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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Hu T., Molokeev M. S., Xia Z., Zhang Q.
Заглавие : Aliovalent substitution toward reinforced structural rigidity in Ce3+-doped garnet phosphors featuring improved performance
Место публикации : J. Mater. Chem. C. - 2019. - Vol. 7, Is. 46. - P.14594-14600. - ISSN 20507534 (ISSN), DOI 10.1039/c9tc05354a
Примечания : Cited References: 38. - This work was supported by the National Natural Science Foundation of China (No. 51722202 and 51972118), the Guangdong Provincial Science & Technology Project (2018A050506004) and the Fundamental Research Funds for the Central Universities (D2190980).
Аннотация: Highly efficient phosphors with thermal stability and color-tunable emission are required for the fabrication of phosphor-converted white light-emitting diodes (pc-WLEDs). Currently developed engineering strategies are generally successful in photoluminescence tuning but, unfortunately, suffer severe deterioration in emission intensity/efficiency and/or thermal stability. Herein, an efficient aliovalent substitution strategy toward reinforced structural rigidity is proposed and demonstrated experimentally. By incorporating Be2+ ion into the garnet-type Lu2SrAl4SiO12:Ce3+ phosphor, the phosphor shows enhanced internal/external quantum efficiency, from 79.2%/26.7% to 84.5%/32.9%, photoluminescence tuning from green (peaking at ∼512 nm) to yellow (peaking at ∼552 nm), and zero thermal quenching, even up to 200 °C. The Be2+ substitution at the Al2/Si2 site enables stable and rigid local surroundings around the Ce3+ activator, which is responsible for the unprecedented performance. In addition, high-quality warm WLED devices with a luminous efficiency of 158.1 lm W-1, correlated color temperature of 3858 K and high color rendering index of 81.7, are obtained by combining Lu2SrAl4SiO12:Ce3+,Be2+ as the yellow emitter, CaAlSiN3:Eu2+ as the red emitter and a blue-emitting InGaN chip. These findings highlight a new strategy for performance optimization of LED phosphors by selecting rigid covalent compounds with further reinforced structural rigidity via aliovalent substitution.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Masyugin A. N., Volochaev M. N., Ishibashi T.
Заглавие : Coexistence of the electric polarization and conductive current in the bismuth–neodymium ferrite garnet films
Место публикации : J. Mater. Sci. Mater. Electron. - 2021. - Vol. 32. - P.3766-3781. - ISSN 09574522 (ISSN), DOI 10.1007/s10854-020-05121-9
Примечания : Cited References: 42
Аннотация: The Nd1Bi2Fe5O12/Nd2Bi1Fe4Ga1O12 polycrystalline films on the glass substrate and the Nd0.5Bi2.5Fe5O12 epitaxial films on the single-crystal gadolinium gallium garnet substrate have been investigated by impedance and dielectric spectroscopy. The inductive contribution to the impedance and two relaxation channels related to ferroelectric domains and migration polarization have been established. The magnetocapacitance and magnetoimpedance have been determined. The conductive and polarization currents and the phase difference between them for the films of two types have been determined. The critical temperatures of the polarization disappearance and hysteresis I–V have been found. A model of the polarization caused by the piezoelectric effect and flexoelectric interaction has been proposed. I–V hysteresis is explained by the presence of ferroelectric domains near the interface and is associated with the hysteresis of the electric polarization.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mukhin A. A., Vorob'ev G. P., Ivanov V. Y., Kadomtseva A. M., Narizhnaya A. S., Kuz'menko A. M., Popov Y. F., Bezmaternykh L. N., Gudim I. A.
Заглавие : Colossal magnetodielectric effect in SmFe3(BO3)(4) multiferroic
Разночтения заглавия :авие SCOPUS: Colossal magnetodielectric effect in SmFe 3(BO 3) 4 multiferroic
Место публикации : JETP Letters. - 2011. - Vol. 93, Is. 5. - P.275-281. - ISSN 0021-3640, DOI 10.1134/S0021364011050079
Примечания : Cited References: 17. - We are grateful to A.K. Zvezdin and A.P. Pyatakov for the discussion of this work and valuable comments. This work was supported by the Russian Foundation for Basic Research, project nos. 10-02-00846 and 09-02-01355.
Предметные рубрики: FERROELECTRICITY
MAGNETOSTRICTION
GARNETS
Аннотация: The colossal (more than threefold) decrease in the dielectric constant E in the easy-plane SmFe3(BO3)(4) ferroborate in a magnetic field of similar to 5 kOe applied in the basal ab plane of the crystal has been found. A close relation of this effect to anomalies in the field dependence of the electric polarization has been established. It has been shown that this magnetodielectric effect is due to the contribution to E from the electric susceptibility, which is related to the rotation of spins in the ab plane, arises in the region of the antiferromagnetic ordering T T (N) and electric polarization in the magnetic field has been proposed, taking into account the additional anisotropy in the basal plane induced by the magnetoelastic stresses.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Popkov S. I., Balaev D. A., Shaihutdinov K. A., Petrov M. I.
Заглавие : Crossover from S-I-S to S-F-S junctions in composites Y3/4Lu1/4Ba2Cu3O7+Y-3(Al1-xFex)(5)O-12
Разночтения заглавия :авие SCOPUS: Crossover from S-I-S to S-F-S junctions in composites Y3/4Lu1/4Ba2Cu3O7 + Y3(Al1-xFex)5O12
Место публикации : Physica C: ELSEVIER SCIENCE BV, 2007. - Vol. 460: 8th International Conference on Materials and Mechanisms of Superconductivity and High Temperature Superconductors (JUL 09-14, 2006, Dresden, GERMANY). - P1311-1312. - ISSN 0921-4534, DOI 10.1016/j.physc.2007.03.348
Примечания : Cited References: 4
Ключевые слова (''Своб.индексиров.''): s-f-s structures--high-t-c superconductors--high-tc superconductors--s-f-s structures--ferrimagnetic materials--garnets--josephson junction devices--magnetization--transport properties--yttrium alloys--critical concentration--ferrimagnet junctions--magneto-active ions--super current carriers--high temperature superconductors
Аннотация: The transport properties of the two phases composites based on Y3/4Lu1/4Ba2Cu3O7 (YBCO) and Y-3(Al1-xFex)(5)O-12 (X = 0-0... 1.0) have been studied to investigate the effect of magnetic ordering in garnet on superconducting properties of the composites. The composites represent network of Josephson junctions where the non-superconducting ingredient (garnet) acts as barriers separating YBCO grains. It is found that magneto-active ions (Fe) in garnet are responsible for an additional suppression of Josephson coupling in the composites. At some critical concentration of Fe atoms full suppression of super current is observed in a temperature range from T-C of YBCO grains down to the characteristic temperature T,,,. This behavior is attributed to the interaction of super current carriers with spins of Fe atoms located in the barriers. The crossover from S-I-S (S-superconductor, I-insulator) to S-F-S (F-ferrimagnet) junctions is observed in the compdsites Y3/4Lu1/4Ba2Cu3O7 + Y-3(Al1-xFex)(5)O-12 with x increase. (c) 2007 Elsevier B.V. All rights reserved.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vorotynov A. M., Petrakovskii G. A., Rudenko V. V.
Заглавие : Exchange dependence of the spin-Hamiltonian constants for antiferromagnetically coupled S-ion pairs
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2010. - Vol. 52, Is. 7. - P1424-1426. - ISSN 1063-7834, DOI 10.1134/S1063783410070164
Примечания : Cited References: 10
Предметные рубрики: PARAMAGNETIC-RESONANCE
MAGNETIC-ANISOTROPY
GARNETS
Аннотация: Experimental data that indicate the existence of an exchange-dependent contribution to single-ion spin-Hamiltonian constants for antiferromagnetically coupled S-ion pairs in diamagnetic crystals are reported and generalized.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisov V. M., Denisova L. T., Irtyugo L. A., Patrin G. S., Volkov N. V., Chumilina L. G.
Заглавие : High-Temperature Heat Capacity of Y2.9Ho0.1Al5O12
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2013. - Vol. 55, Is. 4. - P.692-695. - ISSN 1063-7834, DOI 10.1134/S1063783413040082
Примечания : Cited References: 21
Предметные рубрики: CRYSTALS
GARNETS
Аннотация: This paper presents data on the heat capacity of Y2.9Ho0.1Al5O12 as a function of temperature (360-1020 K). The experimental data obtained are used to derive the thermodynamic functions of the oxide compound.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Men'shikov V. V., Ovchinnikov S. G., Rudenko V. V., Sudakov A. N., Tugarinov V. I., Vorotynov A. M.
Заглавие : Magnetic anisotropy quantitative estimation for the rhombohedral antiferromagnetic crystals containing S-state ions - art. no. 224405 (Retracted Article. see vol 72, art. no. 189901, 2005)
Разночтения заглавия :авие SCOPUS: Magnetic anisotropy quantitative estimation for the rhombohedral antiferromagnetic crystals containing S-state ions
Место публикации : Phys. Rev. B: AMER PHYSICAL SOC, 2005. - Vol. 71, Is. 22. - Ст.224405. - ISSN 1098-0121, DOI 10.1103/PhysRevB.71.224405
Примечания : Cited References: 33
Предметные рубрики: ELECTRON-PARAMAGNETIC-RES
EXCHANGE-COUPLED PAIRS
RESONANCE MEASUREMENTS
GARNETS
MN-2
Аннотация: The method to investigate "single-ion" exchange anisotropy (as predicted by the pair model) is treated by exploration of several isostructural diamagnetic crystals containing magnetic impurities. The electron paramagnetic resonance (EPR) spectra were observed for ferric borate isostructural crystals MBO(3): Fe(3+) (M = Ga, In, Lu, Sc). The experimental dependences of the spin-Hamiltonian axial parameters of the second-order D(S) and fourth-order (a-F)(cS) versus total pair spin S are presented. The contributions arising from the distortion of the parent crystal lattice MBO3 under magnetic dilution are estimated. The microscopic derived expressions for the "single-ion" contribution to the anisotropy are also presented. The present experimental data enable estimation of the "single- ion" exchange contribution for FeBO(3), MnCO(3), and alpha-Fe(2)O(3) crystals at T= 0 K. The quantitative estimations for EPR are in satisfactory agreement among themselves and with the experimental data.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Demidov A. A., Volkov D. V., Gudim I. A., Eremin E. V., Boldyrev K. N.
Заглавие : Magnetic, magnetoelastic, and spectroscopic properties of TmAl3(BO3)4
Коллективы : Russian Foundation for Basic Research [13-02-12442ofi_m2]; Russian Federation [MK-1700.2013.2]
Место публикации : J. Exp. Theor. Phys.: MAIK Nauka-Interperiodica / Springer, 2014. - Vol. 119, Is. 4. - P.737-744. - ISSN 1063-7761, DOI 10.1134/S106377611410015X. - ISSN 1090-6509
Примечания : Cited References: 28. - This study was supported financially by the Russian Foundation for Basic Research (project no. 13-02-12442ofi_m2) and (K.N.B.) by the grant no. MK-1700.2013.2 from the President of the Russian Federation.
Предметные рубрики: THERMAL-EXPANSION
CRYSTALS
MAGNETOSTRICTION
HoAl3(BO3)4
GARNETS
Аннотация: The thermodynamic properties of alumoborate TmAl3(BO3)4 single crystal are studied experimentally and theoretically. A theoretical analysis based on the crystal field model makes it possible to interpret all measured parameters. The crystal field parameters are determined. The temperature (3–300 K) and field (up to 9 T) dependences of magnetization are described. The field and temperature dependences of multipole moments of the Tm3+ ion in TmAl3(BO3)4 make it possible to describe magnetostriction and low-temperature anomalies in thermal expansion.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Dai X., Zou X., Zhang H., Chen W., Yang C., Molokeev M. S., Xia Z., Liu Y., Zhang X., Zheng M., Lei B.
Заглавие : Novel Cr3+-doped garnet phosphor with broadband efficient far-red emission for photochrome matching plant-lighting
Колич.характеристики :9 с
Место публикации : Adv. Opt. Mater. - 2024. - Vol. 12, Is. 11. - Ст.2302380. - ISSN 21951071 (eISSN), DOI 10.1002/adom.202302380
Примечания : Cited References: 54. - The work was supported by the National Natural Science Foundations of China (No. 12274144), the Guangdong Provincial Special Fund for Modern Agriculture Industry Technology Innovation Teams (No. 2023KJ122), the Key Realm R&D Program of Guangdong Province (No. 2021B0707010003), the Guangdong Provincial Science and Technology Project (No. 2022A1515010229), and the Project of GDUPS (2018) for Prof. Bingfu LEI
Аннотация: Cr3+-doped phosphors are highly recognized in various fields for their remarkable luminous efficiency and spectral flexibility, including modern agriculture and horticulture. However, the shortage of suitable Cr3+-doped phosphors for far-red LED devices has inhibited their popularization in plant lighting. Herein, an innovative Cr3+-doped phosphor Ca2YAl3Ge2O12:Cr3+ (CYAG:Cr3+), achieving a broad far-red emission at 770 nm upon 450 nm blue light excitation is designed. The optimal CYAG:Cr3+ phosphor exhibits a high internal quantum yield of 78.2% and low thermal-quenching behavior of 85%@373 K. Thus, the fabricated phosphor-converted LEDs (pc-LEDs) for plant far-red lighting have a high output power of 33.3 mW and photovoltaic conversion efficiency of 11.5% at 100 mA. The potential of CYAG:Cr3+ in plant lighting is assessed by supplementing the far-red lighting of Italian lettuce with fabricated pc-LEDs, and the biomass of Italian lettuce is significantly increased by 33%. The successful development of CYAG:Cr3+ phosphors provides a high-quality option for plant far-red light devices and further stimulates the development of new Cr3+-doped plant-lighting phosphors.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrovsky A. S., Arkhipkin V. G., Bezmaternykh L. N., Gudim I. A., Krylov A. S., Vagizov F.
Заглавие : Origin of color centers in the flux-grown europium gallium garnet
Место публикации : J. Appl. Phys.: AMER INST PHYSICS, 2008. - Vol. 103, Is. 8. - Ст.83102. - ISSN 0021-8979, DOI 10.1063/1.2902365
Примечания : Cited References: 7
Предметные рубрики: SPECTRA
IONS
Ключевые слова (''Своб.индексиров.''): absorption--europium alloys--garnets--ultraviolet radiation--calcium-free flux--flux-grown europium gallium garnet--color centers
Аннотация: Europium gallium garnet (EuGG) single crystals were grown from fluxes with various contents. Optical absorption spectra of EuGG grown from a flux containing calcium show an additional band in the ultraviolet and blue regions of the spectra as compared to the case of a calcium-free flux. Mossbauer spectra of the samples grown from the fluxes with different additives show no signs of other valence states of the europium ions except for 3+. However, they indicate changes in the crystal field due to the entrance of additive ions. The nature of the additional absorption must be the same as that for calcium-doped gadolinium gallium garnet, i.e., anion vacancies. Mossbauer isotope shifts and quadrupole splitting for EuGG are determined. (C) 2008 American Institute of Physics.
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