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Small-angle light scattering by monolayer of liquid crystal droplets in polymer matrix / V. A. Loiko [et al.] // Atti della Accademia Peloritana dei Pericolanti, Classe di Scienze Fisiche, Matematiche e Naturali. - 2011. - Т. 89, №SUPPL. 1, DOI 10.1478/C1V89S1P059 . - ISSN 0365-0359. - ISSN 1825-1242

РИНЦ
Держатели документа:
Kirenski Institute of Physics,Siberian Branch,Russian Academy of Sciences
Laboratoire de Chimie Macromoleculaire,Universite des Sciences et Technologies de Lille
Stepanov Institute of Physics,National Academy of Sciences of Belarus

Доп.точки доступа:
Loiko, V. A.; Konkolovich, A. V.; Miskevich, A. A.; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Maschke, U.
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Multichannel photonic devices based on tristable polymer-stabilized cholesteric textures / Y. C. Hsiao [et al.] // Optics Express. - 2011. - Т. 19, № 24. - P23952-23957, DOI 10.1364/OE.19.023952 . - ISSN 1094-4087

РИНЦ
Держатели документа:
Center for Nanotechnology,Chung Yuan Christian University
Department of Physics,Chung Yuan Christian University
Kirensky Institute of Physics,Krasnoyarsk Scientific Center,Siberian Branch of the Russian Academy of Sciences

Доп.точки доступа:
Hsiao, Y. C.; Hou, C. T.; Lee, W.; Zyryanov, V. Y.
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Electrooptical characteristics of polymer dispersed liquid crystal films [Text] / Krakhalev M.N.Prishchepa О.О.Gardymova А.Р. [et al.] // International Display Manufacturing Conference (IDMC’ll). - 2011. - P52-53

Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Krakhalev, M.N.; Prishchepa, О.О.; Gardymova, А.Р.; Sutormin, V.S.; Zyryanov, V.Ya.; Fee, W.; International Display Manufacturing Conference(2011 ; Taipei, Taiwan)
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    Оптическая мультистабильность в композиционном материале на основе полимера, жидкого кристалла и ионного сурфактанта при воздействии электрического поля / А. П. Гардымова, А. Я. Тихонов, В. Я. Зырянов // Перспективные материалы. - 2011. - № 4. - С. 32-35 . - ISSN 1028-978X
   Перевод заглавия: Optical multistability of composite material based on polymers, liquid crystals and ionic surfactant under electric field effect
Кл.слова (ненормированные):
cholesteric liquid crystal -- polymer -- ionic surfactant -- optical multistability -- холестерический жидкий кристалл -- полимер -- ионный сурфактант -- оптическая мультистабильность
Аннотация: Разработан композиционный материал на основе полимера, жидкого кристалла (ЖК) и ионного сурфактанта, характеризующийся оптической мультистабильностью и механической гибкостью. Оптические свойства данного материала варьируются за счет переключения капель холестерического ЖК между различными структурными состояниями, остающимися стабильными после выключения управляющего электрического сигнала. Функциональным инструментом для управления ориентационной структурой капель холестерика внешним электрическим полем является наноразмерный слой ионного сурфактанта. Подобраны параметры электрических сигналов, переключающих капли в новые стабильные состояния, а также возвращающих их в исходную радиальную структуру.
A composite material based on polymer, liquid crystal and ionic surfactant is developed, which is characterized by the optical multistability and mechanical flexibility. Optical properties of the material are varied by switching the cholesteric droplets between different structural states remaining stable after breaking the control electrical signal. Functional tool to control the orientational structure of cholesteric droplets by an external electric field is a nanosized layer of ionic surfactant. The parameters of electrical signals switching the droplets in new stable states and returning them in the initial radial structure are chosen.

РИНЦ
Держатели документа:
Институт инженерной физики и радио- электроники ФГОУ ВПО Сибирский федеральный университет
Институт физики им. Л.В. Киренского, Красноярский научный центр, СО РАН
Новосибирский институт органической химии им. Н.Н. Ворожцова СО РАН

Доп.точки доступа:
Гардымова, Анна Петровна; Gardymova A.P.; Тихонов, Алексей Яковлевич; Tikhonov A. Ya.; Зырянов, Виктор Яковлевич; Zyryanov, V. Ya.
}
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    Electro-optical response of a monolayer polymer dispersed nematic liquid crystal film doped with surfactant / V. A. Loiko, A. V. Konkolovich, A. A. Misckevich [et al.] // Liquid crystal polymer nanocomposites / ed.: P. M. Visakh [et al.] : Elsevier, 2022. - Chap. 7. - P. 163-211. - (Woodhead publishing in materials), DOI https://doi.org/10.1016/B978-0-12-822128-0.00006-6. - References: 86 . - ISBN 978-0-12-822128-0
   Перевод заглавия: Электро-оптический отклик монослоя нематического жидкого кристалла, допированного сурфактантом, диспергированного в полимере
Аннотация: Light scattering and transmission by a monolayer polymer dispersed liquid crystal film containing liquid crystal droplets with inhomogeneous anchoring of liquid crystal molecules at the polymer-droplet interface is considered theoretically and experimentally. The developed optical model is based on the anomalous diffraction and interference approximations of the theory of scattering of waves. It is applied to describe the interference quenching effect for the coherently transmitted light and electrically controllable symmetry breaking effect in small-angle structure of light scattered by film containing droplets with inhomogeneous anchoring. The analysis of transmittance and reflectance of the one-dimensional photonic crystals composed of monolayers is carried out. The formation of the photonic band gaps is analyzed.

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Доп.точки доступа:
Visakh, P. M. \ed.\; Semkin, Artem \ed.\; Özdemir, Zeynep Güven \ed.\; Loiko, V. A.; Konkolovich, A. V.; Misckevich, A. A.; Мискевич А. А.; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Shabanov, A. V.; Шабанов, Александр Васильевич; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич
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A study of the properties and efficacy of microparticles based on P(3HB) and P(3HB/3HV) loaded with herbicides / R. Vijayamma, H. J. Maria, S. Thomas [et al.] // J. Appl. Polym. Sci. - 2022. - Vol. 139, Is. 10. - Ст. 51756, DOI 10.1002/app.51756. - Cited References: 58. - This work was supported by Project “Agropreparations of the new generation: a strategy of construction and realization” (Agreement No 074-02-2018-328) in accordance with Resolution No 220 of the Government of the Russian Federation of April 9, 2010, “On measures designed to attract leading scientists to the Russian institutions of higher learning”. Instruments of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center «Krasnoyarsk Science Center SB RAS» were used . - ISSN 0021-8995
Кл.слова (ненормированные):
biodegradable -- drug delivery systems -- microparticles
Аннотация: The wide use of pesticides in agriculture has caused uncontrolled distribution of these chemicals in the environment, calling for the development and investigation of new environmentally friendly formulations, which would reduce human impact on nature. In the present study, the metribuzin (MET), tribenuron-methyl (TBM), and fenoxaprop-P-ethyl (FPE) herbicides were encapsulated in microparticles of degradable microbial polymers – polyhydroxyalkanoates (PHAs) – of two types – poly-3-hydroxybutyrate [P(3HB)] and poly(3-hydroxybutyrate-co-3-hydroxyvalerate [P(3HB/3HV)]. The use of P(3HB) resulted in higher yields of microparticles (63% to 79%) and larger sizes of the particles, whose average diameter was 0.60 ± 0.06–0.75 ± 0.11 μm, while the average diameter of copolymer particles varied between 0.43 ± 0.12 and 0.55 ± 0.05 μm. Encapsulation efficiency was rather determined by the type of herbicide and its solubility, varying from 24.7% to 48.2%. In vitro herbicide release from microparticles to water was affected by herbicide solubility and PHA chemical composition. The readily soluble MET showed the highest release rate, and over 30 days, 64% and 78% of the encapsulated amounts were released from P(3HB) and P(3HB/3HV) microparticles, respectively. High herbicidal activity of microparticles loaded with metribuzin and tribenuron-methyl was demonstrated in the laboratory stands of the Elsholtzia ciliata weed plant.

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Держатели документа:
Institute of Fundamental Biology and Biotechnology, Siberian Federal University, Krasnoyarsk, Russian Federation
International and Inter University Centre for Nanoscience and Nanotechnology, Mahatma Gandhi University, Kottayam, India
Institute of Biophysics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, Krasnoyarsk, Russian Federation
Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS”, Krasnoyarsk, Russian Federation
L.V. Kirensky Institute of Physics, Federal Research Center “Krasnoyarsk Science Center SB RAS”, Krasnoyarsk, Russian Federation
Scientific Laboratory, Reshetnev Siberian State University of Science and Technology, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Vijayamma, R.; Maria, H. J.; Thomas, S.; Shishatskaya, E. I.; Kiselev, E. G.; Nemtsev, I. V.; Немцев, Иван Васильевич; Sukhanova, A. A.; Volova, T. G.
}
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    Электрооптический отклик пленок капсулированного полимером нематика с коническими граничными условиями / Фейзер К. А., Крахалев М. Н., Шабанов В. Ф., Зырянов В. Я // Сиб. аэрокосм. журн. - 2021. - Т. 22, № 1. - С. 201-209, DOI 10.31772/2712-8970-2021-22-1-201-209. - Библиогр.: 16 . - ISSN 2587-6066
   Перевод заглавия: Electrooptical response of the films of polymer dispersed nematic with conical boundary conditions
Кл.слова (ненормированные):
электрооптический материал -- капсулированный полимером жидкий кристалл -- нематик -- конические граничные условия -- ориентационная структура -- electro-optical material -- nematic -- polymer dispersed liquid crystal -- electro-optical response -- conical boundary conditions -- orientation structure
Аннотация: Исследован электрооптический отклик пленок капсулированного полимером нематика с коническими граничными условиями. В каплях нематика формируется аксиал-биполярная конфигурация директора. Показано, что изначально ориентация осей симметрии структуры капель хаотичная как в плоскости образца, так и по отношению к нормали к подложкам. Приложенное напряжение U ориентирует биполярные оси капель параллельно электрическому полю, а процесс переориентации является пороговым только в случае исходно ортогональной ориентации биполярной оси и нормали к подложкам. Соответственно, в исходном состоянии образцы интенсивно рассеивают свет, а процесс отклика на электрическое поле имеет беспороговый характер. Исследовались образцы с толщиной пленки 5, 10, 20 и 30 мкм. Для всех исследуемых образцов характерно высокое значение максимального коэффициента пропускания и коэффициента контрастности, которые для пленки толщиной 30 мкм равны 84 % и 5536, соответственно, и достигаются при напряжении U = 12 В. Полученные результаты актуальны для использования в оптоэлектронных устройствах с низким энергопотреблением, которые требуются для развития энергосберегающих технологий в аэрокосмической технике.
The electrooptic response of films of polymer dispersed nematic under conical boundary conditions has been investigated. An axial-bipolar director configuration is formed in nematic droplets. It has been shown that initially, the orientation of droplet’s bipolar axes is chaotic both in the sample plane and relative to the normal to the substrates. The applied voltage U orients the droplet’s bipolar axes parallel to the electric field and the reorientation process is threshold only when the bipolar axis is initially orthogonal to the substrate normal. Accordingly, the samples strongly scatter light in the initial state, and the optical response to an electric field is thresholdless. The samples with a film thickness of 5, 10, 20 and 30 μm have been studied. All the samples under study are characterized by a high transmittance and contrast ratio, which for a 30 μm sample are equal to 84 % and 5536, respectively, and achieved at U = 12 V. The results obtained are relevant for use in low-power optoelectronic devices required for the development of energy-saving technologies in aerospace engineering.

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Держатели документа:
Институт физики имени Л. В. Киренского Сибирского отделения Российской академии наук – обособленное подразделение ФИЦ КНЦ СО РАН, Российская Федерация, 660036, г. Красноярск, Академгородок, 50/38
Институт инженерной физики и радиоэлектроники, Сибирский федеральный университет, Российская Федерация, 660041, г. Красноярск, просп. Свободный, 79
Федеральный исследовательский центр «Красноярский научный центр Сибирского отделения Российской академии наук», Российская Федерация, 660036, г. Красноярск, Академгородок, 50

Доп.точки доступа:
Фейзер, Кристина Андреевна; Feyzer K. A.; Крахалев, Михаил Николаевич; Krakhalev, M. N.; Шабанов, Василий Филиппович; Shabanov, V. F.; Зырянов, Виктор Яковлевич; Zyryanov, V. Ya.
}
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    Chemical modification of films from biosynthetic poly-3-hydroxybutyrate aimed to improvement of their surface properties / A. N. Boyandin, A. A. Sukhanova, E. D. Nikolaeva, I. V. Nemtsev // Macromolecular Symposia. - 2021. - Vol. 395: 4th International Conference on Progress on Polymers and Composites (NOV 26-28, 2020, Electr. Network), Is. 1. - Ст. 2000281, DOI 10.1002/masy.202000281. - Cited References: 11. - This work was carried out by the team of the scientific laboratory "Smart Materials and Structures" within the state assignment of the Ministry of Science and Higher Education of the Russian Federation for the implementation of the project "Development of multifunctional smart materials and structures based on modified polymer composite materials capable to function in extreme conditions" (No. FEFE-2020-0015). The surface of the samples was investigated using a scanning electron microscope Hitachi TM3000 in the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS" . - ISSN 1022-1360. - ISSN 1521-3900
   Перевод заглавия: Химическая модификация плёнок из биосинтетического поли-3-гидроксибутирата, направленная на улучшение их поверхностных свойств

РУБ Polymer Science

Кл.слова (ненормированные):
biocompatibility -- polyhydroxyalkanoates -- polyhydroxybutyrate -- polymer modification
Аннотация: Films from biodegradable poly-3-hydroxybutyrate are treated with chemical reagents to improve their hydrophilicity and biocompatibility. Two approaches are tested: a single treatment with alkali, acids, oxidizing or reducing agents, and a step-by step treatment of the alkali pre-activated surface of polymer films with bromine water and amino-compounds (ammonia or triethylamine). The maximal level of hydrophilicity (the lowest water contact angle and the highest polar component of the surface free energy) is registered after a single treatment with NaOH and after the step-by-step treatment. These samples also showed the best adhesion of mouse fibroblasts of NIH 3T3 line on the film surface. So, the proposed methods can be used to enhance hydropilicity and biocompatibility of biopolymer surface.

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Держатели документа:
Reshetnev Siberian State Univ Sci & Technol, 31 Krasnoyarsky Rabochy Av, Krasnoyarsk 660037, Russia.
Russian Acad Sci, Siberian Branch, Fed Res Ctr, Inst Biophys,Krasnoyarsk Sci Ctr, 50,Build 50, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Int Sci Ctr Studying Extreme States Organism, Fed Res Ctr,Krasnoyarsk Sci Ctr, 50,Build 12-2, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Krasnoyarsk Sci Ctr, Fed Res Ctr, 50 Akademgorodok, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Boyandin, A. N.; Sukhanova, Anna Alekseevna; Nikolaeva, Elena Dmitrievna; Nemtsev, I. V.; Немцев, Иван Васильевич; Ministry of Science and Higher Education of the Russian Federation [FEFE-2020-0015]; International Conference on Progress on Polymers and Composites(4th ; 26-28 Nov. 2020)
}
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Laser processing of polymer films fabricated from phas differing in their monomer composition / T. G. Volova, A. I. Golubev, I. V. Nemtsev [и др.] // Биотехнология новых материалов - окружающая среда - качество жизни : материалы IV Международной научной конференция : Красноярск, 10–13 октября 2021 г. - Красноярск, 2021. - С. 51-54

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Доп.точки доступа:
Volova, T. G.; Волова, Татьяна Григорьевна; Golubev, A. I.; Голубев Алексей И.; Nemtsev, I. V.; Немцев, Иван Васильевич; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Dudaev, A. E.; Shishatskaya, E. I.; Шишацкая, Екатерина Игоревна; "Biotechnology of new materials - environment - quality of life", International scientific conference(4 ; 2021 ; Oct. ; Krasnoyarsk (on-line)); "Биотехнология новых материалов - окружающая среда - качество жизни", международная научная конференция(4 ; 2021 ; окт. ; Красноярск (on-line))
}
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10.

Collagen conjugation to carboxyl-modified poly(3-hydroxybutyrate) microparticles: preparation, characterization and evaluation in vitro / A. V. Murueva, A. M. Shershneva, I. V. Nemtsev [et al.] // J. Polym. Res. - 2022. - Vol. 29, Is. 8. - Ст. 324, DOI 10.1007/s10965-022-03181-5. - Cited References: 45. - This work was supported by the State Assignment of the Ministry of Science and Higher Education of the Russian Federation No. FSRZ-2020–0006 . - ISSN 1022-9760
Кл.слова (ненормированные):
Poly(3-hydroxybutyrate) -- Collagen -- Microparticles -- Surface conjugation -- Cytotoxicity
Аннотация: The objective of this study was to produce and characterize collagen conjugated poly(3-hydroxybutyrate) (P3HB) microparticles. The double emulsion solvent evaporation technique was used to fabricate biopolymer microparticles. Alkaline hydrolysis method was used for carboxylation of P3HB microparticles followed by collagen (type I) conjugation using 1-ethyl-3-(3-dime-thylaminopropyl) carbodiimide and N-hydroxysuccinimide cross linkers. The successful chemical modification of P3HB-MP surface was evidenced by XPS analysis and FTIR spectroscopy, confirming an increase in the number of carboxyl groups and covalent bonding of collagen on the surface of functionalized P3HB microparticles (Col-P3HB-MPs). The amount of collagen present on Col-P3HB-MPs microparticles was quantified by the Lowry method. The average diameter and zeta-potential of microparticles were found to be dependent upon the method of preparation. The absence of cytotoxicity of modified Col-P3HB-MPs to fibroblast NIH 3T3 cells in vitro was corroborated by results of MTT assay. Staining with the fluorescent dye showed enhanced adhesion of fibroblasts onto Col-P3HB-MPs compared to the unmodified P3HB-MPs.

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Держатели документа:
Institute of Biophysics, Siberian Branch of the Russian Academy of Sciences (IBP SB RAS), 50/50 Akademgorodok, Krasnoyarsk, Russian Federation
Institute of Fundamental Biology and Biotechnology, Siberian Federal University, 79 Svobodny, Krasnoyarsk, 660041, Russian Federation
Federal Research Center Krasnoyarsk Scientific Center of the Siberian Branch of the RAS (FRC KSC SB RAS), 50 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
L.V. Kirensky Institute of Physics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS, 50/38 Akademgorodok, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Murueva, A. V.; Shershneva, A. M.; Nemtsev, I. V.; Немцев, Иван Васильевич; Shishatskaya, E. I.; Volova, T. G.
}
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11.

Modification of polycaproamide composites based on 1H,1H,13H-rihydroperfluorotridecan-1-ol and montmorillonite / S. V. Kudashev, A. A. Kondrasenko, A. N. Maiulev [et al.] // Fibre Chem. - 2022. - Vol. 53, Is. 5. - P. 291-295, DOI 10.1007/s10692-022-10287-5. - Cited References: 24 . - ISSN 0015-0541
Кл.слова (ненормированные):
Decomposition -- Nuclear magnetic resonance spectroscopy -- Macromolecular chain -- Macroradicals -- NMR-spectroscopy -- Organoclays -- Paramagnetic centers -- Polycaproamides -- Polymer composite -- Possible mechanisms -- Stabilizing effects -- X ray structure analysis -- Clay minerals
Аннотация: Modification of polycaproamide by 1H,1H,13H-trihydroperfluorotridecan-1-ol immobilized on montmorillonite produced an F-containing polymer composite. The structure of the resulting composite was investigated using x-ray structure analysis and solid-state 19F NMR spectroscopy. The polymorphous composition of this heterochain polymer was shown to reorganize to enhance its thermal stability and diminish its flammability. Possible mechanisms for the stabilizing effect of the used modifier that were related to the involvement of organo-clay paramagnetic centers in the binding of macroradicals formed during thermal decomposition of macromolecular chains were discussed.

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Держатели документа:
Volgograd State Technical University, Volgograd, Russian Federation
Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Sebryakovskii Filial, Volgograd State Technical University, Volgograd Region, Mikhailovka, Russian Federation
L. V. Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
I. M. Sechenov First Moscow State Medical University (Sechenov University), Moscow, Russian Federation

Доп.точки доступа:
Kudashev, S. V.; Kondrasenko, A. A.; Кондрасенко, Александр Александрович; Maiulev, A. N.; Мацулев, Александр Николаевич; Babkin, V. A.; Belousova, V. S.; Andreev, D. S.; Zheltobryukhov, V. F.; Kuznetsova, N. V.
}
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12.

Zyryanov, V. Ya.
Electrooptic and polarizing properties of oriented polymer dispersed liquid crystals films / V. Ya. Zyryanov, S. L. Smorgon, V. F. Shabanov // First Summer European Liquid Crystal Conference : abstracts. - Vilnius, 1991. - Vol. 1. - P. 89

Доп.точки доступа:
Smorgon, S. L.; Сморгон, Сергей Леонидович; Shabanov, V. F.; Шабанов, Василий Филиппович; Зырянов, Виктор Яковлевич; Summer European Liquid Crystals conference(1 ; 1991 ; Aug. 19-25 ; Vilnius)
}
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13.

Electro-optical properties of the polymer dispersed liquid crystal films with conical boundary conditions / K. Feizer, M. N. Krakhalev, O. O. Prishchepa [et al.] // Abstracts of 28th International Liquid Crystal Conference (ILCC 2022). - 2022. - Ст. PF.326. - Cited References: 2

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Feizer, K.; Фейзер, Кристина Андреевна; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Sutormin, V. S.; Сутормин, Виталий Сергеевич; Loiko, V. A.; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; International Liquid Crystal Conference(28 ; 2022 ; July ; 24-29 ; Lisbon, Portugal)
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14.

    Температурно индуцированные изменения конфигурации директора в каплях нематика, диспергированного в поли- винилпирролидоне / Виталий С. Сутормин, Михаил Н. Крахалев, Оксана О. Прищепа // Журнал Сибирского федерального университета. Серия: Математика и физика. - 2009. - Т. 2, № 3. - С. 352-359 . - ISSN 1997-1397
   Перевод заглавия: Thermo-Induced Transformations of Director Configuration within Nematic Droplets Dispersed in Polyvinylpyrrolidone
Кл.слова (ненормированные):
граница раздела -- interface -- polymer dispersed liquid crystals -- Nematic -- surfactant -- Surface anchoring -- director configuration -- капсулированные полимером жидкие кристаллы -- нематик -- сурфактант -- поверхностное сцепление -- конфигурация директора
Аннотация: В работе изучены преобразования конфигурации директора в каплях нематика, вызванные тер- моиндуцированной модификацией граничных условий. Исследования проводились для нематиче- ского жидкого кристалла 5СВ (4-н-пентил-4-цианобифенил), который допировался сурфактан- том лецитином, а затем диспергировался в поливинилпирролидоне. Показано, что при нагре- вании граничные условия изменяются от планарных к гомеотропным, что приводит к транс- формации конфигурации директора в капле нематика. При охлаждении образца наблюдалось об- ратное изменение поверхностного сцепления от гомеотропного к планарному. В обоих случаях ориентационно-структурные превращения могут происходить по двум различным сценариям.
The transformations of the director configuration within the nematic droplets induced by temperature modification of boundary conditions have been studied. Nematic liquid crystal 5CB (4-n-penthyl-4- cyanobiphenyl) doped with lecithin and dispersed in polyvinylpyrrolidone has been tested. As was shown, under heating the boundary conditions are changed from planar to homeotropic. It results in transformation of the director configuration in the nematic droplets. The inverse modification of the surface anchoring from homeotropic to planar has been observed at cooling. In both cases the transformations of orientational structure may occur in two different scenarios.

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Институт инженерной физики и радиоэлектроники, Сибирский федеральный университет
Институт физики им. Л.В. Киренского СО РАН
Сибирский государственный аэрокосмический университет

Доп.точки доступа:
Сутормин, Виталий С.; Крахалев, Михаил Н.; Прищепа, Оксана О.
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15.

Polymer-dispersed cholesteric liquid crystal under homeotropic anchoring: Electrically induced structures with λ1/2-disclination / A. P. Gardymova, M. N. Krakhalev, V. Yu. Rudyak [et al.] // Polymers. - 2022. - Vol. 14, Is. 7. - Ст. 1454, DOI 10.3390/polym14071454. - Cited References: 44. - This research was funded by Russian Science Foundation, Grant No. 20-72-10038 . - ISSN 2073-4360
Кл.слова (ненормированные):
polymer-dispersed cholesteric liquid crystal -- orientational structure -- electric field-induced transformation -- topological defect -- metastable state
Аннотация: Orientational structures of polymer-dispersed cholesteric liquid crystal under homeotropic anchoring and their transformations under the action of an electric field are studied. The switching of cholesteric droplets between different topological states are experimentally and theoretically demonstrated. Structures with λ+1/2-disclination are found and considered. These structures are formed during the transformation of a twisted toroidal configuration induced by a decrease in the electric field when a relative chiral parameter N0>6.3. The transformation of the initial structure with a bipolar distribution of the helix axis into a twisted toroidal configuration and then into a structure with λ+1/2-disclination is investigated in detail. The behavior of these structures under the influence of an external electric field, as well as the appearance of structures with λ−1/2-disclination, are studied. Obtained results are promising for the development of optical materials with programmable properties.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Faculty of Physics, Lomonosov Moscow State University, Moscow, 119991, Russian Federation
Lebedev Physical Institute of the Russian Academy of Sciences, Moscow, 119991, Russian Federation

Доп.точки доступа:
Gardymova, A. P.; Гардымова, Анна Петровна; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Rudyak, V. Yu.; Рудяк, В. Ю.; Barbashov, V. A.; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич
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16.

Surface modification of bioresorbable polymer scaffolds by laser treatment / V. V. Slabko [et al.] // Biophysics. - 2010. - Vol. 55, Is. 2. - P234-238, DOI 10.1134/S0006350910020120 . - ISSN 0006-3509
Кл.слова (ненормированные):
hydrophilicity -- laser irradiation -- microbial biocompatible and biodegradable polymers -- polyhydroxybuturate -- surface properties
Аннотация: The effect of laser irradiation on the properties of the surface of films prepared from a bioresorbable polymer poly(hydroxybuturate) has been studied. To determine the spectral region of the polymer optimal for the effective action of radiation on electron molecular bonds, theoretical investigations have been performed, which have shown that, for modifying the surface of PHB scaffolds, it is expedient to use a vacuum laser at a wavelength of 160 nm. Using laser irradiation at a power from 3 to 30 W, a series of films with modified surface, from roughnesses to perforations, have been obtained. The microstructure and properties of the film surface depending on the mode of irradiation have been examined, and conditions have been found under which the contact marginal angles of film wetting with water can be decreased to 50° (compared with 76-80° in starting products). Thus, conditions of laser treatment of PHB scaffolds have been theoretically substantiated and experimentally realized that provide a beneficial effect on the properties of the surface without destroying the structure of the material. © 2010 Pleiades Publishing, Ltd.

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Держатели документа:
Siberian Federal University, Krasnoyarsk, Russian Federation
Institute of Biophysics, Russian Academy of Sciences, Siberian Division, Krasnoyarsk 660036, Russian Federation
Siberian State Technological University, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Slabko, V.V.; Volova, T.G.; Shishatskaya, E.I.; Kuzubov, A.A.; Krasnov, P.O.
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17.

Inverse mode of ion-surfactant method of director reorientation inside nematic droplets / M. N. Krakhalev, O. O. Prishchepa, V. Y. Zyryanov // Mol. Cryst. Liquid Cryst. - 2009. - Vol. 512, Is. 1. - P. 1998-2003, DOI 10.1080/15421400903050814. - Cited Reference Count: 8. - Гранты: This work was partially supported by the grants Nos. NSh-3818.2008.3; 02.740.11.0220, and No. 08-03-01007 of RFBR, and Nos. 27.1; 110; 144 of SB RAS. M. Krakhalev acknowledges the financial support from K. I. Zamaraev MBN Foundation. O. Prishchepa acknowledges the financial support from Russian Science Support Foundation. - Финансирующая организация: RFBR [NSh-3818.2008.3, 02.740.11.0220, 08-03-01007]; SB RAS [27.1; 110; 144]; Zamaraev MBN Foundation; Russian Science Support Foundation . - ISSN 1542-1406
Кл.слова (ненормированные):
electrically commanded surfaces -- ion surfactant -- nematic -- polymer dispersed liquid crystals -- surface anchoring -- Electrically commanded surfaces -- Ion surfactant -- Nematic -- Polymer dispersed liquid crystals -- Surface anchoring -- Applied voltages -- Crossed polarizers -- Director fields -- Director reorientation -- Droplet structure -- Electrically commanded surfaces -- High concentration -- Homeotropic -- Initial state -- Ionic modification -- Liquid-crystal droplets -- Nematic droplets -- Nematic polymer -- Surface-active cations -- Surface-anchoring -- Trimethyl -- Ammonium compounds -- Cationic surfactants -- Crystals -- Drop formation -- Dyes -- Ionization of liquids -- Ions -- Liquid crystal displays -- Liquid crystals -- Liquids -- Nematic liquid crystals
Аннотация: Inverse mode of a novel electrooptical effect caused by the ionic modification of boundary conditions has been studied for liquid crystal droplets. We have considered the droplets of nematic 5CB doped with cationic surfactant cetyl-trimethyl-ammonium-bromide and dispersed in polyvinyl alcohol. In the initial state the surface anchoring was normal on the whole interface due to the high concentration of homeotropic surfactant. Applied voltage results in the purification of a section of the interface from the surface-active cations thereby restoring here a tangential anchoring and stimulating the significant transformation of droplet structure. At that three different types of director field distribution can be realized within the same droplet. The proper textures of the droplet both in the crossed polarizers and without analyzer are considered.

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Держатели документа:
SB RAS, LV Kirensky Phys Inst, Krasnoyarsk Sci Ctr, Krasnoyarsk, Russia
Siberian Fed Univ, Krasnoyarsk, Russia

Доп.точки доступа:
Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич
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18.

    Bipolar-homogeneous structural phase transition in nematic droplets formed in the polymer matrix in a magnetic field / A. M. Parshin [et al.] // Crystallogr. Rep. - 2009. - Vol. 54, Is. 7. - P1191-1196, DOI 10.1134/S1063774509070098. - Cited Reference Count: 19. - Гранты: This study was supported by the Council on Grants from the President of the Russian Federation for the Support of Leading Scientific Schools ( grant no. NSh-3818.2008.3), the Russian Foundation for Basic Research ( project no. 08-03-01007), the Presidium of the Russian Academy of Sciences ( project no. 27.1), and the Siberian Branch of the Russian Academy of Sciences ( project nos. 110 and 144). - Финансирующая организация: President of the Russian Federation [NSh-3818.2008.3]; Russian Foundation for Basic Research [08-03-01007]; Russian Academy of Sciences [27.1, 110, 144] . - DEC. - ISSN 1063-7745
Рубрики:
DISPERSED LIQUID-CRYSTALS
   FRANK CONSTANTS
   ALIGNMENT
Кл.слова (ненормированные):
Bipolar configuration -- Bipolar structure -- Cyanobiphenyls -- Homogeneous structure -- Mutual transformations -- Nematic director -- Nematic droplets -- Order parameter -- Poly(vinyl butyral) -- Structural phase transition -- Temperature range -- Thermal fluctuations -- Crystal structure -- Drop formation -- Liquid crystals -- Magnetic fields -- Nematic liquid crystals -- Phase transitions
Аннотация: The phase transition from the bipolar structure to the homogeneous structure in droplets formed from the nematic liquid crystal 4-n-pentyl-4'-cyanobiphenyl in poly(vinyl butyral) in the presence of a magnetic field has been investigated. The phase transition is associated with the expansion of the regions with a tilted orientation of the director in the vicinity of defects (the disappearance of boojums) and with the alignment of the nematic director lines in the bulk of the droplet in the direction of the magnetic field. In the temperature range T = 24-34A degrees C, cyclic mutual transformations between the bipolar configuration of the nematic director and the homogeneous structure, which have a period of similar to 0.5-3.5 s and result from thermal fluctuations of the order parameter, are observed in droplets 3-15 A mu m in size after the forming field is switched off.

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Держатели документа:
Russian Acad Sci, Siberian Branch, Krasnoyarsk Sci Ctr, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia

Доп.точки доступа:
Parshin, A. M.; Паршин, Александр Михайлович; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Shabanov, V. F.; Шабанов, Василий Филиппович; Nazarov, V. G.
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19.

Properties of degradable polyhydroxyalkanoates (PHAs) synthesized by a new strain, Cupriavidus necator IBP/SFU-1, from various carbon sources / N. O. Zhila, K. Yu. Sapozhnikova, E. G. Kiselev [et al.] // Polymers. - 2021. - Vol. 13, Is. 18. - Ст. 3142, DOI 10.3390/polym13183142. - Cited References: 78. - This work was financially supported by Project “Agropreparations of the new generation: a strategy of construction and realization” (Agreement No 075-15-2021-626) in accordance with Resolution No 220 of the Government of the Russian Federation of 9 April 2010, “On measures designed to attract leading scientists to the Russian institutions of higher learning” (strain isolation, polymer synthesis and investigation), and by the State Assignment of the Ministry of Science and Higher Education of the Russian Federation No. FSRZ-2020-0006 (study of film properties) . - ISSN 2073-4360
Кл.слова (ненормированные):
Cupriavidus necator IBP/SFU-1 -- cell growth and PHA synthesis -- various carbon sources -- PHA composition and properties -- polymer films
Аннотация: The bacterial strain isolated from soil was identified as Cupriavidus necator IBP/SFU-1 and investigated as a PHA producer. The strain was found to be able to grow and synthesize PHAs under autotrophic conditions and showed a broad organotrophic potential towards different carbon sources: sugars, glycerol, fatty acids, and plant oils. The highest cell concentrations (7–8 g/L) and PHA contents were produced from oleic acid (78%), fructose, glucose, and palm oil (over 80%). The type of the carbon source influenced the PHA chemical composition and properties: when grown on oleic acid, the strain synthesized the P(3HB-co-3HV) copolymer; on plant oils, the P(3HB-co-3HV-co-3HHx) terpolymer, and on the other substrates, the P(3HB) homopolymer. The type of the carbon source influenced molecular-weight properties of PHAs: P(3HB) synthesized under autotrophic growth conditions, from CO2, had the highest number-average (290 ± 15 kDa) and weight-average (850 ± 25 kDa) molecular weights and the lowest polydispersity (2.9 ± 0.2); polymers synthesized from organic carbon sources showed increased polydispersity and reduced molecular weight. The carbon source was not found to affect the degree of crystallinity and thermal properties of the PHAs. The type of the carbon source determined not only PHA composition and molecular weight but also surface microstructure and porosity of the polymer films. The new strain can be recommended as a promising P(3HB) producer from palm oil, oleic acid, and sugars (fructose and glucose) and as a producer of P(3HB-co-3HV) from oleic acid and P(3HB-co-3HV-co-3HHx) from palm oil.

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Держатели документа:
Basic Department of Biotechnology, School of Fundamental Biology and Biotechnology, Siberian Federal University, 79 Svobodnyi Av., Krasnoyarsk, 660041, Russian Federation
Federal Research Center, “Krasnoyarsk Science Center SB RAS”, Institute of Biophysics SB RAS, 50/50 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Federal Research Center, “Krasnoyarsk Science Center SB RAS”, L.V. Kirensky Institute of Physics SB RAS, 50/38 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Federal Research Center, “Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences”, 50 Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Zhila, N. O.; Sapozhnikova, K. Yu.; Kiselev, E. G.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Nemtsev, I. V.; Немцев, Иван Васильевич; Shishatskaya, E. I.; Volova, T. G.
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20.

Small-angle scattering and radiation polarization by a stretched polymer film with nematic liquid crystal droplets having a single-domain structure / V. A. Loiko, A. V. Konkolovich, A. A. Miskevich [et al.] // Opt. Spectrosc. - 2020. - Vol. 128, Is. 3. - P. 331-338, DOI 10.1134/S0030400X20030121. - Cited References: 24. - This work was carried out within the framework of the agreement on interacademic collaboration between the National Academy of Sciences of Belarus and Siberian Branch of the Russian Academy of Sciences. It was supported by the Belarusian Republican Foundation for Fundamental Research (project no. F18RA-003). M.N. Krakhalev acknowledges the support of the Russian Foundation for Basic Research, the Government of Krasnoyarsk krai, and Krasnoyarsk Krai Foundation of Science (grant no. 18-42-243006). . - ISSN 0030-400X. - ISSN 1562-6911

РУБ Optics + Spectroscopy
Рубрики:
IONIC MODIFICATION
LIGHT
Кл.слова (ненормированные):
light scattering -- radiation polarization -- liquid crystal
Аннотация: The coefficient of directed transmittance of a stretched polymer-dispersed liquid crystal film with a defect-free single-domain liquid crystal droplet structure formed by a stretched surfactant-doped film and the polarization degree of forward-transmitted light in the visible and near-infrared spectrum ranges are studied. Results are presented for the 5CB, E7, and E44 nematic liquid crystals. Dependences of the transmission coefficient and polarizing ability of the film on the photodetector field of view are studied. Relationships allowing one to determine film parameters at which the transmission coefficient and polarizing ability of the films simultaneously reach values close to limit ones (0.5 and ±1.0, respectively) are obtained in the Foldy–Twersky and anomalous diffraction approximations.

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Публикация на русском языке Малоугловое рассеяние и поляризация излучения вытянутой полимерной пленкой с каплями нематического жидкого кристалла, имеющими монодоменную структуру [Текст] / В. А. Лойко, А. В. Конколович, А. А. Мискевич, М. Н. Крахалев // Оптика и спектроскопия. - 2020. - Т. 128 Вып. 3. - С. 343-350

Держатели документа:
Natl Acad Sci Belarus, Stepanov Inst Phys, Minsk 220072, BELARUS.
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Loiko, V. A.; Konkolovich, A. V.; Miskevich, A. A.; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Belarusian Republican Foundation for Fundamental Research [F18RA-003]; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of Krasnoyarsk krai; Krasnoyarsk Krai Foundation of Science [18-42-243006]
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