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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Saunin V. N., Telegin S. V., Kalita V. I., Denisova E. A.
Заглавие : Formation of bulk magnetically soft materials with nano- and amorphous structure using plasma spraying
Место публикации : Inorganic Materials: Applied Research. - 2012. - Vol. 3, Is. 3. - P.201-209. - ISSN 2075-1133, DOI 10.1134/S2075113312030070
Ключевые слова (''Своб.индексиров.''): amorphous structure--coatings--nanostructure--plasma sputtering--plasmatron--amorphous coating--amorphous structures--magnetically soft materials--plasma sputtering--plasmatrons--coatings--magnetic properties--nanostructures--plasma spraying--plasma jets
Аннотация: A technique for producing coatings with an amorphous and nanostructure using a plasmatron with a gas-dynamic nozzle is proposed. The effect of the technical parameters of plasma spraying on the structure and magnetic properties of amorphous coatings is investigated. В© Pleiades Publishing, Ltd., 2012.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Avramov P. V., Kuzubov A. A., Sakai S., Entani S., Naramoto H., Eliseeva N. S.
Заглавие : Spin states of 2D nanocomposites of Ni and V nanoclusters on hexagonal h-BN, BC3 and graphene
Коллективы : Russian Scientific Foundation [14-13-00139]
Место публикации : J. Mater. Sci. Technol. - 2015. - Vol. 31, Is. 10. - P.979-985. - ISSN 1005-0302, DOI 10.1016/j.jmst.2015.08.008
Примечания : Cited References:21. - The work of Russian team was supported by Russian Scientific Foundation (Grant No. 14-13-00139). P.V.A. acknowledges JAEA ASRC and Molecular Spintronics Group for hospitality and fruitful collaboration.
Предметные рубрики: BORON-NITRIDE
FILMS
Ключевые слова (''Своб.индексиров.''): electronic structure--metal nanostructure--nanocomposites--graphene--h-bn--bc3--spin states
Аннотация: Atomic and electronic structures of adsorbed nickel and vanadium atoms and nanoclusters (Ni-n and V-n, n = 1-10) on hexagonal h-BN and BC3 lattices were studied using DFT PBE/PBC/PW (Perdew-Burke-Ernzerhof potential of density functional theory/periodic boundary conditions/plane wave basis set) technique. For the sake of comparison the structure and properties of the same nanoclusters deposited on pristine graphene were calculated as well. It was found that for all types of supports an increase of n from 1 to 10 leaded to decrease of coordination types from eta(6) to eta(2) and eta(1). The h-BN- and BC3-based nanocomposites were characterized by high (up to 18 mu for Ni10/BC3) magnetic moments of the nanoclusters and featured by positive binding energies. The graphene-based nanocomposites revealed energetic stability and, in general, lower magnetic moments per unit cell. The direct potential energy barriers for migration of Ni eta(2)/eta(2) and eta(6)/eta(6) types of dimers on graphene were low (10.9-28.9 kJ/mol) with high reverse barriers for eta(6)/eta(6) dimers, which favored dynamically equilibrated Ni clusterization on graphene. Copyright (C) 2015, The editorial office of Journal of Materials Science & Technology. Published by Elsevier Limited. All rights reserved.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Val'kov V. V., Aksenov S. V.
Заглавие : Effects of inelastic spin-dependent electron transport through a spin nanostructure in a magnetic field
Место публикации : J. Exp. Theor. Phys.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2011. - Vol. 113, Is. 2. - P266-275. - ISSN 1063-7761, DOI 10.1134/S1063776111060070
Примечания : Cited References: 30. - This study was carried out under the program of the Physical Science Department of the Russian Academy of Sciences, Federal Target Program "Scientific and Scientific-Pedagogical Personnel of Innovative Russia in 2009-2013," Interdisciplinary Integration project no. 53 of the Siberian Branch of the Russian Academy of Sciences, and under partial support from the Russian Foundation for Basic Research (project no. 09-02-00127). The research work of one of the authors (S.V.A) was supported by grant no. MK-1300.2011.2 from the President of the Russian Federation.
Предметные рубрики: CONDUCTION
ANISOTROPY
JUNCTIONS
Ключевые слова (''Своб.индексиров.''): antiferromagnetic coupling--colossal magnetoresistance effect--iv characteristics--metallic contacts--potential profiles--spectral characteristics--spin dependent transport--spin dimer--spin moments--spin-dependent electron transport--spin-flip process--tight-binding approximations--transmission coefficients--antiferromagnetism--colossal magnetoresistance--current voltage characteristics--electric resistance--nanostructures--transport properties--magnetic field effects
Аннотация: The transport properties and current-voltage (I-V) characteristics of a system of spin dimers with antiferromagnetic coupling arranged between metallic contacts are investigated in the tight binding approximation using the Landauer-Buttiker formalism. It is shown that the s-d(f) exchange interaction between the spin moments of the electrons being transported and the spins of the nanostructure leads to the formation of a potential profile as well as its variation due to spin-flip processes. As a result, the spin-dependent transport becomes inelastic, and the transmission coefficient and the I-V characteristic are strongly modified. It is found that the application of a magnetic field induces additional transparency peaks in the spectral characteristic of the system and causes the colossal magnetoresistance effect.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Fedorov A. S., Kuzubov A. A., Visotin M. A., Tomilin F. N.
Заглавие : New method for calculations of nanostructure kinetic stability at high temperature
Коллективы : Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium, Институт физики им. Л.В. Киренского Сибирского отделения РАН , Russian Foundation for Basic Research [N15-02-06869A]; President of Russia Scientific School Program [NSh 7559.2016.2]
Место публикации : J. Magn. Magn. Mater.: Elsevier Science, 2017. - Vol. 440: EURO-Asian Symposium on Trends in Magnetism (EASTMAG) (AUG 15-19, 2016, Siberian Fed Univ, Krasnoyarsk, RUSSIA). - P.167-170. - ISSN 0304-8853, DOI 10.1016/j.jmmm.2016.12.131. - ISSN 1873-4766(eISSN)
Примечания : Cited References:8. - The work was supported by the Russian Foundation for Basic Research Grant N15-02-06869A and by President of Russia Scientific School Program NSh 7559.2016.2. The authors would like to thank Joint Supercomputer Center of RAS, Moscow, for the access to the MVS 100K cluster and Institute of Computational Modelling of SB RAS, Krasnoyarsk, for providing the computational resources.
Предметные рубрики: AUGMENTED-WAVE METHOD
Ключевые слова (''Своб.индексиров.''): kinetic stability--nanostructures--graphene nanoribbons
Аннотация: A new universal method is developed for determination of nanostructure kinetic stability (KS) at high temperatures, when nanostructures can be destroyed by chemical bonds breaking due to atom thermal vibrations. The method is based on calculation of probability for any bond in the structure to stretch more than a limit value L-max, when the bond breaks. Assuming the number of vibrations is very large and all of them are independent, using the central limit theorem, an expression for the probability of a given bond elongation up to L-max is derived in order to determine the KS. It is shown that this expression leads to the effective Arrhenius formula, but unlike the standard transition state theory it allows one to find the contributions of different vibrations to a chemical bond cleavage. To determine the KS, only calculation of frequencies and eigenvectors of vibrational modes in the groundstate of the nanostructure is needed, while the transition states need not be found. The suggested method was tested on calculating KS of bonds in some alkanes, octene isomers and narrow graphene nanoribbons of different types and widths at the temperature T=1200 K. The probability of breaking of the C-C bond in the center of these hydrocarbons is found to be significantly higher than at the ends of the molecules. It is also shown that the KS of the octene isomers decreases when the double C=C bond is moved to the end of the molecule, which agrees well with the experimental data. The KS of the narrowest graphene nanoribbons of different types varies by 1-2 orders of magnitude depending on the width and structure, while all of them are by several orders of magnitude less stable at high temperature than the hydrocarbons and benzene.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shevtsov D. V., Lyashchenko S. A., Varnakov S. N.
Заглавие : An ultrahigh-vacuum multifunctional apparatus for synthesis and in situ investigation of low-dimensional structures by spectral magnetoellipsometry in the temperature range of 85–900 K
Место публикации : Instrum. Exp. Tech. - 2017. - Vol. 60, Is. 5. - P.759-763. - ISSN 00204412 (ISSN), DOI 10.1134/S0020441217050086
Примечания : Cited References: 19. - This study was supported by a Grant of the President of the Russian Federation for Support of Leading Schools (project no. NSh-7559.2016.2), by the Russian Foundation for Basic Research, the Government of Krasnoyarsk krai, and the Krasnoyarsk krai foundation for support of scientific and research and technical activity as a part of the scientific project no. 16-42-243058.
Ключевые слова (''Своб.индексиров.''): semiconducting silicon--temperature distribution--ultrahigh vacuum--ellipsometric measurements--in-situ investigations--low dimensional structure--metallic nanostructure--multifunctional apparatus--optical and magneto-optical properties--temperature dependence--temperature range--optical properties
Аннотация: This paper presents the results of modernizing an ultrahigh-vacuum multifunctional apparatus that allows one to obtain semiconductor or metallic nanostructures in a single technological cycle and to investigate their optical and magneto-optical properties in a temperature range of 85–900 K. The capabilities of the developed system were demonstrated based on the example of studying the temperature dependence of the bulk Si permittivity via spectral ellipsometric measurements. © 2017, Pleiades Publishing, Inc.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Tkachenko V. A., Tsipotan A. S., Slabko V. V., Aleksandrovsky A. S.
Заглавие : Three-dimensional model of quantum dots'' self-assembly under the action of laser radiation
Место публикации : Комп. оптика: Институт систем обработки изображений РАН, 2017. - Т. 41, № 4. - С.577-580. - ISSN 0134-2452, DOI 10.18287/2412-6179-2017-41-4-577-580
Примечания : Библиогр.: 14. - The work was funded by the Russian Foundation for Basic Research (RFBR) and Krasnoyarsk Krai administration under research project No. 16-42-240410r_a, RFBR research project No. 16-32-00129 and by the Ministry of Education and Science of the Russian Federation (Grant 3.6341.2017/VU).
Ключевые слова (''Своб.индексиров.''): nanostructure fabrication--plasmonics--optical tweezers or optical manipulation
Аннотация: This study considered a process of quantum dots' self-assembly into nanostructure arrays with predefined geometry, which proceeds in the external resonant laser field. We considered the simplest case of assembling a stable structure of two particles. The problem was solved numerically using a three-dimensional model of Brownian dynamics. The idea of the method is that the attraction of the dots occurs due to the interaction of resonantly induced dipole moments, with the dots being then captured by the Van der Waals force. Finally, a three-dimensional model was considered; the average nanoparticle aggregation time as a function of the laser radiation wavelength was calculated; the probability of such structures' being formed was estimated for the calculated average aggregation time and for the laser pulse duration used in the experiment. The wavelength of the maximum probability was found to be shifted from the single particle resonance wavelength of 525 nm to the red area of 535 nm, which is in qualitative agreement with the redshift of the resonance wavelength of interacting particles.
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Вид документа : Статья из сборника (выпуск монографической серии)
Шифр издания :
Автор(ы) : Zhuravlev V., Nevmyvaka A., Itin V., Velikanov D. A.
Заглавие : Mechanochemical synthesis of hexagonal ferrites BaFe12O19
Коллективы : International Conference on Radiation-Thermal Effects and Processes in Inorganic Materials
Место публикации : Key Eng. Mater. - 2018. - Vol. 781 KEM. - P.119-124. - , DOI 10.4028/www.scientific.net/KEM.781.119
Примечания : Cited References: 15
Ключевые слова (''Своб.индексиров.''): ferromagnetic resonance--magnetization curve--magnetocrystalline anisotropy--mechanochemical synthesis--nanostructure hexaferrites
Аннотация: The phase composition, structural parameters, and basic magnetic characteristics of BaFe12O19 hexaferrites prepared by the mechanochemical synthesis with subsequent annealing at a temperature of 1000°С and 1100°С for 1 h are investigated. The influence of the annealing temperature on the properties of synthesized materials is analyzed. Values of the saturation magnetization and the anisotropy field are determined. It is established that annealing temperature in the interval 1000 - 1100 °C does not significantly affect on the phase composition and the size of nanoparticles. The value of the anisotropy field increases substantially with increasing temperature.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bondarev I. A., Rautskii M. V., Yakovlev I. A., Volochaev M. N., Lukyanenko A. V., Tarasov A. S., Volkov N. V.
Заглавие : Study of the Photovoltage in Mn/SiO2/n-Si MOS Structure at Cryogenic Temperatures
Место публикации : Semiconductors. - 2019. - Vol. 53, Is. 14. - P.88-92. - ISSN 1063-7826 (ISSN), DOI 10.1134/S1063782619140045. - ISSN 1090-6479 (eISSN)
Примечания : Cited References: 27. - The work was supported by the Russian Foundation for Basic Research project no. 17-02-00302.
Предметные рубрики: NANOSTRUCTURE DEVICES
Аннотация: Lateral photovoltaic effect in metal/insulator/semiconductor hybrid structures is a significant phenomenon for spintronics, as it establishes the interplay between the optical irradiation, electronic transport and spin-dependent properties of carriers. In present work we investigated photovoltaic phenomena in Mn/SiO2/n-Si MOS structure. The sample was prepared on a single-crystal n-Si (phosphorus-doped) substrate. The SiO2 layer with thickness of 1.5 nm was formed on the substrate surface by a chemical method. Manganese film with thickness of 15nm was deposited by thermal evaporation in ultrahigh vacuum in the “Angara” chamber. It was observed that at T 45 K the values of lateral and transversal photovoltage nonmonotonically depend on the temperature and such dependences show complex behavior. Features of the photovoltage dependence on temperature, in the region above 20 K are explained by the change of carriers’ mobility and the competition between carriers’ drift velocity in the electric field of the space-charge region and their diffusion rate in the transverse and lateral directions. Below 20 K, the main contribution into the photovoltage is given by hot electrons injected from surface states levels to the conduction band. A strong magnetic field influence on the photovoltage below 20 K was observed. We associate it with the Lorenz force effect on the hot electrons, although we also don’t exclude the presence of mechanisms caused by spindependent scattering and recombination of hot electrons at occupied donor states.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Smolyakov D. A., Tarasov A. S., Yakovlev I. A., Volochaev M. N.
Заглавие : Magnetoimpedance Effect in a SOI-Based Structure
Место публикации : Semiconductors. - 2019. - Vol. 53, Is. 14. - P.98-100. - ISSN 1063-7826 (ISSN), DOI 10.1134/S1063782619140215. - ISSN 1090-6479 (eISSN)
Примечания : Cited References: 10. - This study was supported by the Russian Foundation for Basic Research, project no. 18-32-00035. The work was partially supported by the Ministry of Education and Science of the Russian Federation and by Siberian Branch of the Russian Academy of Sciences (Project II.8.70) and Fundamental research program of the Presidium of the RAS no. 32 “Nanostructures: physics, chemistry, biology, basics of technologies”.
Предметные рубрики: NANOSTRUCTURE DEVICES
Аннотация: This paper presents the results of the study the transport properties of the SOI-based structure. Measurements were carried out on an alternating current with an external magnetic field in a wide temperature range. The influence of the magnetic field was found. We associate this effect with the influence on the surface states located at the interface, this appears as a change of the energy of their levels. This effect is enhanced by the nanoscale of the silicon channel.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kremneva A. M., Fedorov A. V., Bulavchenko O. A., Knyazev Yu. V., Saraev A. A., Yakovlev V. A., Kaichev V. V.
Заглавие : Effect of calcination temperature on activity of Fe2O3-Al2O3 nanocomposite catalysts in CO oxidation
Коллективы : Russian Science FoundationRussian Science Foundation (RSF) [17-73-20157]; National center of investigation of catalysts" at Boreskov Institute of Catalysis
Место публикации : Catal. Lett. - 2020. - Vol. 150. - P.3377-3385. - ISSN 1011-372X, DOI 10.1007/s10562-020-03250-8. - ISSN 1572-879X(eISSN)
Примечания : Cited References: 31. - This work was supported by the Russian Science Foundation (Grant No. 17-73-20157). The experiments were performed using facilities of the shared research center "National center of investigation of catalysts" at Boreskov Institute of Catalysis. The authors thank A.Yu. Gladky for the TPR measurements and Z.S. Vinokurov for the XRD measurements.
Предметные рубрики: MOSSBAUER
SPECTROSCOPY
CHEMISTRY
IRON
XPS
ADSORPTION
OXYGEN
FE
Аннотация: Nanocomposite Fe–Al oxide catalysts were prepared by the melting of iron and aluminum nitrates with the subsequent calcination in air at different temperatures. It was found that the catalysts calcined at 450 °C are more active in the oxidation of CO than the catalysts calcined at 700 °C. X-ray diffraction and X-ray photoelectron spectroscopy showed that all the catalysts consist of hematite, α-Fe2O3 nanoparticles, and Al2O3 in an amorphous state. Iron oxide is the active component, which provides the oxidation of CO, while alumina is a texture promoter. The increase in the calcination temperature leads to a minor increase in the average size of hematite nanoparticles and an insignificant decrease in the specific surface area. Kinetic measurements showed that the oxidation of CO over the Fe–Al catalysts calcined at 450 and 700 °C proceeds with the activation energy of 61–69 and 91 kJ/mol, respectively. This means that the low-temperature and high-temperature catalysts contain different active species. Temperature-programmed reduction with CO indicated that the decrease in the calcination temperature improves the reducibility of the Fe-Al nanocomposites. According to 57Fe Mössbauer spectroscopy, the low-temperature catalysts contain hydrated iron oxides (acagenite and ferrihydrite) and a significant amount of highly defective hematite, which is absent in the high-temperature catalyst. These species can provide the enhanced activity of the low-temperature catalysts in the oxidation of CO.
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