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Каталог книг и брошюр библиотеки ИФ СО РАН

Каталог журналов библиотеки ИФ СО РАН

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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stepin E. A., Sushko E. S., Vnukova N. G., Churilov G. N., Rogova A. V., Tomilin F. N., Kudryasheva N. S.
Заглавие : Effects of endohedral Gd-containing fullerenols with a different number of oxygen substituents on bacterial bioluminescence
Колич.характеристики :19 с
Место публикации : Int. J. Mol. Sci. - 2024. - Vol. 25, Is. 2. - Ст.708. - ISSN 16616596 (ISSN), DOI 10.3390/ijms25020708. - ISSN 14220067 (eISSN)
Примечания : Cited References: 102. - This research was funded by the State Assignment of the Ministry of Science and Higher Education of the Russian Federation, project No. 0287-2021-0020, and partly supported by the Russian Science Foundation No. 23-26-10018, Krasnoyarsk Regional Science Foundation
Аннотация: Gadolinium (Gd)-containing fullerenols are perspective agents for magnetic resonance imaging and cancer research. They combine the unique paramagnetic properties of Gd with solubility in water, low toxicity and antiradical activity of fullerenols. We compared the bioeffects of two Gd-containing fullerenols with a different number of oxygen groups—20 and 42: Gd@C82O20H14 and Gd@C82O42H32. The bioluminescent bacteria-based assay was applied to monitor the toxicity of fullerenols, bioluminescence was applied as a signal physiological parameter, and bacterial enzyme-based assay was used to evaluate the fullerenol effects on enzymatic intracellular processes. Chemiluminescence luminol assay was applied to monitor the content of reactive oxygen species (ROS) in bacterial and enzymatic media. It was shown that Gd@C82O42H32 and Gd@C82O20H14 inhibited bacterial bioluminescence at 10?1 and 10?2 gL?1, respectively, revealing a lower toxicity of Gd@C82O42H32. Low-concentration (10?3–10?1 gL?1) bacterial bioluminescence activation by Gd@C82O42H32 was observed, while this activation was not found under exposure to Gd@C82O20H14. Additional carboxyl groups in the structure of Gd@C82O42H32 were determined by infrared spectroscopy and confirmed by quantum chemical calculations. The groups were supposed to endow Gd@C82O42H32 with higher penetration ability through the cellular membrane, activation ability, lower toxicity, balancing of the ROS content in the bacterial suspensions, and lower aggregation in aqueous media.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Abulkhaev M. U., Molokeev M. S., Oreshonkov A. S., Aleksandrovsky A. S., Kertman A. V., Kamaev D. N., Trofimova O. V., Elyshev A. V., Andreev O. V.
Заглавие : Properties of GdSF and phase diagram of the GdF3 - Gd2S3 system
Место публикации : J. Solid State Chem. - 2023. - Vol. 322. - Ст.123991. - ISSN 00224596 (ISSN), DOI 10.1016/j.jssc.2023.123991. - ISSN 1095726X (eISSN)
Примечания : Cited References: 44. - The authors of the article are grateful to P.P. Fedorov for valuable critical comments on the manuscriptThis research was funded by the Tyumen Oblast Government, as a part of the West-Siberian Interregional Science and Education Center’s project No. 89-DON (3)
Аннотация: The objectives of this study were to refine the phase diagram of the GdF3-Gd2S3 system and to calculate their liquidus, and to synthesize GdSF and to study their properties. The GdSF compound (ST PbFCl, P4/nmm, a (Å) 3.83006(17), c (Å) 6.8529(3), has an optical band gap for a direct interband transition of 2.56 eV and is characterized by a pronounced increase in the Kubelka-Munk function in the region of this transition. Direct optical bandgap of GdSF is measured to be equal to 2.77 eV. Two indirect bandgaps are detected to be 1.54 and 2.4 eV. Meta-GGA simulations of band structure predicting 1.481 eV direct bandgap of GdSF are in good agreement with these features of the experimental absorption spectrum. To explain this complicated case, we argue that formally direct optical transitions to highly dispersive subbands contribute not to direct but to indirect bandgaps measured by Tauc analysis. The GdSF compound melts incongruently with the formation of a melt and γ-Gd2S3 compound at t = 1280 ± 2°С, ΔН = 40.6 ± 2.8 kJ/mol, ΔS = 26.1 ± 1.8 J/mol∗K. The eutectic has a composition of 13 mol.% Gd2S3 (0.74 GdF3 + 0.26 GdSF), the melting characteristics of the eutectic are 1182 ± 2°С, ΔН = 36.2 ± 2.5 kJ/mol, ΔS = 24.9 ± 1.7 J/mol∗K. In the system GdF3 - Gd2S3 the balance equations for five phase transformations recorded by the DSC method were compiled. Convergence was achieved in the liquidus of the system constructed according to DSC data and calculated with the use of the Redlich-Kister equation.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Денисова Л. Т., Молокеев, Максим Сергеевич, Голубева Е. О., Галиахметова Н. А.
Заглавие : Синтез, кристаллическая структура и термодинамические свойства апатитоподобных ванадато-германатов свинца гадолиния
Коллективы : Siberian Federal University [FSRZ-2020-0013]
Место публикации : Журн. СФУ. Химия. - 2022. - Т. 15, № 1. - Ст.128-136. - ISSN 1998-2836, DOI 10.17516/1998-2836-0277; J. Sib. Fed. Univ. Chem. - 2022. - ISSN 2313-6049(eISSN)
Примечания : Библиогр.: 25. - Авторы выражают благодарность Красноярскому региональному центру коллективного пользования ФИЦ КНЦ СО РАН. Работа выполнена при частичной финансовой поддержке в рамках государственного задания на науку ФГАОУ ВО «Сибирский федеральный университет», номер проекта FSRZ‑2020–0013
Аннотация: Методом твердофазных реакций обжигом на воздухе стехиометрических смесей PbO, Gd2O3, GeO2 и V2O5 в интервале температур 773–1073 K синтезированы апатиты Pb10-xGdx(GeO4)2+x(VO4)4-x (x = 0.5, 1.0). С использованием рентгеноструктурного анализа определена их кристаллическая структура. Методом дифференциальной сканирующей калориметрии измерена высокотемпературная теплоемкость (350–1000 K). По экспериментальным данным Cp = f(T) рассчитаны термодинамические свойства апатитов.The Pb10-xGdx(GeO4)2+x(VO4)4-x (x = 0.5, 1.0) apatites were synthesized by the solid-phase synthesis by roasting stoichiometric mixtures of PbO, Gd2O3, GeO2, and V2O5 in air at temperatures of 773–1073 K. Their crystal structure was determined using X‑ray diffraction analysis. The high-temperature heat capacity (350–1000 K) was measured by differential scanning calorimetry. The experimental data Cp = f (T) were used to calculate the thermodynamic properties of apatites.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sushko E. S., Vnukova N. G., Churilov G. N., Kudryasheva N. S.
Заглавие : Endohedral Gd-containing fullerenol: Toxicity, antioxidant activity and regulation of reactive oxygen species in cellular and enzymatic systems
Место публикации : Int. J. Mol. Sci. - 2022. - Vol. 23, Is. 9. - Ст.5152. - ISSN 16616596 (ISSN), DOI 10.3390/ijms23095152
Примечания : Cited References: 117. - This research was funded by Russian Foundation for Basic Research, N18-29-19003; Russian Foundation for Basic Research, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, N20-44-243001; and partly supported by the Program of the Federal Service for Surveillance on Consumer Rights Protection and Human Wellbeing, Fundamental Study 2020-2025 (Russia)
Аннотация: The Gd-containing metallofullerene derivatives are perspective magnetic resonance imaging contrast agents. We studied the bioeffects of a water-soluble fullerene derivative, gadolinium-endohedral fullerenol, with 40–42 oxygen groups (Gd@Fln). Bioluminescent cellular and enzymatic assays were applied to monitor toxicity and antioxidant activity of Gd@Fln in model solutions; bioluminescence was applied as a signaling physiological parameter. The Gd@Fln inhibited bioluminescence at high concentrations (2·10−1 gL−1), revealing lower toxicity as compared to the previously studied fullerenols. Efficient activation of bioluminescence (up to almost 100%) and consumption of reactive oxygen species (ROS) in bacterial suspension were observed under low-concentration exposure to Gd@Fln (10−3–2·10−1 gL−1). Antioxidant capability of Gd@Fln was studied under conditions of model oxidative stress (i.e., solutions of model organic and inorganic oxidizers); antioxidant coefficients of Gd@Fln were determined at different concentrations and times of exposure. Contents of ROS were evaluated and correlations with toxicity/antioxidant coefficients were determined. The bioeffects of Gd@Fln were explained by hydrophobic interactions, electron affinity, and disturbing of ROS balance in the bioluminescence systems. The results contribute to understanding the molecular mechanism of “hormetic” cellular responses. Advantages of the bioluminescence assays to compare bioeffects of fullerenols based on their structural characteristics were demonstrated.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Dudnik A. I., Vnukova N. G., Drokin N. A., Bondarev V. S., Shestakov N. P., Tomashevich Y. V., Churilov G. N.
Заглавие : Electrophysical properties of hydroxylated endohedral metallofullerene with gadolinium
Место публикации : J. Phys. Chem. Solids. - 2019. - Vol. 135. - Ст.109094. - ISSN 00223697 (ISSN) , DOI 10.1016/j.jpcs.2019.109094
Примечания : Cited References: 35. - The reported study was funded by RFBR according to the research project No 18-29-19003.
Аннотация: The paper presents the results of experimental measurements of constitutive and electrophysical properties in hydroxylated endohedral metallofullerene with gadolinium sample. We extracted endohedral metallofullerene from carbon condensate, synthesized in high-frequency arc discharge plasma. Later hydroxyl groups were added. Via methods of infrared and x-ray photoelectronic spectroscopy, it was established that the molecules of hydroxylated endohedral metallofullerene have the Gd@C82Ox(OH)y, x + y=(40–42) composition. The method of measuring the electrical impedance in the frequency range from 100 Hz to 100 MHz shows that the resulting hydroxylated fullerene is an ion conductor. The measured frequency dependences of the dielectric permittivity and conductivity of hydroxylated fullerene are explained based on the assumption of an inhomogeneous distribution of electric charges in the material volume. Dielectric-hysteresis loops in the frequency range of 25 Hz–1 MHz and temperature range of 80–300 K, and volt-ampere characteristics were measured. The obtained results imply the appearance of residual polarization induced by the electric field in hydroxylated fullerene. However, the constant dipole moment is absent. © 2019
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Edelman I. S., Kliava J., Ivanova O. S., Ivantsov R. D., Velikanov D. A., Zaikovskii V., Petrakovskaja E. A., Zubavichus Y., Stepanov S.
Заглавие : Effect of gadolinium on magnetic circular dichroism and electron magnetic resonance of ε-Fe2O3 nanoparticles formed in borate glasses
Место публикации : J. Non-Cryst. Solids. - 2019. - Vol. 506. - P.68-79. - ISSN 00223093 (ISSN) , DOI 10.1016/j.jnoncrysol.2018.12.006
Примечания : Cited References: 81. - The work is supported by Russian Academy of Sciences in the frame of the Project № 0356-2017-0030.
Ключевые слова (''Своб.индексиров.''): iron oxides--ε-fe2o3--borate glasses--nanoparticles--magnetic circular dichroism--electron magnetic resonance
Аннотация: A remarkable characteristic of borate glasses is the ability of forming magnetic nanoparticles at low doping with transition element oxides. We have studied structure and magnetic properties of iron oxide nanoparticles formed in borate glasses, in particular, concentration and temperature dependences of magnetic circular dichroism (MCD) and electron magnetic resonance (EMR) spectra. A series of glasses of molar composition 22.5K2O-22.5Al2O3–55B2O3 doped with 1.5 mass % of Fe2O3 and different contents of Gd2O3 from 0.1 to 1.0 mass % was prepared using a conventional melt quenching technique and subjected to an additional thermal treatment. The whole set of results allows to identify the predominant magnetic phase in these glasses as ε-Fe2O3 nanoparticles, with a considerable part of iron ions substituted by gadolinium. Analysis and computer simulations of the EMR spectra allow separating the contribution of electron paramagnetic resonance of diluted iron ions and together with the temperature dependences of magnetization demonstrate a superparamagnetic character of the nanoparticle magnetism.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gerasimova Y. V., Oreshonkov A. S., Romanova O. B., Ivanenko A. A., Krylov A. S.
Заглавие : Raman and infrared characterization of gadolinium-doped manganese sulfide
Место публикации : Spectrosc. Lett.: Taylor and Francis, 2017. - Vol. 50, Is. 1. - P.55-58. - ISSN 00387010 (ISSN), DOI 10.1080/00387010.2017.1287092
Примечания : Cited References: 34. - The authors are thankful to Dr. A.V. Shabanov for scanning electron microscopy study of the samples.
Ключевые слова (''Своб.индексиров.''): infrared--lattice dynamics--manganese sulfide--raman
Аннотация: Gadolinium manganese sulfide solid solutions are investigated by infrared and Raman spectroscopy. Longitudinal optical–transverse optical splitting of the manganese–sulfur bond vibration is observed in the vibrational spectra. The Raman spectra contain modes that are prohibited in the crystal structure of the alpha phase of manganese sulfide, which are associated with activation of the phonons from both the Brillouin zone center and its X and L points. The concentration dependence of transverse optical and longitudinal optical modes’ frequencies is calculated within the frame of the modified random-element-isodisplacement model, being in good agreement with the experimental results. Both theory and experiment show that the solid solution under study exhibits a “one-mode” behavior. © 2017 Taylor & Francis.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Ivantsov R. D., Ivanova O. S., Petrakovskaja E. A., Zubavichus Y. V., Mikhlin Y. L., Edelman I. S.
Заглавие : Magnetic nanoparticles origin in glasses co-doped with iron and gadolinium oxides
Коллективы : Asian School-Conference on Physics and Technology of Nanostructured Materials, Азиатская школа-конференция по физике и технологии наноструктурированных материалов
Место публикации : Third Asian school-conference on physics and technology of nanostructured materials (ASCO-NANOMAT 2015): proceedings. - Vladivostok: Dalnauka, 2015. - Ст.VI.21.06p. - ISBN 978-5-8044-1556-4
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Romanova O., Gorev M. V., Velikanov D. A., Gamzatov A. G., Aliev A. M.
Заглавие : Magnetic and thermophysical properties of GdxMn1-xS solid solutions
Место публикации : J. Phys.: Condens. Matter. - 2013. - Vol. 25, Is. 2. - Ст.025802. - P. - ISSN 0953-8984, DOI 10.1088/0953-8984/25/2/025802
Ключевые слова (''Своб.индексиров.''): antiferromagnetic orders--band state--face-centered cubic lattices--magnetic phase transitions--paramagnetic phase--temperature dependence--antiferromagnetism--electron transitions--gadolinium--manganese--paramagnetism--sodium chloride--specific heat--organic polymers
Аннотация: The structural, magnetic, and thermophysical properties of cation-substituted sulfides GdXMn1-XS (0.04 ? X ? 0.25) with the NaCl-type face-centered cubic lattice have been investigated. The range of existence of long-range antiferromagnetic order has been established. The anomalies observed in the temperature dependence of the specific heat correspond to the temperatures of the magnetic phase transition. The anomaly in the specific heat caused by electron transitions between the 4f levels and d band states has been observed. It has been found that the coefficient of thermal expansion decreases with increasing concentration of substituents in the magnetically ordered region and remains nearly invariable in the paramagnetic phase. В© 2013 IOP Publishing Ltd.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stolyar S. V., Bayukov O. A., Ladygina V. P., Ischenko L. A., Iskhakov R. S.
Заглавие : Structure and magnetic properties of biogenic ferrihydrite nanoparticles doped with gadolinium
Место публикации : J. Sib. Fed. Univ. Math. Phys. - 2013. - Vol. 6, Is. 3. - P.358-365. - ISSN 1997-1397; Журн. СФУ. Сер. "Математика и физика"
Ключевые слова (''Своб.индексиров.''): ferrihydrite nanoparticle--bacterial culture klebsiela oxytoca--mössbauer spectroscopy--gadolinium doping
Аннотация: Bacterial culture Klebsiella oxytoca was grown in a Lovley medium at various concentrations of gadolinium salt. Biogenic magnetic nanoparticles of ferrihydrite were investigated by Mossbauer spectroscopy and magnetization curves were obtained. The results of structural studies showed that iron Fe(5) takes new position when cultivating is carried out in medium with high concentrations of gadolinium. It was found that gadolinium is fit into the crystal structure of ferrihydrite. These results are consistent with the analysis of the magnetization curves.
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