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Effect of gadolinium on magnetic circular dichroism and electron magnetic resonance of ε-Fe2O3 nanoparticles formed in borate glasses / I. Edelman [et al.] // J. Non-Cryst. Solids. - 2019. - Vol. 506. - P. 68-79, DOI 10.1016/j.jnoncrysol.2018.12.006. - Cited References: 81. - The work is supported by Russian Academy of Sciences in the frame of the Project № 0356-2017-0030. . - ISSN 0022-3093
Кл.слова (ненормированные):
Iron oxides -- ε-Fe2O3 -- Borate glasses -- Nanoparticles -- Magnetic circular dichroism -- Electron magnetic resonance
Аннотация: A remarkable characteristic of borate glasses is the ability of forming magnetic nanoparticles at low doping with transition element oxides. We have studied structure and magnetic properties of iron oxide nanoparticles formed in borate glasses, in particular, concentration and temperature dependences of magnetic circular dichroism (MCD) and electron magnetic resonance (EMR) spectra. A series of glasses of molar composition 22.5K2O-22.5Al2O3–55B2O3 doped with 1.5 mass % of Fe2O3 and different contents of Gd2O3 from 0.1 to 1.0 mass % was prepared using a conventional melt quenching technique and subjected to an additional thermal treatment. The whole set of results allows to identify the predominant magnetic phase in these glasses as ε-Fe2O3 nanoparticles, with a considerable part of iron ions substituted by gadolinium. Analysis and computer simulations of the EMR spectra allow separating the contribution of electron paramagnetic resonance of diluted iron ions and together with the temperature dependences of magnetization demonstrate a superparamagnetic character of the nanoparticle magnetism.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
LOMA, UMR 5798 Universite de Bordeaux-CNRS, Talence cedex, 33405, France
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Boreskov Institute of Catalysis, Siberian Branch of RAS, Novosibirsk, 630090, Russian Federation
NRC “Kurchatov Institute”, Moscow, 123182, Russian Federation
Vavilov State Optical Institute, St.-Petersburg, 199053, Russian Federation

Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Kliava, J.; Ivanova, O. S.; Иванова, Оксана Станиславовна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Zaikovskii, V.; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна; Zubavichus, Y.; Stepanov, S.
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X-Ray, Dielectric, and Thermophysical Studies of Rubidium Tetrachlorozincate inside Porous Glasses / L. N. Korotkov [et al.] // Bull. Russ. Acad. Sci. Phys. - 2019. - Vol. 83, Is. 9. - P. 1072-1076, DOI 10.3103/S1062873819090132. - Cited References: 17 . - ISSN 1062-8738
Кл.слова (ненормированные):
Borosilicate glass -- Chlorine compounds -- Ferroelectric materials -- Glass ceramics -- Rubidium -- Thermal expansion -- Zinc compounds
Аннотация: Results are presented from studying the X-ray diffraction, heat capacities, dielectric permittivities, and coefficients of the volumetric thermal expansion of composite materials obtained by embedding of Rb2ZnCl4 salt into the porous matrices of borosilicate glass with average pore diameters of 46 and 320 nm in the temperature range of 120–350 K. The temperatures of transitions to the incommensurate and ferroelectric phases are determined, along with the freezing temperature of the mobility of domain boundaries in Rb2ZnCl4 particles. A substantial increase in their Curie temperature is observed.

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Публикация на русском языке

Держатели документа:
Voronezh State Technical University, Voronezh, 394000, Russian Federation
Kirensky Institute of Physics, Krasnoyarsk, 660036, Russian Federation
Wroclaw University of Science and Technology, Wroclaw, 50-370, Poland
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Military Training and Scientific Center, Zhukovsky and Gagarin Air Force Academy, Voronezh, 394064, Russian Federation

Доп.точки доступа:
Korotkov, L. N.; Stekleneva, L. S.; Flerov, I. N.; Флёров, Игорь Николаевич; Mikhaleva, E. A.; Михалева, Екатерина Андреевна; Rysiakiewicz-Pasek, E.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bondarev, I. A.; Бондарев, Илья Александрович; Gorev, M. V.; Горев, Михаил Васильевич; Sysoev, O. I.
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Microwave and magneto-optic properties of ϵ-Fe2O3 nanoparticles arising in borate glasses doped with Fe and Gd / O. Ivanova [et al.] // EPJ Web Conf. : 1-7 July 2017 : book of abstracts. - 2018. - Vol. 185. - Ст. 03011DOI 10.1051/epjconf/201818503011. - Cited References: 15
Аннотация: The ϵ-Fe2O3 nanoparticles in borate glasses co-doped with low concentrations of Fe2O3 and Gd2O3 were investigated with two experimental techniques-visible magnetic circular dichroism (MCD) and electron spin resonance (ESR). The most prominent features of the MCD spectra are: non-linear dependence of the spectral maxima intensities on the Gd concentration and strong increase with the temperature decrease. The ESR spectra of these glasses exhibit two features with g = 4.3 due to the diluted Fe3+ ions and 2.0 associated both with Fe3+ ions and with nanoparticles. The integrated spectra intensities do not follow the T-1 Curie law suggesting a considerable contribution from the magnetically ordered nanoparticles to ESR. Analysis of the MCD and ESR concentration dependences allow suggestion on the Gd ions incorporation into nanoparticles.

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Держатели документа:
Kirensky Institute of Physics, FRC KSC RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660036, Russian Federation
LOMA, UMR 5798 Universite Bordeaux 1-CNRS, Talence Cedex, 33405, France

Доп.точки доступа:
Ivanova, O. S.; Иванова, Оксана Станиславовна; Kliava, J.; Edelman, I. S.; Эдельман, Ирина Самсоновна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна; Moscow International Symposium on Magnetism(7 ; 2017 ; Jul. ; Moscow); Московский государственный университет им. М.В. Ломоносова; Российский фонд фундаментальных исследований
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    Иванова, Оксана Станиславовна.
    Прозрачные магнитные стеклокерамики на основе боратных и германатных стекол с наночастицами ферритов / О. С. Иванова, И. С. Эдельман // Четвертый междисциплинарный научный форум с международным участием “Новые материалы и перспективные технологии” : сборник материалов. - 2018. - Т. 1. - С. 215-220. - Библиогр.: 5
   Перевод заглавия: Transparance magnetic glass ceramics based on borate and germanate glasses with ferrite nanoparticles

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Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Эдельман, Ирина Самсоновна; Edelman, I. S.; Ivanova, O. S.; "Новые материалы и перспективные технологии", междисциплинарный научный форум с международным участием(4 ; 2018 ; нояб. ; 27-30 ; Москва); Российская академия наук; Совет молодых ученых Российской академии наукРоссийское химическое общество им. Д.И. Менделеева; Институт металлургии и материаловедения им. А. А. Байкова РАН
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    Influence of Glass Matrix on Magneto-Optical Activity of f-f Transitions in Dy(3+) Ion / A. L. Sukhachev, A. Ya. Strokova, A. V. Malakhovskii // Solid State Phenomena. - 2011. - Vol. 168-169. - P. 557-560, DOI 10.4028/www.scientific.net/SSP.168-169.557. - Cited Reference Count: 4 . - ISBN 1012-0394
Рубрики:
Materials Science, Multidisciplinary
   Physics, Condensed Matter
Кл.слова (ненормированные):
magnetic circular dichroism -- magneto-optical activity -- rare earth glasses
Аннотация: The absorption and magnetic circular dichroism spectra of f-f transitions (6)H(15/2) -> (6)F(3/2), (6)F(5/2), (6)(F(7/2) + H(5/2)) and (6)(F(9/2) + H(7/2)) in Dy(3+) ion were studied in the glasses: Dy(2)O(3)-P(2)O(5)-SiO(2)-GeO(2) and Dy(2)O(3)-La(2)O(3)-Al(2)O(3)-B(2)O(3)-SiO(2)-GeO(2) with different concentrations of Dy(3+) ions in temperature range 100-300 K. :Basing on this data, absolute values and temperature dependences of the paramagnetic magneto-optical activity (MOA) of the transitions were determined. The origin of the MOA of f-f transitions was analyzed with the help of two models. In the first model, MOA is considered as a consequence of admixture of states with opposite parity by odd components of crystal field. The second approach is based on the Judd-Ofelt theory. The same f-f transitions reveal different values and temperature dependences in different glasses, what testifies to a different symmetry of the nearest environment of Dy(3+) ions in these glasses.

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Держатели документа:
SB RAS, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Sukhachev, A. L.; Сухачев, Александр Леонидович; Strokova, A. Yu.; Строкова, Алёна Юрьевна; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Russian Acad Sci, Inst Metal Phys; Euro-Asian Symposium "Trends in MAGnetism"(4 ; 2010 ; Jun.-Jul. ; Ekaterinburg); "Trends in MAGnetism", Euro-Asian Symposium(4 ; 2010 ; Jun.-Jul. ; Ekaterinburg)
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    Phase formation upon crystallization of SrO center dot 2B(2)O(3) glasses / A. I. Zaitsev [et al.] // Crystallogr. Rep. - 2011. - Vol. 56, Is. 1. - P44-51, DOI 10.1134/S1063774511010263. - Cited Reference Count: 21 . - JAN. - ISSN 1063-7745
Рубрики:
STRONTIUM TETRABORATE
   LUMINESCENCE
   SRB4O7
   GROWTH
Кл.слова (ненормированные):
crystalline form -- crystalline formation -- crystalline phasis -- glass surfaces -- phase formations -- thermal analysis -- thermal stability -- crystalline materials -- crystallization -- glass -- thermoanalysis -- thermodynamic stability -- metastable phases
Аннотация: The crystallization of SrO center dot 2B(2)O(3) glasses has been studied. Four different crystalline formations were found to form simultaneously and independently on the glass surface: stable alpha-SrB4O7 crystals and metastable crystalline forms (beta-SrB4O7, Sr4B14O25, and spherulites (presumably, mixtures of crystalline phases)). The ranges of thermal stability of the newly formed metastable phases have been established using thermal analysis.

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Держатели документа:
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia

Доп.точки доступа:
Zaitsev, A. I.; Зайцев, Александр Иванович; Zamkov, A. V.; Замков, Анатолий Васильевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Cherepakhin, A. V.; Черепахин, Александр Владимирович; Koroleva, N. S.
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Electron magnetic resonance and magnetooptical studies of nanoparticle-containing borate glasses / J. Kliava [et al.] // Journal of Magnetism and Magnetic Materials. - 2011. - Vol. 323, Is. 5. - P. 451-460, DOI 10.1016/j.jmmm.2010.09.045. - Cited Reference Count: 40. - RFBRRussian Foundation for Basic Research (RFBR) [07-02-92174]; CNRSCentre National de la Recherche Scientifique (CNRS)European Commission [07-02-92174]; Russian Federal Program [FCP NK-209P/GK P1227], This work was supported in part by RFBR-CNRS joint project, Grant no. 07-02-92174 and by the Russian Federal Program, project FCP NK-209P/GK P1227. It is a pleasure to thank I. Bruckental and Y. Yeshurun for the magnetization measurements. . - ISSN 0304-8853

ГРНТИ

29.19

Кл.слова (ненормированные):
borate glasses -- Electron magnetic resonance -- magnetic nanoparticles -- magnetooptics
Аннотация: We report electron magnetic resonance (EMR) and magnetooptical studies of borate glasses of molar composition 22.5K2O22.5Al2O 355B2O3 co-doped with low concentrations of Fe2O3

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Держатели документа:
CEMHTI,UPR3079 CNRS et Universit d'Orlans
CPMOH,UMR 5798,Universit Bordeaux 1-CNRS
CRMD,UMR 6619,Universit d'Orlans-CNRS
L.V. Kirensky Institute of Physics,Siberian Branch of the RAS
Synchrotron SOLEIL,L'Orme des Merisiers

Доп.точки доступа:
Kliava, J.; Edelman, I.; Ivanova, O.; Ivantsov, R.; Petrakovskaja, E. A.; Hennet, L.; Thiaudire, D.; Saboungi, M. L.
}
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    Magnetooptical Studies of Nanoparticle-Containing Borate Glasses / I. S. Edelman, O. S. Ivanova, R. D. Ivantsov // Solid State Phenomena. - 2011. - Vol. 168-169. - P. 525-528, DOI 10.4028/www.scientific.net/SSP.168-169.525. - Cited Reference Count: 9 . - ISBN 1012-0394
Рубрики:
Materials Science, Multidisciplinary
   Physics, Condensed Matter
Кл.слова (ненормированные):
magnetic nanoparticles -- oxide glasses -- faraday rotation -- magnetic circular dichroism
Аннотация: Faraday rotation (FR) and magnetic circular dichroism (MCD) of nanocomposite structures based on potassium-aluminum-germanium-boron glasses co-doped with Fe and rare earth (RE) or Y+Bi oxides have been studied. Formation of magnetic nanoparticles as a result of the glass heat treatment ensures them magnetic and magneto-optical properties typical of magnetically ordered substances. At the same time, glasses keep transparence in visual spectral range owing to low paramagnetic oxides concentration. FR and MCD spectra of the heat treated glasses are shown to be very close to those of gamma-Fe(2)O(3) and practically independent of the RE element nature for the light wave energies lower than 22000 cm(-1). For higher energies, the MCD spectrum shape depends strongly an RE what evidences the different origin of magneto-optical effects in two spectral ranges.

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Держатели документа:
RAS, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Ivanova, O. S.; Иванова, Оксана Станиславовна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Euro-Asian Symposium "Trends in MAGnetism"(4 ; 2010 ; Jun.-Jul. ; Ekaterinburg); "Trends in MAGnetism", Euro-Asian Symposium(4 ; 2010 ; Jun.-Jul. ; Ekaterinburg)
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Effect of interaction of components on thermal properties of ferroelectric nanocomposites / E. A. Mikhaleva [et al.] // Eleventh Seminar Porous Glasses-Special Glasses (PGL'2018) : Abstracts and program. - 2018. - Ст. 18. - P. 23. - Библиогр.: 2

,
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Доп.точки доступа:
Mikhaleva, E. A.; Михалева, Екатерина Андреевна; Flerov, I. N.; Флёров, Игорь Николаевич; Kartashev, A. V.; Карташев, Андрей Васильевич; Gorev, M. V.; Горев, Михаил Васильевич; Bogdanov, E. V.; Богданов, Евгений Витальевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Kogotkov, L. N.; Rysiakiewicz-Pasek, E.; "Porous Glasses-Special Glasses", Seminar(11 ; 2018 ; Sept. ; 12-16 ; Szklarska Poręba, Poland); Wroclaw University of Science and Technology
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10.

Deich, L. I.
Absorption of light by glasses in the far infrared / L. I. Deich // Jetp Lett. - 1992. - Vol. 56, Is. 10. - P. 492-495. - Cited References: 9 . - ISSN 0021-3640

РУБ Physics, Multidisciplinary
Рубрики:
STATES
Аннотация: An explanation is proposed for the deviation from the Debye shape of the absorption curve of glasses in the far infrared.

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Доп.точки доступа:
Дейч, Лев Исаакович
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