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Каталог книг и брошюр библиотеки ИФ СО РАН (23)

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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Vtyurin A.N., Krylov A.S., Gerasimova Ju.V., Ivanenko A.A., Shestakov N.P., Laptash N.M.
Заглавие : Ordering processes and phase transitions in ammonium-containing crystals of A2BWO3F3 elpasolites – com?parative Raman and infrared study
Коллективы : International Seminar on Ferroelastic Physics
Место публикации : The 6th International Seminar on Ferroelastics Physics (ISFP-6): Voronezh, September 22–25, 2009. - С. 23
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zhang, Qianqian, Li, Guogang, Li, Guangzhi, Liu, Dongjie, Dang, Peipei, Qiu, Lei, Lian, Hongzhou, Molokeev M. S., Lin, Jun
Заглавие : Optical thermometer based on efficient near-infrared dual-emission of Cr3+ and Ni2+ in magnetoplumbite structure
Колич.характеристики :9 с
Место публикации : Adv. Optical Mater. - 2024. - Vol. 12, Is. 1. - Ст.2301429. - ISSN 21951071 (eISSN), DOI 10.1002/adom.202301429
Примечания : Cited References: 22. - This work was financially supported by the National Science and Technology Major Project (2022YFB3503800), the Projects for Science and Technology Development Plan of Jilin Province (20210402046GH), the National Natural Science Foundation of China (NSFC No. 51932009, 51720105015, 51929201, 52072349, 52172166), the Natural Science Foundation of Zhejiang Province (LR22E020004), and the Project funded by China Postdoctoral Science Foundation (2022TQ0365). M.S. Molokeev acknowledges the support by the Ministry of Science and Higher Education of Russian Federation (Project No. FSRZ-2023-0006)
Аннотация: Recently, an optical thermometer based on the dual-emitting fluorescent intensity ratio (FIR) in the visible light (VIS) region has achieved great development. However, there is very little progress in thermometers from NIR light. In this work, a novel optical thermometer based on highly efficient NIR dual-emission of Cr3+ and Ni2+ in LaZnGa11O19 (LZG) with a magnetoplumbite structure is designed. Utilizing energy transfer from Cr3+ to Ni2+, the dual-emission shows a wide coverage in the 650–1600 nm region, covering the NIR I and II windows, respectively. The as-reported LZG:0.3Cr3+ and LZG:0.3Cr3+,0.01Ni2+ phosphors can reach internal/external quantum efficiency (IQE/EQE) of 94%/64% and 77%/53%, respectively. The electroluminescence property and potential applications in spectroscopic analysis, night-vision, and bioimaging of fabricated NIR-LED with LZG:0.3Cr3+,0.01Ni2+ have also been investigated. In addition, the designed ratiometric optical thermometer responds to wide temperature ranges (100-175 K, 200–475 K) and shows a maximum relative sensitivity value (Sr) of 2.4% K−1 at 475 K. The optical performance of absorption in the red region and emission in the NIR region enables the LZG:0.3Cr3+,0.01Ni2+ to become a candidate for NIR optical thermometers in biotechnological applications.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stepin E. A., Sushko E. S., Vnukova N. G., Churilov G. N., Rogova A. V., Tomilin F. N., Kudryasheva N. S.
Заглавие : Effects of endohedral Gd-containing fullerenols with a different number of oxygen substituents on bacterial bioluminescence
Колич.характеристики :19 с
Место публикации : Int. J. Mol. Sci. - 2024. - Vol. 25, Is. 2. - Ст.708. - ISSN 16616596 (ISSN), DOI 10.3390/ijms25020708. - ISSN 14220067 (eISSN)
Примечания : Cited References: 102. - This research was funded by the State Assignment of the Ministry of Science and Higher Education of the Russian Federation, project No. 0287-2021-0020, and partly supported by the Russian Science Foundation No. 23-26-10018, Krasnoyarsk Regional Science Foundation
Аннотация: Gadolinium (Gd)-containing fullerenols are perspective agents for magnetic resonance imaging and cancer research. They combine the unique paramagnetic properties of Gd with solubility in water, low toxicity and antiradical activity of fullerenols. We compared the bioeffects of two Gd-containing fullerenols with a different number of oxygen groups—20 and 42: Gd@C82O20H14 and Gd@C82O42H32. The bioluminescent bacteria-based assay was applied to monitor the toxicity of fullerenols, bioluminescence was applied as a signal physiological parameter, and bacterial enzyme-based assay was used to evaluate the fullerenol effects on enzymatic intracellular processes. Chemiluminescence luminol assay was applied to monitor the content of reactive oxygen species (ROS) in bacterial and enzymatic media. It was shown that Gd@C82O42H32 and Gd@C82O20H14 inhibited bacterial bioluminescence at 10?1 and 10?2 gL?1, respectively, revealing a lower toxicity of Gd@C82O42H32. Low-concentration (10?3–10?1 gL?1) bacterial bioluminescence activation by Gd@C82O42H32 was observed, while this activation was not found under exposure to Gd@C82O20H14. Additional carboxyl groups in the structure of Gd@C82O42H32 were determined by infrared spectroscopy and confirmed by quantum chemical calculations. The groups were supposed to endow Gd@C82O42H32 with higher penetration ability through the cellular membrane, activation ability, lower toxicity, balancing of the ROS content in the bacterial suspensions, and lower aggregation in aqueous media.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Oreshonkov A. S., Aleksandrovsky A. S., Chimitova O.D., Pankin D.V., Popov Z.I., Sukhanova E.V., Molokeev M. S., Adichtchev S.V., Pugachev A.M., Nemtsev I. V.
Заглавие : Solid state synthesis, structural, DFT and spectroscopic analysis of EuAl3(BO3)4
Колич.характеристики :10 с
Место публикации : Mater. Chem. Phys. - 2024. - Vol. 320. - Ст.129400. - ISSN 02540584 (ISSN), DOI 10.1016/j.matchemphys.2024.129400. - ISSN 18793312 (eISSN)
Примечания : Cited References: 55. - The work was carried out within the state assignment No FWES-2024-0003 of Kirensky Institute of Physics. This work was partially supported by the state order of BINM SB RAS (0273-2021-0008). The samples for this research were synthesized using equipment of the CCU BINM SB RAS. The reflectance spectrum was obtained at the Center for Optical and Laser Materials Research of Research park of St. Petersburg State University. The SEM measurements were performed at Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS"
Аннотация: Huntite-like borates are versatile and promising materials with wide range of applications in frequency conversion, UV light generation, lighting, displays, quantum information storage, and more, demonstrated by their various properties and uses in scientific research. In this work, EuAl3(BO3)4 powder was prepared through multi-stage solid-state reaction method using high-purity starting reagents: Eu2O3, Al2O3 and H3BO3, considering a 20 wt% excess of H3BO3 to compensate for B2O3 volatilization. Obtained samples undergo several treatments at varying temperatures and their phase purity is subsequently verified through powder X-ray diffraction analysis. The scanning electron microscopy reveals that resulting EuAl3(BO3)4 powder consists of granules exhibiting irregular morphologies with dimensions of 0.5–8 μm. The electronic band structure of EuAl3(BO3)4, calculated using the GGA PBE method, reveals f-states of Eu near 4 eV. These states do not produce emphasized peaks on simulated absorbance spectra. Using of DFT + U for the f-states of Eu pushed up f-bands above 6 eV and the charge transfer from p-O to d-Eu was obtained (Egdirect = 5.63 eV, Egindirect = 5.37 eV using Ueff = 4 eV). The variation of Ueff has a weak influence on the position of the bottom of the conduction band. The experimental bandgaps of EuAl3(BO3)4 crystalline powder, both direct and indirect, are found to be 3.96 and 3.67 eV, correspondingly. These values are lower than theoretical values what is associated with limitations of DFT calculations involving f electrons. The Raman spectrum of EuAl3(BO3)4 powder is discussed, detailing the contributions of different ions to specific spectral bands. Investigation of high-resolution luminescence spectra shows the possibility to estimate the content of defects by the testing the violation of the prohibition of ultranarrow 5D0 → 7F0 line that is forbidden in the ideal crystalline structure of trigonal EuAl3(BO3)4.
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Вид документа : Статья из журнала
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Автор(ы) : Konov Yu. V., Pykhtin D. A., Bikbaev R. G., Timofeev I. V.
Заглавие : Tamm plasmon polariton-based planar hot-electron photodetector for the near-infrared region
Место публикации : Nanoscale. - 2024. - Article in press. - ISSN 20403364 (ISSN), DOI 10.1039/D4NR00710G. - ISSN 20403372 (eISSN)
Примечания : Cited References: 36
Аннотация: Light-trapping devices have always been a topic of intense interest among researchers. One such device that has gained attention is the hot-electron photodetector with a tunable detection wavelength. Photodetectors based on plasmon nanostructures that provide excitation of surface plasmon polaritons are challenging to manufacture. To address this issue, a planar hot-electron photodetector based on a Tamm plasmon polariton localized in a metal–semiconductor-multilayer mirror structure has been proposed in this study. The parameters and materials of the structure were adjusted to ensure perfect absorption at the resonance wavelength. As a result, the photoresponsivity of the proposed device can reach 42.6 mA W−1 at 905 nm. For the first time, the photosensitivity was calculated analytically by solving the dispersion law for the Tamm plasmon polariton.
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Вид документа : Статья из журнала
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Автор(ы) : Zhu, Yingze, Wang, Xuesong, Qiao, Jianwei, Molokeev M. S., Swart, Hendrik C., Ning, Lixin, Xia, Zhiguo
Заглавие : Regulating Eu2+ multisite occupation through structural disorder toward broadband near-infrared emission
Место публикации : Chem. Mater. - 2023. - Vol. 35, Is. 3. - P.1432-1439. - ISSN 08974756 (ISSN), DOI 10.1021/acs.chemmater.2c03631. - ISSN 15205002 (eISSN)
Примечания : Cited References: 33. - This research was supported by the National Key Research and Development Program of China (2021YFB3500400 and 2021YFE0105700), the National Natural Science Foundations of China (Grant Nos. 51972118, 11974022, and 52102169), the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (2017BT01X137), the China Postdoctoral Science Foundation (2021M691053), and the Young Elite Scientists Sponsorship Program by China Association for Science and Technology (No. YESS20200053)
Аннотация: To promote the development of near-infrared (NIR) light sources in optoelectronic and biomedical applications, the discovery of NIR-emitting phosphor materials and their design principles are essential. Herein, we report a novel Eu2+-activated broadband NIR-emitting phosphor, BaSrGa4O8:Eu2+, which features multisite occupation due to Ba/Sr and oxygen site occupancy disorder. With an increase in the Ba/Sr atomic ratio from 1:1 to 1.7:0.3, the Eu2+ emission band maximum red-shifts from 670 to 775 nm, along with an enlargement of the full width at half-maximum (FWHM) from 140 to 230 nm. The underlying mechanism for the structure–property relationship is elucidated using density functional theory calculations. The application of the NIR phosphor-converted light-emitting diodes (pc-LEDs) is demonstrated, showing their potential in night-vision technology. Our results can initiate further exploitation of the host structural disorder toward Eu2+ broadband NIR luminescence for applications in pc-LEDs.
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Вид документа : Статья из журнала
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Автор(ы) : Lyu, Kuangnan, Liu, Gaochao, Molokeev M. S., Xia, Zhiguo
Заглавие : Double-site occupation triggered broadband and tunable NIR-I and NIR-II luminescence in AlNbO4:Cr3+ phosphors
Место публикации : Adv. Phys. Res. - 2023. - Vol. 2, Is. 4. - Ст.2200056. - ISSN 27511200 (eISSN), DOI 10.1002/apxr.202200056
Примечания : Cited References: 38. - This research was supported by the International Cooperation Project of the National Key Research and Development Program of China (2021YFB3500400 and 2021YFE0105700), National Natural Science Foundations of China (Grant No. 51972118), Guangzhou Science & Technology Project (202007020005), the State Key Laboratory of Luminescent Materials and Devices (Skllmd-2022-02), and the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (2017BT01×137). This work was also funded by RFBR according to the research project No. 19-52-80003
Аннотация: Near-infrared (NIR) phosphor-converted light-emitting diodes (pc-LEDs) are desired for optoelectronic and biomedical applications, while the development of target broadband NIR phosphors still remains a significant challenge. Herein, a kind of Cr3+-doped AlNbO4 phosphors with a broad NIR emission ranging from 650 to 1400 nm under 450 nm excitation are reported. A giant red-shift emission peak from 866 to 1020 nm together with broadened full width at half-maximum of 320 nm is achieved simply by varying the doped Cr3+ concentrations. Structural and spectroscopy analysis demonstrate that a concentration-dependent site-occupation of Cr3+ emitters in different Al3+ sites is responsible for the tunable NIR luminescence. The as-fabricated NIR pc-LED based on optimized AlNbO4:Cr3+ phosphor exhibits great potential in night-vision applications. This work provides a novel design principle on the Cr3+-doped AlNbO4 phosphor with tunable broadband luminescence from NIR-I to NIR-II, and these materials can be employed in NIR spectroscopy applications.
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Вид документа : Статья из журнала
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Автор(ы) : Isaenko, Lyudmila, Dong, Linfeng, Korzhneva, Ksenia, Yelisseyev, Alexander, Lobanov, Sergey, Gromilov, Sergey, Molokeev, Maxim S., Kurus, Alexey, Lin, Zheshuai
Заглавие : Evolution of structures and optical properties in a series of infrared nonlinear optical crystals LixAg1–xInSe2 (0 ≤ x ≤ 1)
Колич.характеристики :7 с
Место публикации : Inorg. Chem. - 2023. - Vol. 62, Is. 39. - P.15936-15942. - ISSN 00201669 (ISSN), DOI 10.1021/acs.inorgchem.3c01993. - ISSN 1520510X (eISSN)
Примечания : Cited References: 27. - This work was supported by the National Natural Science Foundation of China (Grant No. 22133004), Russian Science Foundation, grant # 19-12-00085-P (crystal growth, crystal structure analysis, band gap measurement), Ministry of Education and Science of the Russian Federation, grant FSUS-2020-0036 (SHG coefficients measurements), and partly done on state assignment of IGM SB RAS No. 122041400031-2 (composition chemical analysis)
Аннотация: In this work, a number of new infrared nonlinear optical (NLO) crystals of LixAg1–xInSe2, in which the ratio x of Li/Ag varies in a wide range from 0 to 1, are investigated. Structural analysis reveals that the space group of LixAg1–xInSe2 evolved from I4̅2d in AgInSe2 to Pna21 in LiInSe2 as x increases from low values (0, 0.2, 0.37) to large values (0.55, 0.78, 0.81, 1). Compared to other Li/Ag coexisting chalcogenides such as LixAg1–xGaS2 and LixAg1–xGaSe2, the structural distortions in LixAg1–xInSe2 are much more prominent. This may explain the limited crystallization region in the phase graph of the tetragonal structure LixAg1–xInSe2. The fundamental optical absorption edges in these LixAg1–xInSe2 compounds are determined from the direct electronic transitions and the band gaps Eg gradually increase as the lithium content increases, consistent with the first-principles calculations. The composition x = 0.78 is calculated to have a good set of optical properties with a large NLO coefficient (dpowder = 28.8 pm/V) and moderate birefringence (Δn ∼ 0.04). Accordingly, the Li0.78Ag0.22InSe2 crystal is grown by the modified Bridgman–Stockbarger method, and it exhibits a wide transparency range from 0.546 to 14.3 μm at the 2% transmittance level.
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Вид документа : Статья из журнала
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Автор(ы) : Molokeev M. S., Kostyukov A. S., Ershov A. E., Maksimov D. N., Gerasimov V. S., Polyutov S. P.
Заглавие : Infrared bound states in the continuum: random forest method
Колич.характеристики :4 с
Место публикации : Opt. Lett. - 2023. - Vol. 48, Is. 17. - P.4460-4463. - ISSN 01469592 (ISSN), DOI 10.1364/OL.494629. - ISSN 15394794 (eISSN)
Примечания : Cited References: 42. - Ministry of Science and Higher Education of the Russian Federation (FSRZ-2023-0006)
Аннотация: In this Letter, we consider optical bound states in the continuum (BICs) in the infrared range supported by an all-dielectric metasurface in the form of subwavelength dielectric grating. We apply the random forest machine learning method to predict the frequency of the BICs as dependent on the optical and geometric parameters of the metasurface. It is found that the machine learning approach outperforms the standard least square method at the size of the dataset of ≈4000 specimens. It is shown that the random forest approach can be applied for predicting the subband in the infrared spectrum into which the BIC falls. The important feature parameters that affect the BIC wavelength are identified.
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10.

Вид документа : Статья из журнала
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Автор(ы) : Wang, Xuejiao, Feng, Xiaowen, Molokeev M. S., Zheng, Huiling, Wang, Qiushi, Xu, Chunyan, Li, Ji-Guang
Заглавие : Modulation of Bi3+ luminescence from broadband green to broadband deep red in Lu2WO6 by Gd3+ doping and its applications in high color rendering index white LED and near-infrared LED
Место публикации : Dalton Trans. - 2023. - Vol. 52, Is. 9. - P.2619-2630. - ISSN 14779226 (ISSN), DOI 10.1039/D2DT03751C. - ISSN 14779234 (eISSN)
Примечания : Cited References: 4. - This work is supported in part by the Project of Education Department of Liaoning Province (Grant No. LQ2019014) and he Natural Science Foundation of Liaoning Province (Grant No. 2020-MS-286). The authors are thankful for the support for the 4B9A Beamline from the Beijing Synchrotron Radiation Facility (BSRF) (Project No. 2021-BEPC-PT-005290). The authors would like to thank Siqi Liu from Shiyanjia Lab (
Аннотация: Phosphors that exhibit tunable broadband emissions are highly desired in multi-functional LEDs, including pc-WLEDs and pc-NIR LEDs. In this work, broadband emissions were obtained and modulated in the unexpectedly wide spectral range of 517–609 nm for (Lu0.99−xGdxBi0.01)2WO6 phosphors by tuning the Gd3+ content (x = 0–0.99). The effects of Gd3+ doping on phase constituents, particle morphology, crystal structure, and photoluminescence were systematically investigated. Broadband green emission was obtained from Gd3+-free (Lu0.99Bi0.01)2WO6 phosphors (x = 0), whose emission intensity was enhanced by 50% with 5 at% Gd3+ (x = 0.05). The phase transition happened when x 0.50 and the broadband red-NIR emission was obtained when x = 0.75–0.99. Three luminescence centers were proved to be responsible for the broadband green emissions via crystal structure, spectral fitting and fluorescence decay analysis. A pc-WLED with a high color rendering index (Ra = 91.3), a stable emission color, and a low color temperature (3951 K) was fabricated from the (Lu0.94Gd0.05Bi0.01)2WO6 broadband green phosphor, and an LED device that simultaneously emits high color rendering index white light and NIR light was obtained with the (Gd0.99Bi0.01)2WO6 broadband red-NIR phosphor. Night vision and noninvasive imaging were also demonstrated using the latter LED device.
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