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    Верещагин, С. Н.
    Изучение фазового перехода порядок-беспорядок в нестехиометрическом Sr-Gd-кобальтате методами ДСК, ТГ и РСА / С. Н. Верещагин, В. А. Дудников, Л. А. Соловьев // Журн. СФУ. Сер. "Химия". - 2016. - Т. 9, № 3. - С. 326-336 ; J. Sib. Fed. Univ. Chem., DOI 10.17516/1998-2836-2016-9-3-326-336. - Библиогр.: 26. - Исследование выполнено при финансовой поддержке Российского фонда фундаментальных исследований, Правительства Красноярского края, Красноярского краевого фонда поддержки научной и научно-технической деятельности в рамках научного проекта 16-43-240505 «р_а». . - ISSN 1998-2836. - ISSN 2313-6049
   Перевод заглавия: DSC+TG and XRD study of order-disorder transition in nonstoichiometric Sr-Gd-cobaltate
Рубрики:
PEROVSKITE-TYPE OXIDES
   PHASE-TRANSITION
   OXYGEN SORPTION
   PERFORMANCE
Кл.слова (ненормированные):
perovskite -- order-disorder -- phase transition -- DSC -- перовскит -- порядок-беспорядок -- фазовый переход -- ДСК
Аннотация: Методами термического и рентгеноструктурного анализа в интервале температур 11001473 К изучен процесс взаимопревращения тетрагонального перовскита Sr ( 0.8 ) Gd ( 0.2 ) CoO ( 3-d ) с упорядоченным расположением катионов Sr/Gd и анионных вакансий в кубическую разупорядоченную модификацию. Показано, что фазовое превращение протекает как размытый фазовый переход первого рода. Процесс разупорядочения не зависит от скорости нагрева и контролируется термодинамическими характеристиками процессов в кристалле, тогда как процесс образования упорядоченной тетрагональной структуры контролируется кинетическими факторами. Проведен количественный анализ температурной зависимости теплоемкости на основе размытых фазовых переходов.
Process of interconversion of tetragonal Sr(0.8) Gd(0.2) CoO(3-d) (with ordered Sr/Gd cations and anion vacancies) to cubic one (with disordered structure) was studied by X-ray structural and thermal analysis at 1100-1473 K. It was shown that the transformation is a first order diffuse phase transition. The ramp rate does not affect cation and anion vacancies disordering which is controlled by thermodynamic parameters of the processes in the solid whereas cubic to tetragonal transition is kinetically controlled. A theory of diffuse phase transition was applied to quantitatively analyze heat capacity temperature dependence.

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Держатели документа:
Институт химии и химической технологии СО РАН
Институт физики им. Л. В. Киренского СО РАН

Доп.точки доступа:
Дудников, Вячеслав Анатольевич; Dudnikov, V. A.; Соловьев, Леонид Александрович; Solovyov L. A.; Vereshchagin S. N.

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Using Redox-Active pi Bridging Ligand as a Control Switch of Intramolecular Magnetic Interactions / X. Z. Ma [et al.] // J. Am. Chem. Soc. - 2019. - Vol. 141, Is. 19. - P. 7721-7725, DOI 10.1021/jacs.9b03044. - Cited References: 38. - This work was supported by the ANR (ANR-16-CE29-0001-01, Active-Magnet project), the University of Bordeaux, the Region Nouvelle Aquitaine, the CNRS, the MOLSPIN COST action CA15128 and the Chinese Scholarship Council (CSC) for the PhD funding of X.M. E.A.S. thanks EPSRC for support (EP/N006895/1), the IRIDIS High Performance Computing Facility and associated services at the University of Southampton and RSC for travel grant. The authors thank also S. De, D. Woodruff, P. Perlepe, I. Oyarzabal, and S. Exiga for their assistance and fruitful discussions as well as the GdR MCM-2. . - ISSN 0002-7863

РУБ Chemistry, Multidisciplinary
Рубрики:
GROUND-STATE
COMPLEXES
Аннотация: Intramolecular magnetic interactions in the dinuclear complexes [(tpy)Ni(tphz)Ni(tpy)]n+ (n = 4, 3, and 2; tpy, terpyridine; tphz, tetrapyridophenazine) were tailored by changing the oxidation state of the pyrazine-based bridging ligand. While its neutral form mediates a weak antiferromagnetic (AF) coupling between the two S = 1 Ni(II), its reduced form, tphz•–, promotes a remarkably large ferromagnetic exchange of +214(5) K with Ni(II) spins. Reducing twice the bridging ligand affords weak Ni–Ni interactions, in marked contrast to the Co(II) analogue. Those experimental results, supported by a careful examination of the involved orbitals, provide a clear understanding of the factors which govern strength and sign of the magnetic exchange through an aromatic bridging ligand, a prerequisite for the rational design of strongly coupled molecular systems and high TC molecule-based magnets.

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Держатели документа:
CNRS, CRPP, UMR 5031, F-33600 Pessac, France.
Univ Bordeaux, CRPP, UMR 5031, F-33600 Pessac, France.
Univ Bath, CSCT, Claverton Down, Bath BA2 7AY, Avon, England.
ESRF, CS 40220, F-38043 Grenoble 9, France.

Доп.точки доступа:
Ma, Xiaozhou; Suturina, Elizaveta A.; Rouzieres, Mathieu; Platunov, M. S.; Платунов, Михаил Сергеевич; Wilhelm, Fabrice; Rogalev, Andrei; Clerac, Rodolphe; Dechambenoit, Pierre; ANRFrench National Research Agency (ANR) [ANR-16-CE29-0001-01]; University of Bordeaux; Region Nouvelle Aquitaine; CNRSCentre National de la Recherche Scientifique (CNRS); MOLSPIN COST actionEuropean Cooperation in Science and Technology (COST) [CA15128]; Chinese Scholarship Council (CSC)China Scholarship Council; EPSRCEngineering & Physical Sciences Research Council (EPSRC) [EP/N006895/1]; IRIDIS High Performance Computing Facility; University of Southampton; RSC
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Thermoelectric properties and cost optimization of spark plasma sintered n-type Si0.9Ge0.1 - Mg2Si nanocomposites / A. Usenko [et al.] // Scripta Mater. - 2018. - Vol. 146. - P. 295-299, DOI 10.1016/j.scriptamat.2017.12.019. - Cited References: 28. - This work was supported by Russian Science Foundation (project No. 16-13-00060). Part of the work (structural characterization of the samples) was carried out with financial support of the Ministry of Education and Science of the Russian Federation in the framework of Increase Competitiveness Program of NUST “MISiS”. Partial support by Act 211 Government of the Russian Federation, contract # 02.A03.21.0011, is also acknowledged. . - ISSN 1359-6462
Кл.слова (ненормированные):
Cost optimization -- Lattice thermal conductivity -- Magnesium silicides -- Spark plasma -- Thermo-Electric materials -- Thermoelectric figure of merit -- Thermoelectric performance -- Thermoelectric properties
Аннотация: We report on thermoelectric properties of low Ge content n-type Si0.9Ge0.1–Mg2Si nanocomposite. Introduction of the Mg2Si phase into a SiGe matrix resulted in a dramatic drop of the lattice thermal conductivity beyond the previously reported lowest limit for SiGe alloys due to intensification of phonon scattering on SiGe–Mg2Si grain boundaries. For a sample doped with 1 at.% of Mg2Si, the peak value of thermoelectric figure of merit ZT reached ~ 0.8 at 800 °C. Sintered nanocomposites still exhibit high thermoelectric performance while being almost two times cheaper than Si0.8Ge0.2.

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Держатели документа:
National University of Science and Technology “MISiS”, Moscow, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Krasnoyarsk, Russian Federation
National Research South Ural State University, Chelyabinsk, Russian Federation

Доп.точки доступа:
Usenko, A.; Moskovskikh, D.; Korotitskiy, A.; Gorshenkov, M.; Zakharova, E.; Fedorov, A. S.; Федоров, Александр Семенович; Parkhomenko, Y.; Khovaylo, V.
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The effect of copper and iron adsorption on the catalytic performance of alumina nanofiber / nanodiamond composite in sensing applications / N. O. Ronzhin, E. D. Posokhina, E. V. Mikhlina [et al.] // J. Phys. Chem. Solids. - 2022. - Vol. 167. - Ст. 110785, DOI 10.1016/j.jpcs.2022.110785. - Cited References: 68. - This work is supported by the Russian Foundation for Basic Research, Project 18–29–19078. The authors would like to express their special thanks to Krasnoyarsk Regional Center of Research Equipment of Federal Research Center «Krasnoyarsk Science Center SB RAS» for providing the equipment to ensure the accomplishment of this project . - ISSN 0022-3697
Кл.слова (ненормированные):
Nanodiamonds -- Alumina nanofibers -- Indicator system -- Copper ions -- Iron ions -- Phenol detection
Аннотация: Phenolic compounds are common environmental pollutants, which are used in many industries and contaminate water environment due to industrial wastewater discharge. Presently, there is an increasing demand for the development and improvement of inexpensive, easy-to-use analytical tools for in-situ detection of phenolic compounds. In this work, we investigate the effect of adsorption of Cu2+ and Fe2+ ions on the catalytic activity of a composite material based on alumina nanofibers (ANF) and detonation nanodiamonds (DND) in the co-oxidation of phenols with 4-aminoantipyrine in the presence of hydrogen peroxide. We have found more than two-fold increase of the catalytic activity for ANF + DND + Cu composite, while the activity of ANF + DND + Fe composite is found to decrease by several times in comparison with the original ANF + DND material. The results of FTIR analysis indicate that the adsorption of iron ions occurs with the formation of hydroxide surface groups and hydrogen bonds, which apparently block their catalytic activity in the Fenton redox cycle. The higher catalytic performance of AND + DND composite functionalized with copper ions makes it possible to detect two times lower concentrations of analytes (phenol and 4-chlorophenol) in comparison with the original composite. It is shown that the AND + DND + Cu composite provides a linear yield of the co-oxidation reaction product in a wide range of analyte concentrations (0.25–100 μM for phenol and 0.5–25 μM for 4-chlorophenol). Model experiments demonstrate the applicability of copper-functionalized composite as a reusable sensor for the determination of phenol in aqueous samples.

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Держатели документа:
Institute of Biophysics SB RAS, Akademgorodok 50/50, Krasnoyarsk, 660036, Russian Federation
Institute of Computational Modelling SB RAS, Akademgorodok 50/44, Krasnoyarsk, 660036, Russian Federation
Kirensky Institute of Physics SB RAS, Akademgorodok 50/38, Krasnoyarsk, 660036, Russian Federation
Federal Research Center KSC SB RAS, Akademgorodok 50/38, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Svobodny 79, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Ronzhin, N. O.; Posokhina, E. D.; Mikhlina, E. V.; Shestakov, N. P.; Шестаков, Николай Петрович; Nemtsev, I. V.; Немцев, Иван Васильевич; Bondar, V. S.; Ryzhkov, I. I.
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    Structural analysis and optical temperature sensing performance of Eu3+-doped Ba3In(PO4)3 / G. Q. Zhang, M. S. Molokeev, Q. C. Ma [et al.] // CrystEngComm. - 2020. - Vol. 22, Is. 35. - P. 5809-5817, DOI 10.1039/d0ce00997k. - Cited References: 52. - This work was supported by the National Natural Science Foundation of China (Grant No. 51802172) and the Qinghai Provincial Natural Science Foundation for Young Scholars (No. 2018-ZJ-957Q) . - ISSN 1466-8033
   Перевод заглавия: Структурный анализ и эффективность оптического измерения температуры Ba3In(PO4)3, легированного Eu3+

РУБ Chemistry, Multidisciplinary + Crystallography
Рубрики:
FLUORESCENCE INTENSITY RATIO
UP-CONVERSION EMISSIONS
RARE-EARTH IONS
Аннотация: Eu3+-Doped Ba3In(PO4)3 was synthesized through a high-temperature solid-phase method. According to the structure refinement based on X-ray diffraction and density functional theory, the crystal and energy band structures of Ba3In(1−x)(PO4)3:xEu3+ were studied and analyzed in detail. The effect of Eu3+ doping concentrations on emission was studied at an excitation wavelength of 393 nm. For the material Ba3In(1−x)(PO4)3:xEu3+(x = 0.01–0.30), the optimal doping level is confirmed to be 0.18. Due to the thermal quenching differences of Eu3+ at the 5D0 and 5D1 energy levels, and based on the temperature-variable fluorescence intensity ratio between emission peaks, the optical temperature measurement performance of this material in the temperature range from 298.15 K to 623.15 K was characterized, and the maximum absolute and relative sensor sensitivities (Sa and Sr) were determined to be 0.1002 K−1 and 4.058%, respectively. With temperature as the only variable, the color of the phosphor changes from red to yellow light with rising temperature. Besides, Sa and Sr values of this phosphor are comparable to other sensing materials. The results indicate that Eu3+-doped Ba3In(PO4)3 phosphors have great potential to be applied in optical temperature sensing.

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Держатели документа:
Qinghai Univ, Qinghai Prov Engn Res Ctr High Performance Light, Qinghai Prov Key Lab New Light Alloys, Xining 810016, Peoples R China.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.

Доп.точки доступа:
Zhang, Guangqing; Molokeev, M. S.; Молокеев, Максим Сергеевич; Ma, Qianchao; Yang, Xuening; Han, Shuiquan; Chen, Q.i.; Zhong, Binnian; Ma, Bin
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    Room temperature magneto-transport properties of nanocomposite Fe–In2O3 thin films / I. A. Tambasov [et al.] // Physica B. - 2015. - Vol. 478. - P. 135-137, DOI 10.1016/j.physb.2015.08.054. - Cited References: 28. - This study was supported by the Russian Foundation for Basic Research (Grants # 15-02-00948-A,), by the Council for Grants of the President of the Russian Federation (SP-317.2015.1), and by the program of Foundation for Promotion of Small Enterprises in Science and Technology (No 6662 FY2015) ("UMNIK" program). . - ISSN 0921-4526
   Перевод заглавия: Магнитно-транспортные свойства композитных Fe –In2O3 тонких пленок при комнатной температуре

РУБ Physics, Condensed Matter
Рубрики:
Doped In2O3 Films
   High-performance
   Indium oxide
   Transistors
   Magnetoresistance
   Ferromagnetism
Кл.слова (ненормированные):
Indium oxide -- Fe-In2O3 thin films -- Weak localization -- Disordered semiconductors
Аннотация: A ferromagnetic Fe–In2O3 nanocomposite thin film has been synthesized by the thermite reaction Fe2O3+In→Fe–In2O3. Measurements of the Hall carrier concentration, Hall mobility and magnetoresistance have been conducted at room temperature. The nanocomposite Fe–In2O3 thin film had n=1.94·1020 cm−3, μ=6.45 cm2/Vs and negative magnetoresistance. The magnetoresistance for 8.8 kOe was ~−0.22%.The negative magnetoresistance was well described by the weak localization and model proposed by Khosla and Fischer.

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Держатели документа:
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk, Russian Federation
Reshetnev Siberian State Aerospace University, Krasnoyarsk Worker 31, Krasnoyarsk, Russian Federation
Siberian Federal University, Svobodny prospect 79, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Tambasov, I. A.; Тамбасов, Игорь Анатольевич; Gornakov, K. O.; Myagkov, V. G.; Мягков, Виктор Григорьевич; Bykova, L. E.; Быкова, Людмила Евгеньевна; Zhigalov, V. S.; Жигалов, Виктор Степанович; Matsynin, A. A.; Мацынин, Алексей Александрович; Yozhikova, E. V.
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Reversible UV induced metal-semiconductor transition in In2O3 thin films prepared by autowave oxidation / I. A. Tambasov [et al.] // Semicond. Sci. Technol. - 2014. - Vol. 29, Is. 8. - Ст. 82001, DOI 10.1088/0268-1242/29/8/082001. - Cited References: 56. - This work was supported by the Federal Target Program through Contract No 14.513.11.0023; the Russian Foundation for Basic Research, Project No. 14-02-31156. . - ISSN 0268-1242. - ISSN 1361-6641

РУБ Engineering, Electrical & Electronic + Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
TRANSPARENT CONDUCTING OXIDES
   Ga-DOPED ZnO
   LOW-TEMPERATURE
   HIGH-PERFORMANCE
   SUBSTRATE-TEMPERATURE
   INSULATOR-TRANSITION
   ROOM-TEMPERATURE
   TRANSISTORS
   COMBUSTION
   PHOTOREDUCTION
Кл.слова (ненормированные):
indium oxide thin films -- autowave oxidation -- metal-semiconductor transition -- UV irradiation -- photoreduction
Аннотация: We have prepared thin indium oxide films by the autowave oxidation reaction. Measurements of temperature dependence of resistivity, Hall carrier concentration and Hall mobility have been conducted in the temperature range 5-272 K. Before ultraviolet (UV) irradiation, the indium oxide film had a semiconductor-like temperature dependence of resistivity. and the ratio of rho (5 K)/rho(272 K) was very limited (similar to 1.2). It was found that after UV irradiation of the In2O3 film, the metal-semiconductor transition (MST) was observed at similar to 100 K. To show that this MST is reversible and repeatable, two full cycles of 'absence of MST-presence of MST' have been done using UV irradiation (photoreduction) as the induced mechanism and exposure to an oxygen environment as the reversible mechanism, respectively. MST in transparent conducting oxide (TCO) is possibly associated with the undoped structure of metal oxide, which has some disorder of oxygen vacancies. It was suggested that reversible UV induced metal-semiconductor transition would occur in other TCOs.

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Держатели документа:
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Reshetnev Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
Russian Acad Sci, Siberian Branch, Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Tambasov, I. A.; Тамбасов, Игорь Анатольевич; Myagkov, V. G.; Мягков, Виктор Григорьевич; Tarasov, A. S.; Тарасов, Антон Сергеевич; Ivanenko, A. A.; Иваненко, Александр Анатольевич; Bykova, L. E.; Быкова, Людмила Евгеньевна; Nemtsev, I. V.; Немцев, Иван Васильевич; Eremin, E. V.; Еремин, Евгений Владимирович; Yozhikova, E. V.; Federal Target Program [14.513.11.0023]; Russian Foundation for Basic Research [14-02-31156]
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    Quaternary selenides EuLnCuSe3: Synthesis, structures, properties and in silico studies / M. V. Grigoriev, L. A. Solovyov, A. V. Ruseikina [et al.] // Int. J. Mol. Sci. - 2022. - Vol. 23, Is. 3. - Ст. 1503, DOI 10.3390/ijms23031503. - Cited References: 90 . - ISSN 1422-0067
   Перевод заглавия: Четвертичные селениды EuLnCuSe3: синтез, структура, свойства и компьютерное моделирование

РУБ Biochemistry & Molecular Biology + Chemistry, Multidisciplinary
Рубрики:
RARE-EARTH
   CRYSTAL-STRUCTURES
   MAGNETIC-PROPERTIES
   THERMOELECTRIC PERFORMANCE
Кл.слова (ненормированные):
inorganic materials -- ab initio calculations -- magnetic measurements -- lattice dynamics -- vibrational spectroscopy -- optical spectroscopy -- negative magnetization
Аннотация: In this work, we report on the synthesis, in-depth crystal structure studies as well as optical and magnetic properties of newly synthesized heterometallic quaternary selenides of the Eu+2Ln+3Cu+1Se3 composition. Crystal structures of the obtained compounds were refined by the derivative difference minimization (DDM) method from the powder X-ray diffraction data. The structures are found to belong to orthorhombic space groups Pnma (structure type Ba2MnS3 for EuLaCuSe3 and structure type Eu2CuS3 for EuLnCuSe3, where Ln = Sm, Gd, Tb, Dy, Ho and Y) and Cmcm (structure type KZrCuS3 for EuLnCuSe3, where Ln = Tm, Yb and Lu). Space groups Pnma and Cmcm were delimited based on the tolerance factor t’, and vibrational spectroscopy additionally confirmed the formation of three structural types. With a decrease in the ionic radius of Ln3+ in the reported structures, the distortion of the (LnCuSe3) layers decreases, and a gradual formation of the more symmetric structure occurs in the sequence Ba2MnS3 → Eu2CuS3 → KZrCuS3. According to magnetic studies, compounds EuLnCuSe3 (Ln = Tb, Dy, Ho and Tm) each exhibit ferrimagnetic properties with transition temperatures ranging from 4.7 to 6.3 K. A negative magnetization effect is observed for compound EuHoCuSe3 at temperatures below 4.8 K. The magnetic properties of the discussed selenides and isostructural sulfides were compared. The direct optical band gaps for EuLnCuSe3, subtracted from the corresponding diffuse reflectance spectra, were found to be 1.87–2.09 eV. Deviation between experimental and calculated band gaps is ascribed to lower d states of Eu2+ in the crystal field of EuLnCuSe3, while anomalous narrowing of the band gap of EuYbCuSe3 is explained by the low-lying charge-transfer state. Ab initio calculations of the crystal structures, elastic properties and phonon spectra of the reported compounds were performed.

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Держатели документа:
Univ Tyumen, Lab Theory & Optimizat Chem & Technol Processes, Tyumen 625003, Russia.
SB RAS, Inst Chem & Chem Technol, Fed Res Ctr KSC, Krasnoyarsk 660036, Russia.
Univ Tyumen, Inst Chem, Tyumen 625003, Russia.
Siberian Fed Univ, Dept Photon & Laser Technol, Krasnoyarsk 660079, Russia.
RAS, SB, Fed Res Ctr KSC, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Ural Fed Univ, Inst Nat Sci & Math, Mira Str 19, Ekaterinburg 620002, Russia.
Univ Tyumen, Inst Phys & Technol, Tyumen 625003, Russia.
Kemerovo State Univ, Res & Dev Dept, Kemerovo 650000, Russia.
Siberian Fed Univ, Inst Engn Phys & Radioelect, Krasnoyarsk 660079, Russia.
Siberian Fed Univ, Sch Engn & Construct, Krasnoyarsk 660041, Russia.
Univ Tyumen, Engn Ctr Composite Mat Based Wolfram Cpds & Rare, Tyumen 625003, Russia.
Univ Stuttgart, Inst Inorgan Chem, D-70569 Stuttgart, Germany.
Kurgan State Univ, Adv Mat Ind & Biomed Lab, Sovetskaya Str 63-4, Kurgan 640020, Russia.
Ural Fed Univ, Innovat Ctr Chem & Pharmaceut Technol, Mira Str 19, Ekaterinburg 620002, Russia.

Доп.точки доступа:
Grigoriev, Maxim V.; Solovyov, Leonid A.; Ruseikina, Anna V.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Chernyshev, Vladimir A.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Garmonov, Alexander A.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Shestakov, N. P.; Шестаков, Николай Петрович; Matigorov, Alexey V.; Volkova, Svetlana S.; Ostapchuk, Evgeniy A.; Kertman, Alexander V.; Schleid, Thomas; Safin, Damir A.
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Quasi-lumped multimode stripline resonator and filter with good stopband performance / B. A. Belyaev [et al.] // Microwave Opt. Technol. Lett. - 2020. - Vol. 62, Is. 3. - P. 1183-1187, DOI 10.1002/mop.32173. - Cited References: 10. - The work was supported by the Ministry of Education and Science of the Russian Federation (No. 03.G25.31.0279). . - ISSN 0895-2477
Кл.слова (ненормированные):
bandpass filter -- multimode resonator -- quasi-lumped resonator -- stripline resonator -- wide stopband
Аннотация: A novel multimode resonator is proposed, containing five resonant modes that are incorporated in the passband forming. The structure is based on a dielectric substrate suspended in a metallic case that allows solving the problem of electromagnetic compatibility. Due to features of the resonator's structure, several higher modes do not excite that significantly improves the performance of the filter's stopband. The resonator advantages are proved on the bandpass filter (3.1…10.6 GHz) with a small overall size (0.19λ0 × 0.11λ0 × 0.11λ0) and a good stopband performance (first spurious band locates at 29 GHz and suppression is 70 dB).

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Держатели документа:
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Belyaev, B. A.; Беляев, Борис Афанасьевич; Serzhantov, A. M.; Сержантов, Алексей Михайлович; Leksikov, A. A.; Лексиков, Александр Александрович; Bal'va, Y. F.; Бальва, Ярослав Федорович; Leksikov, An. A.; Лексиков, Андрей Александрович
}
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10.

Phase transformation behavior of Sr0.8Gd0.2CoO3-delta perovskite in the vicinity of order-disorder transition / S. N. Vereshchagin [et al.] // Thermochim. Acta. - 2017. - Vol. 655. - P. 34-41, DOI 10.10164/j.tca.2017.06.003. - Cited References:40. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project #16-43-240505 p_a and #16-02-00507A. . - ISSN 0040-6031. - ISSN 1872-762X

РУБ Thermodynamics + Chemistry, Analytical + Chemistry, Physical
Рубрики:
OXYGEN SORPTION
   OXIDES
   PERFORMANCE
   DIFFUSE
   LN
Кл.слова (ненормированные):
Perovskite -- Ruddlesden-Popper phase -- Order-disorder -- Phase transition -- DSC
Аннотация: The phase transformation behavior of a single-phase tetragonal Sr0.8Gd0.2CoO3-δ (with ordered distribution of Sr2+/Gd3+ cations and anion vacancies) was investigated by TG–DSC and XRD at 1100–1473 K and oxygen partial pressure p(O2) from 1 to 5·104 Pa. The first-order smeared order-disorder (o-d) phase transition involving heat absorption was observed at about 1383 K under O2-Ar flow with p(O2) > 2.5 kPa. The crystal structure of the high-temperature phase was found to be cubic perovskite with disordered Sr2+/Gd3+ cations and anion vacancies. The temperature of o-d transition at p(O2) > 2.5 kPa was not influenced by the heating rate or oxygen partial pressure. It was shown that at p(O2) < 2.5 kPa the o-d transition gives rise to Sr0.8Gd0.2CoO3−δ decomposition to form CoO and Sr2.4Gd0.6Co2O7-δ − Ruddlesden-Popper type phase with novel composition. The phase boundaries between the ordered tetragonal Sr0.8Gd0.2CoO3−δ, disordered cubic Sr0.8Gd0.2CoO3−δ and CoO + Sr2.4Gd0.6Co2O7-δ composite as a function of temperature and p(O2) values were determined.

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Держатели документа:
Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia.
Kirensky Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Vereshchagin, S. N.; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Shishkina, N. N.; Solovyov, L. A.; Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund [16-43-240505 p_a, 16-02-00507A]
}
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11.

Original concept of cracked template with controlled peeling of the cells perimeter for high performance transparent EMI shielding films / A. S. Voronin, Y. V. Fadeev, F. S. Ivanchenko [et al.] // Surf. Interfaces. - 2023. - Vol. 38. - Ст. 102793, DOI 10.1016/j.surfin.2023.102793. - Cited References: 73. - The development of the processes of synthesis of a cracked template and conceptualization and optimization parameters peeling cells perimeter of the cracked template for the requirements of the final products were carried out with the financial support of the Ministry of Science and Higher Education of the Russian Federation within the framework of state task No. 0287–2021–0026. The development of the processes of the formation of metal films and the study of the structural, optical, electrical and shielding properties of the samples were carried out with the financial support of the Ministry of Science and Higher Education of the Russian Federation within the framework of state assignment No. FSFN-2022–0007. The physicochemical analysis of materials was carried out on equipment from the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center «Krasnoyarsk Science Center SB RAS». We would like to thank Anastasia Tamarovskaya for the macro photo of thick Ag mesh samples. . - ISSN 2468-0230
Кл.слова (ненормированные):
Transparent conductor -- Cracked template -- Cells perimeter peeling -- EMI shielding films
Аннотация: The problem of sputtering of thick metal films on micro and nanotemplates is important for obtaining mesh transparent conductors with excellent optoelectric characteristics. In this work, we demonstrate for the first time the possibility of controlling the degree of peeling of the cell perimeter from the substrate for a cracked template based on egg white by alternating the operations of moistening the template with saturated water vapor and shock drying with hot air. Local peeling of the cracked template cells perimeter makes it possible to increase the thickness of the metal sputtered on the cracked template by more than 1 µm, which is not achievable for other lithographic approaches. Our technique was used to obtain thick Ag meshes with a low sheet resistance of no more than 1.59 Ω/sq and a transparency of about 89.1%. The thick Ag meshes show a shielding efficiency (SE) of 49 dB or 99.998% of the incident power of an electromagnetic wave at a frequency of 1 GHz. In a sandwich geometry, thick Ag meshes, which simulates a real shielding window, the shielding efficiency (SE) reaches 71 dB with a transparency of more than 80%.

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Держатели документа:
Federal Research Center «Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences» (FRC KSC SB RAS), Krasnoyarsk, Russia 660036
Siberian Federal University, Krasnoyarsk, Russia 660041
Bauman Moscow State Technical University, Moscow Russia 105005
N.N. Semenov Federal Research Center of Chemical Physics of Russian Academy of Sciences, Moscow, Russia 119334
Reshetnev Siberian University Science and Technology, Krasnoyarsk, Russia 660037
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk Russia 660036
LLC Research and Production Company “Spectehnauka”, Krasnoyarsk, Russia 660043
Tomsk Polytechnic University, Tomsk, Russia 634050
V.E. Zuev Institute of Atmospheric Optics, Siberian Branch, Russian Academy of Sciences, Tomsk, Russia 634055

Доп.точки доступа:
Voronin, A. S.; Fadeev, Y. V.; Ivanchenko, F. S.; Dobrosmyslov, S. S.; Makeev, M. O.; Mikhalev, P. A.; Osipkov, A. S.; Damaratsky, I. A.; Ryzhenko, D. S.; Yurkov, G. Y.; Simunin, M. M.; Volochaev, M. N.; Волочаев, Михаил Николаевич; Tambasov, I. A.; Тамбасов, Игорь Анатольевич; Nedelin, S. V.; Неделин, С. В.; Zolotovsky, N. A.; Золотовский, Н. А.; Bainov, D. D.; Khartov, S. V.
}
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12.

    Novel far-red phosphors (La, Gd, Y)2MgTiO6:Cr3+ with tunable luminescence spectra for grow light / P.-X. Gao, P. Dong, Z.-Y. Zhou [и др.] // Faguang Xuebao/Chin. J. Lumines. - 2022. - Vol. 43, Is. 1. - P. 58-68, DOI 10.37188/CJL.20210327. - Cited References: 27. - Supported by National Natural Science Foundation of China(51974123); The Distinguished Youth Foundation of Hunan Province(2020JJ2018); Key R & D Projects in Hunan Province(2020WK2016&2020SK2032&2022NK2044), Hunan High Level Talent Gathering Project(2019RS1077&2020RC5007); Natural Science Foundation of Hunan Province(2021JJ40261); The Scientific Research Fund of Hunan Provincial Education Department(19C0903); The Natural Sciences Foundation of Hunan Agricultural University(19QN11); Hunan Provincial Key Laboratory of Crop Germplasm Innovation and Resource Utilization Science Foundation(19KFXM12); Changsha Science and Technology Plan(KH2005114) . - ISSN 1000-7032
   Перевод заглавия: Новые ИК люминофоры (La,Gd,Y)2MgTiO6:Cr3+ с настраиваемыми спектрами люминесценции для агроламп
Кл.слова (ненормированные):
phosphor -- double perovskite structure -- luminescence tuning performance -- far-red light -- Cr3+
Аннотация: Cr3+-activated double perovskite structure phosphor has drawn wide attention due to its far-red and near-infrared emission. In this work, we synthesized a series of (La,Gd,Y)2MgTiO6∶Cr3+ phosphors which can be excited by ultraviolet light of about 345 nm, and the emission bands are in the range of 700-900 nm. The spectra were tuned by ions substitution strategy. The main emission peaks were blue shifted from 766 nm to 737 nm and 757 nm by substituting the La site with Gd and Y, respectively. Meanwhile, the thermal stability at 150 ℃ increased from 41.7% to 69.1% and 67%, respectively. The crystal structure, microstructure, decay time, thermal stability and band gap were investigated systematically. The substitution of Gd/Y ions causes the lattice contraction, which results in the change of the nephelauxetic effect, and eventually leads to the blue shift of the spectra. The emission spectra of these phosphors have good matching with the 730 nm absorption peak of phytochrome FR(PFR), indicating their application prospect in plant growth lighting. Cationic substitution strategy can regulate the luminescence properties of Cr3+, which provides ideas for the development of phosphors for plant growth lamps in the future.

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Держатели документа:
Hunan Provincial Key Laboratory of Crop Germplasm Innovation and Resource Utilization, Changsha, 410128, China
School of Chemistry and Materials Science, Hunan Agricultural University, Hunan Agricultural University, Changsha, 410128, China
Hunan Optical Agriculture Engineering Technology Research Center, Hunan Agricultural University, Changsha, 410128, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Gao, P. -X.; Dong, P.; Zhou, Z. -Y.; Zhang, X. -J.; Li, Y. -N.; Yang, J. -K.; Li, Q.; Chen, K.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zhou, Z.; Xia, M.
}
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13.

    Novel AMoO4:Eu3+ (A = Ca and Ba) optical thermometer: Investigation of effect of local ionic coordination environment on optical performance and temperature measurement sensitivity / H. Gao, M. S. Molokeev, Q. Chen [et al.] // Ceram. Int. - 2023. - Vol. 49, Is. 16. - P. 26803-26810, DOI 10.1016/j.ceramint.2023.05.217. - Cited References: 52. - The work was supported by the program of Science and Technology International Cooperation Project of Qinghai province (No. 2022-HZ-807) and the National Natural Science Foundation of China (Grant No. 51802172), and was carried out within the framework of the Strategic Academic Leadership Program “Priority-2030′′ for the Siberian Federal University . - ISSN 0272-8842. - ISSN 1873-3956
   Перевод заглавия: Новый оптический термометр AMoO4:Eu3+ (A = Ca и Ba): исследование влияния локального ионного координационного окружения на оптические характеристики и чувствительность измерения температуры
Кл.слова (ненормированные):
Phosphor -- Optical thermometer -- Coordination environment -- Abnormal thermal quenching
Аннотация: A range of Eu3+-doped AMoO4 (A = Ca and Ba) phosphors were successfully synthetized, and their crystal structures, optical performance, and temperature measurement sensitivities were investigated in detail. Peak doping concentration of CaMoO4:Eu3+ phosphor was 0.18, while peak doping concentration of BaMoO4:Eu3+ phosphor may be greater than 0.18. Then, temperature-dependent photoluminescence emission spectra of representative CaMoO4:0.09Eu3+ and BaMoO4:0.03Eu3+ phosphors were recorded. CaMoO4:0.09Eu3+ phosphor exhibited abnormal thermal quenching, which was attributed to defects caused by heterovalent substitution of ions and increase in the temperature, and good thermal stability. Finally, the possibility of using both phosphors as optical thermometers was discussed, which exhibited good temperature sensitivity. However, CaMoO4:0.09Eu3+ phosphor exhibited two peak absolute (Sa, 1.28 %K−1 and 1.39 %K−1) and relative sensitivities (Sr, 1.21 %K−1 and 1.20 %K−1). In addition, variation trend of Sr value with temperature was considerably peculiar. Two optimum Sa and Sr values were attributed to abnormal thermal quenching of CaMoO4:0.09Eu3+ phosphor. Peak Sa and Sr values of BaMoO4:0.03Eu3+ phosphor was 12.39 %K−1 and 0.89 %K−1, respectively. In addition, Sa of AMoO4:Eu3+ phosphor was negatively related to Eu3+ central asymmetry, while peak Sr value was more inclined to appropriate ionic central asymmetry.

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Держатели документа:
School of Mechanical Engineering, Qinghai University, Xining, 810016, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
Siberian Federal University, Krasnoyarsk, 660041, Russia
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russia
Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences (Beijing), Beijing, 100083, China

Доп.точки доступа:
Gao, Huabo; Molokeev, M. S.; Молокеев, Максим Сергеевич; Chen, Qi; Min, Xin; Ma, Bin
}
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14.

New method for regulating the activity of ABO3 perovskite catalysts / S. N. Vereshchagin [et al.] // Kinet. Catal. - 2015. - Vol. 56, Is. 5. - P. 640-645, DOI 10.1134/S0023158415040199. - Cited References:23. - This work was supported in part by the Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools (grant no. NSh-2886.2014.2). . - ISSN 0023. - ISSN 1608-3210. -

РУБ Chemistry, Physical
Рубрики:
MEMBRANE REACTORS
   METHANE COMBUSTION
   OXIDATION
   OXIDES
   OXYGEN
   PERFORMANCE
   FEATURES
   PHASES
   CO
Кл.слова (ненормированные):
perovskite -- cobalt -- methane -- deep oxidation -- oxidative condensation
Аннотация: A new possibility of changing the activity and selectivity of perovskite catalysts in the oxidative conversion of methane was demonstrated using the Sr x Gd1–x CoO3–δ (0.5 < x < 0.9) compounds as an example. It was established that, at the same chemical composition, the disordering of Sr2+/Gd3+ ions over the A positions of the crystal structure led to a significant increase in activity in the deep oxidation reaction of CH4, as compared with the samples with an ordered distribution of cations.

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Публикация на русском языке Новый способ регулирования активности катализаторов АВО3 со структурой перовскита [Текст] / С. Н. Верещагин [и др.] // Кинетика и катализ. - М. : Наука, 2015. - Т. 56 № 5. - С. 649-664

Держатели документа:
Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Kirenskii Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Vereshchagin, S. N.; Solov'ev, L. A.; Соловьев, Леонид Александрович; Rabchevskii, E. V.; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Anshits, A. G.; Аншиц, Александр Георгиевич; Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools [NSh-2886.2014.2]
}
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15.

    Multiple strategies to approach high-efficiency luminescence controllable in blue/cyan/green-emitting Bi3+-activated phosphors / P. Gao, Q. Li, S. Li [et al.] // J. Phys. Chem. C. - 2022. - Vol. 126, Is. 21. - P. 9195-9206, DOI 10.1021/acs.jpcc.2c02560. - Cited References: 53. - The authors would like to gratefully acknowledge funds from the National Natural Science Foundation of China (grant no. 51974123), the Distinguished Youth Foundation of Hunan Province (grant no.2020JJ2018), the Key R&D projects in Hunan Province (2020WK2016, 2020SK2032, 2021SK2047, and 2022NK2044), the Natural Science Foundation of Hunan Province, China (grant no. 2021JJ40261), the Hunan High Level Talent Gathering Project (2019RS1077 and 2020RC5007), the Scientific Research Fund of Hunan Provincial Education Department (19C0903), the Natural Sciences Foundation of Hunan Agricultural University, China (grant no. 19QN11), the Hunan Provincial Key Laboratory of Crop Germplasm Innovation and Resource Utilization Science Foundation (19KFXM12), the Changsha Science and Technology Plan (KH2005114, KH2201428), and the College Students’ Innovative Training (S202110537012) . - ISSN 1932-7447
   Перевод заглавия: Многочисленные стратегии достижения высокоэффективной управляемой люминесценции в синих/голубых/зеленых Bi3+-активированных люминофорах
Кл.слова (ненормированные):
Energy transfer -- Luminescence -- Blue phosphors -- Emitting phosphors -- High quality -- Higher efficiency -- Multiple strategy -- Optical tuning -- Performance -- Photoluminescence spectrum -- Red green blues -- White light emitting diodes
Аннотация: Cyan gap is a major block in achieving high-quality white light-emitting diodes (WLEDs). Hence, a novel cyan-emitting phosphor Sr2GdGaO5/0.02Bi3+ with optical tuning performance is synthesized based on the local crystal field regulation strategy surrounding the luminescence center. With the substitution of Al3+ for Ga3+, the photoluminescence (PL) spectra of Sr2GdGa1–xAlxO5/0.02Bi3+ (0 ≤ x ≤ 1) phosphors adjust from cyan (466 nm) to blue (450 nm). Moreover, such a Ba2+ doping adjusts the PL spectra of Sr2–xBaxGdGaO5/0.02Bi3+ (0 ≤ x ≤ 0.5) phosphors from cyan (466 nm) to green (482 nm). These phenomena are contributed to the crystal field splitting and nephelauxetic effect. The energy transfer from Bi3+ to Eu3+ is realized by co-doping Bi3+ and Eu3+ ions in the A2GdBO5/Bi3+ (A = Sr, Ba; B = Ga, Al) host materials, and two single-phase white phosphors Sr2GdGaO5/0.02Bi3+, 0.05Eu3+ and Sr1.5Ba0.5GdGaO5/0.02Bi3+, 0.05Eu3+ are obtained. Finally, a WLED with high color rendering index (Ra = 93.6) is prepared by using red/green/blue (RGB) phosphors and Sr2GdGaO5/0.02Bi3+ phosphor, which is higher than that of the WLED prepared by RGB phosphors (Ra = 86.7), indicating that Sr2GdGaO5/0.02Bi3+ phosphor can close the cyan gap. These results provide multiple strategies in achieving luminescence controllable and WLED.

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Держатели документа:
School of Chemistry and Materials Science, Hunan Agricultural University, Changsha, 410128, China
Hunan Optical Agriculture Engineering Technology Research Center, Changsha, 410128, China
College of Bioscience and Biotechnology, Hunan Agricultural University, Changsha, 410128, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Gao, P.; Li, Q.; Li, S.; Gai, S.; Li, Y.; Ma, Y.; Zhang, Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zhou, Z.; Xia, M.
}
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16.

Multi-mode resonator for ultra-wide bandpass filter with good stopband performance / I. V. Podshivalov [et al.] // IOP Conf. Ser.: Mater. Sci. Eng. - 2019. - Vol. 537: International Workshop on Advanced Technologies in Material Science, Mechanical and Automation Engineering - MIP: Engineering-2019 (4 April 2019 through 6 April 2019) Conference code: 149243, Is. 5. - Ст. 052025, DOI 10.1088/1757-899X/537/5/052025. - Cited References: 10. - This work was supported by the Ministry of Education and Science of the Russian Federation in the framework of the Federal target program “Research and development of priority directions of development of the scientific-technological complex of Russia for 2014-2020” (agreement № 14.575.21.0142, unique ID project RFMEFI57517X0142).
Рубрики:
Information Reliability and Data Protection in Automation Systems
Кл.слова (ненормированные):
Automation -- Dielectric materials -- Resonators
Аннотация: A multimode resonator is proposed, containing five resonant modes that are incorporated in the passband forming. The structure is based on a dielectric substrate suspended in a metallic case that allows solving problem of electromagnetic compatibility. Due to features of the resonator's structure, several higher modes do not excite that significantly improve the performance of the filter's stopband. The resonator advantages are proved on the ultra-wide bandpass filter (101%) with small overall size (0.11λ 0×0.06λ 0×0.03λ 0) and good stopband performance (first spurious band locates at 8 GHz, suppression is 80 dB).

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Держатели документа:
Kirensky Institute of Physics SB RAS, Krasnoyarsk, Russian Federation
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Scientific and Educational Laboratory Systems of Navigation Control and Communication, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Reshetnev Siberian State University of Science and Technology, Krasnoyarsky Rabochy Av. 31, Krasnoyarsk, 660037, Russian Federation

Доп.точки доступа:
Podshivalov, I. V.; Подшивалов, Иван Валерьевич; Savishnikov, M. O.; Leksikov, An. A.; Лексиков, Андрей Александрович; Dmitriev, D. D.; Kartsan, I. N.; International Workshop on Advanced Technologies in Material Science, Mechanical and Automation Engineering - MIP: Engineering-2019(4 - 6 April 2019 ; Krasnoyarsk, Russian Federation)
}
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17.

    Su, Binbin.
    Mn2+-Based narrow-band green-emitting Cs3MnBr5 phosphor and the performance optimization by Zn2+ alloying / B. B. Su, M. S. Molokeev, Z. G. Xia // J. Mater. Chem. C. - 2019. - Vol. 7, Is. 36. - P. 11220-11226, DOI 10.1039/c9tc04127c. - Cited References: 24. - The present work was supported by the National Natural Science Foundations of China (Grant No. 51722202, 51972118 and 51572023), Natural Science Foundations of Beijing (2172036) and the Guangdong Provincial Science & Technology Project (no. 2018A050506004). . - ISSN 2050-7526. - ISSN 2050-7534
   Перевод заглавия: Узкополосный зеленый люминофор Cs3MnBr5 на основе Mn2+ и оптимизация рабочих характеристик путем легирования Zn2+

РУБ Materials Science, Multidisciplinary + Physics, Applied
Рубрики:
THERMAL-STABILITY
BACKLIGHT
EMISSION
Аннотация: To discover new narrow-band green-emitting phosphors is a challenge for backlighting light-emitting diodes (LEDs) used in liquid crystal displays (LCDs). The synthesis and optical properties of Cs3MnBr5 are demonstrated herein. The intrinsic Mn2+ luminescence without concentration quenching leads to intense green emission at 520 nm with narrow full width at half maximum of 42 nm and high photoluminescence quantum yield (PLQY) of 49% under the excitation at 460 nm. When a small amount of Zn2+ is introduced into Cs3MnBr5, the luminescence intensity decreases slightly. However, the thermal stability of Cs3MnBr5 is improved from 82% to 87% with the intensity values at 423 K compared to that at 298 K. The white LED device fabricated using Cs3Mn0.96Zn0.04Br5 (green) and K2SiF6:Mn4+ (red) phosphors with a blue LED chip exhibit a high luminous efficiency (107.76 lm W-1) and wide color gamut (101% National Television System Committee standard (NTSC) in Commission Internationale de L'Eclairage (CIE) 1931 color space), demonstrating its potential application in wide color gamut LCD backlights.

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Держатели документа:
South China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510641, Guangdong, Peoples R China.
South China Univ Technol, Inst Opt Commun Mat, Guangzhou 510641, Guangdong, Peoples R China.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.

Доп.точки доступа:
Molokeev, M. S.; Молокеев, Максим Сергеевич; Xia, Zhiguo
}
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18.

Methane oxidation over A-site ordered and disordered Sr0.8Gd0.2CoO3−δ perovskites / S. N. Vereshchagin [et al.] // Chem. Commun. - 2014. - Vol. 50, Is. 46. - P. 6112-6115, DOI 10.1039/c4cc00913d. - Cited References: 20. - The authors acknowledge the financial support from SB RAS project N 38 (2012) and RFBR grant 13-02-00358. . - ISSN 1359-7345. - ISSN 1364-548X

РУБ Chemistry, Multidisciplinary
Рубрики:
MEMBRANE REACTORS
   OXYGEN
   OXIDES
   PERFORMANCE
   COMBUSTION
   FEATURES
   PHASES
Аннотация: A tetragonal phase Sr0.8Gd0.2CoO3−δ with ordered Gd3+/Sr2+ ions and oxygen vacancy sites is found to be about five times less active in the reaction of methane combustion than a quenched cubic perovskite phase with randomly distributed (disordered) Gd3+/Sr2+ ions over the A-sites of the crystal lattice.

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Держатели документа:
Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk 660036, Russia
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia

Доп.точки доступа:
Vereshchagin, S. N.; Solovyov, L. A.; Соловьев, Леонид Александрович; Rabchevskii, E. V.; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Anshits, A. G.; Аншиц, Александр Георгиевич; SB RAS project [38]; RFBR [13-02-00358]
}
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19.

Maghemite nanoparticles for DNA extraction: Performance and blocking temperature / S. V. Stolyar, S. V. Komogortsev, A. S. Gorbenko [et al.] // J. Supercond. Novel Magn. - 2022. - Vol. 35, Is. 7. - P. 1929-1936, DOI 10.1007/s10948-022-06233-5. - Cited References: 33. - This work was supported by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund, with research projects no. 20–42-242902. We are grateful to the Center of Collective Use of FRC KSC SB RAS for the provided equipment . - ISSN 1557-1939
Кл.слова (ненормированные):
Magnetic nanoparticles -- Superparamagnetism -- Blocking temperature -- Magnetic separation
Аннотация: Iron oxide nanoparticles coated with polyethylene glycol were synthesized by coprecipitation for use in the magnetic separation of DNA (deoxyribonucleic acid). The blocking temperature of nanoparticles was studied by the methods of Mossbauer spectroscopy, ferromagnetic resonance, and using magnetometric measurements. The blocking temperature calculated from the temperature dependence of the coercive force was ~ 200 K. The calculation of the blocking temperature from the relaxation time obtained using Mossbauer spectroscopy gave a value of ~ 450 K. The blocking temperature obtained using ferromagnetic resonance was ~ 910 K. The relationship between the obtained blocking temperatures is in good agreement with the Neel-Brown formula. The constants of effective and surface anisotropy were determined by the method of ferromagnetic resonance. Isolation of DNA from blood using prepared particles and separation in a permanent magnet field revealed sufficient productivity, high speed, and the “chemical delicacy” of this approach.

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Держатели документа:
Krasnoyarsk Scientific Center, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Ural Federal University, Ekaterinburg, Russian Federation

Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Komogortsev, S. V.; Комогорцев, Сергей Викторович; Gorbenko, A. S.; Knyazev, Yu. V.; Князев, Юрий Владимирович; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Olkhovskiy, I. A.; Neznakhin, D. S.; Tyumentseva, A. V.; Bayukov, O. A.; Баюков, Олег Артемьевич; Iskhakov, R. S.; Исхаков, Рауф Садыкович
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20.

Low cost embedded copper mesh Based on cracked template for highly durability transparent EMI shielding films / A. S. Voronin, Y. V. Fadeev, M. O. Makeev [et al.] // Materials. - 2022. - Vol. 15, Is. 4. - Ст. 1449, DOI 10.3390/ma15041449. - Cited References: 55. - This research work was supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of state tasks No. 0287-2021-0026 and No. 0705-2020-0032 . - ISSN 1996-1944

РУБ Chemistry, Physical + Materials Science, Multidisciplinary + Metallurgy & Metallurgical Engineering + Physics, Applied + Physics, Condensed Matter
Рубрики:
PERFORMANCE
   REALIZATION
   ELECTRODE
   NANOMESH
   PATTERN
Кл.слова (ненормированные):
transparent electromagnetic interference (EMI) shielding films -- cracked template -- electroplating -- photocurable resin -- embedded mesh -- durability
Аннотация: Embedded copper mesh coatings with low sheet resistance and high transparency were formed using a low-cost Cu seed mesh obtained with a magnetron sputtering on a cracked template, and subsequent operations electroplating and embedding in a photocurable resin layer. The influence of the mesh size on the optoelectric characteristics and the electromagnetic shielding efficiency in a wide frequency range is considered. In optimizing the coating properties, a shielding efficiency of 49.38 dB at a frequency of 1 GHz, with integral optical transparency in the visible range of 84.3%, was obtained. Embedded Cu meshes have been shown to be highly bending stable and have excellent adhesion strength. The combination of properties and economic costs for the formation of coatings indicates their high prospects for practical use in shielding transparent objects, such as windows and computer monitors.

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Держатели документа:
Russian Acad Sci, Dept Mol Elect, Fed Res Ctr, Krasnoyarsk Sci Ctr,Siberian Branch,FRC,KSC,SB,RA, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Sch Engn & Construct, Krasnoyarsk 660041, Russia.
Bauman Moscow State Syst Univ, Lab EMI Shielding Mat, Moscow 105005, Russia.
Russian Acad Sci, Lab Reinforced Plast, NN Semenov Fed Res Ctr Chem Phys, Moscow 119991, Russia.
Siberian Fed Univ, Sch Nonferrous Met & Mat Sci, Krasnoyarsk 660041, Russia.
Reshetnev Siberian Univ Sci & Technol, Dept Aircraft, Krasnoyarsk 660037, Russia.
Siberian Fed Univ, Sch Engn Phys & Radio Elect, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Lab Radiospectroscopy & Spintron, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia.
Reshetnev Siberian Univ Sci & Technol, Sci & Training Ctr Space Res, Krasnoyarsk 660037, Russia.
Reshetnev Siberian Univ Sci & Technol, High Technol Inst, Krasnoyarsk 660037, Russia.
Tomsk Polytech Univ, Lab Radiat & Plasma Technol, Tomsk 634050, Russia.
Russian Acad Sci, Lab Radiophoton, Siberian Branch, VE Zuev Inst Atmospher Opt, Tomsk 634055, Russia.
Russian Acad Sci, Lab Photon Mol Syst, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia.
LLC Res & Prod Co Spectehnauka, Krasnoyarsk 660043, Russia.

Доп.точки доступа:
Voronin, Anton S.; Fadeev, Yurii V.; Makeev, Mstislav O.; Mikhalev, Pavel A.; Osipkov, Alexey S.; Provatorov, Alexander S.; Ryzhenko, Dmitriy S.; Yurkov, Gleb Y.; Simunin, Mikhail M.; Karpova, Darina V.; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Kokh, Dieter; Bainov, Dashi D.; Tambasov, I. A.; Тамбасов, Игорь Анатольевич; Nedelin, Sergey V.; Zolotovsky, Nikita A.; Khartov, Stanislav V.; Ministry of Science and Higher Education of the Russian Federation [0705-2020-0032]; [0287-2021-0026]
}
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