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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zou X., Wang X., Zhang H., Kang Y., Yang X., Zhang X., Molokeev M. S., Lei B.
Заглавие : A highly efficient and suitable spectral profile Cr3+-doped garnet near-infrared emitting phosphor for regulating photomorphogenesis of plants
Место публикации : Chem. Eng. J. - 2022. - Vol. 428. - Ст.132003. - ISSN 13858947 (ISSN), DOI 10.1016/j.cej.2021.132003
Примечания : Cited References: 46. - The work was supported from the National Natural Science Foundations of China (Nos. 21671070, 51802101), the Guangdong Basic and Applied Basic Research Foundation (No. 2021A1515012613), the Guangdong Provincial Science & Technology Project (Nos. 2020A1414010046, 2021A0505050006), the Guangzhou Science & Technology Project (No. 202007020005), the Natural Science Foundation of Guangdong Province (No. 2018A030310217), the Project of GDUPS (2018) for Prof. Bingfu LEI, and the Guangdong Provincial Special Fund for Modern Agriculture Industry Technology Innovation Teams (Nos. 2021KJ131 , 2021KJ122)
Аннотация: Far-red/phytochrome (PFR) plays a key role in photomorphogenesis of plants. However, how to obtain a near-infrared (NIR) emitting phosphor with high external quantum efficiency (EQE), suitable spectral profile, and low thermal quenching remains a huge challenge. Herein, a NIR phosphor, Gd2.4Lu0.6Ga4AlO12:Cr3+,H3BO3 (GLGA:Cr3+) was developed via regulating the crystal field environment and adding fluxes, which exhibits a peak maximum at 728 nm with a relatively narrow full-width at half maximum (FWHM) of 107 nm, matching well with the absorption band of PFR. Upon 450 nm excitation, the internal quantum efficiency (IQE) and EQE of the optimal phosphor are 90.3% and 32.0%, respectively. At 423 K, the integrated emission intensity of the investigated phosphor is about 75% of that at room temperature. Benefiting from the excellent optical performance, a NIR phosphor-converted light-emitting diode (pc-LED) was fabricated, which shows a NIR output power of 505.99 mW and photoelectric conversion efficiency of 11.24% at 300 mA. Moreover, plant growth experiments demonstrate that the biomass of pea seedlings is increased by 67.72% under supplementary NIR light irradiation. The findings of this research will motivate further research on new Cr3+-doped NIR phosphors for regulating photomorphogenesis of plants.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : KVASHNINA O. P., KAPITONOV A. M., SMOKOTIN E. M., TITOVA A. G.
Заглавие : ACOUSTIC PROPERTIES OF TERBIUM FERRITE-GARNET AT LOW-TEMPERATURES
Место публикации : Fiz. Tverd. Tela: MEZHDUNARODNAYA KNIGA, 1984. - Vol. 26, Is. 8. - P2408-2410. - ISSN 0367-3294
Примечания : Cited References: 5
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Hu T., Molokeev M. S., Xia Z., Zhang Q.
Заглавие : Aliovalent substitution toward reinforced structural rigidity in Ce3+-doped garnet phosphors featuring improved performance
Место публикации : J. Mater. Chem. C. - 2019. - Vol. 7, Is. 46. - P.14594-14600. - ISSN 20507534 (ISSN), DOI 10.1039/c9tc05354a
Примечания : Cited References: 38. - This work was supported by the National Natural Science Foundation of China (No. 51722202 and 51972118), the Guangdong Provincial Science & Technology Project (2018A050506004) and the Fundamental Research Funds for the Central Universities (D2190980).
Аннотация: Highly efficient phosphors with thermal stability and color-tunable emission are required for the fabrication of phosphor-converted white light-emitting diodes (pc-WLEDs). Currently developed engineering strategies are generally successful in photoluminescence tuning but, unfortunately, suffer severe deterioration in emission intensity/efficiency and/or thermal stability. Herein, an efficient aliovalent substitution strategy toward reinforced structural rigidity is proposed and demonstrated experimentally. By incorporating Be2+ ion into the garnet-type Lu2SrAl4SiO12:Ce3+ phosphor, the phosphor shows enhanced internal/external quantum efficiency, from 79.2%/26.7% to 84.5%/32.9%, photoluminescence tuning from green (peaking at ∼512 nm) to yellow (peaking at ∼552 nm), and zero thermal quenching, even up to 200 °C. The Be2+ substitution at the Al2/Si2 site enables stable and rigid local surroundings around the Ce3+ activator, which is responsible for the unprecedented performance. In addition, high-quality warm WLED devices with a luminous efficiency of 158.1 lm W-1, correlated color temperature of 3858 K and high color rendering index of 81.7, are obtained by combining Lu2SrAl4SiO12:Ce3+,Be2+ as the yellow emitter, CaAlSiN3:Eu2+ as the red emitter and a blue-emitting InGaN chip. These findings highlight a new strategy for performance optimization of LED phosphors by selecting rigid covalent compounds with further reinforced structural rigidity via aliovalent substitution.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Zelenov F. V., Semenov S. V., Bayukov O. A.
Заглавие : Anomalies in the magnetic properties of bismuth-substituted diluted yttrium iron garnet
Колич.характеристики :9 с
Место публикации : J. Magn. Magn. Mater. - 2023. - Vol. 582. - Ст.171030. - ISSN 03048853 (ISSN), DOI 10.1016/j.jmmm.2023.171030. - ISSN 18734766 (eISSN)
Примечания : Cited References: 61. - The authors are grateful to T. N. Tarasenko for providing samples for magnetic measurements
Аннотация: The magnetic properties and Mossbauer spectra of the Y1.8Bi1.2Fe3.5Ga1.5O12 compound were investigated. A linear temperature dependence of the saturation magnetization, hysteresis, and stability of the coercive field in the magnetically ordered state were found. Using the Mossbauer measurements, the distribution of iron ions over octahedral and tetrahedral sites and the concentration of paramagnetic iron ions were determined. Two critical temperatures – the sublattice magnetization compensation temperature and the ferrimagnet–paramagnet transition temperature – were established. The disappear of the phonon mode in the vicinity of the magnetic transition was observed. The experimental data have been interpreted in terms of the spin–lattice interaction model.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Belyaev B. A., Izotov A. V.
Заглавие : Micromagnetic calculation of magnetostatic oscillation modes of an orthogonally magnetized disk of yttrium iron garnet
Место публикации : Phys. Solid State. - 2013. - Vol. 55, Is. 12. - P.2491-2500. - ISSN 1063-7834, DOI 10.1134/S1063783413120068
Аннотация: The absorption spectrum of a normally magnetized disk of yttrium iron garnet, which is associated with resonances of magnetostatic oscillation modes excited by a homogeneous high-frequency magnetic field, has been investigated using a numerical analysis of the micromagnetic model developed for ferromagnetic objects. The distribution of magnetization oscillation amplitudes over the disk surface area has been obtained for the first four modes. A good agreement between the results of the micromagnetic simulation and the data of analytical calculations for special cases has proved the reliability and efficiency of the proposed approach in numerical experiments on the study of the magnetization dynamics in objects with different geometries and shapes, including multilayer magnetic film structures.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zhang, Qiuhong, Li, Junhao, Jiang, Wei, Lin, Litian, Ding, Jianhong, Brik, Mikhail G., Molokeev M. S., Ni, Haiyong, Wu, Mingmei
Заглавие : CaY2Al4SiO12:Ce3+,Mn2+: a single component phosphor to produce high color rendering index WLEDs with a blue chip
Место публикации : J. Mater. Chem. C. - 2021. - Vol. 9, Is. 34. - P.11292-11298. - ISSN 2050-7526, DOI 10.1039/d1tc01770e. - ISSN 2050-7534(eISSN)
Примечания : Cited References: 35. - This work has been financially supported by the National Nature Science Foundation of China (51902063, 51902354, U1801253), the Science and Technology Project of Guangdong Province (2018A050506061), the Science and Technology Project of Guangzhou City (202007020005, 202007020008) and GDAS' Project of Science and Technology Development (2020GDASYL-20200302010, 2018GDASCX-0110). M. G. Brik also thanks the support from the Chongqing Recruitment Program for 100 Overseas Innovative Talents (Grant No. 2015013), the Program for the Foreign Experts (Grant No. W2017011) and Wenfeng High-End Talents Project (Grant No. W2016-01) offered by Chongqing University of Posts and Telecommunications (CQUPT), Estonian Research Council grant PUT PRG111, European Regional Development Fund (TK141) and NCN project 2018/31/B/ST4/00924
Предметные рубрики: GARNET PHOSPHOR
ENERGY-TRANSFER
RED EMISSION
LUMINESCENCE PROPERTIES
Аннотация: A high color rendering index white light emitting diode (WLED) is generally produced by combining yellow and red mixed phosphors on a blue chip. Herein we report a single component phosphor based on CaY2Al4SiO12 (CYAS) to achieve warm white light emission with a high color rendering index (Ra), which can be up to 90.5. Ce3+, Mn2+ singly doped and co-doped CYAS phosphors have been synthesized by solid state reactions, respectively, for comparative investigations. The Rietveld X-ray diffraction (XRD) refinements show that the CYAS host crystallizes in a cubic structure with the Ia[3 with combining macron]d space group. The valence states of Ce and Mn inside the CYAS host have been confirmed by XPS and EPR. Ce3+ occupies the Ca2+/Y3+ site and generates a yellow emission band around 543 nm from its characteristic 5d–4f transition. Mn2+ occupies both the dodecahedron Ca2+/Y3+ and octahedral Al3+ sites, emitting red and deep red lights at 616 nm and 750 nm, respectively. These two emission bands are attributed to the 4T1(4G)–6A1(6S) transitions of Mn2+. Upon 460 nm light excitation, both the Ce3+ and Mn2+ characteristic emissions can be obtained, in which the emissions of Mn2+ result from the occurrence of energy transfer from Ce3+ in CYAS. All the results indicate that the prepared CYAS:Ce3+,Mn2+ could be a promising single component phosphor for blue chip WLEDs.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Masyugin A. N., Volochaev M. N., Ishibashi T.
Заглавие : Coexistence of the electric polarization and conductive current in the bismuth–neodymium ferrite garnet films
Место публикации : J. Mater. Sci. Mater. Electron. - 2021. - Vol. 32. - P.3766-3781. - ISSN 09574522 (ISSN), DOI 10.1007/s10854-020-05121-9
Примечания : Cited References: 42
Аннотация: The Nd1Bi2Fe5O12/Nd2Bi1Fe4Ga1O12 polycrystalline films on the glass substrate and the Nd0.5Bi2.5Fe5O12 epitaxial films on the single-crystal gadolinium gallium garnet substrate have been investigated by impedance and dielectric spectroscopy. The inductive contribution to the impedance and two relaxation channels related to ferroelectric domains and migration polarization have been established. The magnetocapacitance and magnetoimpedance have been determined. The conductive and polarization currents and the phase difference between them for the films of two types have been determined. The critical temperatures of the polarization disappearance and hysteresis I–V have been found. A model of the polarization caused by the piezoelectric effect and flexoelectric interaction has been proposed. I–V hysteresis is explained by the presence of ferroelectric domains near the interface and is associated with the hysteresis of the electric polarization.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Masyugin A. N., Sitnicov M. N., Rybina U. I., Ishibashi T.
Заглавие : Colossal magnetostriction and electrostriction of bismuth-substituted neodymium iron garnet films
Место публикации : J. Magn. Magn. Mater. - 2018. - Vol. 464. - P.44-49. - ISSN 03048853 (ISSN), DOI 10.1016/j.jmmm.2018.05.038
Примечания : Cited References: 27. - This study were supported by the Russian Foundation for Basic Research project №18-52-00009 Bel_a, № 18-32-00079 mol_a, the state order № 3.5743.2017/6.7.
Ключевые слова (''Своб.индексиров.''): thermal expansion--magnetostriction--electrostriction
Аннотация: Electro- and magnetostriction mechanisms and temperature behavior of the length of bismuth-substituted neodymium iron garnet films on glass and gallium gadolinium garnet have been investigated. Electric- and magnetic-field and temperature dependences of the electro- and magnetostriction constants have been determined. It has been established that the magnetostriction constant changes its sign upon temperature variation. The experimental data are explained using a model of dipole glass with the magnetoelectric and magnetoelastic interaction.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bataleva, Yu. V., Palyanov, Yu. N., Borzdov, Yu. M., Novoselov I. D., Bayukov O. A., Sobolev N. V.
Заглавие : Conditions of formation of iron-carbon melt inclusions in garnet and orthopyroxene under P-T conditions of lithospheric mantle
Коллективы : Russian Foundation for Basic Research [16-35-60024]; [0330-2016-0007]
Место публикации : Petrology. - 2018. - Vol. 26, Is. 6. - P.565-574. - ISSN 0869-5911, DOI 10.1134/S0869591118060024. - ISSN 1556-2085(eISSN)
Примечания : Cited References: 45. - This work was supported by the Russian Foundation for Basic Research (project no. 16-35-60024) and a State Assignment (project no. 0330-2016-0007).
Предметные рубрики: EARTHS LOWER MANTLE
DIAMOND FORMATION
DEEP MANTLE
PHYSICOCHEMICAL PARAMETERS
Ключевые слова (''Своб.индексиров.''): high-pressure experiment--metal-carbon melt--graphite--diamond--co2-fluid--mantle silicates--mantle metasomatism
Аннотация: Of great importance in the problem of redox evolution of mantle rocks is the reconstruction of scenarios of alteration of Fe0- or Fe3C-bearing rocks by oxidizing mantle metasomatic agents and the evaluation of stability of these phases under the influence of fluids and melts of different compositions. Original results of high-temperature high-pressure experiments (P = 6.3 GPa, T = 1300–1500°С) in the carbide–oxide–carbonate systems (Fe3C–SiO2–(Mg,Ca)CO3 and Fe3C–SiO2–Al2O3–(Mg,Ca)CO3) are reported. Conditions of formation of mantle silicates with metallic or metal–carbon melt inclusions are determined and their stability in the presence of CO2-fluid representing the potential mantle oxidizing metasomatic agent are estimated. It is established that garnet or orthopyroxene and CO2-fluid are formed in the carbide–oxide–carbonate system through decarbonation, with subsequent redox interaction between CO2 and iron carbide. This results in the formation of assemblage of Fe-rich silicates and graphite. Garnet and orthopyroxene contain inclusions of a Fe–C melt, as well as graphite, fayalite, and ferrosilite. It is experimentally demonstrated that the presence of CO2-fluid in interstices does not affect on the preservation of metallic inclusions, as well as graphite inclusions in silicates. Selective capture of Fe–C melt inclusions by mantle silicates is one of the potential scenarios for the conservation of metallic iron in mantle domains altered by mantle oxidizing metasomatic agents.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Alekseyev K. N., Berman G. P., Tsifrinovich V. I., Frishman A. M.
Заглавие : Dynamic chaos in magnetic systems
Место публикации : Uspekhi Fiz. Nauk. - 1992. - Vol. 162, Is. 7. - P.81-118. - ISSN 0042-1294
Примечания : Cited References: 99
Предметные рубрики: CLASSICAL SPIN CLUSTERS
YTTRIUM-IRON-GARNET
PARALLEL-PUMPED MAGNONS
NON-LINEAR SYSTEMS
QUANTUM CHAOS
FAT FRACTALS
FERROMAGNETIC (CH3NH3)2CUCL4
NONLINEAR DYNAMICS
LEVEL REPULSION
KICKED TOP
Аннотация: A review of the theoretical and experimental investigations of chaos in magnetic systems is represented. Both dissipative and Hamiltonian systems are considered. Basic scenarios of transitions to chaos in such systems are overlooked. Models and characteristics of chaotic oscillations in a parametric excitation of spin waves. NMR-masers, dynamics of spin chains, motion of spin in an external oscillating magnetic field and nonlinear NMR with a dynamic frequency shift are discussed. A problem of the quantum chaos in spin systems is analysed.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Masyugin A. N., Sitnikov M. N., Ishibashi T.
Заглавие : Effect of a Substrate on the Magnetoelectric Effect in Rare-Earth-Doped Bismuth Iron Garnet
Место публикации : JETP Letters. - 2019. - Vol. 110, Is. 3. - P.223-230. - ISSN 00213640 (ISSN), DOI 10.1134/S0021364019150074
Примечания : Cited References: 29. - This work was supported jointly by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory, and the Krasnoyarsk Science Foundation (project no. 18-42-240001 “Temperature-Induced Reversal of the Sign of Magnetoelectric Tensor Components in Neodymium-Doped Bismuth Iron Garnet”), as well as in part by the Russian Foundation for Basic Research (project nos. 18-32-00079_mol_a and 18-52-00009_bel_a) and by the Russian Ministry of Science and Higher Education (state contract no. 3.5743.2017/6.7).
Аннотация: The mechanism of relaxation of the electric polarization in thin films of rare-earth-doped bismuth iron garnet on glass and gallium gadolinium garnet substrates is determined in magnetic fields of 0 and 12 kOe in the temperature range of 80–380 K. The change in the sign of the residual electric polarization after switching off the electric field and the magnetic-field-induced shift of the hysteresis loop in the applied magnetic field are found. Linear and quadratic magnetoelectric effects with the tensor components depending on the substrate type are observed. The linear magnetoelectric effect is related to the spin–orbit coupling of electrons at the film–substrate interface, whereas the quadratic one is determined by the exchange–striction mechanism.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kaminskii A. A., Butashin A. V., Aleksandrov K. S., Bezmaternykh L. N., Temerov V. L., Kravtsov N. V., Firsov V. V., Seo D. T., Hommerich U., Temple D., Braud A.
Заглавие : Gd3Ga5O12:Nd3+ crystals for a continuous-wave diode-pumped laser operating in 4F3/2 4I11/2 and 4F3/2 4I13/2 channels
Место публикации : Crystallogr. Rep. - 2002. - Vol. 47, Is. 2. - P.308-312. - ISSN 1063-7745, DOI 10.1134/1.1466508
Примечания : Cited References: 15
Предметные рубрики: GALLIUM GARNET
EMISSION
Ключевые слова (''Своб.индексиров.''): gadolinium--gallium--neodymium--article--concentration response--crystal--pump--spectroscopy--x ray--x ray topography
Аннотация: Garnet crystals of the composition Gd3Ga5O12:Nd3+ (concentration series CNd = 1-10 at. %) were grown from flux. In terms of spectroscopy, these crystals, unlike those grown from melts, form a medium with a single activator center. For the first time, continuous-wave lasing was excited by diode pumping with the use of Gd3Ga5O12:Nd3+ crystals at the wavelengths ?3 = 1.3315 and ?4 = 1.3370 ?m of the 4F3/2 4I13/2 channel and also the simultaneous generation at two wavelengths, ?1 = 1.0621 and ?2 = 1.0600 ?m, of the 4F3/2 4I11/2 channel. В© 2002 MAIK "Nauka/Interperiodica".
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bataleva Y., Palyanov Y., Borzdov Y., Novoselov I., Bayukov O. A.
Заглавие : Graphite and diamond formation in the carbide–oxide–carbonate interactions (Experimental modeling under mantle P,T-conditions)
Место публикации : Minerals. - 2018. - Vol. 8, Is. 11. - Ст.522. - ISSN 2075163X (ISSN), DOI 10.3390/min8110522
Примечания : Cited References: 67. - The authors express their sincere thanks to the in-house Editor, the guest Academic Editor, and three anonymous Reviewers for helpful and constructive reviews. The authors thank S. Ovchinnikov for his assistance in implementation of Mössbauer spectroscopy measurements and A. Moskalev for his assistance in the work preparation.
Ключевые слова (''Своб.индексиров.''): cohenite--graphite--diamond--co2 fluid--carbonate--garnet--experiment--high pressure--lithospheric mantle--metasomatism
Аннотация: Experimental modeling of the formation of graphite and diamond as a result of carbide–fluid interactions was performed in the Fe3C–SiO2–Al2O3–(Mg,Ca)CO3 systems at 6.3 and 7.5 GPa and 1100–1650 °C. In the experiments with ƒO2-gradient (7.5 GPa, 1250–1350 °C), graphite + magnesiowüstite + garnet ± cohenite assemblage was formed. Graphite was produced through the redox interactions of carbide with carbonate or CO2 (reducing conditions), and redox reactions of magnesiowüstite and CO2 (oxidizing conditions). At 1450–1650 °C, crystallization of graphite, garnet, magnesiowüstite and ferrospinel, as well as generation of Fe2+,3+-rich carbonate–silicate melt occurred. This melt, saturated with carbon, acted as a medium of graphite crystallization and diamond growth on seeds. In the experiments without ƒO2-gradient (6.3 GPa), decarbonation reactions with the formation of CO2-fluid and Fe,Mg,Ca-silicates, as well as C0-producing redox reactions of CO2-fluid with cohenite were simultaneously realized. As a result, graphite (± diamond growth) was formed in assemblage with Fe2+,Fe3+,Mg-silicates and magnetite (1100–1200 °C), or with Fe3+-rich garnet and orthopyroxene (1300–1500 °C). It has been established that a potential mechanism for the crystallization of graphite or diamond growth is the oxidation of cohenite by CO2-fluid to FeO and Fe3O4, accompanied by the extraction of carbon from Fe3C and the corresponding reduction of CO2 to C0.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : KIM P. D., DROKINA T. V., BALBASHOV A. M., CHERKASOV A. P.
Заглавие : INFLUENCE OF LIGHT ON RESONANCE OF DOMAIN BOUNDARIES IN EPITAXIAL GARNET-FILMS
Место публикации : Zhurnal Tek. Fiz.: MEZHDUNARODNAYA KNIGA, 1980. - Vol. 50, Is. 3. - P653-654. - ISSN 0044-4642
Примечания : Cited References: 4
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15.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Masyugin A. N., Aplesnin S. S., Sitnikov M. N., Ishibashi T.
Заглавие : Influence of the substrate on the magnetoresistance of bismuth garnet ferrite substitute by rare earth
Коллективы : Российская академия наук, Уральское отделение РАН, Институт физики металлов им. М. Н. Михеева Уральского отделения РАН, Уральский федеральный университет им. первого Президента России Б.Н. Ельцина, Российский фонд фундаментальных исследований, Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium
Место публикации : Euro-asian symposium "Trends in magnetism" (EASTMAG-2019): Book of abstracts/ чл. конс. ком.: S. G. Ovchinnikov, N. V. Volkov [et al.] ; чл. прогр. ком. D. M. Dzebisashvili [et al.]. - 2019. - Vol. 1. - Ст.E.P14. - P.444-445. - ISBN 978-5-9500855-7-4 (Шифр В33/E12-125657784)
Примечания : Cited References: 4. - The reported study was funded by Krasnoyarsk Regional Fund of Science according to the participation in the event/internship: The VII Euro-Asian Symposium “Trends in Magnetism” (EASTMAG-2019)
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Masyugin A. N., Kretinin V. V., Konovalov S. O., Shestakov N. P.
Заглавие : Magnetoresistance and IR spectrum of impurity states in the Ce3Fe5O12 film
Место публикации : Phys. Solid State. - 2021. - Vol. 63, Is. 2. - P.242-247. - ISSN 10637834 (ISSN), DOI 10.1134/S1063783421020025
Примечания : Cited References: 28. - This study was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Krai, and the Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project no. 18-42-240001 “Inversion of the Sign of Magnetoelectric Tensor Components with Temperature in the Neodymium-Doped Bismuth Iron Garnet Films”
Аннотация: In polycrystalline cerium iron garnet films, the gap in the electron excitation spectrum and electronic transitions between di- and tetravalent iron and cerium impurity ions have been established from the IR absorption spectra. The temperatures of delocalization of the ferrous states of iron have been found from the impedance spectroscopy, electrical resistance, and IR spectroscopy data. The difference between the ac and dc magnetoresistances has been established and explained using a model of a dielectrically inhomogeneous medium.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Liu C., Xia, Zhiguo, Chen M., Molokeev M. S., Liu Q.
Заглавие : Near-infrared luminescence and color tunable chromophores based on Cr3+-Doped Mullite-Type Bi2(Ga,Al)4O9 solid solutions
Место публикации : Inorg. Chem.: American Chemical Society, 2015. - Vol. 54, Is. 4. - P.1876-1882. - ISSN 0020-1669, DOI 10.1021/ic502779d
Примечания : Cited References: 26. - The present work was supported by the National Natural Science Foundations of China (Grants 51002146, 51272242), Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), Beijing Youth Excellent Talent Program (YETP0635), the Funds of the State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University (KF201306), and Fundamental Research Funds for the Central Universities (FRF-TP-14-005A1).
Предметные рубрики: PERSISTENT LUMINESCENCE
PHOSPHORS
PIGMENT
GARNET
OXIDES
FIELD
RED
Аннотация: Cr3+-activated mullite-type Bi2Ga(4-x)AlxO9 (x = 0, 1, 2, 3, and 4) solid solutions were prepared by the solid state reaction, and their spectroscopic properties were investigated in conjunction with the structural evolution. Under excitation at 610 nm, Bi2[Ga(4-y)Aly]3.97O9:0.03Cr3+ (y = 0, 1, 2, 3, and 4) phosphors exhibited broad-band near-infrared (NIR) emission peaking at ?710 nm in the range 650?850 nm, and the optimum Cr3+ concentrations and concentration quenching mechanism were determined. Except for the interesting NIR emission, the body color changed from white (at x = 0) to green (at x = 0.08) for Bi2Ga4?xO9:xCr3+, and from light yellow (at x = 0) to deep brown (at x = 0.08) for Bi2Al4?xO9:xCr3+, respectively. Moreover, as a result of variable Al/Ga ratio, the observed body color for Bi2[Ga(4-y)Aly]3.97O9:0.03Cr3+ (y = 0, 1, 2, 3, and 4) varied from deep brown to green. The relationship between the observed colors and their diffuse reflectance spectra were also studied for the understanding of the different absorption bands. The results indicated that Cr3+-doped Bi2Ga(4-x)AlxO9 solid solutions appeared as the bifunctional materials with NIR phosphors and color-tunable pigments.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Yang X., Chen W., Wang D., Chai X., Xie G., Xia Z., Molokeev M. S., Liu Y., Lei B.
Заглавие : Near-infrared photoluminescence and phosphorescence properties of Cr3+-Doped garnet-type Y3Sc2Ga3O12
Место публикации : J. Lumin. - 2020. - Vol. 225. - Ст.117392. - ISSN 00222313 (ISSN), DOI 10.1016/j.jlumin.2020.117392
Примечания : Cited References: 26. - The present work was supported by the National Natural Science Foundations of China (Grant No. 21671070); the Project of GDUPS (2018) for Prof. Bingfu LEI; the Guangzhou Science & Technology Project, China (No. 201704030086); and the National Undergraduate Innovation and Entrepreneurship Training Program granted for Gening Xie (No. 201910564035)
Аннотация: Garnet-type Y3Sc2Ga3O12:Cr3+ phosphor has been synthesized by a solid-state reaction. XRD result revealed the successful phase formation and Cr3+ doping in Y3Sc2Ga3O12. The excitation spectrum at about 260, 450, and 630 nm corresponded to three spin-allowed Cr3+ d-d intra-transitions of 4A2-4T1 (4P), 4A2-4T1 (4F), and 4A2-4T2 (4F), respectively, among which the near infrared (NIR) emission peak at around 740 nm is identified. Moreover, the phosphorescence emission property, thermoluminescence and related luminescence mechanisms are discussed as well. The fabricated NIR phosphor-converted light-emitting diodes (pc-LEDs) suggest its potential of Y3Sc2Ga3O12:Cr3+ phosphor for non-visible light source application.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ji H., Wang L., Molokeev M. S., Hirosaki N., Huang Z., Xia Z., Ten Kate O. M., Liu L., Xie R.
Заглавие : New garnet structure phosphors, Lu3-xYxMgAl3SiO12:Ce3+ (x = 0-3), developed by solid solution design
Место публикации : J. Mater. Chem. C: Royal Society of Chemistry, 2016. - Vol. 4, Is. 12. - P.2359-2366. - ISSN 20507534 (ISSN), DOI 10.1039/c6tc00089d
Примечания : Cited References: 33. - This work was partly supported by the National Natural Science Foundation of China (Grant No. 51511130035, 51272259, 61575182, 51572232 and 51561135015) and the Russian Foundation for Basic Research (Grant No. 15-52-53080). H. J. thanks the China Scholarship Council (CSC) for providing a scholarship to support his study in NIMS.
Предметные рубрики: Particle-diagnosis approach
Luminescence
Photoluminescence
Ce3+
Substitution
Discovery
Oxygen
Аннотация: New garnet phosphors, Lu3−xYxMgAl3SiO12:Ce3+ (x = 0–3), which can be efficiently excited by blue light and emit the yellow-orange light, were developed using the solid solution design strategy combining the chemical unit substitution and the cation substitution. Crystal structures of the four compounds were reported for the first time via the Rietveld refinement of their powder XRD patterns. All phosphors show the general cubic garnet structure with the space group Iad. The specific occupancy of Lu/Y, Al/Mg, Al/Si and O atoms in different positions was identified. The evolution of cell parameters and Y/Lu/Ce–O bond lengths were identified. Photoluminescence properties were evaluated on aspects of emission/excitation spectra, internal/external quantum efficiency and thermal emission stability. Under the 450 nm blue light excitation, the phosphors exhibit bright yellow color emission, peaking in the 575–597 nm spectral range. The internal and external quantum efficiency can reach 83% and 58%, respectively. The emission red-shift in response to the Y/Lu ratio variation was discussed in relation to the local structure evolution. The phosphors are relatively promising to act as wavelength converter of blue light in white light emitting diodes.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Dai X., Zou X., Zhang H., Chen W., Yang C., Molokeev M. S., Xia Z., Liu Y., Zhang X., Zheng M., Lei B.
Заглавие : Novel Cr3+-doped garnet phosphor with broadband efficient far-red emission for photochrome matching plant-lighting
Колич.характеристики :9 с
Место публикации : Adv. Opt. Mater. - 2024. - Vol. 12, Is. 11. - Ст.2302380. - ISSN 21951071 (eISSN), DOI 10.1002/adom.202302380
Примечания : Cited References: 54. - The work was supported by the National Natural Science Foundations of China (No. 12274144), the Guangdong Provincial Special Fund for Modern Agriculture Industry Technology Innovation Teams (No. 2023KJ122), the Key Realm R&D Program of Guangdong Province (No. 2021B0707010003), the Guangdong Provincial Science and Technology Project (No. 2022A1515010229), and the Project of GDUPS (2018) for Prof. Bingfu LEI
Аннотация: Cr3+-doped phosphors are highly recognized in various fields for their remarkable luminous efficiency and spectral flexibility, including modern agriculture and horticulture. However, the shortage of suitable Cr3+-doped phosphors for far-red LED devices has inhibited their popularization in plant lighting. Herein, an innovative Cr3+-doped phosphor Ca2YAl3Ge2O12:Cr3+ (CYAG:Cr3+), achieving a broad far-red emission at 770 nm upon 450 nm blue light excitation is designed. The optimal CYAG:Cr3+ phosphor exhibits a high internal quantum yield of 78.2% and low thermal-quenching behavior of 85%@373 K. Thus, the fabricated phosphor-converted LEDs (pc-LEDs) for plant far-red lighting have a high output power of 33.3 mW and photovoltaic conversion efficiency of 11.5% at 100 mA. The potential of CYAG:Cr3+ in plant lighting is assessed by supplementing the far-red lighting of Italian lettuce with fabricated pc-LEDs, and the biomass of Italian lettuce is significantly increased by 33%. The successful development of CYAG:Cr3+ phosphors provides a high-quality option for plant far-red light devices and further stimulates the development of new Cr3+-doped plant-lighting phosphors.
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