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1.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Abramova G. M., Petrakovskii G. A., Sokolov V. V., Velikanov D. A., Vorotynov A. M., Bovina A. F., Amirov A. A., Aliev A. M., Khanov L. N., Patrin G. S.
Заглавие
: New magnetic materials Cu x Mn1 − x S with a metal-insulator transition
Место публикации
: Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 54, Is. 3. - P.531–536. - ISSN 1063-7834,
DOI
10.1134/S106378341203002X
Примечания
: Cited References: 9
Предметные рубрики:
Alpha-MnS
Manganese
Аннотация:
This paper reports on first results of the synthesis and study of the thermal, structural, electrical, resonance, and magnetic properties of new sulfide materials Mex Mn1 – S (Me = Cu, 0 ˂ x ˂ 0.2) synthesized based on
manganese
monosulfide. The materials have a NaCl cubic structure at 300 K and undergo a con centration metal–insulator transition with increasing degree of substitution and with varying temperature. The magnetic transition occurs in the region of the heat capacity anomaly. The Néel temperature is slightly dependent on the copper concentration. The samples with a high copper content exhibit metallic conduction at T ˂ 260 K and semiconductor conduction at T ˃ 260 K.
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2.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Knyazev Yu.V., Ivanova N. B., Kazak N. V., Platunov M. S., Bezmaternykh L. N., Velikanov D. A., Vasiliev A. D., Ovchinnikov S. G., Yurkin G. Yu.
Заглавие
: Crystal structure and magnetic properties of Mn substituted ludwigite Co3O2BO3
Место публикации
: J. Magn. Magn. Mater.: Elsevier Science BV, 2012. - Vol. 324, Is. 6. - P.923-927. - ISSN 0304-8853,
DOI
10.1016/j.jmmm.2011.07.044
Примечания
: Cited References: 15. - The study was supported by the Russian Foundation for Basic Research (Project no. 09-02-00171-a), the Federal Agency for Science and Innovation (Rosnauka) (Project no. MK-5632.2010.2), the Physical Division of the Russian Academy of Science, the program "Strongly Correlated Electrons", Project 2.3.1.
Предметные рубрики:
BOND VALENT SUMS
COORDINATION CHEMISTRY
OXIDATION -STATE
O BONDS
COMPLEXES
MANGANESE
COBALT
Ключевые слова
(''Своб.индексиров.''): transition metal oxyborate--distinct crystallographic position--spin glass magnetic ordering
Аннотация:
The needle shape single crystals Co3−x MnxO2BO3 with ludwigite structure have been prepared. According to the X-ray diffraction data the preferable character of distinct crystallographic positions occupation by Mn ions is established. Magnetization field and temperature dependencies are measured. Paramagnetic Curie temperature value Θ=−100 K points out the predominance of antiferromagnetic interactions. Spin-glass magnetic ordering takes the onset at TN=41 K. The crystallographic and magnetic properties of Co3O2BO3:Mn are compared with the same for the isostructural analogs Co3O2BO3 and CoO2BO3:Fe.
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3.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Aplesnin S. S., Romanova O. B., Gorev M. V., Vasil'ev A. D., Demidenko O. F., Makovetskii G. I., Yanushkevich K. I.
Заглавие
: Synthesis, structure, and magnetic properties of anion-substituted
manganese
chalcogenides
Место публикации
: Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 54, Is. 7. - P.1374-1379. - ISSN 1063-7834
Примечания
: Cited References: 14. - This study was supported by the Russian Foundation for Basic Research (project nos. 12-02-00125_a, 09-02-92001-NNS_a, 11-02-98018 r_sibir'_a, and 12-02-93001 V'et_a), the Belarusian Republican Foundation for Fundamental Research-Russian Foundation for Basic Research (joint project RFBR-BRFFR no. 12-02-90004), the Belarusian Republican Foundation for Fundamental Research (project no. F08R-037), and the Ministry of Education and Science of the Russian Federation within the framework of the Analytical Department Targeted Program "Development of the Scientific Potential of the Higher School" (state contract no. 2.1.1/11763).
Предметные рубрики:
Solid-Solutions
MnSe
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4.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Makovetskii G., Demidenko O. F., Galyas A., Yanushkevich K., Aplesnin S. S., Romanova O. B., Ryabinkina L. I.
Заглавие
: Magnetic and thermoelectric properties of the Mn1-X Ni (X) S solid solutions
Место публикации
: J. Korean Phys. Soc. - 2013. - Vol. 62, Is. 12. - P.2059-2062. - ISSN 0374-4884,
DOI
10.3938/jkps.62.2059
Примечания
: Cited References: 9. - This study was supported by the Russian Foundation for Basic Research project No. 09-02-92001-NNS_a; No.12-02-90004 Bel_a; No. 12-02-00125_a; No. 11-02-98018 r_sibir_a, F12R-060
Предметные рубрики:
NICKEL SULPHIDE
TRANSITION
Ключевые слова
(''Своб.индексиров.''): antiferromagnetic materials--semiconductor conductivity--
manganese
sulphides
Аннотация:
The new sulphide Mn1-X Ni (X) S (0X a parts per thousand currency sign 0.1) solid solutions are synthesized. The structural, magnetic, electric and thermoelectric properties of the obtained materials have been studied. The X-ray diffraction analysis has shown that the synthesized Mn1-X Ni (X) S samples have a NaCl-type FCC lattice. The Mn1-X Ni (X) S samples are antiferromagnets with the Neel temperature (T (N) T (N) . The conductivity type change from the hole to the electronic at X 0.05 is revealed on the basis of the thermoelectric power measurements. The resistivity and thermopower behaviors are explained in terms of the impurity subband formation into MnS electron excitation gap.
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5.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Balaev D. A., Bulavchenko O. A., Dubrovskii A. A., Tsybulya S. V., Cherepanova S. V., Gerasimov E. Y., Shaikhutdinov K. A.
Заглавие
: Features of the structure, microstructure, and magnetic properties of
manganese
-aluminum spinels obtained in various thermal treatment conditions
Место публикации
: Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2013. - Vol. 55, Is. 7. - P.1401-1406. - ISSN 1063-7834,
DOI
10.1134/S1063783413070056
Примечания
: Cited References: 18. - This study was supported by the Russian Foundation for Basic Research (project no. 12-03-90839-mol_rf_nr) and the Ministry of Education and Science of the Russian Federation (agreement no. 8429).
Предметные рубрики:
A-SITE SPINELS
CATALYSTS
OXIDE
MN3O4
Аннотация:
The structural, microstructural, and magnetic properties of aluminum-
manganese
oxide in the ratio Mn: Al = 1: 1 in the well-crystallized and nanoheterogeneous states have been investigated. This oxide is obtained under various thermal treatment conditions and at different partial pressures of oxygen. The composition and cation distribution of the
manganese
and aluminum ions in spinel sites are determined. It is shown that the studied compound is a ferrimagnet with the Curie point T (C) a parts per thousand 26 K.
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6.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Antonova A. B., Chudin O. S., Vasiliev A. D., Rubaylo A. I., Verpekin V. V., Sokolenko W. A., Pavlenko N. I., Semeikin O. V.
Заглавие
: Chemistry of vinylidene complexes. XX. Intramolecular carbonylation of vinylidene on the MnFe center: Spectroscopic and structural study. X-ray structure of the new trimethylenemethane type MnFe complex
Место публикации
: J. Organomet. Chem.: Elsevier, 2011. - Vol. 696, Is. 4. - P.963-970. - ISSN 0022-328X,
DOI
10.1016/j.jorganchem.2010.10.035
Примечания
: Cited References: 52. - This work was partially supported by the Presidium of the Russian Academy of Sciences (Program for Basic Research, Project No. 7.18) and Russian Foundation for Basic Research (Grant No. 09-03-90745-mob_st). Authors are grateful to Prof. N.A. Ustynyuk for useful discussions, Dr. E.A. Shor and Dr. A.M. Shor for giving the data of quantum chemical study.
Предметные рубрики:
MOLECULAR-STRUCTURE
ORGANOMETALLIC CHEMISTRY
TRICARBONYL COMPLEXES
UNSATURATED CARBENES
METAL VINYLIDENES
TRANSITION-METALS
ORGANIC-SYNTHESIS
CRYSTAL-STRUCTURE
IRON TRICARBONYL
MANGANESE
Ключевые слова
(''Своб.индексиров.''):
manganese
--iron--carbonyl complexes--heteronuclear vinylidene complexes--intramolecular vinylidene carbonylation--trimethylenemethane complexes
Аннотация:
Reactions of Fe-2(CO)(9) with Cp(CO)(2)Mn=C=CHPh (1) and Cp(CO)(PPh3)Mn=C=CHPh (3) gave the heterometallic trimethylenemethane complexes eta(4)-{C[Mn(CO)(2)Cp](CO)CHPh}Fe(CO)(3) (2) and eta(4)-{C[Mn(CO)(PPh3)Cp](CO)CHPh}Fe(CO)(3) (4), respectively. The formation of the benzylideneketene [PhHC=C=C=O] fragment included in complexes 2 and 4 occurs via intramolecular coupling of the carbonyl and vinylidene ligands. The structures of 3 and 4 were determined by single crystal XRD methods. The influence of the nature of the L ligands at the Mn atom on the structural and spectroscopic characteristics of eta(4)-{C[Mn(CO)(L)Cp](CO)CHPh}Fe(CO)(3) (L = CO (2), PPh3 (4)) is considered. According to the VT H-1 and C-13 NMR spectra, complex 2 reversibly transforms in solution into mu-eta(1):eta(1)-vinylidene isomer Cp(CO)(2)MnFe(mu-C=CHPh)(CO)(4) (2a), whereas complex 4 containing the PPh3 ligand is not able to a similar transformation. (C) 2010 Elsevier B.V. All rights reserved.
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7.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Балаев, Дмитрий Александрович, Булавченко О. А., Дубровский, Андрей Александрович, Цыбуля С. В., Черепанова С. В., Герасимов Е. Ю., Шайхутдинов, Кирилл Александрович
Заглавие
: Особенности структуры, микроструктуры и магнитных свойств марганец-алюминиевых шпинелей, полученных при различных условиях термообработки
Место публикации
: Физ. тверд. тела. - 2013. - Т. 55, Вып. 7. - С. 1304-1309
Аннотация:
Исследованы структурные, микроструктурные и магнитные характеристики алюмомарганцевого оксида в соотношении Mn : Al = 1: 1 в хорошо окристаллизованном и наногетерогенном состояниях, получаемого при различных условиях температурной обработки и разном парциальном давлении кислорода. Определены состав и катионное распределение ионов марганца и алюминия в позициях шпинели. Показано, что исследованное соединение является ферримагнетиком с точкой Кюри TC~ 26 K. Работа выполнена при частичной поддержке гранта РФФИ N 12-03-90839-мол\_рф\_нр, программы Министерства образования и науки РФ (соглашение N 8429).
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8.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Aplesnin S. S., Romanova O., Gorev M. V., Velikanov D. A., Gamzatov A. G., Aliev A. M.
Заглавие
: Magnetic and thermophysical properties of GdxMn1-xS solid solutions
Место публикации
: J. Phys.: Condens. Matter. - 2013. - Vol. 25, Is. 2. - Ст.025802. - P. - ISSN 0953-8984,
DOI
10.1088/0953-8984/25/2/025802
Ключевые слова
(''Своб.индексиров.''): antiferromagnetic orders--band state--face-centered cubic lattices--magnetic phase transitions--paramagnetic phase--temperature dependence--antiferromagnetism--electron transitions--gadolinium--
manganese
--paramagnetism--sodium chloride--specific heat--organic polymers
Аннотация:
The structural, magnetic, and thermophysical properties of cation-substituted sulfides GdXMn1-XS (0.04 ? X ? 0.25) with the NaCl-type face-centered cubic lattice have been investigated. The range of existence of long-range antiferromagnetic order has been established. The anomalies observed in the temperature dependence of the specific heat correspond to the temperatures of the magnetic phase transition. The anomaly in the specific heat caused by electron transitions between the 4f levels and d band states has been observed. It has been found that the coefficient of thermal expansion decreases with increasing concentration of substituents in the magnetically ordered region and remains nearly invariable in the paramagnetic phase. В© 2013 IOP Publishing Ltd.
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9.
Вид документа
: Статья из сборника (выпуск продолж. издания)
Шифр издания
:
Автор(ы)
: Edelman I. S., Ivanova O. S., Ivantsov R. D., Velikanov D. A., Petrakovskaja E. A., Artemenko A., Curely J., Kliava J., Zaikovskiy V. I., Stepanov S.
Заглавие
: Magnetic properties and morphology of
manganese
ferrite nanoparticles in glasses
Коллективы
: Baltic Conference on Silicate Materials
Место публикации
: IOP Conf. Ser.: Mater. Sci. Eng. - 2011. - Vol. 25, Is. 1. - Ст.012017. - ,
DOI
10.1088/1757-899X/25/1/012017
Ключевые слова
(''Своб.индексиров.''): average diameter--borate glass--co-doped--electron magnetic resonance--magnetic and magneto-optical properties--magnetic behaviour--magnetic circular dichroisms--magnetic nanoparticles--magnetically ordered material--
manganese
ferrite nanoparticles--
manganese
ferrites--morphological characteristic--paramagnetic ions--resonance field--size and shape--static magnetization--temperature dependence--temperature dependent--variable temperature--visible and near infrared--alumina--dichroism--ferrite--glass--iron oxides--magnetic properties--magnetic resonance--magnetocrystalline anisotropy--
manganese
--
manganese
oxide--nanoparticles--paramagnetism--silicates--spectroscopy--nanomagnetics
Аннотация:
Static magnetization (SM), magnetic circular dichroism (MCD) and electron magnetic resonance (EMR) studies are reported of borate glasses 22.5 K 2O-22.5 Al 2O 3-55 B 2O 3 co-doped with iron and
manganese
oxides. In as-prepared glasses the paramagnetic ions usually are in diluted state; however, if the ratio of the iron and
manganese
oxides in the charge is 3/2, magnetic nanoparticles are found already in as-prepared glass. After additional thermal treatment all glasses show magnetic behaviour, MCD and EMR due to the presence of magnetic nanoparticles with characteristics close to those of
manganese
ferrite. By computer simulating the EMR spectra at variable temperatures, their morphological characteristics are deduced: relatively broad size and shape distribution with average diameter of ca. 3-4 nm. The characteristic temperature-dependent shift of the apparent resonance field is explained by a strong temperature dependence of the magnetocrystalline anisotropy in the nanoparticles. The potassium-alumina-borate glasses containing magnetic nanoparticles represent a novel class of materials: "transparent magnets". Indeed, they remain transparent in a part of visible and near infrared spectral range while showing magnetic and magneto-optical properties characteristic of magnetically ordered materials.
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10.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Popov E. A., Kotlyarskii M. M., Edelman I. S.
Заглавие
: Temperature and field dependence of exciton-magnon absorption of NaMnCl//3.
Место публикации
: Physica Status Solidi B - Basic Research. - 1985. - Vol. 132, Is. 2. - P.465-470. - ISSN 0370-1972
Ключевые слова
(''Своб.индексиров.''): band structure--light - absorption--sodium compounds - optical properties--exciton-magnon absorption--sodium
manganese
chloride--magnetic materials
Аннотация:
The behaviour of the optical absorption bands of NaMnCl//3 is experimentally studied in the region of the **6A//1//g to **4A//1//g, **4E//g(**4G) transition of the Mn**2** plus ion in the temperature range 1. 8 to 20 K and in magnetic fields up to 20 T. Exciton and its 'hot' magnon sidebands are observed in the spectrum. The anomalous temperature dependence of the exciton-magnon bands intensity is explained by participation of magnons with wave vector K does not equal 0 in absorption. The low energy exciton-magnon band is supposed to be due to simultaneous creation of an exciton and annihilation of three thermally created magnons.
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11.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Volkov N. V., Rautskii M. V., Eremin E. V., Patrin G. S., Kim P. D., Lee C. G.
Заглавие
: Response of a manganite-based magnetic tunnel structure to microwave radiation
Коллективы
: Moscow International Symposium on Magnetism
Место публикации
: Diffusion and Defect Data Pt.B: Solid State Phenomena. - 2012. - Vol. 190. - P.125-128. - ISBN 978,
DOI
10.4028/www.scientific.net/SSP.190.125. - ISBN 9783037854365
Ключевые слова
(''Своб.индексиров.''): magnetic tunnel structure--microwave detection effect--spintronics--current flowing--current-in-plane geometry--magnetic tunnels--magnetization dynamics--microwave detection--non-linearity--rectification effects--spin-polarized currents--voltage signals--magnetic materials--magnetoelectronics--
manganese
oxide--microwaves--magnetism
Аннотация:
We demonstrate that a magnetic tunnel structure irradiated by microwaves can generate a significant voltage signal due to the rectification effect. The measurements were carried out using current-in-plane geometry with a current flowing parallel to the interfaces in the structure. A value of the microwave-induced voltage strongly depends on a bias current and can be driven by a magnetic field. The rectification effect is discussed both in "Classical" terms of nonlinearity of the current-voltage characteristic and using a mechanism that involves the interplay between the spinpolarized current and magnetization dynamics in the magnetic tunnel structure. В© (2012) Trans Tech Publications.
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12.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Edelman I. S., Ivanova O. S., Ivantsov R. D., Petrakovskaja E. A., Velikanov D. A., Zabluda V. N., Hennet L., Thiaudiere D., Saboungi M.-L., Zubavichus Y. V., Veligzhanin A. A., Zaikovskiy V. I., Stepanov S., Curély J., Kliava J.
Заглавие
: Transperant nanomagnetic materials based on borate glasses co-doped with iron,
manganese
and rare-earth elements
Коллективы
: International Conference on Nanostructured Materials (11; 2012 ; August ; 26 – 31; Rhodes, Greece)
Место публикации
: XI International Conference on Nanostructured Materials. - 2012. - P.
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13.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Kosyrev N. N., Varnakov S. N., Tarasov I. A., Lyashenko S. A., Ovchinnikov S. G.
Заглавие
: Characterization of
manganese
and iron silicides by in situ spectral generalized magneto-optical ellipsometry
Коллективы
: Workshop Ellipsometry (7; 2012 ; март ; 5-7; Leipzig, Germany)
Место публикации
: 7th Workshop on Ellipsometry: abstract book. - 2012. - P. - 82
Аннотация:
Dilute magnetic semiconductors (DMS) combine the electronic transport properties of semiconductors and memory characteristics of magnetic materials. The complementary properties of semiconductor and ferromagnetic material can manipulate both degrees of freedoms of electrons0 spins and charges for spintronic devices. In recent years, group IV(Ge,Si)-based DMSs attract considerable experimental effort due to the compatibility with mainstream silicon technology. In ourworkwe present the investigation of structural,magnetic and optical properties ofmanganese and iron silicides thin films on Si (100) substrate by in situ spectral generalizedmagneto-optical ellipsometry. Themeasurementswere performed by spectral and laser ellipsometers (“Spectroscan“ and “LEF-71“ respectively by Institute Semiconductors Physics SB RAS), optimized tomeasure not only traditional ellipsometric parameters, but also magneto-optical response of the sample. The magnetoellipsometers were integrated into the ultrahigh vacuum chambers of molecular beam epitaxy setup, which allowed to control the optical and magnetic properties of thin films directly in the growth process. As a result of the magneto-optical response analysis, it was found that iron and
manganese
silicides in magnetic phase were formed on the Si surface and by analysis of the ellipsometric parameters dependence on evaporation time the silicide nanoclusters were identified and their structural properties were found. The work was supported by project 4.1 of the OFN RAS, project 27.10 of the Presidium RAS, integration project22 of SB RAS and FEB RAS, and also the FCP NK-744P/6 .
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14.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Varnakov S. N., Gomoyunova M. V., Grebenyuk G. S., Zabluda V. N., Ovchinnikov S. G., Pronin I. I.
Заглавие
: Initial growth stages of
manganese
films on the Si(100)2 x 1 surface
Коллективы
: Russian-German Laboratory at HZB BESSY; Ministry of Education and Science of the Russian Federation [14V37.21.1276]; Russian Foundation for Basic Research [13-02-00398, 13-02-01265]
Место публикации
: Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2014. - Vol. 56, Is. 2. - P.380-384. - ISSN 1063-7834,
DOI
10.1134/S1063783414020310. - ISSN 1090-6460
Примечания
: Cited References: 20. - This study was supported by the Russian-German Laboratory at HZB BESSY, the Ministry of Education and Science of the Russian Federation (agreement 14V37.21.1276), and the Russian Foundation for Basic Research (project nos. 13-02-00398 and 13-02-01265).
Предметные рубрики:
PHOTOELECTRON-SPECTROSCOPY
ROOM-TEMPERATURE
SILICIDES
SILICON
Аннотация:
Initial growth stages of
manganese
films on the Si(100)2 × 1 surface at room temperature have been investigated using high-energy-resolution photoelectron spectroscopy, and the dynamics of the variation in their phase composition and electronic structure with the coverage growth has been revealed. It has been shown that the interfacial
manganese
silicide and the film of the solid solution of silicon in
manganese
are sequentially formed under these conditions on the silicon surface. The growth of the metal
manganese
film starts after the deposition of ~0.9 nm Mn. Segregation of silicon on the film surface is observed in the range of coverages up to 1.6 nm Mn.
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15.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Volkov N. V., Solovyev L. A., Eremin E. V., Sablina K. A., Misjul S. V., Molokeev M. S., Zaitsev A. I., Gorev M. V., Bovina A. F., Mikhashenok N. V.
Заглавие
: Temperature-dependent features of Pb3Mn7O15 crystal structure
Место публикации
: Physica B: Elsevier Science BV, 2012. - Vol. 407, Is. 4. - P.689-693. - ISSN 0921-4526,
DOI
10.1016/j.physb.2011.11.058
Примечания
: Cited References: 23. - This study was supported by the Russian Foundation for Basic Research 'Siberia', Project no. 09-02-98003, and the Siberian Branch of the Russian Academy of Sciences, integration Project no. 101. This work was partially supported by the Russian Ministry of Education and Science Federal Program Grant P2430.
Предметные рубрики:
PROFILE REFINEMENT
PHASE-TRANSITIONS
Ключевые слова
(''Своб.индексиров.''):
manganese
--layered compounds--x-ray diffraction
Аннотация:
The results of X-ray diffraction (XRD) structural investigations of Pb3Mn7O15 crystals carried out for a wide temperature range including the room temperature are presented. It has been observed for the first time that with increasing temperature the Pb3Mn7O15 crystals transform from the orthorhombic (Pnma space group) to the hexagonal (P6(3)/mcm space group) structure. The results of the thermal analysis have revealed two sharp peaks in the temperature dependence correlating with the XRD data. According to the results of the group-theoretical analysis, the Pb3Mn7O15 symmetry transformation can be described as P6(3)/mcm M-2(-)(12-4)(eta,0,0) over right arrow Pnma. (C) 2011 Elsevier B.V. All rights reserved.
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16.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Varnakov S. N., Gomoyunova M. V., Grebenyuk G.S ., Zabluda V. N., Ovchinnikov S. G., Pronin I. I.
Заглавие
: Solid-phase synthesis of
manganese
silicides on the Si(100)2 x 1 surface
Коллективы
: Russian-German Laboratory at HZB BESSY; Russian Foundation for Basic Research [13-02-00398, 13-02-01265]; Council on Grants from the President of the Russian Federation for Support of the Leading Scientific Schools [NSh-1044.2012.2]; Siberian Branch of the Russian Academy of Sciences [85]; Ural Branch of the Russian Academy of Sciences [85]
Место публикации
: Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2014. - Vol. 56, Is. 4. - P.812-815. - ISSN 1063-7834,
DOI
10.1134/S1063783414040337. - ISSN 1090-6460
Примечания
: Cited References: 20. - This study was supported by the Russian-German Laboratory at HZB BESSY, the Russian Foundation for Basic Research (project nos. 13-02-00398 and 13-02-01265), the Council on Grants from the President of the Russian Federation for Support of the Leading Scientific Schools (grant no. NSh-1044.2012.2), and the Integration Project No. 85 of the Siberian and Ural Branches of the Russian Academy of Sciences.
Предметные рубрики:
PHOTOELECTRON-SPECTROSCOPY
GROWTH
FILMS
Аннотация:
The solid-phase synthesis of
manganese
silicides on the Si(100)2 × 1 surface coated at room temperature by a 2-nm-thick
manganese
film has been investigated using high-energy-resolution photoelectron spectroscopy with synchrotron radiation. The dynamics of variation of the phase composition and electronic structure of the near-surface region with increasing sample annealing temperature to 600°C, has been revealed. It has been shown that, under these conditions, a solid solution of silicon in
manganese
, metallic
manganese
monosilicide MnSi, and semiconductor silicide MnSi1.7 are successively formed on the silicon surface. The films of both silicides are not continuous, with the fraction of the substrate surface occupied by them decreasing with increasing annealing temperature. The binding energies of the Si 2p and Mn 3p electrons in the compounds synthesized have been determined.
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17.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Myagkov V. G., Matsunin A. A., Mikhlin Y. L., Zhigalov V. S., Bykova L. E., Tambasov I. A., Bondarenko G. N., Patrin G. S., Velikanov D. A.
Заглавие
: Synthesis of ferromagnetic germanides in 40Ge/60Mn films: Magnetic and structural properties
Коллективы
: Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism
Место публикации
: Solid State Phenom.: Selected, peer reviewed papers/ ed. S. G. Ovchinnikov: Trans Tech Publications, 2014. - Vol. 215: Trends in Magnetism: Nanomagnetism (EASTMAG-2013). - P.167-172. - ISSN 978-303835054-5,
DOI
10.4028/www.scientific.net/SSP.215.167. - ISSN 1662-9779
Примечания
: Cited References: 28
Ключевые слова
(''Своб.индексиров.''): diluted semiconductors--
manganese
germanides--solid-state reactions--spinodal decomposition
Аннотация:
Solid-state reactions between Ge and Mn films are systematically examined using X-ray diffraction, photoelectron spectroscopy and magnetic measurements. The films have a nominal atomic ratio Ge:Mn = 40:60 and are investigated at temperatures from 50 to 500 °C. It is established that after annealing at ~120 °C, the ferromagnetic Mn5Ge phase is the first phase to form at the 40Ge/60Mn interface. Increasing the annealing temperature to 500 °C leads to the formation of the ferromagnetic phase with a Curie temperature TC ~ 360 K and magnetization MS ~ 140-200 emu/cc at room temperature. Analysis of X-ray diffraction patterns and the photoelectron spectra suggests that the increased Curie temperature and magnetization are related to the migration of C and O atoms into the Mn5Ge3 lattice and the formation of the Nowotny phase Mn5GeXCxOy. The initiation temperature (~120 °C) of the Mn5Ge3 phase is the same both for solid-state reactions in Ge/Mn films, as well as for phase separation in GexMn1-x diluted semiconductors. We conclude that the synthesis of the Mn5Ge3 phase is the moving force for the spinodal decomposition of the GexMn1-x diluted semiconductors. © (2014) Trans Tech Publications, Switzerland.
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18.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Verpekin V. V., Kondrasenko A. A., Chudin O. S., Vasiliev A. D., Burmakina G. V., Pavlenko N. I., Rubaylo A. I.
Заглавие
: Chemistry of vinylidene complexes. XXIII. Binuclear rhenium-palladium vinylidene bridged complexes, their reactions with diiron nonacarbonyl
Место публикации
: J. Organomet. Chem.: Elsevier Science, 2014. - Vol. 770. - P.42-50. - ISSN 0022-328X,
DOI
10.1016/j.jorganchem.2014.07.024. - ISSN 1872-8561
Примечания
: Cited References: 56. - This article is dedicated to the memory of Alla B. Antonova.
Предметные рубрики:
TRANSITION-METAL-COMPLEXES
CATIONIC CARBYNE COMPLEXES
RAY CRYSTAL-STRUCTURE
MOLECULAR-STRUCTURE
HETEROBIMETALLIC COMPLEXES
LIGANDS
MANGANESE
CLUSTERS
DINUCLEAR
PD2CL2(MU-PH2PCH2PPH2)2
Ключевые слова
(''Своб.индексиров.''): rhenium--palladium--iron--vinylidene complexes--heterometallic complexes
Аннотация:
The reaction of [Cp(CO)2ReCCHPh] (1) with [Pd(PPh3)4] followed by the treatment of resulting [Cp(CO)2RePd(μ-CCHPh)(PPh3)2] (2) with diphosphines (dppe, dppp) gave new complexes [Cp(CO)2RePd(μ-CCHPh)(dppe)] (3) and [Cp(CO)2RePd(μ-CCHPh)(dppp)] (4). Treatment of the synthesized complexes with [Fe2(CO)9] led to mixtures of [Cp(CO)2ReFe(μ-CCHPh)(CO)4] (5), [(dppe)PdFe2(CO)8] (6), [CpReFe2(μ3-CCHPh)(CO)8] (7), [CpReFePd(μ3-CCHPh)(CO)5(dppe)] (8) and of 5, [(dppp)PdFe2(CO)8] (9), [CpReFePd(μ3-CCHPh)(CO)5(dppp)] (10), respectively. The main products of both reactions were trinuclear μ3-vinylidene clusters 8 and 10. Reactions of the trinuclear μ3-vinylidene ReFePd clusters 8 and 10 with Fe2(CO)9 were also studied. New complexes were characterized by IR, 1H, 13C, 31P NMR spectroscopy and cyclic voltammetry. The structure of [CpReFe2(μ3-CCHPh)(CO)8] was determined by single-crystal X-ray diffraction.
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19.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Romanova O. B., Aplesnin S. S., Vorotynov A. M., Makovetskii G. I., Demidenko O. F., Yanushkevich K. I.
Заглавие
: Peculiarities of transport, resonance and optical properties of the anion-substituted chalcogenides
manganese
Коллективы
: Moscow International Symposium on Magnetism, Московский государственный университет им. М.В. Ломоносова
Место публикации
: Moscow Int. Symp. on Magnet. (MISM-2014): Book of abstracts. - 2014. - Ст.1PO-K-9. - P.542. - ISBN 978-5-91978-025-0
Материалы конференции
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20.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Vasilyeva I. G., Dovlitova L. S., Zaikovskii V. I., Malakhov V. V., Edel'man I. S., Stepanov A. S., Aleksandrov K. S.
Заглавие
: Actual composition and structure of
manganese
ferrite nanoparticles dispersed in the borate glass matrix
Место публикации
: Doklady Chemistry. - 2005. - Vol. 401, Is. 1-3. - P.47-50. - ISSN 0012-5008,
DOI
10.1007/s10631-005-0029-y
Ключевые слова
(''Своб.индексиров.''): boric acid--ferrite--glass--
manganese
derivative--analytic method--article--chemical composition--chemical structure--nanoparticle--stoichiometry--structure analysis--transmission electron microscopy--x ray analysis
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