed to explain the reasons for the appearance of ferromagnetism and electrical conductivity found in beryllium ceramics. Using the spin-polarized electron method, the electronic structure of nanoclusters with different short-range orders has been calculated.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golovnev N. N., Molokeev M. S., Sterkhova I. V., Lesnikov M. K.
Заглавие : Two novel mixed-ligand Ni(II) and Co(II) complexes with 1,10-phenanthroline: Synthesis, structural characterization, and thermal stability
Место публикации : Chem. Phys. Lett. - 2018. - Vol. 708. - P.11-16. - ISSN 00092614 (ISSN), DOI 10.1016/j.cplett.2018.07.058
Примечания : Cited References: 29. - The study was carried out within the public task of the Ministry of Education and Science of the Russian Federation to the Siberian Federal University (4.7666.2017/BP) in 2017-2019. X-ray data from single crystals were obtained with use the analytical equipment of Baikal Center of collective use of SB RAS and with use the analytical equipment of Krasnoyarsk Center of collective use of SB RAS.
Ключевые слова (''Своб.индексиров.''): barbituric acid--1,10-phenanthroline complexes--x-ray diffraction--thermal decomposition--infrared spectroscopy
Аннотация: Two nickel(II) and cobalt(II) complexes with phenanthroline, [Ni(Phen)(H2O)3Br]Br (1) and [Co(Phen)2(H2O)2](Hba)2·2H2O (2), Phen = 1,10-phenanthroline and Hba− = barbiturate anion, were synthesized and characterized by powder XRD, TGA and FT-IR. Their structures were determined by single crystal X-ray diffraction techniques. The Ni2+ ion is coordinated by two N atoms of Phen molecule, Br− ion and three H2O molecules forming an octahedron. Uncoordinated and coordinated Br− ions are connected with water molecules by OH⋯Br intermolecular hydrogen bonds with the formation of a 2D plane network which is extended into a 3D network by π−π stacking interactions. The [Co(Phen)2(H2O)2]2+ cation contains a six-coordinated cobalt atom chelated by two Phen ligands and two aqua ligands in the cis arrangement. NH⋯O, OH⋯O and CH⋯O intermolecular hydrogen bonds form a 3D net. NH⋯O hydrogen bonds form the infinite chains of Hba–. In addition, coordinated Phen molecules and lattice water molecules are linked via CH⋯OW hydrogen bonds to form infinite zigzag chains. These different chains are connected by OWH⋯O hydrogen bonds. π−π interaction plays an important role in the stabilization of structures 1–2. FT-IR, TGA, the diffuse reflectance, and UV–Vis spectra were also used to characterize these compounds.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Xia Z., Liu G., Wen J., Mei Z., Balasubramanian M., Molokeev M. S., Peng L., Gu L., Miller D. J., Liu Q., Poeppelmeier K. R.
Заглавие : Tuning of photoluminescence by cation nanosegregation in the (CaMg)x(NaSc)1-xSi2O6 solid solution
Место публикации : J. Am. Chem. Soc.: American Chemical Society, 2016. - Vol. 138, Is. 4. - P.1158-1161. - ISSN 00027863 (ISSN), DOI 10.1021/jacs.5b12788
Примечания : Cited References: 23. - Work performed by Z.X. and Q.L. was supported by the National Natural Science Foundation of China (51272242 and 51572023), the Program for New Century Excellent Talents in the University of the Ministry of Education of China (NCET-12-0950), and the Beijing Nova Program (Z131103000413047). Work performed by G.L., J.W., Z.M., M.B., and D.J.M. at Argonne National Laboratory was supported by the Office of Basic Energy Sciences of the U.S. Department of Energy (DOE) through Grant DE-AC02-06CH11357 for research on heavy elements chemistry and materials sciences. TEM was accomplished in part at the Center for Nanoscale Materials, a DOE Office of Science User Facility under Contract DE-AC02-06CH11357. Sector 20 operations at APS are supported by DOE and the Canadian Light Source, with additional support from the University of Washington. G.L. acknowledges travel support from the CAS/SAFEA International Partnership Program for Creative Research Teams. K.R.P. gratefully acknowledges support from the National Science Foundation (DMR-1307698).
Предметные рубрики: SPINODAL DECOMPOSITION
ENERGY-TRANSFER
EXSOLUTION
CLINOPYROXEN
NANOCRYSTALS
SEGREGATION
MECHANISMS
PYROXENESS
JERVISITE
PHOSPHORS
Аннотация: Controlled photoluminescence tuning is important for the optimization and modification of phosphor materials. Herein we report an isostructural solid solution of (CaMg)x(NaSc)1-xSi2O6 (0 < x < 1) in which cation nanosegregation leads to the presence of two dilute Eu2+ centers. The distinct nanodomains of isostructural (CaMg)Si2O6 and (NaSc)Si2O6 contain a proportional number of Eu2+ ions with unique, independent spectroscopic signatures. Density functional theory calculations provided a theoretical understanding of the nanosegregation and indicated that the homogeneous solid solution is energetically unstable. It is shown that nanosegregation allows predictive control of color rendering and therefore provides a new method of phosphor development. © 2016 American Chemical Society.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Myagkov V. G., Matsunin A. A., Mikhlin Y. L., Zhigalov V. S., Bykova L. E., Tambasov I. A., Bondarenko G. N., Patrin G. S., Velikanov D. A.
Заглавие : Synthesis of ferromagnetic germanides in 40Ge/60Mn films: Magnetic and structural properties
Коллективы : Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism
Место публикации : Solid State Phenom.: Selected, peer reviewed papers/ ed. S. G. Ovchinnikov: Trans Tech Publications, 2014. - Vol. 215: Trends in Magnetism: Nanomagnetism (EASTMAG-2013). - P.167-172. - ISSN 978-303835054-5, DOI 10.4028/www.scientific.net/SSP.215.167. - ISSN 1662-9779
Примечания : Cited References: 28
Ключевые слова (''Своб.индексиров.''): diluted semiconductors--manganese germanides--solid-state reactions--spinodal decomposition
Аннотация: Solid-state reactions between Ge and Mn films are systematically examined using X-ray diffraction, photoelectron spectroscopy and magnetic measurements. The films have a nominal atomic ratio Ge:Mn = 40:60 and are investigated at temperatures from 50 to 500 °C. It is established that after annealing at ~120 °C, the ferromagnetic Mn5Ge phase is the first phase to form at the 40Ge/60Mn interface. Increasing the annealing temperature to 500 °C leads to the formation of the ferromagnetic phase with a Curie temperature TC ~ 360 K and magnetization MS ~ 140-200 emu/cc at room temperature. Analysis of X-ray diffraction patterns and the photoelectron spectra suggests that the increased Curie temperature and magnetization are related to the migration of C and O atoms into the Mn5Ge3 lattice and the formation of the Nowotny phase Mn5GeXCxOy. The initiation temperature (~120 °C) of the Mn5Ge3 phase is the same both for solid-state reactions in Ge/Mn films, as well as for phase separation in GexMn1-x diluted semiconductors. We conclude that the synthesis of the Mn5Ge3 phase is the moving force for the spinodal decomposition of the GexMn1-x diluted semiconductors. © (2014) Trans Tech Publications, Switzerland.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golovnev N. N., Molokeev M. S., Vereshchagin S. N., Atuchin V. V.
Заглавие : Synthesis and thermal transformation of a neodymium(III) complex [Nd(HTBA)2(C2H3O2)(H2O)2]·2H2O to non-centrosymmetric oxosulfate Nd2O2SO4
Коллективы : Ministry of Education and Science of the Russian Federation
Место публикации : J. Coord. Chem.: Taylor & Francis, 2015. - Vol. 68, Is. 11. - P.1865-1877. - ISSN 0095, DOI 10.1080/00958972.2015.1031119. - ISSN 10290389(eISSN)
Примечания : Cited References:59. - The study was carried out within the public task of the Ministry of Education and Science of the Russian Federation for research engineering at the Siberian Federal University in 2014. V.V.A. is grateful to the Ministry of Education and Science of the Russian Federation for the financial support of this investigation.Cover image: Artwork representing main idea of this article
Предметные рубрики: THIOBARBITURIC ACID COMPLEXES
TRANSITION-METAL-COMPLEXES
Ключевые слова (''Своб.индексиров.''): neodymium--2-thiobarbituric acid--crystal structure--thermal--decomposition--ir spectroscopy
Аннотация: Neodymium complex [Nd(HTBA)2(C2H3O2)(H2O)2]n·2nH2O (1) (H2TBA = 2-thiobarbituric acid, C4H4N2O2S) has been synthesized in an aqueous solution at 80–90 °C. The crystal structure of 1 has been determined by the Rietveld method in space group P21/n, a = 8.5939(2), b = 22.9953(5), c = 10.1832(2) Å, β = 112.838(1)°, Z = 4, and R = 0.0181. In 1, the Nd(III) is coordinated by four μ2-HTBA– ions through O, three oxygens from two μ2-η2 : η1-bridging CH3COO– anions, and two terminal waters with a tri-capped trigonal prism structure. The prisms form an edge-contact pair through two O from two acetates. The pairs are connected by HTBA– and form a 3-D framework. The principle product of thermal decomposition of 1 at 750 °C is Nd2O2SO4 (2). The crystal structure of 2 has been obtained in space group I222, a = 4.1199(4), b = 4.2233(4), c = 13.3490(12) Å, Z = 2, and R = 0.0246. The structure is related to an orthorhombic structure type of M2O2SO4 (M = Ln) compounds. In 2, the Nd3+ is coordinated by six oxygens in a trigonal prism. Each NdO6 prism links with two SO4 tetrahedra by nodes, with four other NdO6 prisms by edges, and with four other NdO6 prisms by nodes, and the units form the 3-D frame. In the frame, the layers of SO4 tetrahedra are alternated by two NdO6 prism layers.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Li, Oksana A., Lin, Chun-Rong, Chen, Hung-Yi, Hsu, Hua-Shu, Wu, Kai-Wun, Tseng, Yaw-Teng, Bayukov O. A., Edelman I. S., Ovchinnikov S. G., Shih, Kun-Yauh
Заглавие : Structural and magnetic properties of Fe1−xCoxSe1.09 nanoparticles obtained by thermal decomposition
Место публикации : Mater. Res. Express: IOP Publishing, 2015. - Vol. 2, No. 12. - Ст.126501. - ISSN 2053-1591, DOI 10.1088/2053-1591/2/12/126501
Примечания : Cited References: 30. - This work is supported by the Ministry of Science and Technology of Taiwan (MOST103-2811-M-153 -001 and MOST102-2112-M-153 -002 -MY3).
Предметные рубрики: X-RAY-DIFFRACTION
MOSSBAUER-SPECTROSCOPY
CRYSTAL-STRUCTURES
IRON SELENIDES
SUPERCONDUCTIVITY
FeSe
MARCASITE
PYRITE
Ключевые слова (''Своб.индексиров.''): nanoparticles--chalcogenide--iron-cobalt selenide--ferrimagnetism--paramagnetism--mossbauer spectroscopy
Аннотация: A series of Fe1−xCoxSe1.09 (x = 0 to ) nanoparticles were synthesized by thermal decomposition method. Particles in composition range Fe0.5Co0.5Se1.09 to CoSe1.09 crystallized in monoclinic structure of Co6.8Se8 , while FeSe1.09 crystallized in hexagonal structure of FeSe achavalite. Magnetization dependences on temperature and external magnetic field reveal complicated magnetic behavior and correspond to the sum of paramagnetic and superparamagnetic response. Mössbauer spectra contain several paramagnetic doublets with parameters corresponding to nonequivalent positions of divalent and trivalent iron cations with low spin. The nonequivalent positions appeared due to inhomogeneous distribution of Co ions or metal vacancies in iron surrounding.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bukhtiyarova G. A., Mart'yanov O. N., Yakushkin S. S., Shuvaeva M. A., Bayukov O. A.
Заглавие : State of iron in nanoparticles prepared by impregnation of silica gel and aluminum oxide with FeSO4 solutions
Коллективы :
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2010. - Vol. 52, Is. 4. - P826-837. - ISSN 1063-7834, DOI 10.1134/S1063783410040268
Примечания : Cited References: 27. - This study was supported by the Presidium of the Russian Academy of Sciences within the framework of the Program no. 27 "Principles of Basic Research of Nanotechnologies and Nanomaterials," Project no. 46 "Magnetically Ordered Nanoparticles in Catalytic Systems: Synthesis, Evolution, and Physicochemical Properties."
Предметные рубрики: THERMAL-DECOMPOSITION
BETA-FEOOH
MOSSBAUER
FERRIHYDRITE
EPSILON-FE2O3
FE-2(SO4)(3)
SULFATE
FE-57
Аннотация: The state of iron in nanoparticles prepared by impregnating silica gel and aluminum oxide with iron(II) sulfate solutions has been investigated using Mossbauer spectroscopy. It has been revealed that the state of iron depends on the nature of the support. Iron(III) hydroxysulfate and iron(III) oxysulfate nanoparticles are formed on the surface of silica gel, and iron oxide nanoparticles are formed on the surface of aluminum oxide. An increase in the concentration of iron ions or in the size of iron-containing particles leads to hydration of the nanoparticle surface. The calcination of the samples results in the formation of E -Fe2O3 oxide in a strongly disordered or amorphous state in iron-containing particles on the surface of silica gel.
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Вид документа : Статья из сборника (однотомник)
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Автор(ы) : Goryainov S. V., Krylov A. S., Likhacheva A. Y., Prasad P. S. R., Vtyurin A. N.
Заглавие : Raman study of thaumasite and its decomposition at simultaneously high P-T parameters
Коллективы : "GeoRaman", International conference, Российская академия наук, Сибирское отделение РАН, Институт геологии и минералогии им. В.С. Соболева Сибирского отделения РАН
Место публикации : XII Int. conf. "GeoRaman-2016": abstract volume/ compiled and edited by T.A. Alifirova, S.V. Rashchenko, A.V. Korsakov. - Novosibirsk: Офсет, 2016. - P.22. - ISBN 978-5-85957-124-6
Примечания : References: 1. - This work was supported by the Russian Foundation for Basic Research (projects No. 14-05-00616 and 15-55-45070-IND) and the Russian Science Foundation (project No. 15-17-30012).
Аннотация: Thaumasite Ca3Si(OH)6(SO4)(CO3)12H2O is extraordinary mineral that possibly plays particular role in silicate-sulfate-carbonate balance of the Earth‟s interiors. High pressure behavior of thaumasite was studied only in He medium at room T [1]. We present Raman spectroscopy study of thaumasite compressed in water at simultaneously high P-T conditions up to ~300 °C and ~2 GPa, in order to elucidate possible non-quenchable states (polymorphism, overhydration, reversible amorphization and dehydration), as well as its decomposition. Raman bands of thaumasite diminish in intensity and widen in the range of 200-300 °C (Fig. 1). Thaumasite crystals are partly dissolved in water. After the release of high P-T, strong band at 991 cm–1 shifts to 985 cm –1, corresponding to partly disordered thaumasite. The stability range of thaumasite is extended up to ~250 °C at ~2 GPa. At 300 °C and ~2 GPa, thaumasite is decomposed to aragonite, gypsum and partly amorphous silicate within 30 min.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Volova T. G., Vinogradova O. N., Zhila N. O., Peterson I. V., Kiselev E. G., Vasiliev A. D., Sukovatiy A. G., Shishatskaya E. I.
Заглавие : Properties of a novel quaterpolymer P(3HB/4HB/3HV/3HHx)
Место публикации : Polymer: Elsevier, 2016. - Vol. 101. - P.67-74. - ISSN 00323861 (ISSN), DOI 10.1016/j.polymer.2016.08.048
Ключевые слова (''Своб.индексиров.''): physicochemical and mechanical properties--polyhydroxyalkanoates--quaterpolymers--biocompatibility--cell culture--chain length--chains--decomposition--3-hydroxyhexanoate--degrees of crystallinity--elongation at break--physico-chemical and mechanical properties--polyhydroxyalkanoates--quaterpolymers--short chain lengths--thermal decomposition temperature--film preparation
Аннотация: Cupriavidus eutrophus В10646 was used to synthesize a series of polyhydroxyalkanoate (PHA) quaterpolymers composed of the short-chain-length 3-hydroxybutyrate (3HB), 4-hydroxybutyrate (4HB), and 3-hydroxyvalerate (3HV) and the medium-chain-length 3-hydroxyhexanoate (3HHx). The molar fraction of 3HB in the quaterpolymers varied between 63.5 and 93.1 mol.%, 3HV – between 1.1 and 24.6 mol.%, 4HB – between 2.4 and 15.6 mol.%, and 3HHx – between 0.4 and 4.8 mol.%. The properties of PHA quaterpolymers were significantly different from those of the P(3HB) homopolymer: they had much lower degrees of crystallinity (up to 30–45%), and lower melting points and thermal decomposition temperatures, with the interval between these temperatures remaining practically unchanged. Films prepared from PHA quaterpolymers were rougher and more porous than P(3HB) films; they showed higher values of elongation at break (up to 6–113%), i.e. were more elastic. Films prepared from PHA quaterpolymers were biocompatible and had no toxic effect on mouse fibroblast NIH 3T3 cells. © 2016 Elsevier Ltd
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golovnev N. N., Gerasimova M. A., Molokeev M. S., Plyaskin M. E., Baronin M. E.
Заглавие : Photoluminescence of pefloxacindi-ium manganese(II) and zinc(II) tetrahalides
Место публикации : J. Mol. Struct. - 2022. - Vol. 1248. - Ст.131468. - ISSN 00222860 (ISSN), DOI 10.1016/j.molstruc.2021.131468
Примечания : Cited References: 42. - The research was funded by RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, project number 20-43-240007. Authors thank the Centre for Equipment Joint User of School of Petroleum and Natural Gas Engineering of Siberian Federal University, Institute of Chemistry and Chemical Technology SB RAS for their technical support
Аннотация: Mn2+-based hybrid materials have become the hotspot of current research studies owing to their high photoluminescence quantum yield (PLQY), low-cost, environmental friendliness and stability. For the first time, we report the hydrothermal synthesis of two lead-free zero-dimensional luminescent organic-inorganic hybrid compounds, PefH2[MnBr4] (1) and PefH2[MnCl4] (2) (Pef = pefloxacin). They were characterized by elemental analysis, TG-DSC, single-crystal and powder XRD. Compounds 1–2 exhibit a distorted tetrahedral geometry around the manganese(II) metal center, which is isolated from the same centers by bulky pefloxacindi-ium (PefH22+) ions with a Mn···Mn distance of 7.3 Å. Their structures are stabilized by N—H···O, O—H···X (X = Br, Cl), C—H···O and C—H···X hydrogen bands and π–π stacking interaction. Thermal decomposition starts at T › 230°С for 1 and T › 210°С for 2 and proceeds for several stages. Upon UV excitation compounds exhibit a bright green emission with a moderate PLQY of 45% for 1 and 30% for 2. The influence of the halide ion and metal ion on the photoluminescence properties of isostructural compounds PefH2[MX4] (M = Mn, Zn and X = Br, Cl) is discussed.
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