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1.
Synthesis, structure and
magnetic properties of monoclinic
lanthanum
-chromium borate LaCr3(BO3)4 / E. A. Volkova, M. S. Platunov, A. M. Antipin [et al.]> // J. Alloys Compd. - 2024. -
Vol. 994
. - Ст. 174683,
DOI
10.1016/j.jallcom.2024.174683. - Cited References: 38. - Single crystal X-ray analysis was carried out within the State assignment NRC "Kurchatov institute" (research contribution of A.M.A.). The research contribution of M.S.P. was partially supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental assignment for Synchrotron radiation facility "SKIF", Boreskov Institute of Catalysis (project FWUR-2024–0040) . - ISSN 0925-8388. - ISSN 1873-4669
Кл.слова (ненормированные):
Borates
--
Flux growth
--
Crystal structure
--
Differential scanning calorimetry
--
Powder X-ray diffraction
--
IR spectroscopy
--
Antiferromagnet
Аннотация:
Single crystals of LaCr3(BO3)4 were synthesized through spontaneous nucleation from a K2Mo3O10 flux melt. The crystal structure was determined using single-crystal X-ray diffraction (XRD) at temperatures of 293 K and 85 K. LaCr-borate crystallizes in the monoclinic C2/c space group with unit cell parameters a = 7.47980(5) Å, b = 9.55180(7) Å, c = 11.48330(8) Å, β= 104.0060(6)°, V = 796.04(1) Å3 (for C1, T = 293 K), and a = 7.47380(5) Å, b = 9.55520(7) Å, c = 11.47100(8) Å, β = 103.9330(6)°, V = 795.08(1) Å3 (for C2, T = 85 K), each with Z = 4. The temperature dependence of the unit cell parameters, including the monoclinic angle (β) and the unit cell volume (V), was investigated over the range of 85–293 K. No structural phase transitions were observed in the low-temperature region down to 85 K. Differential scanning calorimetry (DSC) measurements revealed no high-temperature phase transitions between 50 and 1350°C. Infrared (IR) spectroscopy confirmed the monoclinic structure of LaCr3(BO3)4 crystals, revealing characteristic absorption bands, including the lowest frequency mode associated with the translational vibrations of the La3+ ion.
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Держатели документа:
Faculty of Geology, Lomonosov Moscow State University, Moscow, Russian Federation
Synchrotron radiation facility SKIF, Boreskov Institute of Catalysis SB RAS, Kol’tsovo, Russian Federation
Shubnikov Institute of Crystallography, Complex "Crystallography and Photonics", NRC "Kurchatov institute", Moscow, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, Russian Federation
Melnikov Research Institute of Comprehensive Exploitation of Mineral Resources of the Russian Academy of Sciences, Moscow, Russian Federation
Доп.точки доступа:
Volkova, E. A.; Platunov, M. S.; Платунов, Михаил Сергеевич; Antipin, A. M.; Alpanova, R. R.; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Pyastolova, Yu. V.; Пястолова, Юлия Валентиновна; Podobraznyh, A. D.; Kosorukov, V. L.; Koporulina, E. V.; Maltsev, V. V.
}
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2.
Properties of La2F4Se,
B–LaFSe phases. Phase diagram of the LaF3–La2Se3 system / V. M. Grigorchenko, M. S. Molokeev, I. O. Yurev [et al.]> // J. Solid State Chem. - 2024. -
Vol. 338
. - Ст. 124880,
DOI
10.1016/j.jssc.2024.124880. - Cited References: 45. - This research was funded by the Tyumen Oblast Government as part of the West-Siberian Interregional Science and Education Center's project No. 89-DON (3). - This study was funded by the Russian Science Foundation, project No. 23-23-00488 "Search for EMF generation conditions in gradient ceramics of samarium monosulfide (SmS)". - The authors are grateful to I.V. Palamarchuk, a research engineer at the Center for Collective Use “Rational Nature Management and Physico-Chemical Research" of Tyumen State University, for measuring the diffusion spectrum of reflections of samples. A.S.A, A.S.O and A.S.K are grateful for the state assignment funding from Kirensky Institute of Physics . - ISSN 0022-4596. - ISSN 1095-726X
Кл.слова (ненормированные):
Lanthanum
selenidofluoride
--
Band gap
--
Phase diagram
--
Incongruent melting
Аннотация:
Lanthanum
selenidofluorides belong to wide-gap semiconductors and are promising for optoelectronics. La2F4Se, B–LaFSe compounds were obtained by the ampoule method from binary compounds. Crystals La2F4Se, R-3m, a = 4.18245(11) Å, c = 23.2939(6) Å, Z = 3, B–LaFSe P63/mmc, a = 4.21989(5) Å, c = 8.19140(10) Å, Z = 2 have a layered grain structure, their microhardnesses are 340 and 450 HV, which allows samples processing. The optical bandgap of La2F4Se is 4.5 eV. The optical bandgaps of La2F4Se and B–LaFSe were analyzed by comparing the calculated absorption spectra and the experimental Kubelka-Munk Functions. It was shown that this approach is attractive in explaining optical properties in the vicinity of fundamental absorption onset and in neighboring regions. In LaF3–La2Se3 system, temperatures and enthalpies of five phase transformations were determined, and their balance equations were obtained. It was shown that La2F4Se, B–LaFSe compounds melt incongruently and that an eutectic is formed between the phases. A phase diagram of LaF3–La2Se3 system was constructed. The liquidus calculated by Redlich-Kister polynomial agrees with the data of differential scanning calorimetry.
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Держатели документа:
Tyumen State University, Tyumen, Volodarsky str. 6, 625003, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Akademgorodok str. 50, building 38, 660036, Russia
Siberian Federal University, Krasnoyarsk, Svobodnyj av. 79, 660079, Russia
Kurgan State University, Sovetskaya str. 63/4, Kurgan, 640020, Russia
Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Pervomaiskaya str. 91, 620990, Russia
Доп.точки доступа:
Grigorchenko, V.M.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Yurev, I.O.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Krylov, A. S.; Крылов, Александр Сергеевич; Nesterova, N.V.; Kamaev, D.N.; Elyshev, A.V.; Andreev, O.V.
}
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3.
Thermochemistry, structure, and
optical properties of a new β-La2(SO4)3 polymorphic modification / S. A. Basova, M. S. Molokeev, A. S. Oreshonkov [et al.]> // Inorganics. - 2023. -
Vol. 11
,
Is. 11
. - Ст. 434,
DOI
10.3390/inorganics11110434. - Cited References: 58. - The work was partly carried out within the framework of the Strategic Academic Leadership Program “Priority-2030” for the Kazan Federal University and the state assignment of the Kirensky Institute of Physics. - We acknowledge Lisa-Marie Wagner (JLU Giessen) for help with X-ray powder diffractometry, and Svetlana Volkova and Irina Palamarchuk (UTMN) for help with IR- and UV-spectrometry. The use of equipment provided by the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS” is acknowledged . - ISSN 2304-6740
Кл.слова (ненормированные):
rare earths
--
lanthanum
--
sulfate
--
crystal chemistry
--
thermodynamics
--
chemical kinetics
--
dielectrics
Аннотация:
A new polymorphic modification of
lanthanum
sulfate was obtained by thermal dehydration of the respective nonahydrate. According to powder X-ray diffraction, it was established that β-La2(SO4)3 crystallized in the C2/c space group of the monoclinic system with the KTh2(PO4)3 structure type (a = 17.6923(9), b = 6.9102(4), c = 8.3990(5) Å, β = 100.321(3)°, and V = 1010.22(9) Å3). Temperature dependency studies of the unit cell parameters indicated almost zero expansion along the a direction in the temperature range of 300–450 K. Presumably, this occurred due to stretching of the [LaO9]n chains along the c direction, which occurred without a significant alteration in the layer thickness over the a direction. A systematic study of the formation and destruction processes of the
lanthanum
sulfates under heating was carried out. In particular, the decisive impact of the chemical composition and formation energy of compounds on the thermodynamic and kinetic parameters of the processes was established. DFT calculations showed β-La2(SO4)3 to be a dielectric material with a bandgap of more than 6.4 eV. The processing of β-La2(SO4)3 with the Kubelka–Munk function exhibited low values below 6.4 eV, which indicated a fundamental absorption edge above this energy that was consistent with LDA calculations. The Raman and infrared measurements of β-La2(SO4)3 were in accordance with the calculated spectra, indicating that the obtained crystal parameters represented a reliable structure.
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Держатели документа:
Department of Inorganic and Physical Chemistry, Tyumen State University, Tyumen 625003, Russia
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia
Laboratory of Theory and Optimization of Chemical and Technological Processes, Tyumen State University, Tyumen 625003, Russia
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia
School of Engineering and Construction, Siberian Federal University, Krasnoyarsk 660041, Russia
A.M. Butlerov Chemistry Institute, Kazan Federal University, Kazan 420008, Russia
Institute of Inorganic and Analytical Chemistry, Justus-Liebig-University Giessen, 35392 Giessen, Germany
Laboratory of Coherent Optics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia
Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk 660041, Russia
Departement of Science and Innovation, Northern Trans-Ural Agricultural University, Tyumen 625003, Russia
School of Natural Sciences, Tyumen State University, Tyumen 625003, Russia
Center for Materials Research (LaMa), Justus-Liebig-University Giessen, 35392 Giessen, Germany
Construction Institute, Industrial University of Tyumen, Tyumen 625000, Russia
Доп.точки доступа:
Basova, S. A.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Zhernakov, M. A.; Khritokhin, N. A.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Krylov, A. S.; Крылов, Александр Сергеевич; Sal’nikova, E. I.; Azarapin, N. O.; Shelpakova, N. A.; Muller-Buschbaum, K.; Denisenko, Yu. G.
}
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4.
Features of magnetic
and magneto-optical properties of
lanthanum
manganite microparticles / R. D. Ivantsov, M. M. Mikhailov, I. S. Edelman, G. Yu. Yurkin> //
The Sixth Asian school-conference on physics and technology of nanostructured materials : Proceedings. - VLadivostok, 2022. - Ст. III.o.06. - P. 128. - Cited References: 1 . - ISBN 987-5-8044-1716-2
Перевод заглавия:
Особенности магнитных и магнитооптических свойств микрочастиц манганита лантана
Аннотация:
For La1-xSrxMnO3 powders prepared by the solid-phase reaction method using various thermal regimes and x values, the temperature dependences of magnetization, circular magnetic dichroism (MCD), and diffuse reflectance spectra were studied. The powders synthesis at temperatures of 800–900 °C for 2 h leads to the formation of a multiphase state. The higher temperatures and duration of synthesis lead to the formation of two predominant magnetic phases with the Curie temperature (TC) of about 250 and 360 K. Correlation is established between magnetic states of the powder and the shape of the diffuse reflection spectra. The strong red shift of the MCD spectrum for the La1-xSrxMnO3 powder is revealed comparing to the MCD spectra of La1-xSrxMnO3 films available in literature.
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Держатели документа:
Kirensky Institute of Physics, FRC KSC SB RAS
Tomsk State University of Control System & Radioelectronics
Siberian Federal University
Доп.точки доступа:
Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Mikhailov, M. M.; Edelman, I. S.; Эдельман, Ирина Самсоновна; Yurkin, G. Yu.; Юркин, Глеб Юрьевич; Asian School-Conference on Physics and Technology of Nanostructured Materials(6 ; 2022 ; Apr. 25-29 ; Vladivostok); Азиатская школа-конференция по физике и технологии наноструктурированных материалов(6 ; 2022 ; 25-29 апр. ; Владивосток)
}
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5.
Preparation, phase evolution,
and magnetic properties of
lanthanum
manganite perovskite powders synthesized by solid-state reaction / R. D. Ivantsov [et al.]> //
Euro-asian symposium "Trends in magnetism" (EASTMAG-2019) : Book of abstracts / чл. конс. ком.: S. G. Ovchinnikov, N. V. Volkov [et al.] ; чл. прогр. ком. D. M. Dzebisashvili [et al.]. - 2019. -
Vol. 1
. - Ст. C.P14. - P. 294-295. - Cited References: 6. - The reported study was carried out with the financial support of the Russian Foundation for Fundamental Research, the Government of the Krasnoyarsk Territory, the Krasnoyarsk Territory Fund for Support of Scientific and Technical Activity in the framework of scientific Projects No. 18-43-243003 and No. 18-42-243011. The work is supported by the Special Program of the Ministry of Education and Science of the Russian Federation for the Siberian Federal University . - ISBN 978-5-9500855-7-4
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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia
Siberian Federal University, Krasnoyarsk, Russia
Tomsk State University of Control System & Radioelectronics, Tomsk, Russia
Доп.точки доступа:
Ovchinnikov, S. G. \чл. конс. ком.\; Овчинников, Сергей Геннадьевич; Volkov, N. V. \чл. конс. ком.\; Волков, Никита Валентинович; Dzebisashvili, D. M. \чл. прогр. ком.\; Дзебисашвили, Дмитрий Михайлович; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Mikhailov, M. M.; Yurkin, G. Yu.; Юркин, Глеб Юрьевич; Edelman, I. S.; Эдельман, Ирина Самсоновна; Российская академия наук; Уральское отделение РАН; Институт физики металлов им. М. Н. Михеева Уральского отделения РАН; Уральский федеральный университет им. первого Президента России Б.Н. Ельцина; Российский фонд фундаментальных исследований; Euro-Asian Symposium "Trends in MAGnetism"(7 ; 2019 ; Sept. ; 8-13 ; Ekaterinburg); "Trends in MAGnetism", Euro-Asian Symposium(7 ; 2019 ; Sept. ; 8-13 ; Ekaterinburg)
Нет сведений об экземплярах (Источник в БД не найден)
}
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6.
Two-dimensional antiferromagnetic correlations
in an La1.4Sr1.6(Mn0.9Co0.1)2O7 single crystal / A. A. Bykov [et al.]> // J. Exp. Theor. Phys. - 2017. -
Vol. 124
,
Is. 5
. - P. 786-791,
DOI
10.1134/S1063776117050120. - Cited References: 20 . - ISSN 1063-7761
Кл.слова (ненормированные):
Antiferromagnetism
--
Cobalt
--
Cobalt compounds
--
Lanthanum
compounds
--
Magnetization
--
Magnetostriction
--
Antiferromagnetic correlations
--
Bi-layer
--
Ferromagnetic orderings
--
Field dependence
--
Lanthanum
manganites
--
Single-crystal neutron diffraction
--
Single crystals
Аннотация:
The temperature and field dependences of the magnetization, the electrical resistivity, and the magnetostriction of bilayer
lanthanum
manganite La1.4Sr1.6Mn2O7 single crystals and cobalt-doped La1.4Sr1.6(Mn0.9Cu0.1)2O7 are measured. The magnetostriction of the cobalt-doped compound increases as compared to the initial La1.4Sr1.6Mn2O7 compound, and the magnetization and the magnetoresistance of the former compound change substantially. Powder and single-crystal neutron diffraction patterns are used to detect ferromagnetic ordering in La1.4Sr1.6(Mn0.9Co0.1)2O7 at a temperature below TC ~ 45(2) K, and this ordering coexists with antiferromagnetic correlations, which develop at temperatures below TC ~ 80(5) K. © 2017, Pleiades Publishing, Inc.
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Публикация на русском языке
Двумерные антиферромагнитные корреляции в монокристалле La1.4Sr1.6(Mn0.9Co0.1)2O7 [Текст] / А. А. Быков [и др.] // Журн. эксперим. и теор. физ. : Наука, 2017. - Т. 151 Вып. 5. - С. 924-929
Держатели документа:
Konstantinov St. Petersburg Nuclear Physics Institute, Russian Academy of Sciences, Gatchina, Leningrad oblast, Russian Federation
St. Petersburg State University, St. Petersburg, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Max Plank Institute for Chemical Physics of Solids, Dresden, Germany
Доп.точки доступа:
Bykov, A. A.; Zobkalo, I. A.; Dubrovskii, A. A.; Дубровский, Андрей Александрович; Smirnov, O. P.; Nikitin, S. E.; Terent'ev, K. Yu.; Терентьев, Константин Юрьевич; Gavrilov, S. V.; Shaikhutdinov, K. A.; Шайхутдинов, Кирилл Александрович
}
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7.
Crystal growth and
Raman spectroscopy study of Sm1-xLaxFe3(BO3)4 ferroborates / E. Moshkina [et al.]> // Cryst. Growth Des. - 2016. -
Vol. 16
,
Is. 12
. - P. 6915-6921,
DOI
10.1021/acs.cgd.6b01079. - Cited References: 17. - This work was supported by the Russian Foundation for Basic Research, Project No. 14-02-00307. . - ISSN 1528-7483
Перевод заглавия:
Рост кристаллов и исследование ферроборатов Sm1-xLaxFe3(BO3)4 методом спектроскопии комбинационного рассеяния света
Кл.слова (ненормированные):
Crystal lattices
--
Iron compounds
--
Raman spectroscopy
--
Single crystals
--
Crystal nucleation
--
Flux methods
--
Internal structure
--
Magnetic phase transitions
--
Magnon scattering
--
Spectral region
--
Temperature range
--
Wave numbers
--
Lanthanum
Аннотация:
Sm1-xLaxFe3(BO3)4 (x = 0, 0.75) single crystals were synthesized using the flux method. The crystal nucleation procedure and flux parameters are reported. Conditions for growing the Sm1-xLaxFe3(BO3)4 (x = 0, 0.75) single crystals are described. The prepared crystals were studied by Raman spectroscopy in the temperature range of T = 10-300 K. The spectral region corresponding to temperatures of T = 10-55 K, which involves the temperatures of the magnetic phase transition TN = 32 K for x = 0 and TN = 31 K for x = 0.75, was thoroughly analyzed. Anomalies related to the magnetic ordering established in both compounds were found. The main changes occur in the low-wavenumber region (up to 100 cm-1), where the mode corresponding to magnon scattering arises. This mode is shown to have the internal structure indicative of the occurrence of unstable vibrations (40-80 cm-1). The results obtained are analyzed by calculating the empirical lattice dynamics in Sm1-xLaxFe3(BO3)4 with x = 0 and x = 1. © 2016 American Chemical Society.
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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian State Aerospace University, Krasnoyarsk, Russian Federation
Доп.точки доступа:
Moshkina, E. M.; Мошкина, Евгения Михайловна; Krylov, A. S.; Крылов, Александр Сергеевич; Sofronova, S. N.; Софронова, Светлана Николаевна; Gudim, I. A.; Гудим, Ирина Анатольевна; Temerov, V. L.; Темеров, Владислав Леонидович
}
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8.
Linear and circular
magnetic dichroism in thin films of
lanthanum
manganite [Текст] / Yu. E. Greben'kova [и др.]> //
V Euro-Asian simposium "Trend in MAGnetism": Nanomagnetism : abstracts. - Vladivostok : FEFU, 2013. - P. 324 . - ISBN 978-5-7444-3124-2
Доп.точки доступа:
Greben'kova, Yu.E.; Гребенькова, Юлия Эрнестовна; Sokolov, A. E.; Соколов, Алексей Эдуардович; Edel'man, I. S.; Эдельман, Ирина Самсоновна; Andreev, N. V.; Андреев Н. В.; Chichkov, V. I.; Чичков В. И.; Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism(5 ; 2013 ; Sept. ; 15-21 ; Vladivostok)
}
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9.
Magnetoresistance of substituted
lanthanum
manganites La0.7Ca0.3MnO3 upon nonequilibrium overheating of carriers / K. A. Shaykhutdinov [et al.]> // J. Appl. Phys. - 2011. -
Vol. 109
,
Is. 8
. - Ст. 83711,
DOI
10.1063/1.3573666. - Cited References: 15. - This study was partially supported by the Russian Foundation for Basic Research, project no. 08-02-00259a, and the Lavrent'ev's Competition of Young Scientists of the Siberian Branch of the RAS, project no. 12. . - ISSN 0021-8979
РУБ
Physics, Applied
Кл.слова (ненормированные):
Field dependence
--
Lanthanum
manganites
--
Low thermal conductivity
--
Manganite materials
--
Negative differential resistivity
--
Non equilibrium
--
Non-Linearity
--
Nonequilibrium heating
--
Polycrystalline
--
Positive magnetoresistance
--
Transport currents
--
Electric resistance
--
Electron gas
--
Heating
--
Lanthanum
--
Lanthanum
alloys
--
Magnetic fields
--
Magnetoelectronics
--
Magnetoresistance
--
Manganese oxide
--
Manganites
--
Thermal conductivity
--
Current voltage characteristics
Аннотация:
Current-voltage characteristics of the polycrystalline substituted
lanthanum
manganite La0.7Ca0.3MnO3 were experimentally studied at T - 77.4 K in magnetic fields up to 13 kOe. In these characteristics, a portion of negative differential resistivity was observed above a certain threshold value of critical current density j caused, in our opinion, by nonequilibrium heating of the electron gas due to low thermal conductivity of the manganite material. Because of the nonlinearity of the current-voltage characteristics, the field dependences of resistivity rho( H) appear extremely sensitive to the value of a transport current. In this case, the rho( H) dependences reveal both ordinary negative and positive magnetoresistance. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3573666]
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Держатели документа:
[Shaykhutdinov, K. A.
Semenov, S. V.
Popkov, S. I.
Balaev, D. A.
Bykov, A. A.
Dubrovskiy, A. A.
Petrov, M. I.
Volkov, N. V.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Shaykhutdinov, K. A.
Popkov, S. I.
Balaev, D. A.
Dubrovskiy, A. A.
Volkov, N. V.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
ИФ СО РАН
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Доп.точки доступа:
Shaykhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Semenov, S. V.; Семенов, Сергей Васильевич; Popkov, S. I.; Попков, Сергей Иванович; Balaev, D. A.; Балаев, Дмитрий Александрович; Bykov, A. A.; Быков, Алексей Анатольевич; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Petrov, M. I.; Петров, Михаил Иванович; Volkov, N. V.; Волков, Никита Валентинович
}
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10.
Electronic Structure of
p-Type La1-xMx2+MnO3 Manganites in the Ferromagnetic and Paramagnetic Phases in the LDA plus GTB Approach / V. A. Gavrichkov [et al.]> // J. Exp. Theor. Phys. - 2011. -
Vol. 112
,
Is. 5
. - P. 860-876,
DOI
10.1134/S1063776111030101. - Cited References: 47. - This study was supported financially by integration project no. 40 of the Ural and Siberian Branches of the Russian Academy of Sciences, the program "Strong Electron Correlations" of the Russian Academy of Sciences, and the Russian Foundation for Basic Research (project no. 10-02-00251-a). . - ISSN 1063-7761
РУБ
Physics, Multidisciplinary
Рубрики:
DOUBLE-EXCHANGE
COLOSSAL MAGNETORESISTANCE
THIN-FILMS
PHYSICS
LA1-XSRXMNO3
RESISTIVITY
SEPARATION
TRANSPORT
MODEL
Кл.слова (ненормированные):
Complex structure
--
Cubic materials
--
Ferromagnetic phase
--
Half metals
--
Jahn Teller effect
--
Metal properties
--
Metal types
--
Orbitals
--
P-type
--
Paramagnetic phase
--
Paramagnetic phasis
--
Quasi particles
--
Spectral intensity
--
Spin projections
--
Strong electron correlations
--
Barium
--
Density functional theory
--
Electron correlations
--
Electron density measurement
--
Electronic properties
--
Electronic structure
--
Fermi level
--
Ferromagnetic materials
--
Ferromagnetism
--
Manganese oxide
--
Manganites
--
Paramagnetic materials
--
Paramagnetism
--
Valence bands
--
Lanthanum
Аннотация:
The band structure, spectral intensity, and position of the Fermi level in doped p-type La1-xMx2+ MnO3 manganites (M = Sr, Ca, Ba) is analyzed using the LDA + GBT method for calculating the electronic structure of systems with strong electron correlations, taking into account antiferro-orbital ordering and using the Kugel-Khomskii ideas and real spin S = 2. The results of the ferromagnetic phase reproduce the state of a spin half-metal with 100% spin polarization at T = 0, when the spectrum is of the metal type for a quasiparticle with one spin projection and of the dielectric type for the other. It is found that the valence band becomes approximately three times narrower upon a transition to the paramagnetic phase. For the paramagnetic phase, metal properties are observed because the Fermi level is located in the valence band for any nonzero x. The dielectrization effect at the Curie temperature is possible and must be accompanied by filling of d(x) orbitals upon doping. The effect itself is associated with strong electron correlations, and a complex structure of the top of the valence band is due to the Jahn-Teller effect in cubic materials. DOI: 10.1134/S1063776111030101
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Публикация на русском языке
Электронная структура манганитов La[1-x]M[x]2+MnO[3] p-типа в ферромагнитной и парамагнитной фазах в рамках LDA+GTB-подхода [Текст] / В. А. Гавричков [и др.] // Журнал экспериментальной и теоретической физики. - 2011. - Т. 139 Вып. 5. - С. 983-1000
Держатели документа:
[Gavrichkov, V. A.
Ovchinnikov, S. G.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Gavrichkov, V. A.
Ovchinnikov, S. G.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Nekrasov, I. A.] Russian Acad Sci, Ural Branch, Inst Electrophys, Ekaterinburg 620016, Russia
[Pchelkina, Z. V.] Russian Acad Sci, Ural Branch, Inst Met Phys, Ekaterinburg 620990, Russia
ИФ СО РАН
Siberian Branch, Kirensky Institute of Physics, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Ural Branch, Institute of Electrophysics, Russian Academy of Sciences, Yekaterinburg, 620016, Russian Federation
Ural Branch, Institute of Metal Physics, Russian Academy of Sciences, Yekaterinburg, 620990, Russian Federation
Доп.точки доступа:
Gavrichkov, V. A.; Гавричков, Владимир Александрович; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Nekrasov, I. A.; Pchelkina, Z. V.
}
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11.
Relaxation of low-temperature
magnetoresistance and magnetization of polycrystalline (La0.5Eu0.5)(0.7)Pb0.3MnO3 / K. A. Shaykhutdinov [et al.]> // J. Phys. D. - 2011. -
Vol. 44
,
Is. 25
. - Ст. 255001,
DOI
10.1088/0022-3727/44/25/255001. - Cited References: 34. - This work was partially supported by the Lavrentyev Competition of the Young Scientist's Projects of the Siberian Branch of the Russian Academy of Sciences, Project No 12. The authors are grateful to A D Balaev and V M Sosnin for useful discussions on the results. . - ISSN 0022-3727
РУБ
Physics, Applied
Рубрики:
INSULATOR-METAL TRANSITION
GRANULAR FILMS
NANOPARTICLES
PR0.7CA0.3MNO3
PERCOLATION
MANGANITES
Кл.слова (ненормированные):
Antiferromagnetic boundaries
--
Characteristic value
--
Ferromagnetic domains
--
Ferromagnetic metal
--
Lanthanum
manganites
--
Logarithmic law
--
Low temperatures
--
Magneto-resistive effect
--
Polycrystalline
--
Relative orientation
--
Relaxation of magnetization
--
Temperature fluctuation
--
Time evolutions
--
Time interval
--
Tunnel magnetoresistance
--
Antiferromagnetism
--
Electric resistance
--
Europium
--
Ferromagnetic materials
--
Ferromagnetism
--
Grain boundaries
--
Grain size and shape
--
Lanthanum
compounds
--
Lead
--
Magnetic domains
--
Magnetic moments
--
Magnetoelectronics
--
Magnetoresistance
--
Manganese oxide
--
Magnetization
Аннотация:
Hysteresis and relaxation of magnetoresistance and magnetization of substituted (La0.5Eu0.5)(0.7)Pb0.3MnO3
lanthanum
manganite in a low-temperature region (< 40 K) are investigated. It is shown that at these temperature features of the magnetoresistive effect are determined mainly by spin-dependent tunnelling of carriers via insulating grain boundaries. As was demonstrated previously, the grain boundaries may be antiferromagnetically ordered. Therefore, relaxation of magnetization and resistance is determined by the processes of relative orientation of the magnetic moments of ferromagnetic domains neighbouring the antiferromagnetic boundary of ferromagnetic domains under the action of temperature fluctuations. It is shown that relaxation follows the logarithmic law within the time interval t similar to 10(2)-3x10(3) s. A comparison between time evolutions of the magnetic moment and resistance shows that magnetoresistance and magnetization are related as delta R = delta M-n, where n = 2.5. The obtained value n is close to the characteristic value n = 2 for tunnel magnetoresistance of granular ferromagnetic metal/insulator systems.
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Держатели документа:
[Shaykhutdinov, K. A.
Balaev, D. A.
Semenov, S. V.
Popkov, S. I.
Dubrovskiy, A. A.
Sapronova, N. V.
Volkov, N. V.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk 660036, Russian Federation
Доп.точки доступа:
Shaykhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Balaev, D. A.; Балаев, Дмитрий Александрович; Semenov, S. V.; Семенов, Сергей Васильевич; Popkov, S. I.; Попков, Сергей Иванович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Sapronova, N. V.; Volkov, N. V.; Волков, Никита Валентинович
}
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12.
Low-temperature resistance and
magnetoresistance hysteresis in polycrystalline (La0.5Eu0.5)(0.7)Pb0.3MnO3 / K. A. Shaykhutdinov [et al.]> // J. Appl. Phys. - 2011. -
Vol. 109
,
Is. 5
. - Ст. 53711,
DOI
10.1063/1.3559303. - Cited References: 20. - This study was partially supported by the Russian Foundation for Basic Research, Project No. 08-02-00259a and the Lavrentyev Competition of the Young Scientists' Projects of the Siberian Branch of the Russian Academy of Sciences, Project No. 12. . - ISSN 0021-8979
РУБ
Physics, Applied
Рубрики:
RESISTIVITY MINIMUM
MANGANITES
FILMS
Кл.слова (ненормированные):
Antiferromagnets
--
Electrical resistances
--
Ferromagnets
--
Field dependence
--
Inter-grain
--
Lanthanum
manganites
--
Low temperatures
--
Low-temperature resistance
--
Polycrystalline
--
Temperature dependence
--
Tunnel contacts
--
Antiferromagnetic materials
--
Europium
--
Ferromagnetic materials
--
Ferromagnetism
--
Hysteresis
--
Lead
--
Magnetic field effects
--
Magnetoelectronics
--
Magnetoresistance
--
Magnets
--
Manganese oxide
--
Paramagnetism
--
Superconducting materials
--
Electric resistance
Аннотация:
The behavior of temperature dependences of electrical resistance and magnetoresistance of polycrystalline substituted
lanthanum
manganite (La0.5Eu0.5)(0.7)Pb0.3MnO3 at low temperatures was thoroughly studied. A broad hysteresis was found in the field dependences of electrical resistance in the low-temperature region. Above 40 K, no hysteresis feature was observed. The temperature T = 40 K corresponds to the temperature of minimum electrical resistance and the temperature T-N to the antiferromagnet-paramagnet phase transition of the material of the intergrain boundaries. In this work we propose a model which explains the observed features of the rho(T) and rho(H) curves at temperatures below T-N by the formation of a network of ferromagnet-antiferromagnet-ferromagnet tunnel contacts. (C) 2011 American Institute of Physics. [doi:10.1063/1.3559303]
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Держатели документа:
[Shaykhutdinov, K. A.
Popkov, S. I.
Semenov, S. V.
Balaev, D. A.
Dubrovskiy, A. A.
Sablina, K. A.
Sapronova, N. V.
Volkov, N. V.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Shaykhutdinov, K. A.
Balaev, D. A.
Dubrovskiy, A. A.
Volkov, N. V.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
ИФ СО РАН
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk 660036, Russian Federation
Siberian Federal University, Krasnoyarsk 660041, Russian Federation
Доп.точки доступа:
Shaykhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Popkov, S. I.; Попков, Сергей Иванович; Semenov, S. V.; Семенов, Сергей Васильевич; Balaev, D. A.; Балаев, Дмитрий Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Sablina, K. A.; Саблина, Клара Александровна; Sapronova, N. V.; Volkov, N. V.; Волков, Никита Валентинович
}
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13.
Current channel switching
in the manganite-based multilayer structure / N. V. Volkov [et al.]> // J. Phys. Conf. Ser. - 2010. -
Vol. 200
,
Is. SECTION 5
,
DOI
10.1088/1742-6596/200/5/052031 . - ISSN 1742-6588
Кл.слова (ненормированные):
Channel switching
--
Current in planes
--
Magnetic tunnel junction
--
Magnetoresistive
--
Manganese silicide
--
Multilayer structures
--
Optical radiations
--
Potential barriers
--
Lanthanum
--
Magnetic fields
--
Manganese
--
Silicides
--
Transport properties
--
Tunnel junctions
--
Manganese oxide
Аннотация:
The transport properties of the structure La0.7Sr 0.3MnO3/depleted manganite layer/MnSi have been studied. The depleted manganite layer serves as a potential barrier between the ferromagnetic conducting La0.7Sr0.3MnO3 and MnSi layers by forming a magnetic tunnel junction. The study in the CIP (current-in-plane) geometry has revealed the effect of current channel switching between the manganite layer and the manganese silicide layer with higher conductivity. The effect is controlled by bias current, magnetic field, and optical radiation. Such switching is responsible for the features of the transport properties and the magnetoresistive and photovoltaic effects in the structure. © 2010 IOP Publishing Ltd.
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Держатели документа:
Kirensky Institute of Physics SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Institute of Engineering Physics and Radio Electronics, Krasnoyarsk, 660041, Russian Federation
Chungbuk National University, Department of Physics, Cheongju, 361-763, South Korea
Доп.точки доступа:
Volkov, N. V.; Волков, Никита Валентинович; Eremin, E. V.; Еремин, Евгений Владимирович; Patrin, G. S.; Патрин, Геннадий Семёнович; Kim, P. D.; Ким, Пётр Дементьевич; Seong-Cho, Y.; Kim, D. -H.; Chau, N.
}
Найти похожие
14.
Low-temperature resistivity of
polycrystalline (La0.5Eu 0.5)0.7Pb0.3MnO3 in a magnetic fields / K. A. Shaykhutdinov [et al.]> // J. Phys. Conf. Ser. - 2010. -
Vol. 200
,
Is. SECTION 5
,
DOI
10.1088/1742-6596/200/5/052025 . - ISSN 1742-6588
Кл.слова (ненормированные):
Antiferromagnetic grains
--
Comparative analysis
--
Ferromagnetic grain
--
Low temperatures
--
Polycrystalline
--
Specific heat measurement
--
Spin dependent tunneling
--
Transport and magnetic properties
--
Antiferromagnetism
--
Electric resistance
--
Europium
--
Grain boundaries
--
Grain size and shape
--
Lanthanum
compounds
--
Lead
--
Magnetic field effects
--
Magnetic properties
--
Magnetoresistance
--
Manganese oxide
--
Single crystals
--
Thermal variables measurement
--
Lanthanum
Аннотация:
The effect of grain boundaries on magnetoresistance (MR) of manganites have been investigated by the comparative analysis of the properties of single-crystal and polycrystalline (La0.5Eu0.5) 0.7Pb0.3MnO3. While MR of the single crystal is maximum near the Curie temperature and vanishes in the low-temperature region, the polycrystalline (La0.5Eu0.5)0.7Pb 0.3MnO3 sample exhibits high MR in the low-temperature region. In order to clarify the origin of the low-temperature MR, the transport and magnetic properties of the polycrystalline (La0.5Eu 0.5)0.7Pb0.3MnO3 in magnetic fields have been supplemented by study of magnetic properties and specific heat measurements. The results obtained could be attributed to spin-dependent tunneling between ferromagnetic grains through insulating antiferromagnetic grain boundaries. © 2010 IOP Publishing Ltd.
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,
eLibrary
Держатели документа:
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Доп.точки доступа:
Shaikhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Popkov, S. I.; Попков, Сергей Иванович; Semenov, S. V.; Balaev, D. A.; Балаев, Дмитрий Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Sablina, K. A.; Саблина, Клара Александровна; Volkov, N. V.; Волков, Никита Валентинович
}
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15.
Non-linear current-voltage characteristics
of (La0.5Eu0.5)(0.7)Pb0.3MnO3 single crystals: Possible manifestation of the internal heating of charge carriers / K. A. Shaykhutdinov [et al.]> // Physica B. - 2010. -
Vol. 405
,
Is. 24
. - P. 4961-4965,
DOI
10.1016/j.physb.2010.09.043. - Cited References: 19. - The authors are grateful to A.N. Lavrov for useful discussions on the results. This study was partially supported by the Russian Foundation for Basic Research, Project no. 08-02-00259a and the Lavrent'ev Young Scientists' Competition of the Siberian Branch of the Russian Academy of Sciences. Project no. 12. . - ISSN 0921-4526
РУБ
Physics, Condensed Matter
Рубрики:
INSULATOR-METAL TRANSITION
PR0.7CA0.3MNO3
MANGANITES
Кл.слова (ненормированные):
Manganites
--
Negative differential resistance
--
CVC
--
CVC
--
Manganites
--
Negative differential resistance
--
Applied electric field
--
Charge ordering
--
Current switching
--
CVC
--
Dielectric regions
--
Experimental data
--
Internal heating
--
Lanthanum
manganites
--
Metal-dielectric transition
--
Negative differential resistances
--
Non equilibrium
--
Non-linear
--
Sample heating
--
Temperature evolution
--
Transport currents
--
Electric fields
--
Electron gas
--
Europium
--
Heating
--
Lanthanum
--
Lead
--
Manganites
--
Negative resistance
--
Phase separation
--
Single crystals
--
Thermal conductivity
--
Manganese oxide
Аннотация:
Temperature evolution of the current-voltage characteristics (CVCs) of a single-crystal
lanthanum
manganite (La0.5Eu0.5)(0.7)Pb0.3MnO3 is investigated in a wide (up to 1 A) range of instrumental currents. Effects of a transport current and an applied electric field on the resistance of the material are studied in view of possible implementation of the charge ordering break in dielectric regions occurring due to phase separation in manganites. A negative differential resistance portion observed in the CVCs suggests the presence of a current switching effect. Below the temperature of the metal-dielectric transition in (La0.5Eu0.5)(0.7)Pb0.3MnO3, the hysteresis is observed in the CVC. The detailed analysis of the internal sample heating on the basis of experimental data on thermal conductivity showed, however, that these CVC features can be explained within the concept of non-equilibrium heating of electron gas. (C) 2010 Elsevier B.V. All rights reserved.
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Держатели документа:
[Shaykhutdinov, K. A.
Popkov, S. I.
Balaev, D. A.
Semenov, S. V.
Bykov, A. A.
Dubrovskiy, A. A.
Sapronova, N. V.
Volkov, N. V.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Shaykhutdinov, K. A.
Popkov, S. I.
Balaev, D. A.
Dubrovskiy, A. A.
Volkov, N. V.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
ИФ СО РАН
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk 660036, Russian Federation
Siberian Federal University, Krasnoyarsk 660041, Russian Federation
Доп.точки доступа:
Shaykhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Popkov, S. I.; Попков, Сергей Иванович; Balaev, D. A.; Балаев, Дмитрий Александрович; Semenov, S. V.; Семенов, Сергей Васильевич; Bykov, A. A.; Быков, Алексей Анатольевич; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Sapronova, N. V.; Volkov, N. V.; Волков, Никита Валентинович
}
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16.
Thermal expansion, polarization
and phase diagrams of Ba1-yBi2y/3Ti1-xZrxO3 and Ba1-yLayTi1-y/4O3 compounds / M. . Gorev [et al.]> // J. Phys.: Condens. Matter. - 2009. -
Vol. 21
,
Is. 7
. - Ст. 75902. - P.,
DOI
10.1088/0953-8984/21/7/075902. - Cited References: 28. - This work was supported by the Russian Foundation for Basic Research ( project no. 07-02-00069) and the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools ( project no. NSh-1011.2008.2). . - ISSN 0953-8984
РУБ
Physics, Condensed Matter
Рубрики:
HEAT-CAPACITY
CERAMICS
BA(TI1-XZRX)O-3
FERROELECTRICS
BEHAVIOR
BATIO3
BATI0.65ZR0.35O3
CONDUCTIVITY
PEROVSKITES
CHEMISTRY
Кл.слова (ненормированные):
Barium
--
Dielectric properties
--
Lanthanum
--
Phase diagrams
--
Polarization
--
Thermal stress
--
Zirconium
--
Ceramic compositions
--
Root mean squares
--
Temperature ranges
--
Temperature-dependent measurements
--
Thermal expansion co-efficient
--
Thermal-expansion properties
--
Thermal expansion
Аннотация:
The thermal expansion properties of the ceramic compositions Ba1-yLayTi1-y/4O3 (y = 0.0, 0.026, 0.036, 0.054) and Ba1-yBi2y/3Ti1-xZrxO3 (y = 0.10; x = 0.0, 0.04, 0.05, 0.10, 0.15) were determined in the temperature range 120-700 K. We report the temperature- dependent measurements of the strain, thermal expansion coefficient and the magnitude of root mean square polarization. The results obtained are discussed together with the data on the structure and dielectric properties.
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Держатели документа:
[Gorev, Michail
Bondarev, Vitaly
Flerov, Igor] Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Gorev, Michail
Bondarev, Vitaly
Flerov, Igor] Siberian Fed Univ, Inst Engn Phys, Krasnoyarsk 660041, Russia
[Maglione, Mario
Simon, Annie] Univ Bordeaux 1, ICMCB CNRS, F-33608 Pessac, France
[Sciau, Philippe] Univ Toulouse, CEMES CNRS, F-31055 Toulouse, France
[Boulos, Madona
Guillemet-Fritsch, Sophie] Univ Toulouse, CIRIMAT CNRS UPS INPT, F-31062 Toulouse, France
ИФ СО РАН
L v Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Institute of Engineering Physics, Siberian Federal University, av. Svobodny 79, Krasnoyarsk, 660041, Russian Federation
ICMCB-CNRS, Universite de Bordeaux i, 87 avenue A Schweitzer, 33608 Pessac, France
CEMES-CNRS, Universite de Toulouse, 29 rue Jeanne Marvig, 31055 Toulouse, France
CIRIMAT CNRS/UPS/INPT, Universite de Toulouse, Batiment 2R1, 118 route de Narbonne, 31062 Toulouse, France
Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Flerov, I. N.; Флёров, Игорь Николаевич; Maglione, M.; Simon, A.; Sciau, P.; Boulos, M.; Guillemet-Fritsch, S.; Russian Foundation for Basic Research [07-02-00069]; Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools [NSh-1011.2008.2]
}
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17.
Optically driven conductivity
and magnetoresistance in a manganite-based tunnel structure / N. V. Volkov [et al.]> // J. Phys. D. - 2009. -
Vol. 42
,
Is. 20
. - Ст. 205009,
DOI
10.1088/0022-3727/42/20/205009. - Cited References: 13. - This study was supported by the Russian Foundation for Basic Research (Projects Nos 08-02-00259-a and 08-02-00397-a) and the Division of Physical Sciences of the RAS, Programme 'Spin-dependent Effects in Solids and Spintronics' (Project No 2.4.2 of the Siberian Branch of the RAS). . - ISSN 0022-3727
РУБ
Physics, Applied
Рубрики:
JUNCTIONS
Кл.слова (ненормированные):
Conducting layers
--
Current-in-plane geometry
--
Dielectric layer
--
Electron hole pairs
--
Interband absorption
--
Magnetic tunnel junction
--
Magnetic tunnels
--
Multilayer structures
--
Optical radiations
--
Photoinduced change
--
Potential barriers
--
Radiation power density
--
Threshold characters
--
Tunnel structures
--
Electric resistance
--
Lanthanum
--
Light
--
Magnetic field effects
--
Magnetoelectronics
--
Magnetoresistance
--
Manganese compounds
--
Oxide minerals
--
Photovoltaic effects
--
Semiconductor junctions
--
Transport properties
--
Vehicular tunnels
--
Wind tunnels
--
Tunnel junctions
Аннотация:
In the multilayer structure, La(0.7)Sr(0.3)MnO(3)/depleted manganite layer/MnSi, the photovoltaic effect has been discovered. The depleted manganite layer in the structure is dielectric and serves as a potential barrier between the ferromagnetic conducting La(0.7)Sr(0.3)MnO(3) and MnSi layers by the formation of a magnetic tunnel junction. The photoinduced changes in the transport properties of the magnetic tunnel structure have been observed in the current-in-plane geometry. The changes are reversible and saturate at radiation power densities over 30 mW cm(-2). The photovoltaic effect has a threshold character: it reveals only at h nu > 1.17 eV. Most likely, the effect of optical radiation is related to the formation of electron-hole pairs due to interband absorption of light in the dielectric layer. A photocurrent through the tunnel junctions separating the conducting layers causes a redistribution of the current channels between the conducting layers, which influences the conductivity and the magnetoresistance of the structure.
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Держатели документа:
[Volkov, N. V.
Kim, P. D.
Eremin, E. V.
Patrin, G. S.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Volkov, N. V.
Patrin, G. S.] Siberian Fed Univ, Inst Engn Phys, Krasnoyarsk 660041, Russia
[Lee, C. G.] Changwon Natl Univ, Sch Nano & Adv Mat Engn, Chang Won 641773, Gyeongnam, South Korea
[Eremin, E. V.] Siberian State Aerosp Univ, Inst Space Technol, Krasnoyarsk 660014, Russia
ИФ СО РАН
Kirensky Institute of Physics, Russian Academy of Science, Siberian Branch, Krasnoyarsk 660036, Russian Federation
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk 660041, Russian Federation
Changwon National University, School of Nano and Advanced Materials Engineering, Gyeongnam 641-773, Changwon, South Korea
Institute of Space Technology, Siberian State Aerospace University, Krasnoyarsk 660014, Russian Federation
Доп.точки доступа:
Volkov, N. V.; Волков, Никита Валентинович; Lee, C. G.; Kim, P. D.; Ким, Пётр Дементьевич; Eremin, E. V.; Еремин, Евгений Владимирович; Patrin, G. S.; Патрин, Геннадий Семёнович; Russian Foundation for Basic Research [08-02-00259-a, 08-02-00397-a]; Division of Physical Sciences of the RAS; [2.4.2]
}
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18.
Specific features of
spin, charge, and orbital ordering in cobaltites / N. B. Ivanova [et al.]> // Phys. Usp. - 2009. -
Vol. 52
,
Is. 8
. - P. 789-810,
DOI
10.3367/UFNe.0179.200908b.0837. - Cited References: 278. - This work was financially supported by the RFBR (projects 09-02-00171-a, 07-02-00226, and 09-02-00127), the Federal Agency of Science and Innovation (grant MK-4278.2008.2), and the Presidium of the Russian Academy of Sciences Program No. 5, Quantum Physics of Condensed Media (project No. 7). I.M.E.'s work was supported by the program for Leading Science Schools of the Ministry of Education and Science of the Russian Federation (grant 2.1.1/3199). . - ISSN 1063-7869
РУБ
Physics, Multidisciplinary
Рубрики:
PEROVSKITE-TYPE OXIDES
METAL-INSULATOR-TRANSITION
HIGH-TEMPERATURE SUPERCONDUCTIVITY
ONE-DIMENSIONAL CA3CO2O6
ELECTRONIC-STRUCTURE
MAGNETIC-PROPERTIES
TRANSPORT-PROPERTIES
STATE TRANSITION
FUEL-CELLS
CRYSTAL-STRUCTURE
Кл.слова (ненормированные):
Cobalt oxides
--
Lanthanides
--
Orbital degrees of freedom
--
Orbital ordering
--
Quasi-one-dimensional
--
Spin state
--
Superconducting compounds
--
Theoretical result
--
Calcium
--
Cobalt
--
Lanthanum
--
Oxide minerals
--
Perovskite
--
Spin dynamics
--
Superconductivity
--
Cobalt compounds
Аннотация:
Complex cobalt oxides known as cobaltites are reviewed, including LnCoO(3)-based perovskite-structured rare-earth cobaltites (where Ln is
lanthanum
or a lanthanide), quasi-two-dimensional and quasi-one-dimensional cobaltites of the types LnCo(2)O(5+delta), La2CoO4, and Ca3Co2O8, and NaxCoO2 center dot yH(2)O superconducting compounds. Key experimental and theoretical results are presented, with emphasis on the interplay between charge, spin, and orbital degrees of freedom. Two problems of specific relevance to cobaltites - the spin state instability of Co3+ ions in LnCoO(3), and the nature of superconductivity in NaxCoO2 center dot yH(2)O - are also given significant attention.
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Держатели документа:
[Ivanova, N. B.
Ovchinnikov, S. G.] Siberian Fed Univ, Krasnoyarsk 660074, Russia
[Ovchinnikov, S. G.
Korshunov, M. M.
Kazak, N. V.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Korshunov, M. M.
Eremin, I. M.] Max Planck Inst Phys Komplexer Syst, D-01187 Dresden, Germany
[Eremin, I. M.] Kazan VI Lenin State Univ, Kazan 420008, Russia
ИФ СО РАН
Siberian Federal University, ul. Kirenskogo 26, 660074 Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50-38, 660036 Krasnoyarsk, Russian Federation
Max-Planck-Institut FuE R Physik Komplexer Systeme, NoE thnitzer Straue 38, D-01187 Dresden, Germany
Kazan State University, ul. Kremlevskaya 18, 420008 Kazan, Russian Federation
Доп.точки доступа:
Ivanova, N. B.; Иванова, Наталья Борисовна; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Korshunov, M. M.; Коршунов, Максим Михайлович; Eremin, I. M.; Kazak, N. V.; Казак, Наталья Валерьевна; RFBR [09-02-00171-a, 07-02-00226, 09-02-00127]; Federal Agency of Science and Innovation [MK-4278.2008.2]; Presidium of the Russian Academy of Sciences [5, 7]; Leading Science Schools of the Ministry of Education and Science of the Russian Federation [2.1.1/3199]
}
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19.
Ovchinnikov, S. G.
Covalence-induced stabilization of an intermediate-spin state and the magnetic susceptibility of LaCoO3 / S. G. Ovchinnikov, Y. S. Orlov> // J. Exp. Theor. Phys. - 2007. -
Vol. 104
,
Is. 3
. - P. 436-444,
DOI
10.1134/S1063776107030090. - Cited References: 24. - This work was supported by the program of the Division of Physical Sciences of the Russian Academy of Sciences “Strong Electronic Correlations,” the integration project SORAN-URORAN (grant no. 74), and the Krasnoyarsk krai Science Foundation . - ISSN 1063-7761
РУБ
Physics, Multidisciplinary
Рубрики:
TRANSITION
Кл.слова (ненормированные):
Band structure
--
Electron transitions
--
Ground state
--
Hamiltonians
--
Magnetic susceptibility
--
Magnetic variables measurement
--
Spin dynamics
--
Covalence induced stabilization
--
Diagnoalization
--
Orbital degeneracy
--
Spin states
--
Lanthanum
compounds
Аннотация:
The energies of terms with spins S = 0, 1, 2 have been found using exact diagonalization of the multielectron Hamlitonian of a multiband pd model for the CoO6 cluster. Co (e(g) orbital)-O hops, which form the covalent sigma bond, are shown to decrease the energy of the state (IS) with an intermediate spin (S = 1) as compared to the energy of the state (LS) with a low spin (S = 0). An analogue of the Tanabe-Sugano diagram that takes into account the covalence of the CoO6 cluster is constructed. The state with S = 1 is shown to be a ground state at certain model parameters. An increase in temperature is established to decrease the crystal field and, thus, favors the transition of the ground state from LS to IS at T = 100 K and the transition of the IS ground state to a state (HS) with a high spin (S = 2) at T = 550 K. The magnetic susceptibility of LaCoO3 is calculated with allowance for the LS, IS, and HS states and for the fact that the HS state exhibits threefold orbital degeneracy of the t(2g) shell, which results in an effective orbital moment L = 1 and the importance of spin-orbit interaction. The behavior of this magnetic susceptibility agrees well with the experimental chi(T) dependence of LaCoO3.
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Публикация на русском языке
Овчинников, Сергей Геннадьевич. Стабилизация состояния с промежуточным спином за счет ковалентности и особенности магнитной восприимчивости в LaCoO[3] [Текст] / С. Г. Овчинников, Ю. С. Орлов // Журн. эксперим. и теор. физ. - 2007. - Т. 131 Вып. 3. - С. 485-493
Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
Krasnoyarsk State Univ, Krasnoyarsk 660041, Russia
ИФ СО РАН
Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademogorodok, Krasnoyarsk, 660036, Russian Federation
Krasnoyarsk State University, Krasnoyarsk, 660041, Russian Federation
Доп.точки доступа:
Orlov, Yu. S.; Орлов, Юрий Сергеевич; Овчинников, Сергей Геннадьевич
}
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20.
Current-voltage characteristics of
break junctions of high-T-c superconductors / D. M. Gokhfeld [et al.]> // Physica C. - 2007. -
Vol. 467
,
Is. 1-2
. - P. 80-84,
DOI
10.1016/j.physc.2007.09.001. - Cited References: 19 . - ISSN 0921-4534
РУБ
Physics, Applied
Рубрики:
HIGH-TEMPERATURE SUPERCONDUCTORS
ANDREEV REFLECTION
POLYCRYSTALLINE HTSC
WEAK LINKS
COMPOSITES
Кл.слова (ненормированные):
network of weak links
--
Andreev reflection
--
hysteretic peculiarity
--
Andreev reflection
--
Hysteretic peculiarity
--
Network of weak links
--
Lanthanum
compounds
--
Mathematical models
--
Polycrystalline materials
--
Superconducting materials
--
Andreev reflection
--
Break junctions
--
Hysteretic peculiarity
--
Network of weak links
--
Current voltage characteristics
Аннотация:
The current-voltage (I-V) characteristics of break junctions of polycrystalline La1.85Sr0.15CuO4, Y0.75Lu0.25Ba2Cu3O7-delta, Bi1.8Pb0.3Sr1.9Ca2Cu3Ox and composite YBa2Cu3O7-delta + Ag are investigated. The experimental I-V curves exhibit the specific peculiarities of superconductor/normal-metal/superconductor junctions. The relation between an I-V characteristic of network of weak links and I-V dependencies of typical weak links is suggested to describe the experimental data. The I-V curves of typical weak links are calculated by the Kummel-Gunsenheimer-Nicolsky model considering the multiple Andreev reflections. (c) 2007 Elsevier B.V. All rights reserved.
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Держатели документа:
[Gokhfeld, D. M.
Balaev, D. A.
Shaykhutdinov, K. A.
Popkov, S. I.
Petrov, M. I.] Russian Acad Sci, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
L.V. Kirensky Institute, Physics SD RAS, Krasnoyarsk, 660036, Russian Federation
Доп.точки доступа:
Gokhfeld, D. M.; Гохфельд, Денис Михайлович; Balaev, D. A.; Балаев, Дмитрий Александрович; Shaykhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Popkov, S. I.; Попков, Сергей Иванович; Petrov, M. I.; Петров, Михаил Иванович
}
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