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 Найдено в других БД:Каталог книг и брошюр библиотеки ИФ СО РАН (1)
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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Belousov O. V., Tarabanko V. E., Borisov R. V., Simakova I. L., Zhyzhaev A. M., Tarabanko N., Isakova V. G., Parfenov V. V., Ponomarenko I. V.
Заглавие : Synthesis and catalytic hydrogenation activity of Pd and bimetallic Au–Pd nanoparticles supported on high-porosity carbon materials
Место публикации : React. Kinet. Mech. Catal. - 2019. - Vol. 127, Is. 1. - P.25–39. - ISSN 18785190 (ISSN) , DOI 10.1007/s11144-018-1430-0
Примечания : Cited References: 57
Ключевые слова (''Своб.индексиров.''): mocvd--hydrothermal synthesis--palladium nanoparticles--mesostructured carbon--bimetallic pd–au catalyst--furfural diethyl acetal--hydrogenation
Аннотация: The processes of palladium deposition on various high-porosity carbon matrices (Sibunit, CMK-3) have been studied. Mesostructured carbon material CMK-3 was synthesized using a silicate template of SBA-15 type. Pd nanoparticles were loaded onto carbon matrices by metalorganic chemical vapour deposition (MOCVD) method using palladium(II) acetylacetonate precursor. Bimetal Au–Pd systems were synthesized by autoclave reduction of gold(III) chloride complexes on Pd-containing carbon matrices. Structure of the obtained composite particles was studied by electron microscopy and X-ray diffraction. The average diameter of Pd particles on Sibunit is about 10, and 5–6 nm on CMK-3. The catalytic activity of the synthesized materials was studied in the reaction of furfural diethyl acetal (FDEA) hydrogenation, using gas–liquid chromatographic analysis. There is significant difference in catalytic activity of MOCVD-Pd/C compared to conventional impregnated Pd/C systems: the hydrogenation rate is 3–6 times higher with MOCVD-derived catalysts. Introducing Au into a MOCVD-Pd/C catalyst increases the hydrogenation rate threefold. Considerable difference in the composition of hydrogenation products was observed between these differently prepared catalysts.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Morozov E. V., Buznik V. M., Bespalov A. S., Grashchenkov D. V.
Заглавие : Magnetic Resonance Imaging of Water Absorption by Highly Porous Ceramic Materials
Место публикации : Dokl. Chem. - 2019. - Vol. 484, Is. 2. - P.44-47. - ISSN 00125008 (ISSN), DOI 10.1134/S0012500819020058
Примечания : Cited References: 9. - The studies were performed using equipment of KRTsKP FITs "KNTs SO RAN" in the framework of the program of basic research of the Russian Academy of Sciences (project no. V.44.1.7.) regarding the development of the MRI methodology for studying composite and porous materials, and also supported by the Russian Foundation for Basic Research (project no. 16-29-05334ofi_m "Scientific foundations for creating thin-film coatings with controlled wettability") regarding the development of water-repellent porous materials.
Ключевые слова (''Своб.индексиров.''): magnetic resonance imaging--porosity--ceramic materials--hydrophobic coatings--adsorption--capillary phenomena
Аннотация: A nontrivial character of water absorption in highly porous ceramic materials has been demonstrated for the first time by magnetic resonance imaging: a phenomenon of hygroscopic memory has been detected consisting in the concentration of adsorbed water in certain areas inside the sample, repeated during subsequent wetting with water. It has been shown that hydrophobization of the material by applying fluoro paraffin coatings to oxide fibers using the method of dissolution of fluoropolymers in supercritical CO2 has a significant impact on the transport of water into products and can be considered an efficient means of protecting porous materials from moisture. The results demonstrate the capabilities of the MRI method in studying the water absorption and identifying water migration pathways in highly porous materials.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gokhfeld D. M., Koblischka M. R., Koblischka-Veneva A.
Заглавие : Highly Porous Superconductors: Synthesis, Research, and Prospects
Место публикации : Phys. Metals Metallogr. - 2020. - Vol. 121, Is. 10. - P.936-948. - ISSN 0031-918X, DOI 10.1134/S0031918X20100051. - ISSN 1555-6190(eISSN)
Примечания : Cited References: 146
Предметные рубрики: HIGH-T-C
CRITICAL-CURRENT DENSITY
HIGH-TEMPERATURE SUPERCONDUCTORS
Аннотация: This paper presents a review of studies of superconductors with a porosity above 50%. The pores in such superconducting materials allow refrigerant penetration and provide efficient heat dissipation and stable operation. Methods for the synthesis of the main groups of porous superconductors are described. The results of studies of the structural, magnetic, and electrical transport properties are presented, and the features of the current flow through porous superconductors of various types are considered. The directions of further development and application of porous superconductors are presented.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Tsyganova S. I., Yu. Fetisova O., Velikanov D. A., Taran O. P.
Заглавие : Structural, magnetic and electrochemical characteristics of Ni/C composites fabricated from modified hydrolytic lignin
Колич.характеристики :3 с
Место публикации : Mater. Lett. - 2023. - Vol. 352. - Ст.135120. - ISSN 0167577X (ISSN), DOI 10.1016/j.matlet.2023.135120. - ISSN 18734979 (eISSN)
Примечания : Cited References: 11. - The present work was supported by the Russian Foundation for Basic Research , the Government of the Krasnoyarsk Territory and carried out as part of the budget project ( 0287-2021-0017 ) of the Institute of Chemistry and Chemical Technology SB RAS
Аннотация: The synthesis of metal–carbon materials based on hydrolytic lignin by its modification with subsequent carbonation is studied. It is shown the modification of hydrolysis lignin with ZnCl2 and NiCl2 leads to a significant increase of specific surface area up to 716 m2/g and the apparent specific capacity up to 350F/g of carbonized composite. It was found out that fabricated Ni/C composites are characterized by a coercive force of 80–105 Oe, a saturation magnetization of 4–11 Gs•cm3/g, and a residual magnetization of 0.28–0.45 Gs•cm3/g. This indicates the prospects of their use as a magnetically soft material.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gokhfeld D. M.
Заглавие : Magnetic flux trapping in porous high-Tc superconductors
Колич.характеристики :4 с
Место публикации : Phys. C: Supercond. Appl. - 2024. - Vol. 619. - Ст.1354486. - ISSN 09214534 (ISSN), DOI 10.1016/j.physc.2024.1354486. - ISSN 18732143 (eISSN)
Примечания : Cited References: 39
Аннотация: Porosity affects the properties of high-Tc superconductors and can improve their performance by enhancing oxygenation, cryocooling, etc. Among other factors, the presence of pores plays a significant role in the process of magnetic flux trapping. Relationships with the porosity manifest in the irreversibility field, the full penetration field, and the remnant magnetization of the samples. To account for the effect of porosity on the trapped magnetic flux into type-II superconductors, a simple toy model is suggested. Generally, as the porosity increases, the trapped flux and related parameters tend to diminish. However, in the case of microscopic samples, porosity can enhance magnetic flux trapping.
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