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    Структура и оптические свойства самоорганизованных ансамблей нематических доменов на поверхности поликарбоната / А. М. Паршин, В. А. Гуняков, В. Я. Зырянов, В. Ф. Шабанов // Жидк. крист. и их практич. использ. - 2022. - Т. 22, № 1. - С. 84-88 ; Liq. Cryst. Appl. ; Zidk. Krist. Prakt. Ispol'z., DOI 10.18083/LCAppl.2022.1.84. - Библиогр.: 9 . - ISSN 1991-3966. - ISSN 2499-9644
   Перевод заглавия: Structure and optical properties of self-organized nematic domains ensembles on polycarbonate surface
Кл.слова (ненормированные):
нематик -- поликарбонат -- структура -- переориентация директора -- интерференция -- nematic -- polycarbonate -- structure -- director reorientation -- interference
Аннотация: Рассмотрено структурное упорядочение самоорганизованных ансамблей нематических доменов с радиально-планарной конфигурацией, формирующихся на поверхности поликарбоната. Под влиянием теплового, упругого, электрического или магнитного полей структура доменов трансформируется в радиально-гомеотропную. При переориентации директора в данных структурах наблюдаются интерференционные осцилляции проходящего света с большой глубиной модуляции в отсутствие поляризаторов, что позволяет оценивать их как перспективный материал для оптических модуляторов.
The structural ordering of self-organized ensembles of nematic domains (SEND) with a radial-planar configuration, which are formed on the polycarbonate surface, is considered. The domain structure is transformed into radialhomeotropic one under the influence of a thermal, elastic, electric or magnetic fields. Interference oscillations of transmitted light with a large modulation depth are observed in the absence of polarizers, when the director is reoriented in these structures, which makes it possible to evaluate them as a promising material for optical modulators.

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Держатели документа:
Институт физики им. Л. В. Киренского, Федеральный исследовательский центр КНЦ СО РАН, Красноярск, Россия
Сибирский Федеральный университет, Красноярск, Россия

Доп.точки доступа:
Паршин, Александр Михайлович; Parshin, A. M.; Гуняков, Владимир Алексеевич; Gunyakov, V. A.; Зырянов, Виктор Яковлевич; Zyryanov, V. Ya.; Шабанов, Василий Филиппович; Shabanov, V. F.

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    Bipolar-homogeneous structural phase transition in nematic droplets formed in the polymer matrix in a magnetic field / A. M. Parshin [et al.] // Crystallogr. Rep. - 2009. - Vol. 54, Is. 7. - P1191-1196, DOI 10.1134/S1063774509070098. - Cited Reference Count: 19. - Гранты: This study was supported by the Council on Grants from the President of the Russian Federation for the Support of Leading Scientific Schools ( grant no. NSh-3818.2008.3), the Russian Foundation for Basic Research ( project no. 08-03-01007), the Presidium of the Russian Academy of Sciences ( project no. 27.1), and the Siberian Branch of the Russian Academy of Sciences ( project nos. 110 and 144). - Финансирующая организация: President of the Russian Federation [NSh-3818.2008.3]; Russian Foundation for Basic Research [08-03-01007]; Russian Academy of Sciences [27.1, 110, 144] . - DEC. - ISSN 1063-7745
Рубрики:
DISPERSED LIQUID-CRYSTALS
   FRANK CONSTANTS
   ALIGNMENT
Кл.слова (ненормированные):
Bipolar configuration -- Bipolar structure -- Cyanobiphenyls -- Homogeneous structure -- Mutual transformations -- Nematic director -- Nematic droplets -- Order parameter -- Poly(vinyl butyral) -- Structural phase transition -- Temperature range -- Thermal fluctuations -- Crystal structure -- Drop formation -- Liquid crystals -- Magnetic fields -- Nematic liquid crystals -- Phase transitions
Аннотация: The phase transition from the bipolar structure to the homogeneous structure in droplets formed from the nematic liquid crystal 4-n-pentyl-4'-cyanobiphenyl in poly(vinyl butyral) in the presence of a magnetic field has been investigated. The phase transition is associated with the expansion of the regions with a tilted orientation of the director in the vicinity of defects (the disappearance of boojums) and with the alignment of the nematic director lines in the bulk of the droplet in the direction of the magnetic field. In the temperature range T = 24-34A degrees C, cyclic mutual transformations between the bipolar configuration of the nematic director and the homogeneous structure, which have a period of similar to 0.5-3.5 s and result from thermal fluctuations of the order parameter, are observed in droplets 3-15 A mu m in size after the forming field is switched off.

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Держатели документа:
Russian Acad Sci, Siberian Branch, Krasnoyarsk Sci Ctr, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia

Доп.точки доступа:
Parshin, A. M.; Паршин, Александр Михайлович; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Shabanov, V. F.; Шабанов, Василий Филиппович; Nazarov, V. G.
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Inverse mode of ion-surfactant method of director reorientation inside nematic droplets / M. N. Krakhalev, O. O. Prishchepa, V. Y. Zyryanov // Mol. Cryst. Liquid Cryst. - 2009. - Vol. 512, Is. 1. - P. 1998-2003, DOI 10.1080/15421400903050814. - Cited Reference Count: 8. - Гранты: This work was partially supported by the grants Nos. NSh-3818.2008.3; 02.740.11.0220, and No. 08-03-01007 of RFBR, and Nos. 27.1; 110; 144 of SB RAS. M. Krakhalev acknowledges the financial support from K. I. Zamaraev MBN Foundation. O. Prishchepa acknowledges the financial support from Russian Science Support Foundation. - Финансирующая организация: RFBR [NSh-3818.2008.3, 02.740.11.0220, 08-03-01007]; SB RAS [27.1; 110; 144]; Zamaraev MBN Foundation; Russian Science Support Foundation . - ISSN 1542-1406
Кл.слова (ненормированные):
electrically commanded surfaces -- ion surfactant -- nematic -- polymer dispersed liquid crystals -- surface anchoring -- Electrically commanded surfaces -- Ion surfactant -- Nematic -- Polymer dispersed liquid crystals -- Surface anchoring -- Applied voltages -- Crossed polarizers -- Director fields -- Director reorientation -- Droplet structure -- Electrically commanded surfaces -- High concentration -- Homeotropic -- Initial state -- Ionic modification -- Liquid-crystal droplets -- Nematic droplets -- Nematic polymer -- Surface-active cations -- Surface-anchoring -- Trimethyl -- Ammonium compounds -- Cationic surfactants -- Crystals -- Drop formation -- Dyes -- Ionization of liquids -- Ions -- Liquid crystal displays -- Liquid crystals -- Liquids -- Nematic liquid crystals
Аннотация: Inverse mode of a novel electrooptical effect caused by the ionic modification of boundary conditions has been studied for liquid crystal droplets. We have considered the droplets of nematic 5CB doped with cationic surfactant cetyl-trimethyl-ammonium-bromide and dispersed in polyvinyl alcohol. In the initial state the surface anchoring was normal on the whole interface due to the high concentration of homeotropic surfactant. Applied voltage results in the purification of a section of the interface from the surface-active cations thereby restoring here a tangential anchoring and stimulating the significant transformation of droplet structure. At that three different types of director field distribution can be realized within the same droplet. The proper textures of the droplet both in the crossed polarizers and without analyzer are considered.

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Держатели документа:
SB RAS, LV Kirensky Phys Inst, Krasnoyarsk Sci Ctr, Krasnoyarsk, Russia
Siberian Fed Univ, Krasnoyarsk, Russia

Доп.точки доступа:
Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич
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    Magnetic-field tunable defect modes in a photonic-crystal/liquid-crystal cell / V. Ya. Zyryanov [et al.] // Opt. Express. - 2010. - Vol. 18, Is. 2. - P. 1283-1288, DOI 10.1364/OE.18.001283. - Cited Reference Count: 15. - Гранты: This work was partially supported by the Russian Federal Grant No. 02.740.11.0220 and SB RAS Grant Nos. 5, 27.1 and 144. W. Lee gratefully acknowledges financial support from the National Science Council of the Republic of China (Taiwan) under Grant No. NSC 98-2923-M-033-001-MY3 dedicated to an internationally joint effort between Russia and Taiwan. - Финансирующая организация: Russian Federal [02.740.11.0220]; SB RAS [5, 27.1, 144]; National Science Council of the Republic of China (Taiwan) [NSC 98-2923-M-033-001-MY3] . - JAN 18. - ISSN 1094-4087
Рубрики:
NEMATIC LIQUID-CRYSTAL
   BAND-GAP MATERIALS
   SPONTANEOUS EMISSION
   SPECTRUM
Кл.слова (ненормированные):
Crystal defects -- Magnetic fields -- Photonic crystals -- Applied magnetic fields -- Crossed polarizers -- Crystal cells -- Defect mode -- Homeotropic -- Light transmission spectra -- Light wave -- Nematic director -- Optical cells -- Planar alignment -- Spectral shift -- Tunable defect -- Light transmission -- article -- artifact -- chemistry -- electromagnetic field -- liquid crystal -- materials -- materials testing -- radiation exposure -- refractometry -- Artifacts -- Electromagnetic Fields -- Liquid Crystals -- Manufactured Materials -- Materials Testing -- Refractometry
Аннотация: Light transmission spectrum of a multilayer photonic crystal with a central liquid-crystal defect layer placed between crossed polarizers has been studied. Transmittance was varied due to the magnetically induced reorientation of the nematic director from homeotropic to planar alignment. Two notable effects were observed for this scheme: the spectral shift of defect modes corresponding to the extraordinary light wave and its superposition with the ordinary one. As a result, the optical cell allows controlling the intensity of interfering defect modes by applied magnetic field. (C) 2010 Optical Society of America

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Держатели документа:
SB RAS, LV Kirensky Phys Inst, Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660014, Russia
Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
Chung Yuan Christian Univ, Dept Phys, Chungli 32023, Taiwan
Chung Yuan Christian Univ, Ctr Nanotechnol, Chungli 32023, Taiwan

Доп.точки доступа:
Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Myslivets, S. A.; Мысливец, Сергей Александрович; Gunyakov, V. A.; Гуняков, Владимир Алексеевич; Parshin, A. M.; Паршин, Александр Михайлович; Arkhipkin, V. G.; Архипкин, Василий Григорьевич; Shabanov, V. F.; Шабанов, Василий Филиппович; Lee, Wei
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Director configurations in cholesteric layer with tangential-conical boundary conditions / M. N. Krakhalev [et al.] // 15th Eur. Conf. Liq. Cryst. (ECLC) : conf. progr. - 2019. - Ст. PC-06. - Cited References: 2

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Доп.точки доступа:
Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Sutormin, V. S.; Сутормин, Виталий Сергеевич; Bikbaev, R. G.; Бикбаев, Рашид Гельмединович; Timofeev, I. V.; Тимофеев, Иван Владимирович; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; European Conference on Liquid Crystals(15 ; 2019 ; June 30 - July 5 ; Wroclaw, Poland)
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Polymer dispersed cholesteric liquid crystals with a toroidal director configuration under an electric field / A. P. Gardymova, M. N. Krakhalev, V. Ya. Zyryanov [et al.] // Polymers. - 2021. - Vol. 13, Is. 5. - Ст. 732. - P. 1-11, DOI 10.3390/polym13050732. - Cited References: 49. - This research was funded by Russian Science Foundation, Grant No. 20-72-10038 . - ISSN 2073-4360
Кл.слова (ненормированные):
cholesteric droplet -- orientational structure -- electric field -- polymer dispersted liquid crystal -- dichroic dye
Аннотация: The electro-optical properties of polymer dispersed liquid crystal (PDLC) films are highly dependent on the features of the contained liquid crystal (LC) droplets. Cholesteric LC droplets with homeotropic boundaries can form several topologically different orientational structures, including ones with single and more point defects, layer-like, and axisymmetric twisted toroidal structures. These structures are very sensitive to an applied electric field. In this work, we have demonstrated experimentally and by computer simulations that twisted toroidal droplets reveal strong structural response to the electric field. In turn, this leads to vivid changes in the optical texture in crossed polarizers. The response of droplets of different sizes were found to be equivalent in terms of dimensionless parameters. In addition, the explanation of this phenomenon showed a comparison of theoretical and experimental structural response curves aids to determine the shape of the droplet. Finally, we demonstrated that the addition of a dichroic dye allows such films to be used as optical filters with adjustable color even without polarizers.

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Держатели документа:
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Faculty of Physics, Lomonosov Moscow State University, Moscow, 119991, Russian Federation

Доп.точки доступа:
Gardymova, A. P.; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Gruzdenko, A. A.; Alekseev, A. A.; Rudyak, V. Yu.
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    Nematic structures under conical anchoring at various director tilt angles specified by polymethacrylate compositions / D. A. Kostikov, M. N. Krakhalev, O. O. Prishchepa, V. Y. Zyryanov // Polymers. - 2021. - Vol. 13, Is. 17. - Ст. 2993, DOI 10.3390/polym13172993. - Cited References: 49. - Mikhail N. Krakhalev and Oxana O. Prishchepa acknowledge financial support from Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science (No 20-42-240007) . - ISSN 2073-4360
   Перевод заглавия: Нематические структуры с коническим сцеплением при различных углах наклона директора, задаваемых составами полиметакрилатов

РУБ Polymer Science
Рубрики:
LIQUID-CRYSTAL
   PRETILT ANGLE
   ALIGNMENT LAYERS
   SURFACE
   INTERFACE
Кл.слова (ненормированные):
conical anchoring -- polymethacrylate -- nematic liquid crystal -- orientational structure -- director tilt angle -- domain wall -- electrically-induced reorientation
Аннотация: Dependence of the director tilt angle of nematic liquid crystal (LC) under conical anchoring from the two-component polymer mixture composition has been studied. We varied the ratio of poly(isobutyl methacrylate) (PiBMA), which specifies a conical anchoring for the nematic liquid crystal LN-396, and poly(methylmethacrylate) (PMMA) assigning a tangential alignment for the same nematic. An oblique incidence light technique to determine a tilt angle has been used. It has been shown that the tilt angle increases from 0∘ to 47.7∘ when PiBMA:PMMA ratio changes in the range 30:70 to 100:0. The specific optical textures viewed under the polarizing microscope and proper orientational structures have been considered for various compositions of the polymer films. An electric field action on the formed orientational structures has been investigated. The obtained results are promising for the application in various electro-optical LC devices with a conical anchoring in which the director tilt angle is a crucial parameter: a controlled diffraction gratings, an electrically operated achromatic rotators of linear light polarization, etc.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Kostikov, D. A.; Костиков, Денис Андреевич; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science [20-42-240007]
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Bistable director configurations in polymer dispersed nematic liquid crystals / Parshin A.M., Nazarov V.G., Zyryanov V.Ya., Shabanov V.F. // 22nd International LC Conference : Abstracts. - 2008. - Vol. 1. - P. 382

Доп.точки доступа:
Parshin, A. M.; Паршин, Александр Михайлович; Nazarov, V. G.; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Shabanov, V. F.; Шабанов, Василий Филиппович; IInternational LC Conference(22 ; 2008 ; Jeju, Korea)
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Director transformations within nematic droplets dispersed in polyvinylpirrolydon induced by temperature and moisture / Sutormin V.S., Krakhalev M.N., Prishchepa O.O., Zyryanov V.Ya. // 22nd International LC Conference : Abstracts. - 2008. - Vol. 1. - P. 378

Доп.точки доступа:
Sutormin, V. S.; Сутормин, Виталий Сергеевич; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; IInternational LC Conference(22 ; 2008 ; Jeju, Korea)
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10.

    Electrically induced structural transformations of a chiral nematic under tangential-conical boundary conditions / D. A. Kostikov, M. N. Krakhalev, O. O. Prishchepa, V. Ya. Zyryanov // Molecules. - 2023. - Vol. 28, Is. 23. - Ст. 7842, DOI 10.3390/molecules28237842. - Cited References: 30 . - ISSN 1420-3049
   Перевод заглавия: Электрически индуцированные трансформации структур хирального нематика с тангенциально-коническими граничными условиями
Кл.слова (ненормированные):
chiral nematic -- cholesteric -- conical anchoring -- polymethacrylate -- director tilt angle -- electrically induced transformation -- orientational structure -- polarizing optical microscopy
Аннотация: In this study, structural transformations induced by an electric field in the chiral nematic under tangential-conical boundary conditions have been considered. The composition influence of the orienting polymer films on the director tilt angles, the formation of orientational structures in the LC layer, as well as the electro-optical response and relaxation processes have been studied. It has been shown that the poly(tert-butyl methacrylate) concentration change in the orienting polymer mixture allows for smoothly controlling the director tilt angle without fixing its azimuthal orientation rigidly.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk 660041, Russia

Доп.точки доступа:
Kostikov, D. A.; Костиков, Денис Андреевич; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич
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11.

Inverse mode of ionic-surfactant method of director reorientation inside nematic droplets / Krakhalev M.N., Prishchepa O.O., Shabanov A.V., Zyryanov V.Ya. // 22nd International LC Conference : Abstracts. - 2008. - Vol. 1. - P. 380

Доп.точки доступа:
Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Shabanov, A. V.; Шабанов, Александр Васильевич; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; IInternational LC Conference(22 ; 2008 ; Jeju, Korea)
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12.

    Температурно индуцированные изменения конфигурации директора в каплях нематика, диспергированного в поли- винилпирролидоне / Виталий С. Сутормин, Михаил Н. Крахалев, Оксана О. Прищепа // Журнал Сибирского федерального университета. Серия: Математика и физика. - 2009. - Т. 2, № 3. - С. 352-359 . - ISSN 1997-1397
   Перевод заглавия: Thermo-Induced Transformations of Director Configuration within Nematic Droplets Dispersed in Polyvinylpyrrolidone
Кл.слова (ненормированные):
граница раздела -- interface -- polymer dispersed liquid crystals -- Nematic -- surfactant -- Surface anchoring -- director configuration -- капсулированные полимером жидкие кристаллы -- нематик -- сурфактант -- поверхностное сцепление -- конфигурация директора
Аннотация: В работе изучены преобразования конфигурации директора в каплях нематика, вызванные тер- моиндуцированной модификацией граничных условий. Исследования проводились для нематиче- ского жидкого кристалла 5СВ (4-н-пентил-4-цианобифенил), который допировался сурфактан- том лецитином, а затем диспергировался в поливинилпирролидоне. Показано, что при нагре- вании граничные условия изменяются от планарных к гомеотропным, что приводит к транс- формации конфигурации директора в капле нематика. При охлаждении образца наблюдалось об- ратное изменение поверхностного сцепления от гомеотропного к планарному. В обоих случаях ориентационно-структурные превращения могут происходить по двум различным сценариям.
The transformations of the director configuration within the nematic droplets induced by temperature modification of boundary conditions have been studied. Nematic liquid crystal 5CB (4-n-penthyl-4- cyanobiphenyl) doped with lecithin and dispersed in polyvinylpyrrolidone has been tested. As was shown, under heating the boundary conditions are changed from planar to homeotropic. It results in transformation of the director configuration in the nematic droplets. The inverse modification of the surface anchoring from homeotropic to planar has been observed at cooling. In both cases the transformations of orientational structure may occur in two different scenarios.

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Держатели документа:
Институт инженерной физики и радиоэлектроники, Сибирский федеральный университет
Институт физики им. Л.В. Киренского СО РАН
Сибирский государственный аэрокосмический университет

Доп.точки доступа:
Сутормин, Виталий С.; Крахалев, Михаил Н.; Прищепа, Оксана О.
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13.

    Ориентационный переход в слое нематика с гомеотропно-коническими граничными условиями, индуцированный ионной модификацией поверхностного сцепления / В. С. Сутормин, М. Н. Крахалев, О. О. Прищепа, В. Я. Зырянов // Жидк. крист. и их практич. использ. - 2022. - Т. 22, № 3. - С. 105-110 ; Liq. Cryst. Appl., DOI 10.18083/LCAppl.2022.3.105. - Библиогр.: 4. - В.С. Сутормин, М.Н. Крахалев и О.О. Прищепа благодарят за поддержку грант РФФИ, Правительства Красноярского края и Красноярского краевого фонда науки в рамках научного проекта № 20-42-240007 . - ISSN 1991-3966. - ISSN 2499-9644
   Перевод заглавия: Orientational transition in nematic layer with homeotropic-conical boundary conditions induced by ionic modification of surface anchoring
Кл.слова (ненормированные):
нематик -- ионный сурфактант -- поверхностное сцепление -- конические граничные условия -- конфигурация директора -- оптическая текстура -- nematic -- ionic surfactant -- surface anchoring -- conical boundary conditions -- director configuration -- optical texture
Аннотация: Исследована трансформация ориентационной структуры в слое нематика с гомеотропно-коническими граничными условиями, индуцированная электроуправляемой ионной модификацией поверхностного сцепления. Обнаружено, что изменение азимутального угла директора на подложке с коническим сцеплением возможно осуществить путем модификации граничных условий на второй подложке.
The transformation of the orientational structure induced by the electrically controlled ionic modification of surface anchoring in the nematic layer with homeotropic-conical boundary conditions has been considered. It has been found that the change in the azimuthal angle of director at the substrate with conical anchoring can be realized by modification of boundary conditions at the second substrate.

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Институт физики им. Л. В. Киренского, ФИЦ КНЦ СО РАН, Красноярск, Россия
Институт инженерной физики и радиоэлектроники, Сибирский федеральный университет, Красноярск, Россия

Доп.точки доступа:
Сутормин, Виталий Сергеевич; Sutormin, V. S.; Крахалев, Михаил Николаевич; Krakhalev, M. N.; Прищепа, Оксана Олеговна; Prishchepa, O. O.; Зырянов, Виктор Яковлевич; Zyryanov, V. Ya.

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14.

    Optical textures and orientational structures of nematic and cholesteric droplets with heterogeneous boundary conditions / O. O. Prishchepa [et al.] // Mol. Cryst. Liquid Cryst. - 2008. - Vol. 489, Is. 1. - P. 84-93, DOI 10.1080/15421400802219817. - Cited Reference Count: 17. - Гранты: This work was supported in part by the grants of DSP, No 2.1.1.1814; RFBR, No 0803-01007; Council of the President of the RF for Support of Young Scientists and Leading Scientific Schools (projects NSh-3818-2008.3, MK-3624.2007.2); RAS, No 8.1, 2.10.2; SB RAS, No 33. - Финансирующая организация: DSP [2.1.1.1814]; RFBR [0803-01007]; Young Scientists and Leading Scientific Schools [NSh-3818-2008.3, MK-3624.2007.2]; RAS [8.1, 2.10.2]; SB RAS [33] . - ISSN 1542-1406
Рубрики:
LIQUID-CRYSTAL DROPLETS
   ELECTRIC-FIELD
   BIPOLAR
Кл.слова (ненормированные):
director configuration -- interfaces -- nematic and cholesteric droplets -- surfactant -- Director configuration -- Interfaces -- Nematic and cholesteric droplets -- Surfactant -- Boundary value problems -- Drop formation -- Drops -- Fluid mechanics -- Phospholipids -- Surface active agents -- Boundary conditioning -- Director configuration -- Homeotropic -- Interfaces -- Nematic and cholesteric droplets -- Nematic droplets -- Nematics -- Optical textures -- Orientational structures -- Surface anchoring -- Surfactant -- Boundary conditions
Аннотация: Brief review of the orientational structures within the droplets of chiral as well as achiral nematics with the heterogeneous boundary conditions is reported. The modification of boundary conditions in the 5CB/polyvinylbutyral and LN-396/cholesterylacetate/polyvinylbutyral compositions with the planar anchoring at the interface is created by addition of the homeotropic surfactant (lecithin). Sequences of the novel stable and non-stable orientational structures being realized within the droplets of achiral nematic are presented. For the LN-396 nematic droplets doped by cholesterylacetate the formation of a spherulite structure has been shown when the tangential surface anchoring is modified to the homeotropic one.

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Держатели документа:
Siberian Fed Univ Krasnoyarsk, Krasnoyarsk Sci Ctr, SB RAS, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
L.V. Kirensky Institut of physics

Доп.точки доступа:
Prishchepa, O. O.; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Gardymova, A. P.; Shabanov, V. F.; Шабанов, Василий Филиппович
}
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15.

    Experimental results and theoretical model to describe angular dependence of light scattering by monolayer of nematic droplets / V. A. Loiko [et al.] // J. Quant. Spectrosc. Radiat. Transf. - 2016. - Vol. 178: Electromagnetic and light scattering by nonspherical particles XV: Celebrating 150 years of Maxwell's electromagnetics. - P. 263-268, DOI 10.1016/j.jqsrt.2015.10.024. - Cited References:25 . - ISSN 0022-4073. - ISSN 1879-1352
   Перевод заглавия: Экспериментальные результаты и теоретическая модель, описывающая угловую зависимость рассеяния света монослоем капель нематика

РУБ Optics + Spectroscopy
Рубрики:
Dispersed liquid-crystals
   Inhomogeneous boundary-conditions
   Films
   Transmittance
   Radiation
Кл.слова (ненормированные):
Polymer-dispersed liquid crystal film -- Liquid crystal droplet -- Director -- configuration -- Light scattering -- Monolayer of droplets
Аннотация: Light scattering by a monolayer of bipolar nematic droplets encapsulated in polymer film is examined both experimentally and theoretically. A method for the simulation of the angular distribution of scattered light is based on the anomalous diffraction and interference approximations taking into account the director configuration within liquid crystal droplets and their bipolar axes orientation. The director configuration in nematic droplets is calculated using the relaxation method of the free energy minimization. The characteristics of the sample, including distribution of droplet sizes and shape anisometry, are measured in details. The experimental results and theoretical data agree closely with each other. (C) 2015 Elsevier Ltd. All rights reserved.

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Доп.точки доступа:
Loiko, V. A.; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Konkolovich, A. V.; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Miskevich, A. A.; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Conference on Electromagnetic and Light Scattering(15 ; June 21-26, 2015 ; Leipzig, Germany)
}
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16.

Prishchepa, O. O.
Director configurations in nematic droplets with inhomogeneous boundary conditions / O. O. Prishchepa, A. V. Shabanov, V. Y. Zyryanov // Phys. Rev. E. - 2005. - Vol. 72, Is. 3. - Ст. 31712, DOI 10.1103/PhysRevE.72.031712. - Cited References: 22 . - ISSN 1539-3755

РУБ Physics, Fluids & Plasmas + Physics, Mathematical
Рубрики:
DISPERSED LIQUID-CRYSTALS
TRANSITION
Кл.слова (ненормированные):
Lecithin contents -- Nematic droplets -- Polarizers -- Radial structures -- Approximation theory -- Boundary conditions -- Drop breakup -- Free energy -- Polarization -- Textures -- Nematic liquid crystals
Аннотация: The nematic droplets with director configurations intermediate between the bipolar and radial structures have been investigated experimentally and theoretically. The liquid crystal 4(')-n-pentyl-4-cyanobiphenyl (5CB) with a variable addition of the lecithin dispersed in polyvinylbutyral has been used. The characteristic textures of the droplets formed at various lecithin contents have been examined using polarizing microscope both in the crossed polarizers and without analyzer. The computer simulation has been performed for proper ordering of the director in spherical nematic droplets by minimizing the free energy in the one-constant approximation. The inhomogeneous boundary conditions with strong anchoring of the molecules at the interface have been used. The distribution of the anchoring angle at the droplet surface has been estimated based on analysis of observed patterns. The simulated textures of the droplets under crossed polarizers are shown to compare well with the experimental ones.

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Держатели документа:
LV Kirenskii Inst Phys, Akademgorodok, Krasnoyarsk 660036, Russia
ИФ СО РАН
L.V. Kirensky Institute of Physics, Akademgorodok, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Shabanov, A. V.; Шабанов, Александр Васильевич; Zyryanov, V. Y.; Зырянов, Виктор Яковлевич; Прищепа, Оксана Олеговна
}
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17.

Prischepa, O. O.
Transformation of director configuration upon changing boundary conditions in droplets of nematic liquid crystal / O. O. Prischepa, A. V. Shabanov, V. Y. Zyryanov // JETP Letters. - 2004. - Vol. 79, Is. 6. - P. 257-261, DOI 10.1134/1.1759405. - Cited References: 12 . - ISSN 0021-3640

РУБ Physics, Multidisciplinary
Рубрики:
ISOTROPIC LIQUID
DROPS
Аннотация: The transformation of the director configuration upon changing boundary conditions from planar to homeotropic for bipolar nematic droplets dispersed in a polymeric matrix was studied. The characteristic textural patterns are presented for droplets with different concentrations of homeotropic surfactants, and their orientational structure is identified. The scenario predicted earlier by G.E. Volovik and O.D. Lavrentovich (ZhETF 85, 1997 (1983)) for the transformation of orientational structure of nematic droplets from bipolar to radial, without the formation of additional disclinations, is revealed. It is shown that, by using the computational method of minimization of the director elastic-strain energy in the droplet bulk and by introducing the inhomogeneous boundary conditions, one can obtain orientational structures that are analogous to the observed ones.(C) 2004 MAIK "Nauka / Interperiodica".

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, Akademgorodok, 660036, Russian Federation

Доп.точки доступа:
Shabanov, A. V.; Шабанов, Александр Васильевич; Zyryanov, V. Y.; Зырянов, Виктор Яковлевич; Prishchepa, O. O.
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18.

    Паршин, Александр Михайлович.
    Конфигурации директора в структурах нематика, адсорбированного на поверхности полимера / А. М. Паршин, В. Я. Зырянов, В. Ф. Шабанов // Жидк. кристаллы и их практич. использ. - 2015. - Т. 15, Вып. 1. - С. 56-65 ; Liquid Crystals and their Application. - Библиогр.: 20. - Работа выполнена частично при финансовой поддержке программ Президиума РАН и РФФИ (грант № 15-02-06924). . - ISSN 1991-3966
   Перевод заглавия: Director configurations in the structures of the nematic adsorbed on a polymer surface
Кл.слова (ненормированные):
нематический жидкий кристалл -- полимер -- адсорбция -- дисклинация -- конфигурация директора -- nematic liquid crystal -- polymer -- adsorption -- disclination -- director configuration
Аннотация: Исследованы ориентационные структуры нематических жидких кристаллов, возникающие на поверхности полимера в результате адсорбции, и их устойчивость относительно шлирен-текстуры. Изучены особенности точечных и линейных сингулярностей в исследуемых структурах. Рассмотрены конфигурации директора в слое нематика, определяемые комбинацией двух ориентирующих факторов: воздействием линейной дисклинации, фактора, стремящегося задать однородное планарное упорядочение, а также влиянием точечного дефекта, задающего радиальную структуру директора. С использованием расчетного метода проведен сравнительный анализ энергии упругих искажений поля директора для различных видов конфигураций: радиально-планарной, радиально-гомеотропной и радиально-радиальной в зависимости от толщины слоя нематика.
The orientational structures of nematic liquid crystals that form at the polymer surface due to adsorption and their stability with respect to the schlieren texture are investigated. Features of point and linear singularities in these structures are studied. The director configurations in nematic layer as a result of the combination of two aligning factors, which are the linear disclination that tends to impose uniform planar ordering and point defect that imparts the radial structure to the director are considered. The analysis of the elastic distortions energies of the director configurations for the radial-planar, radial-homeotropic and radial-radial structures, depending on the nematic layer thickness was performed using the calculation method.

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Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Зырянов, Виктор Яковлевич; Zyryanov, V. Ya.; Шабанов, Василий Филиппович; Shabanov, V. F.; Parshin, A. M.

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19.

Electric and magnetic field-assisted orientational transitions in the ensembles of domains in a nematic liquid crystal on the polymer surface / A. M. Parshin [et al.] // Int. J. Mol. Sci. - 2014. - Vol. 15, Is. 10. - P. 17838-17851, DOI 10.3390/ijms151017838. - Cited References: 21. - This work was partially supported by the Russian Foundation for Basic Research (project No. 12-03-00816), and by the Siberian Branch of the Russian Academy of Sciences (SB RAS) through Grants Nos. 30, 24.29, 24.32, and by SB RAS through a Taiwan-SB-RAS joint project. . - ISSN 1422-0067

РУБ Chemistry, Multidisciplinary
Рубрики:
FRANK CONSTANTS
   INTERFACE
   ALIGNMENT
   DISCLINATIONS
   STABILITY
   COATINGS
   DIRECTOR
Кл.слова (ненормированные):
liquid crystal -- polycarbonate -- domain structure -- electric field -- magnetic field
Аннотация: Using electro- and magneto-optical techniques, we investigated orientational transitions in the ensembles of domains in a nematic liquid crystal on the polycarbonate film surface under the conditions of competing surface forces that favor radial and uniform planar alignment of nematic molecules. Having analyzed field dependences of the intensity of light passed through a sample, we established the threshold character of the orientational effects, plotted the calculated intensity versus magnetic coherence length, and compared the latter with the equilibrium length that characterizes the balance of forces on the polymer surface.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Krasnoyarsk Sci Ctr, Siberian Branch, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Dept Energy, Krasnoyarsk 660041, Russia

Доп.точки доступа:
Parshin, A. M.; Паршин, Александр Михайлович; Gunyakov, V. A.; Гуняков, Владимир Алексеевич; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Shabanov, V. F.; Шабанов, Василий Филиппович; Russian Foundation for Basic Research [12-03-00816]; Siberian Branch of the Russian Academy of Sciences (SB RAS) [30, 24.29, 24.32]; SB RAS through a Taiwan-SB-RAS joint project
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20.

    Electronic structure of β-RbSm(MoO4)2 and chemical bonding in molybdates / V. V. Atuchin [et al.] // Dalton Trans. - 2015. - Vol. 44, Is. 4. - P. 1805-1815, DOI 10.1039/c4dt03203a. - Cited References: 121. - VVA and ASA gratefully acknowledge the Ministry of Education and Science of the Russian Federation for financial support. ZL acknowledges the support by National Natural Science Foundation of China (11174297 and 11474292), the National Basic Research Project of China (2011CB922204), and Foundation of the Director of Technical Institute of Physics and Chemistry, CAS. The work was partially supported by RAS Project 24-29 and RFBR Grant 13-02-00825. . - ISSN 1477-9226. - ISSN 1477-9234
   Перевод заглавия: Электронная структура бета-RbSm(MoO4)2 и химическая связь в молибдатах

РУБ Chemistry, Inorganic & Nuclear
Рубрики:
RAY PHOTOELECTRON-SPECTROSCOPY
   CRYSTAL-STRUCTURE
   X-RAY
   NEUTRON-DIFFRACTION
   MAGNETIC-PROPERTIES
   PHASE-FORMATION
   CORE LEVELS
   2ND-HARMONIC GENERATION
   LUMINESCENCE PROPERTIES
   VIBRATIONAL PROPERTIES
Аннотация: Microcrystals of orthorhombic rubidium samarium molybdate, beta-RbSm(MoO4)(2), have been fabricated by solid state synthesis at T = 450 degrees C, 70 h, and at T = 600 degrees C, 150 h. The crystal structure has been refined by the Rietveld method in space group Pbcn with cell parameters a = 5.0984(2), b = 18.9742(6) and c = 8.0449(3) angstrom (R-B = 1.72%). Thermal properties of beta-RbSm(MoO4)(2) were traced by DSC over the temperature range of T = 20-965 degrees C, and the earlier reported β ↔ α phase transition at T similar to 860-910 degrees C was not verified. The electronic structure of beta-RbSm(MoO4) 2 was studied by employing theoretical calculations and X-ray photoelectron spectroscopy. It has been established that the O 2p-like states contribute mainly to the upper part of the valence band and occupy the valence band maximum, whereas the Mo 4d-like states contribute mainly to the lower part of the valence band. Chemical bonding effects have been analysed from the element core level binding energy data. In addition, it was found that the luminescence spectrum of beta-RbSm(MoO4)(2) is rather peculiar among the Sm3+ containing materials. The optical refractive index dispersion in beta-RbSm(MoO4)(2) was also predicted by the first-principles calculations.

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RAS, Inst Semicond Phys, Lab Opt Mat & Struct, SB, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Lab Semicond & Dielectr Mat, Novosibirsk 630090, Russia
RAS, Kirensky Inst Phys, Lab Coherent Opt, SB, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
RAS, Baikal Inst Nat Management, Lab Oxide Syst, SB, Ulan Ude 670047, Russia
Gen Res Inst Nonferrous Met, Beijing 100088, Peoples R China
RAS, Inst Semicond Phys, Lab Nanodiagnost & Nanolithog, SB, Novosibirsk 630090 90, Russia
RAS, Inst Semicond Phys, Lab Phys Bases Integrated Microelect, SB, Novosibirsk 630090 90, Russia
RAS, Kirensky Inst Phys, Lab Crystal Phys, SB, Krasnoyarsk 660036, Russia
RAS, Kirensky Inst Phys, Lab Mol Spect, SB, Krasnoyarsk 660036, Russia
Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China

Доп.точки доступа:
Atuchin, V. V.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Chimitova, O. D.; Diao, C. P.; Gavrilova, T. A.; Kesler, V. G.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Krylov, A. S.; Крылов, Александр Сергеевич; Bazarov, B. G.; Bazarova, J. G.; Lin, Z. S.; Ministry of Education and Science of the Russian Federation; National Natural Science Foundation of China [11174297, 11474292]; National Basic Research Project of China [2011CB922204]; Foundation of the Director of Technical Institute of Physics and Chemistry, CAS; RAS [24-29]; RFBR [13-02-00825]
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